近红外技术在液态食品成分检测中的应用研究进展
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摘要
近红外光谱技术作为一种快速、高效、无损的检测手段,在液态食品品质检测中具有广泛的应用。首先对近红外光谱技术检测原理及特点进行了阐述,列举了定量和定性分析中常用的算法,然后综述了其在牛奶、酒类、果汁、食用油等常见液态食品中的研究现状及成果,对近红外光谱分析技术中的关键点进行了分析,并说明了建模过程中的共性问题,最后对全文进行总结,指出了近红外光谱技术在实际应用过程中存在的一些问题,并对进一步的研究提出了展望。
Near infrared spectroscopy has been widely used in the quality detection of liquid food as a fast,efficient and nondestructive detection method. the theories and characteristics of the near infrared spectrum detection technology are described,the common algorithms in quantitative and qualitative analysis are enumerated,and then summarizes the researches and achievements in liquid foods such as milk,wine,fruit juice and edible oil,the key points of near infrared spectroscopy technology are analyzed,the common problems in the modeling process are also explained,Finally,the whole article is summarized,some problems existing in the practical application process are pointed out,and the prospects of further research are put forward.
Near infrared spectroscopy has been widely used in the quality detection of liquid food as a fast,efficient and nondestructive detection method. the theories and characteristics of the near infrared spectrum detection technology are described,the common algorithms in quantitative and qualitative analysis are enumerated,and then summarizes the researches and achievements in liquid foods such as milk,wine,fruit juice and edible oil,the key points of near infrared spectroscopy technology are analyzed,the common problems in the modeling process are also explained,Finally,the whole article is summarized,some problems existing in the practical application process are pointed out,and the prospects of further research are put forward.
引文
[1]DAGOU S,RICHARD F C.Inheritance of kernel hardness in spring wheat as measured by near-infrared reflectance spectroscopy[J].Euphytica,2016,209(3):679-688.
[2]NEYRINCK E,SMET S D,VERMEULEN L,et al.Application of near-infrared spectroscopy for the classification of fresh pork quality in cooked ham production[J].Food and Bioprocess Technology,2015,8(12):1-9.
[3]MELFSEN A,HARTUNG E,HAEUSSERMANN A.Robustness of near-infrared calibration models for the prediction of milk constituents during the milking process[J].Journal of Dairy Research,2013,80(1):103.
[4]MAUER L J,CHERNYSHOVA A A,HIATT A,et al.Melamine detection in infant formula powder using near-and mid-infrared spectroscopy[J].J Agric Food Chem,2009,57(10):3974-3980.
[5]严衍禄,朱大洲,陈斌.近红外光谱分析原理、技术与应用[M].北京:中国轻工业出版社,2013.
[6]周焕英,高志贤,孙思明,等.食品安全现场快速检测技术研究进展及应用[J].分析测试学报,2008,7(27):788-794.
[7]DAMBERGS R G,KAMBOURIS A,FRANCIS I L,et al.Rapid analysis of methanol in grape-derived distillation products using near-infrared transmission spectroscopy[J].J Agric Food Chem,2002,50(11):3079-3084.
[8]LACHENMEIER D W.Rapid quality control of spirit drinks and beer using multivariate data analysis of Fourier transform infrared spectra[J].Food Chemistry,2007,101(2):825-832.
[9]COZZOLINO D,KWIATKOWSKI M J,PARKER M,et al.Prediction of phenolic compounds in red wine fermentations by visible and near infrared spectroscopy[J].Analytica Chimica Acta,2004,513(1):73-80.
[10]TOHER D,DOWNEY G,MURPHY T B.Acomparison of modelbased and regression classification techniques applied to near infrared spectroscopic data in food authentication studies[J].Chemometrics and Intelligent Laboratory Systems,2007,89(2):102-115.
[11]宋宏新,薛建龙,刘立新,等.采用蛋白质定量方法检测掺假牛乳比较研究[J].食品工业,2015,36(4):210-214.
[12]金萍,丁洪流,陈英,等.乳制品中异种蛋白掺假检测的研究进展[J].食品研究与开发,2015,36(12):135-138.
[13]金垚,杜斌,智秀娟.NIR技术快速鉴定牛奶品牌与掺假识别[J].食品研究与开发,2016,37(3):178-181.
[14]宋宏新,薛建龙,刘立新,等.采用蛋白质定量方法检测掺假牛乳比较研究[J].食品工业,2015,36(4):210-214.
[15]丁美珍,宋岑,胡志明.近红外光谱技术在酒类产品分析中的应用[J].酿酒科技,2013,4:68-70.
[16]吴同,谭超.近红外光谱同时测定白酒中总酯和杂醇油[J].化学研究与应用,2016,28(10):1460-1463.
[17]魏赫楠,谭红,杨昌彪,等.近红外技术在白酒行业的应用现状及展望[J].酿酒科技,2013(11):85-87.
[18]彭帮柱,龙明华,岳田利,等.傅立叶变换近红外光谱法检测白酒总酸和总酯[J].农业工程学报,2006,22(12):216-219.
[19]陈妍,胡慧,汪风祖近红外光谱法快速分析白酒中的关键指标[J].酿酒科技,2010(11):90-94.
[20]杨国强,张淑娟,赵艳茹.基于近红外透射光谱的汾阳王酒快速鉴别[J].农业机械学报,2013,44(增刊1):189-193.
[21]彭帮柱,龙明华,岳田利,等.用偏最小二乘法及傅立叶变换近红外光谱快速检测白酒酒精度[J].农业工程学报,2007,23(4):233-237.
[22]WOO Y A,TERAZAWA Y,CHEN J Y.Development of a new measurement unit(milkspace-1)for rapid determination of fat,lactose,and protein in raw milk using near-infrared transmittance spectroscopy[J].Applied Spectroscopy,2002,56(5):599-604.
[23]KAROUI R,BAERDEMAEKER J.A review of the analytical methods coupled with chemometric tools,for the determination of the quality and identity of dairy products[J].Food Chemistry,2007,102(12):621-640.
[24]LAERTE D C,BEATRIZ S.The use of the Fourier Transform Infrared spectroscopy to determine adulterants in raw milk[J].Revista Brasileira de Zootecnia,2011,40(11):2591-2596.
[25]李庆波,徐可欣,王斌.牛奶主要成分含量近红外光谱快速测量法[J].食品科学,2002,2(6):121-124.
[26]杨仁杰,刘蓉,徐可欣.二维相关光谱结合偏最小二乘法测定牛奶中的掺杂尿素[J].农业工程学报,2012,28(6):259-262.
[27]倪力军,钟霖,张鑫,等.近红外光谱结合非线性模式识别方法进行牛奶中掺假物质的判别[J].光谱学与光谱分析,2014,34(10):2673-2678.
[28]范睿,孙晓凯,杨晨,等.基于近红外光谱定量分析牛奶中掺假的动物水解蛋白含量[J].食品工业科技,2017,38(16):253-256.
[29]于海燕,应义斌,谢丽娟,等.光程对黄酒金属元素近红外透射光谱分析精度的影响[J].光谱学与光谱分析,2007,27(6):1118-1120.
[30]YU H,YING Y,FU X,et al.Quality determination of Chinese rice wine based on Fourier transform near infrared spectroscopy[J].Journal of Near Infrared Spectroscopy,2006,14(1):37-44.
[31]LIU F,HE Y,WANG L,et al.Feasibility of the use of visible and near infrared spectroscopy to assess soluble solids content and p H of rice wines[J].Journal of Food Engineering(S0260-8774),2007,83(3):430-435.
[32]刘飞,王莉,何勇,等.应用可见/近红外光谱进行黄酒品种的判别[J].光谱学与光谱分析,2008,28(3):586-589.
[33]付庆波,索辉,贺馨平,等.温度影响下短波近红外酒精度检测的传递校正[J].光谱学与光谱分析,2012,32(8):2080-2084.
[34]王海英,杨玉珍,任国军,等.利用近红外技术对河套原酒入库指标的检测研究[J].2017,1:37-41.
[35]刘建学,杨国迪,韩四海,等.白酒基酒中典型醇的近红外预测模型构建[J].食品科学,2018,39(02):281-286.
[36]胡梦坤,岑琴,李丹.果汁中果汁含量测定方法探讨[J].农业科技与装备,2012(7):76-78.
[37]SIRISOMBOON P,TANAKA M,FUJITA S,ea al.Evaluation of pectin constituents of Japanese pear by near infrared spectroscopy[J].Journal of Food Engineering,2007,78(2):701-707.
[38]CARAMES E T S,ALAMAR P D,POPPI R J,et al.Quality control of cashew apple and guava nectar by near infrared spectroscopy[J].Journal of Food Composition and Analysis,2017,56(3):41-46.
[39]唐长波,岳田利.近红外光谱法检测果汁中的富马酸[J].西北农业学报,2007,16(2):187-189.
[40]朱大洲,孟超英,屠振华,等.不同类型近红外模型在苹果汁检测中的应用[J].农业工程学报,2009,25(S2):325-329.
[41]谷如祥,赵武奇,石珂心,等.近红外光谱测定苹果饮料中原果汁含量[J].食品工业科技,2013,34(20):75-77.
[42]于修烛,张静亚,李清华,等.基于近红外光谱的食用油酸价和过氧化值自动化检测[J].农业机械学报,2012,43(9):150-154.
[43]张静亚,张建新,于修烛,等.基于近红外透射光谱的食用油氧化定性分析[J].食品科学,2012,33(4):200-203.
[44]冼瑞仪,黄富荣,黎远鹏,等.可见和近红外透射光谱结合区间偏最小二乘法(i PLS)用于橄榄油中掺杂煎炸老油的定量分析[J].光谱学与光谱分析,2016,36(8):2462-2467.
[45]朱向荣,李高阳,秦燕华,等.近红外光谱结合模式识别技术快速鉴别煎炸油质量[J].中国食品学报,2016,16(12):206-210.
[46]DAUN J K,CLEAR K M,WILLIAMS P.Comparison of three whole seed near-infrared analyzers for measuring quality components of canola seed[J].Journal of the American Oil Chemists’Society,1994,71(10):1063-1068.
[47]HOM N H,BECKER H C,MOLLERS C.Non-destructive analysis of rapeseed quality by NIRS of small seed samples and single seeds[J].Euphytica,2007,153(1-2):27-34.
[48]PETISCO C,GARCIA-CRIADO B,VAZQUEZ-DE-ALDANA B R,et al.Measurement of quality parameters in intact seeds of Brassica species using visible and near-infrared spectroscopy[J].Industrial Crops and Products,2010,32(2):139-146.
[49]SIDHU H K,HAAGENSON D M,RAHMAN M,et al.Diode array near infrared spectrometer calibrations for composition analysis of single plant canola(brassica napus)seed[J].Applied Engineering in Agriculture,2014,30(30):69-76.
[50]智文良,信晓阳,崔建民,等.一种国产近红外仪分析油菜籽三种品质参数[J].中国油料作物学报,2012,34(3):305-310.
[51]李水芳,单杨,朱向荣,等.近红外透反射光谱用于检测蜂蜜加入麦芽糖浆掺假[J].食品科技,2010,35(12):299-303.
[52]李水芳,单杨,张欣,等.蜂蜜用葡萄糖溶液掺假的近红外光谱检测[J].食品研究与开发,2011,32(5):114-118.
[53]屠振华,朱大洲,籍保平,等.基于近红外光谱技术的蜂蜜掺假识别[J].农业工程学报,2011,27(11):382-387.
[54]吴燕涛,穆同娜,王绍清,等.现代分析技术在蜂蜜掺假鉴别中应用研究进展[J].食品研究与开发,2015,36(5):137-142.
[55]丁家欣,张秋海,李树莉,等.应用近红外光谱法快速测定蜂蜜中葡萄糖和果糖含量[J].光谱学与光谱分析,2016,36(10):197-198.
[56]褚小立,袁洪福,陆婉珍.近红外分析中光谱预处理及波长选择方法进展与应用[J].化学进展,2004,14(4):528-542.
[57]LI H,LIANG Y,XU Q,et al.Key wavelengths screening using competitive adaptive reweighted sampling method for multivariate calibration Analytica Chimica Acta[J].Analytica Chimica Acta,2009,648(1):77-84.
[58]NODA I.Advances in two-dimensional correlation spectroscopy[J].Vibrational Spectroscopy,2004,36(2):143-165.
[59]YANG R J.Research on the detection of adulterated milk based on 2D correlation spectroscopy[D].Tianjin:Tianjin University,2013.(in Chinese)
[60]SUN S Q,ZHOU Q,CHEN J B,Infrared Spectroscopy for Complex Mixtures:Aplications in Food and Traditional Chinese Medicine[M].Beijing:Chemical Industry Press,2011.
[61]WANG Y,XU C H,WANG P,et al.Analysis and identification of different animal horns by a three-stage infrared spectroscopy[J].Spectrochim Acta Part A:Molecular and Bimolecular Spectroscopy,2011,83(1):265-270.
[62]ZHANG Y L,CHEN J B,LEI Y,et al.Discrimination of different red wine by Fouriertransform infrared and two-dimensional infrared correlation spectroscopy[J].Journal of Molecular Structure,2010,974(1-3):144-150.
[2]NEYRINCK E,SMET S D,VERMEULEN L,et al.Application of near-infrared spectroscopy for the classification of fresh pork quality in cooked ham production[J].Food and Bioprocess Technology,2015,8(12):1-9.
[3]MELFSEN A,HARTUNG E,HAEUSSERMANN A.Robustness of near-infrared calibration models for the prediction of milk constituents during the milking process[J].Journal of Dairy Research,2013,80(1):103.
[4]MAUER L J,CHERNYSHOVA A A,HIATT A,et al.Melamine detection in infant formula powder using near-and mid-infrared spectroscopy[J].J Agric Food Chem,2009,57(10):3974-3980.
[5]严衍禄,朱大洲,陈斌.近红外光谱分析原理、技术与应用[M].北京:中国轻工业出版社,2013.
[6]周焕英,高志贤,孙思明,等.食品安全现场快速检测技术研究进展及应用[J].分析测试学报,2008,7(27):788-794.
[7]DAMBERGS R G,KAMBOURIS A,FRANCIS I L,et al.Rapid analysis of methanol in grape-derived distillation products using near-infrared transmission spectroscopy[J].J Agric Food Chem,2002,50(11):3079-3084.
[8]LACHENMEIER D W.Rapid quality control of spirit drinks and beer using multivariate data analysis of Fourier transform infrared spectra[J].Food Chemistry,2007,101(2):825-832.
[9]COZZOLINO D,KWIATKOWSKI M J,PARKER M,et al.Prediction of phenolic compounds in red wine fermentations by visible and near infrared spectroscopy[J].Analytica Chimica Acta,2004,513(1):73-80.
[10]TOHER D,DOWNEY G,MURPHY T B.Acomparison of modelbased and regression classification techniques applied to near infrared spectroscopic data in food authentication studies[J].Chemometrics and Intelligent Laboratory Systems,2007,89(2):102-115.
[11]宋宏新,薛建龙,刘立新,等.采用蛋白质定量方法检测掺假牛乳比较研究[J].食品工业,2015,36(4):210-214.
[12]金萍,丁洪流,陈英,等.乳制品中异种蛋白掺假检测的研究进展[J].食品研究与开发,2015,36(12):135-138.
[13]金垚,杜斌,智秀娟.NIR技术快速鉴定牛奶品牌与掺假识别[J].食品研究与开发,2016,37(3):178-181.
[14]宋宏新,薛建龙,刘立新,等.采用蛋白质定量方法检测掺假牛乳比较研究[J].食品工业,2015,36(4):210-214.
[15]丁美珍,宋岑,胡志明.近红外光谱技术在酒类产品分析中的应用[J].酿酒科技,2013,4:68-70.
[16]吴同,谭超.近红外光谱同时测定白酒中总酯和杂醇油[J].化学研究与应用,2016,28(10):1460-1463.
[17]魏赫楠,谭红,杨昌彪,等.近红外技术在白酒行业的应用现状及展望[J].酿酒科技,2013(11):85-87.
[18]彭帮柱,龙明华,岳田利,等.傅立叶变换近红外光谱法检测白酒总酸和总酯[J].农业工程学报,2006,22(12):216-219.
[19]陈妍,胡慧,汪风祖近红外光谱法快速分析白酒中的关键指标[J].酿酒科技,2010(11):90-94.
[20]杨国强,张淑娟,赵艳茹.基于近红外透射光谱的汾阳王酒快速鉴别[J].农业机械学报,2013,44(增刊1):189-193.
[21]彭帮柱,龙明华,岳田利,等.用偏最小二乘法及傅立叶变换近红外光谱快速检测白酒酒精度[J].农业工程学报,2007,23(4):233-237.
[22]WOO Y A,TERAZAWA Y,CHEN J Y.Development of a new measurement unit(milkspace-1)for rapid determination of fat,lactose,and protein in raw milk using near-infrared transmittance spectroscopy[J].Applied Spectroscopy,2002,56(5):599-604.
[23]KAROUI R,BAERDEMAEKER J.A review of the analytical methods coupled with chemometric tools,for the determination of the quality and identity of dairy products[J].Food Chemistry,2007,102(12):621-640.
[24]LAERTE D C,BEATRIZ S.The use of the Fourier Transform Infrared spectroscopy to determine adulterants in raw milk[J].Revista Brasileira de Zootecnia,2011,40(11):2591-2596.
[25]李庆波,徐可欣,王斌.牛奶主要成分含量近红外光谱快速测量法[J].食品科学,2002,2(6):121-124.
[26]杨仁杰,刘蓉,徐可欣.二维相关光谱结合偏最小二乘法测定牛奶中的掺杂尿素[J].农业工程学报,2012,28(6):259-262.
[27]倪力军,钟霖,张鑫,等.近红外光谱结合非线性模式识别方法进行牛奶中掺假物质的判别[J].光谱学与光谱分析,2014,34(10):2673-2678.
[28]范睿,孙晓凯,杨晨,等.基于近红外光谱定量分析牛奶中掺假的动物水解蛋白含量[J].食品工业科技,2017,38(16):253-256.
[29]于海燕,应义斌,谢丽娟,等.光程对黄酒金属元素近红外透射光谱分析精度的影响[J].光谱学与光谱分析,2007,27(6):1118-1120.
[30]YU H,YING Y,FU X,et al.Quality determination of Chinese rice wine based on Fourier transform near infrared spectroscopy[J].Journal of Near Infrared Spectroscopy,2006,14(1):37-44.
[31]LIU F,HE Y,WANG L,et al.Feasibility of the use of visible and near infrared spectroscopy to assess soluble solids content and p H of rice wines[J].Journal of Food Engineering(S0260-8774),2007,83(3):430-435.
[32]刘飞,王莉,何勇,等.应用可见/近红外光谱进行黄酒品种的判别[J].光谱学与光谱分析,2008,28(3):586-589.
[33]付庆波,索辉,贺馨平,等.温度影响下短波近红外酒精度检测的传递校正[J].光谱学与光谱分析,2012,32(8):2080-2084.
[34]王海英,杨玉珍,任国军,等.利用近红外技术对河套原酒入库指标的检测研究[J].2017,1:37-41.
[35]刘建学,杨国迪,韩四海,等.白酒基酒中典型醇的近红外预测模型构建[J].食品科学,2018,39(02):281-286.
[36]胡梦坤,岑琴,李丹.果汁中果汁含量测定方法探讨[J].农业科技与装备,2012(7):76-78.
[37]SIRISOMBOON P,TANAKA M,FUJITA S,ea al.Evaluation of pectin constituents of Japanese pear by near infrared spectroscopy[J].Journal of Food Engineering,2007,78(2):701-707.
[38]CARAMES E T S,ALAMAR P D,POPPI R J,et al.Quality control of cashew apple and guava nectar by near infrared spectroscopy[J].Journal of Food Composition and Analysis,2017,56(3):41-46.
[39]唐长波,岳田利.近红外光谱法检测果汁中的富马酸[J].西北农业学报,2007,16(2):187-189.
[40]朱大洲,孟超英,屠振华,等.不同类型近红外模型在苹果汁检测中的应用[J].农业工程学报,2009,25(S2):325-329.
[41]谷如祥,赵武奇,石珂心,等.近红外光谱测定苹果饮料中原果汁含量[J].食品工业科技,2013,34(20):75-77.
[42]于修烛,张静亚,李清华,等.基于近红外光谱的食用油酸价和过氧化值自动化检测[J].农业机械学报,2012,43(9):150-154.
[43]张静亚,张建新,于修烛,等.基于近红外透射光谱的食用油氧化定性分析[J].食品科学,2012,33(4):200-203.
[44]冼瑞仪,黄富荣,黎远鹏,等.可见和近红外透射光谱结合区间偏最小二乘法(i PLS)用于橄榄油中掺杂煎炸老油的定量分析[J].光谱学与光谱分析,2016,36(8):2462-2467.
[45]朱向荣,李高阳,秦燕华,等.近红外光谱结合模式识别技术快速鉴别煎炸油质量[J].中国食品学报,2016,16(12):206-210.
[46]DAUN J K,CLEAR K M,WILLIAMS P.Comparison of three whole seed near-infrared analyzers for measuring quality components of canola seed[J].Journal of the American Oil Chemists’Society,1994,71(10):1063-1068.
[47]HOM N H,BECKER H C,MOLLERS C.Non-destructive analysis of rapeseed quality by NIRS of small seed samples and single seeds[J].Euphytica,2007,153(1-2):27-34.
[48]PETISCO C,GARCIA-CRIADO B,VAZQUEZ-DE-ALDANA B R,et al.Measurement of quality parameters in intact seeds of Brassica species using visible and near-infrared spectroscopy[J].Industrial Crops and Products,2010,32(2):139-146.
[49]SIDHU H K,HAAGENSON D M,RAHMAN M,et al.Diode array near infrared spectrometer calibrations for composition analysis of single plant canola(brassica napus)seed[J].Applied Engineering in Agriculture,2014,30(30):69-76.
[50]智文良,信晓阳,崔建民,等.一种国产近红外仪分析油菜籽三种品质参数[J].中国油料作物学报,2012,34(3):305-310.
[51]李水芳,单杨,朱向荣,等.近红外透反射光谱用于检测蜂蜜加入麦芽糖浆掺假[J].食品科技,2010,35(12):299-303.
[52]李水芳,单杨,张欣,等.蜂蜜用葡萄糖溶液掺假的近红外光谱检测[J].食品研究与开发,2011,32(5):114-118.
[53]屠振华,朱大洲,籍保平,等.基于近红外光谱技术的蜂蜜掺假识别[J].农业工程学报,2011,27(11):382-387.
[54]吴燕涛,穆同娜,王绍清,等.现代分析技术在蜂蜜掺假鉴别中应用研究进展[J].食品研究与开发,2015,36(5):137-142.
[55]丁家欣,张秋海,李树莉,等.应用近红外光谱法快速测定蜂蜜中葡萄糖和果糖含量[J].光谱学与光谱分析,2016,36(10):197-198.
[56]褚小立,袁洪福,陆婉珍.近红外分析中光谱预处理及波长选择方法进展与应用[J].化学进展,2004,14(4):528-542.
[57]LI H,LIANG Y,XU Q,et al.Key wavelengths screening using competitive adaptive reweighted sampling method for multivariate calibration Analytica Chimica Acta[J].Analytica Chimica Acta,2009,648(1):77-84.
[58]NODA I.Advances in two-dimensional correlation spectroscopy[J].Vibrational Spectroscopy,2004,36(2):143-165.
[59]YANG R J.Research on the detection of adulterated milk based on 2D correlation spectroscopy[D].Tianjin:Tianjin University,2013.(in Chinese)
[60]SUN S Q,ZHOU Q,CHEN J B,Infrared Spectroscopy for Complex Mixtures:Aplications in Food and Traditional Chinese Medicine[M].Beijing:Chemical Industry Press,2011.
[61]WANG Y,XU C H,WANG P,et al.Analysis and identification of different animal horns by a three-stage infrared spectroscopy[J].Spectrochim Acta Part A:Molecular and Bimolecular Spectroscopy,2011,83(1):265-270.
[62]ZHANG Y L,CHEN J B,LEI Y,et al.Discrimination of different red wine by Fouriertransform infrared and two-dimensional infrared correlation spectroscopy[J].Journal of Molecular Structure,2010,974(1-3):144-150.