三维荧光淬灭耦合平行因子分析与二维相关光谱在金属与溶解性有机物配位作用中的研究进展
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摘要
溶解性有机物(DOM)来源的多样性和成分结构的复杂性导致DOM与金属配位作用存在不确定性。总结了三维荧光猝灭耦合平行因子分析法和二维相关光谱分析法在DOM与金属配位作用研究中的进展,介绍了两种分析方法的原理、特点和内在联系。
The varied sources and complex structures of dissolved organic matter(DOM) result in uncertain coordination between DOM and metals. In this paper, the applications of 2-D correlation spectroscopy and a coupling technology of 3-D fluorescent quenching and parallel factor analysis method in studying the coordination between DOM and metals were summarized. The principles, characteristics and interrelationships of these two methods were introduced.
The varied sources and complex structures of dissolved organic matter(DOM) result in uncertain coordination between DOM and metals. In this paper, the applications of 2-D correlation spectroscopy and a coupling technology of 3-D fluorescent quenching and parallel factor analysis method in studying the coordination between DOM and metals were summarized. The principles, characteristics and interrelationships of these two methods were introduced.
引文
[1]M.A. Barakat, Arab. J. Chem. 4(2011)361-377.
[2]F.R. Siegel, Environmental Geochemistry of Potentially ToxicMetals, Springer, Berlin Heidelberg, Berlin, 2002.
[3]Allen, H. E.; Hansen, D. J. The importance of trace metal specia-tion to water quality criteria. Water Environ. Res. 1996,68, 42-54.
[4]Scott, D. T.; Runkel, R. L.; McKnight, D. M.; Voelker, B. M.;Kimball, B. A.; Carraway, E. R. Transport and cycling of iron andhydrogen peroxide in a freshwater stream:Influence of organic acids.Water Resour. Res. 2003, 39, 1308.
[5]Bianchi, T. S.; Biogeochemistry of Estuaries; Oxford UniversityPress:New York, NY, 2007.
[6]OGAWA H, TANOUE E. Dissolved Organic Matter in OceanicWaters[J]. Journal ofOceanography, 2003, 59(2):129-47.
[7]CHEN H, LIAO Z L, GU X Y, et al. Anthropogenic Influencesof Paved Runoff and SanitarySewage on the Dissolved OrganicMatter Quality of Wet Weather Overflows:An ExcitationEmissionMatrix Parallel Factor Analysis Assessment[J]. Environ Sci Technol,2017, 51(3):1157-67.
[8]戴春燕,吴静,向熙等,.工业废水为主的城市污水的荧光指纹特征[J].光谱学与光谱分析, 2013, 02):414-7.
[9]HARUN S, BAKER A, BRADLEY C, et al. Spatial and seasonalvariations in the compositionof dissolved organic matter in a tropicalcatchment:the Lower Kinabatangan River, Sabah, Malaysia[J]. Envi-ron Sci Process Impacts, 2016, 18(1):137-50.
[10]HENDERSON R K, BAKER A, MURPHY K R, et al. Fluores-cence as a potential monitoringtool for recycled water systems:a re-view[J]. Water Res, 2009, 43(4):863-81.
[11]CARSTEA E M, BRIDGEMAN J, BAKER A, etal. Fluorescencespectroscopy for wastewatermonitoring:A review[J]. Water Res,2016, 95(205-19.
[12]Cory, R.; McKnight, D. M.; Chin, Y.-P.; Miller, P.; Jaros, C. L.Chemical characteristics of fulvic acids from Arctic surface waters:Microbial contributions and photochemical transformations. J. Geo-phys. Res. 2007, 112.
[13]Dutton, J., Fisher, N.S., 2012. Influence of humic acid on theuptake of aqueous metals by the killifish Fundulus heteroclitus. En-viron. Toxicol. Chem. 31(10),2225-2232.
[14]Sharma, V.K., Sohn, M., 2009. Aquatic arsenic:toxicity, specia-tion, transformations, and remediation. Environ. Int. 35(4), 743-759.
[15]Flora, S.J.S., 2011. Arsenic-induced oxidative stress and its re-versibility. Free Radic. Bio. Med. 51(2), 257-281.
[16]Heibati, M., Stedmon, 2017. Assessment of drinking water quali-ty at the tap using fluorescence spectroscopy. Water Res. 125, 1-10.
[17]Plaza, C.; Brunetti, G.; Senesi, N.; Polo, A. Molecular and quan-titative analysis of metal ion binding to humic acids from sewagesludge and sludge-amended soils by fluorescence spectroscopy. Env-iron. Sci. Technol. 2006, 40, 917-923.
[18]陈诗雨,李燕,李爱民.溶解性有机物研究中三维荧光光谱分析的应用[J].环境科学与技术, 2015:64-8.
[19]Yamashita, Y., Jaffé, R., 2008. Characterizing the interactionsbetween trace metals and dissolved organic matter using excitation-emission matrix and parallel factor analysis. Environ. Sci. Technol.42(19), 7374-7379.
[20]Huang, M., Li, Z., Huang, B., Luo, N., Zhang, Q., Zhai, X., Zeng,G., 2018. Investigating binding characteristics of cadmium and cop-per to DOM derived from compost and rice straw using EEM-PARAFAC combined with two-dimensional FTIR correlation analy-ses. J. Hazard. Mater. 344, 539-548.
[21]Cabaniss, S. E. Synchronous fluorescence spectra ofmetal-fulvicacid complexes. Environ. Sci. Technol. 1992, 26, 1133-1139.
[22]Esteves daSilva, J. C. G.; Machado, A. A. S. C.; Oliveira, C. J.S.; Pinto, M. S. S. D. S. Fluorescence quenching of anthoropogenicfulvic acids by Cu(II), Fe(III)and UO22+. Talanta 1998, 45, 1155-1165.
[23]Ryan, D. K.; Weber, J. H. Fluorescence quenching titration fordetermination of complexing capacities and stability constants of ful-vic acid. Anal. Chem. 1982, 54, 986-990.
[24]Ryan, D. K.; Weber, J. H. Copper(II)complexing capacities ofnaturalwaters by fluorescence quenching.Environ. Sci. Technol.1982,16, 866-872.
[25]Luster, J.; Lloyd, T.; Sposito, G. Multi-wavelength molecular flu-orescence spectroscopy for quantitative characterization of copper(II)and aluminum(III)complexation by dissolvedorganic matter. Environ.Sci. Technol. 1996, 30, 1565-1574.
[26]Lu, X.; Jaffe?, R. Interaction between Hg(II)and natural dis-solved organic matter:A fluorescence spectroscopy based study.Water Res. 2001, 35, 1793-1803.
[27]Wu, F. C.; Mills, R. B.; Evans, R. D.; Dillon, P. J. Kinetics ofmetal-fulvic acid complexation using stopped-flowtechnique andthree-dimensional excitation and emission fluorescence spectropho-tometer. Anal. Chem. 2004, 76, 110-113.
[28]Fu, P.; Wu, F.; Liu, C.; Wang, F.; Li, W.; Yue, L.; Guo, Q. Fluo-rescence characterization of dissolved organic matter in an urban riv-er and its complexation with Hg(II). Appl. Geochem. 2007, 22,1668-1679.
[29]Chen, W.B., Smith, D.S., Gueguen, C., 2013. Influence of waterchemistry and dissolved organic matter(DOM)molecular size oncopper and mercury binding determined by multiresponse fluores-cence quenching. Chemosphere 92, 351-359.
[30]Poulin, B.A., Ryan, J.N., Aiken, G.R., 2014. Effects of iron onoptical properties of dissolved organic matter. Environ. Sci. Technol.48:10098-10106.
[31]Wu J, Zhang H, Yao Q-S, Shao LM, He PJ(2012b)Toward un-derstanding the role of individual fluorescent components in DOM-metal binding. J Hazard Mater 215-216:294-301.
[32]J. Wu, H. Zhang, Q.S. Yao, L.M. Shao, P.J. He, Toward under-standing the role of individual fluorescent components in DOM-met-al binding, J. Hazard. Mater. 215(2012)294-301.
[33]J.B. Fellman, M.P. Miller, R.M. Cory, D.V. D'Amore, D. White,Characterizing dissolved organic matter using PARAFAC modeling offluorescence spectroscopy:a comparison of two models, Environ. Sci.Technol. 43(2009)6228-6234.
[34]Noda, I.; Ozaki, Y. Two-Dimensional Correlation SpectroscopyApplications in Vibrational and Optical Spectroscopy; John Wiley&Sons Ltd.:London, 2004.
[35]余婧,武培怡.二维相关荧光光谱技术[J].化学进展,2006,(12):1691-1702.
[36]Chen, W., Habibul, N., Liu, X.-Y., Sheng, G.-P., Yu, H.-Q.,2015. FTIR and synchronous fluorescence heterospectral two-dimen-sional correlation analyses on the binding characteristi-cs of copper onto dissolved organic matter. Environ. Sci. Technol. 49(4),2052-2058.
[37]Jin, B.M. Lee, Characterization of binding site heterogeneity forcopper within dissolved organic matter fractions using two-dimen-sional correlation fluorescence spectroscopy, Chemosphere 83(2011)1603-1611.
[38]Xu, H.C., Yu, G.H., Yang, L.Y., Jiang, H.L., 2013c. Combinationof two-dimensional correlation spectroscopy and parallel factor anal-ysis to characterize the binding of heavy metals with DOM in lakesediments. J. Hazard. Mater. 263, 412-421.
[39]Huang, M., Li, Z., Huang, B., Luo, N., Zhang, Q., Zhai, X., Zeng,G., 2017. Investigating binding characteristics of cadmium and cop-per to DOM derived from compost and rice straw using EEM-PARAFAC combined with two-dimensional FTIR correlation analy-ses. J. Hazard. Mater.
[2]F.R. Siegel, Environmental Geochemistry of Potentially ToxicMetals, Springer, Berlin Heidelberg, Berlin, 2002.
[3]Allen, H. E.; Hansen, D. J. The importance of trace metal specia-tion to water quality criteria. Water Environ. Res. 1996,68, 42-54.
[4]Scott, D. T.; Runkel, R. L.; McKnight, D. M.; Voelker, B. M.;Kimball, B. A.; Carraway, E. R. Transport and cycling of iron andhydrogen peroxide in a freshwater stream:Influence of organic acids.Water Resour. Res. 2003, 39, 1308.
[5]Bianchi, T. S.; Biogeochemistry of Estuaries; Oxford UniversityPress:New York, NY, 2007.
[6]OGAWA H, TANOUE E. Dissolved Organic Matter in OceanicWaters[J]. Journal ofOceanography, 2003, 59(2):129-47.
[7]CHEN H, LIAO Z L, GU X Y, et al. Anthropogenic Influencesof Paved Runoff and SanitarySewage on the Dissolved OrganicMatter Quality of Wet Weather Overflows:An ExcitationEmissionMatrix Parallel Factor Analysis Assessment[J]. Environ Sci Technol,2017, 51(3):1157-67.
[8]戴春燕,吴静,向熙等,.工业废水为主的城市污水的荧光指纹特征[J].光谱学与光谱分析, 2013, 02):414-7.
[9]HARUN S, BAKER A, BRADLEY C, et al. Spatial and seasonalvariations in the compositionof dissolved organic matter in a tropicalcatchment:the Lower Kinabatangan River, Sabah, Malaysia[J]. Envi-ron Sci Process Impacts, 2016, 18(1):137-50.
[10]HENDERSON R K, BAKER A, MURPHY K R, et al. Fluores-cence as a potential monitoringtool for recycled water systems:a re-view[J]. Water Res, 2009, 43(4):863-81.
[11]CARSTEA E M, BRIDGEMAN J, BAKER A, etal. Fluorescencespectroscopy for wastewatermonitoring:A review[J]. Water Res,2016, 95(205-19.
[12]Cory, R.; McKnight, D. M.; Chin, Y.-P.; Miller, P.; Jaros, C. L.Chemical characteristics of fulvic acids from Arctic surface waters:Microbial contributions and photochemical transformations. J. Geo-phys. Res. 2007, 112.
[13]Dutton, J., Fisher, N.S., 2012. Influence of humic acid on theuptake of aqueous metals by the killifish Fundulus heteroclitus. En-viron. Toxicol. Chem. 31(10),2225-2232.
[14]Sharma, V.K., Sohn, M., 2009. Aquatic arsenic:toxicity, specia-tion, transformations, and remediation. Environ. Int. 35(4), 743-759.
[15]Flora, S.J.S., 2011. Arsenic-induced oxidative stress and its re-versibility. Free Radic. Bio. Med. 51(2), 257-281.
[16]Heibati, M., Stedmon, 2017. Assessment of drinking water quali-ty at the tap using fluorescence spectroscopy. Water Res. 125, 1-10.
[17]Plaza, C.; Brunetti, G.; Senesi, N.; Polo, A. Molecular and quan-titative analysis of metal ion binding to humic acids from sewagesludge and sludge-amended soils by fluorescence spectroscopy. Env-iron. Sci. Technol. 2006, 40, 917-923.
[18]陈诗雨,李燕,李爱民.溶解性有机物研究中三维荧光光谱分析的应用[J].环境科学与技术, 2015:64-8.
[19]Yamashita, Y., Jaffé, R., 2008. Characterizing the interactionsbetween trace metals and dissolved organic matter using excitation-emission matrix and parallel factor analysis. Environ. Sci. Technol.42(19), 7374-7379.
[20]Huang, M., Li, Z., Huang, B., Luo, N., Zhang, Q., Zhai, X., Zeng,G., 2018. Investigating binding characteristics of cadmium and cop-per to DOM derived from compost and rice straw using EEM-PARAFAC combined with two-dimensional FTIR correlation analy-ses. J. Hazard. Mater. 344, 539-548.
[21]Cabaniss, S. E. Synchronous fluorescence spectra ofmetal-fulvicacid complexes. Environ. Sci. Technol. 1992, 26, 1133-1139.
[22]Esteves daSilva, J. C. G.; Machado, A. A. S. C.; Oliveira, C. J.S.; Pinto, M. S. S. D. S. Fluorescence quenching of anthoropogenicfulvic acids by Cu(II), Fe(III)and UO22+. Talanta 1998, 45, 1155-1165.
[23]Ryan, D. K.; Weber, J. H. Fluorescence quenching titration fordetermination of complexing capacities and stability constants of ful-vic acid. Anal. Chem. 1982, 54, 986-990.
[24]Ryan, D. K.; Weber, J. H. Copper(II)complexing capacities ofnaturalwaters by fluorescence quenching.Environ. Sci. Technol.1982,16, 866-872.
[25]Luster, J.; Lloyd, T.; Sposito, G. Multi-wavelength molecular flu-orescence spectroscopy for quantitative characterization of copper(II)and aluminum(III)complexation by dissolvedorganic matter. Environ.Sci. Technol. 1996, 30, 1565-1574.
[26]Lu, X.; Jaffe?, R. Interaction between Hg(II)and natural dis-solved organic matter:A fluorescence spectroscopy based study.Water Res. 2001, 35, 1793-1803.
[27]Wu, F. C.; Mills, R. B.; Evans, R. D.; Dillon, P. J. Kinetics ofmetal-fulvic acid complexation using stopped-flowtechnique andthree-dimensional excitation and emission fluorescence spectropho-tometer. Anal. Chem. 2004, 76, 110-113.
[28]Fu, P.; Wu, F.; Liu, C.; Wang, F.; Li, W.; Yue, L.; Guo, Q. Fluo-rescence characterization of dissolved organic matter in an urban riv-er and its complexation with Hg(II). Appl. Geochem. 2007, 22,1668-1679.
[29]Chen, W.B., Smith, D.S., Gueguen, C., 2013. Influence of waterchemistry and dissolved organic matter(DOM)molecular size oncopper and mercury binding determined by multiresponse fluores-cence quenching. Chemosphere 92, 351-359.
[30]Poulin, B.A., Ryan, J.N., Aiken, G.R., 2014. Effects of iron onoptical properties of dissolved organic matter. Environ. Sci. Technol.48:10098-10106.
[31]Wu J, Zhang H, Yao Q-S, Shao LM, He PJ(2012b)Toward un-derstanding the role of individual fluorescent components in DOM-metal binding. J Hazard Mater 215-216:294-301.
[32]J. Wu, H. Zhang, Q.S. Yao, L.M. Shao, P.J. He, Toward under-standing the role of individual fluorescent components in DOM-met-al binding, J. Hazard. Mater. 215(2012)294-301.
[33]J.B. Fellman, M.P. Miller, R.M. Cory, D.V. D'Amore, D. White,Characterizing dissolved organic matter using PARAFAC modeling offluorescence spectroscopy:a comparison of two models, Environ. Sci.Technol. 43(2009)6228-6234.
[34]Noda, I.; Ozaki, Y. Two-Dimensional Correlation SpectroscopyApplications in Vibrational and Optical Spectroscopy; John Wiley&Sons Ltd.:London, 2004.
[35]余婧,武培怡.二维相关荧光光谱技术[J].化学进展,2006,(12):1691-1702.
[36]Chen, W., Habibul, N., Liu, X.-Y., Sheng, G.-P., Yu, H.-Q.,2015. FTIR and synchronous fluorescence heterospectral two-dimen-sional correlation analyses on the binding characteristi-cs of copper onto dissolved organic matter. Environ. Sci. Technol. 49(4),2052-2058.
[37]Jin, B.M. Lee, Characterization of binding site heterogeneity forcopper within dissolved organic matter fractions using two-dimen-sional correlation fluorescence spectroscopy, Chemosphere 83(2011)1603-1611.
[38]Xu, H.C., Yu, G.H., Yang, L.Y., Jiang, H.L., 2013c. Combinationof two-dimensional correlation spectroscopy and parallel factor anal-ysis to characterize the binding of heavy metals with DOM in lakesediments. J. Hazard. Mater. 263, 412-421.
[39]Huang, M., Li, Z., Huang, B., Luo, N., Zhang, Q., Zhai, X., Zeng,G., 2017. Investigating binding characteristics of cadmium and cop-per to DOM derived from compost and rice straw using EEM-PARAFAC combined with two-dimensional FTIR correlation analy-ses. J. Hazard. Mater.