涤纶基材表面银/铜薄膜制备及其性能
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摘要
为探索涤纶基Ag/Cu薄膜结构及性能,采用直流和射频共溅法,以不同组织结构纯涤纶织物为基材,金属银和铜为靶材,制备纳米薄膜。借助场发射扫描电子显微镜、X射线衍射仪、光电子能谱仪、织物感应式静电仪、纺织品防紫外线性能测试仪和电磁防辐射性能测试仪对试样表面薄膜形貌及结构、抗静电、防紫外线、电磁屏蔽性能进行表征。结果表明:非织造布表面薄膜均匀连续,机织布表面纳米颗粒直径较小,针织布表面颗粒分布较为连续,但仍然存在部分岛状颗粒;试样表面Cu(111)、Cu(200)、Ag(111)和Ag(200)衍射峰均不明显,结晶度低;纳米薄膜没有被氧化,以单质形式存在;以非织造布为基材的试样其抗静电、抗紫外线、电磁屏蔽性能最优,针织布最差。
In order to explore the structure and properties of polyester-based Ag/Cu films,nanoscale films were prepared by direct current and radio frequency co-sputtering using pure polyester fabrics of different structures as the substrate and metallic silver and copper as targets. Field emission scanning electron microscopy, X-ray diffractometry, photoelectron spectroscopy, fabric inductive electrostatic analysis,fabric UV protection and electromagnetic radiation test were utilized to characterize the surface morphology and structure and antistatic,anti-UV and anti-electromagnetic shielding performance of the samples. The experimental results show that the film on the surface of the nonwoven fabric is uniform and continuous,the diameter of the nano-particles on the surface of the woven fabric is small,and the surface distribution of the knitted fabric is continuous,but some island-like particles still exist. Cu( 111),Cu( 200),Ag( 111) and Ag( 200) diffraction peaks of Cu/Ag film on the surface of the sample are not obvious,and the crystallinity is low. XPS image shows that the nano-film is not oxidized,and exists in elemental form. The nonwoven fabric is used as the substrate, the antistatic, anti-UV, antielectromagnetic shielding performance of the sample is the best,and the knitted fabric is the worst.
In order to explore the structure and properties of polyester-based Ag/Cu films,nanoscale films were prepared by direct current and radio frequency co-sputtering using pure polyester fabrics of different structures as the substrate and metallic silver and copper as targets. Field emission scanning electron microscopy, X-ray diffractometry, photoelectron spectroscopy, fabric inductive electrostatic analysis,fabric UV protection and electromagnetic radiation test were utilized to characterize the surface morphology and structure and antistatic,anti-UV and anti-electromagnetic shielding performance of the samples. The experimental results show that the film on the surface of the nonwoven fabric is uniform and continuous,the diameter of the nano-particles on the surface of the woven fabric is small,and the surface distribution of the knitted fabric is continuous,but some island-like particles still exist. Cu( 111),Cu( 200),Ag( 111) and Ag( 200) diffraction peaks of Cu/Ag film on the surface of the sample are not obvious,and the crystallinity is low. XPS image shows that the nano-film is not oxidized,and exists in elemental form. The nonwoven fabric is used as the substrate, the antistatic, anti-UV, antielectromagnetic shielding performance of the sample is the best,and the knitted fabric is the worst.
引文
[1]师艳丽,李娜娜,付元静,等.用于纺织品表面改性的磁控溅射技术研究进展[J].纺织学报,2016,37(4):165-169.SHI Yanli,LI Nana,FU Yuanjing,et al.Research progress of magnetron sputtering in textiles[J].Journal of Textile Research,2016,37(4):165-169.
[2]盛澄成.表面沉积Cu薄膜复合材料屏蔽效能优化及抗氧化性能研究[D].无锡:江南大学,2017:15-20.SHENG Chengcheng.Optimization of shielding effectiveness and anti-oxidation performance of Cu film composites with surface deposition[D].Wuxi:Jiangnan University,2017:15-20.
[3]黄美林,鲁圣国,杜文琴,等.磁控溅射法制备柔性纺织面料基纳米薄膜的研究与进展[J].真空科学与技术学报,2017,37(12):1194-1200.HUANG Meilin,LU Shengguo,DU Wenqin,et al.Research and development of magnetron sputtering method for preparation of nanofilms based on flexible textile fabrics[J].Journal of Vacuum Science and Technology,2017,37(12):1194-1200.
[4]YUAN X H,WEI Q F,CHEN D,et al.Electrical and optical properties of polyester fabric coated with Ag/Ti O2composite films by magnetron sputtering[J].Textile Research Journal,2015,86(8):887-894.
[5]彭灵慧,郭荣辉,兰建武,等.激光前处理磁控溅射镀铜涤纶织物的制备及性能[J].电镀与涂饰,2017(13):684-688.PENG Linghui,GUO Ronghui,LAN Jianwu,et al.Preparation and performance of magnetron sputtering copper-coated polyester fabric before laser treatment[J].Electroplating and Coating,2017(13):684-688.
[5]HUANG X M,MENG L L,WEI Q F,et al.Effect of substrate structures on the morphology and interfacial bonding properties of copper films sputtered on polyester fabrics.[J].International Journal of Clothing Science and Technology,2017,29(1):39-46.
[6]李超荣,舒顺新,谢勇.磁控溅射纳米纤维基银膜的结构和性能[J].纺织学报,2014,35(4):32-34.LI Chaorong,SHU Shunxin,XIE Yong.Structure and properties of Ag coatings on nanofibers prepared by magnetron sputtering[J].Journal of Textile Research,2014,35(4):32-34.
[7]JIANG S X,PENG L H,GUO R H,et al.Preparation and characterization of Fe2O3coating on quartz fabric by electron beam evaporation[J].Ceramics International,2016(42):19386-19392.
[8]谈淑咏,张旭海,朱迪,等.直流脉冲磁控溅射铜膜的结构与性能研究[J].功能材料,2017,48(2):2144-2148.TAN Shuyong,ZHANG Xuhai,ZHU Di,et al.Study on structure and performance of DC pulse magnetron sputtering copper film[J].Functional Materials,2017,48(2):2144-2148.
[9]MENG L L,HUANG X M,WEI Q F,et al.Study on the conductive effectiveness of nanoscale copper films sputtered on the surface of polyester nonwoven fabrics[J].Journal of The Textile Institute,2018,109(11):1395-1399.
[10]徐文正,魏取福,杨莉,等.磁控溅射玄武岩纤维基纳米Cu薄膜微观结构分析的研究[J].化工新型材料,2016(7):136-138.XU Wenzheng,WEI Qufu,YANG Li,et al.Study on microstructure analysis of magnetron sputtering basalt fiber with nano Cu thin films[J].New Chemical Materials,2016(7):136-138.
[2]盛澄成.表面沉积Cu薄膜复合材料屏蔽效能优化及抗氧化性能研究[D].无锡:江南大学,2017:15-20.SHENG Chengcheng.Optimization of shielding effectiveness and anti-oxidation performance of Cu film composites with surface deposition[D].Wuxi:Jiangnan University,2017:15-20.
[3]黄美林,鲁圣国,杜文琴,等.磁控溅射法制备柔性纺织面料基纳米薄膜的研究与进展[J].真空科学与技术学报,2017,37(12):1194-1200.HUANG Meilin,LU Shengguo,DU Wenqin,et al.Research and development of magnetron sputtering method for preparation of nanofilms based on flexible textile fabrics[J].Journal of Vacuum Science and Technology,2017,37(12):1194-1200.
[4]YUAN X H,WEI Q F,CHEN D,et al.Electrical and optical properties of polyester fabric coated with Ag/Ti O2composite films by magnetron sputtering[J].Textile Research Journal,2015,86(8):887-894.
[5]彭灵慧,郭荣辉,兰建武,等.激光前处理磁控溅射镀铜涤纶织物的制备及性能[J].电镀与涂饰,2017(13):684-688.PENG Linghui,GUO Ronghui,LAN Jianwu,et al.Preparation and performance of magnetron sputtering copper-coated polyester fabric before laser treatment[J].Electroplating and Coating,2017(13):684-688.
[5]HUANG X M,MENG L L,WEI Q F,et al.Effect of substrate structures on the morphology and interfacial bonding properties of copper films sputtered on polyester fabrics.[J].International Journal of Clothing Science and Technology,2017,29(1):39-46.
[6]李超荣,舒顺新,谢勇.磁控溅射纳米纤维基银膜的结构和性能[J].纺织学报,2014,35(4):32-34.LI Chaorong,SHU Shunxin,XIE Yong.Structure and properties of Ag coatings on nanofibers prepared by magnetron sputtering[J].Journal of Textile Research,2014,35(4):32-34.
[7]JIANG S X,PENG L H,GUO R H,et al.Preparation and characterization of Fe2O3coating on quartz fabric by electron beam evaporation[J].Ceramics International,2016(42):19386-19392.
[8]谈淑咏,张旭海,朱迪,等.直流脉冲磁控溅射铜膜的结构与性能研究[J].功能材料,2017,48(2):2144-2148.TAN Shuyong,ZHANG Xuhai,ZHU Di,et al.Study on structure and performance of DC pulse magnetron sputtering copper film[J].Functional Materials,2017,48(2):2144-2148.
[9]MENG L L,HUANG X M,WEI Q F,et al.Study on the conductive effectiveness of nanoscale copper films sputtered on the surface of polyester nonwoven fabrics[J].Journal of The Textile Institute,2018,109(11):1395-1399.
[10]徐文正,魏取福,杨莉,等.磁控溅射玄武岩纤维基纳米Cu薄膜微观结构分析的研究[J].化工新型材料,2016(7):136-138.XU Wenzheng,WEI Qufu,YANG Li,et al.Study on microstructure analysis of magnetron sputtering basalt fiber with nano Cu thin films[J].New Chemical Materials,2016(7):136-138.