十二烷基伯胺盐酸盐与十二烷基聚氧乙烯硫酸钠复配体系中的表面性质
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摘要
研究了十二烷基胺盐酸盐(DAC)和十二烷基聚氧乙烯硫酸钠(AES)复配体系的表面性质与胶束化行为.发现该体系在广泛的复配比例区间和温度区间内保持了极为优异的表面活性,测定了该体系的临界胶束浓度(cmc)与其对应的表面张力(γcmc)的具体值,并研究了温度、pH值和离子强度等环境因素对相关体系的影响.
The surface properties and micellar behaviors of mixed systems composed of dodecylammonium chloride(DAC) and sodium alcohol ether sulphate(AES) have been studied in great detail. The results of this study revealed that the mixed systems possessed excellent surface activities over a wide range of molar ratios and temperature intervals. Variations in the critical micelle concentrations(cmc) and corresponding surface tension(γcmc) of the mixtures were determined over a range of molar ratios and temperatures, and several environmental factors were also evaluated, such as pH and ionic strength.
The surface properties and micellar behaviors of mixed systems composed of dodecylammonium chloride(DAC) and sodium alcohol ether sulphate(AES) have been studied in great detail. The results of this study revealed that the mixed systems possessed excellent surface activities over a wide range of molar ratios and temperature intervals. Variations in the critical micelle concentrations(cmc) and corresponding surface tension(γcmc) of the mixtures were determined over a range of molar ratios and temperatures, and several environmental factors were also evaluated, such as pH and ionic strength.
引文
(1)Zhao,G.X.;Cheng,Y.Z.;Ou,J.G.;Tian,B.S.;Huang,Z.M.Acta Chim.Sin.1980,38(5),409.[赵国玺,程玉珍,欧进国,田丙申,黄智民.化学学报,1980,38(5),409.]
(2)Zhang,L.H.;Qiao,J.;Ding,H.J.;Zhao,G.X.Acta Phys.-Chim.Sin.1993,9,478.[张兰辉,谯静,丁慧君,赵国玺.物理化学学报,1993,9,478.]doi:10.3866/PKU.WHXB19930411
(3)Yin,H.Q.;Zhou,Z.K.;Huang,J.B.;Zheng,R.;Zhang,Y.Y.Angew.Chem.Int.Edit.2003,42,2188.doi:10.1002/anie.200350913
(4)Wang,C.Z.;Tang,S.H.;Huang,J.B.;Zhang,X.R.;Fu,H.L.Colloid Polymer Sci.2002,280,770.doi:10.1007/s00396-002-0676-1
(5)Huang,J.B.;Zhao,G.X.Colloid Polymer Sci.1995,273,56.
(6)Cao,X.L.;Lü,K.;Cui,X.H.;Shi,J.;Yuan,S.L.Acta Phys.-Chim.Sin.2010,26,1959.[曹绪龙,吕凯,崔晓红,石静,苑世领.物理化学学报,2010,26,1959.]doi:10.3866/PKU.WHXB20100143
(7)Huang,J.B.;Zhao,G.X.Colloid Polymer Sci.1996,274,747.doi:10.1007/BF00654670
(8)Tang,S.H.;Huang,J.B.;Dai,L.R.;Wang,C.Z.;Fu,H.L.Acta Chim.Sin.2002,60,1331.[唐世华,黄建滨,戴乐蓉,王传忠,付宏兰.化学学报,2002,60,1331.]
(9)Chen,L.;Xiao,J.X.;Ma,J.M.Acta Phys.-Chim.Sin.2003,19,577.[陈莉,肖进新,马季铭.物理化学学报,2003,19,577.]doi:10.3866/PKU.WHXB20030701
(10)Yin,H.Q.;Huang,J.B.;Mao,M.;Fu,H.L.Langmuir 2002,18,9198.doi:10.1021/la025902n
(11)Han,F.;Fu,H.L.;He,X.;Huang,J.B.Acta Chim.Sin.2003,61,1399.[韩峰,付宏兰,何潇,黄建滨.化学学报,2003,61,1399.]
(12)Yan,Y.;Huang,J.B.;Li,Z.C.;Zhao,X.L.;Zhu,B.Y.;Ma,J.M.Colloids and Surfaces A 2003,215,263.doi:10.1016/S0927-7757(02)00486-7
(13)Xiao,J.X.;Zhao,G.X.Chemical Research and Application2001,13(5),502.[肖进新.赵国玺.化学研究与应用,2001,13(5),502.]
(14)Wang,K.;Yin,H.Q.;Sha,W.;Huang,J.B.;Fu,H.L.J.Phys.Chem.B 2007,111,12997.
(15)Yin,H.Q.;Lei,S.;Zhu,S.B.;Huang,J.B.;Ye,J.P.Chem.Eur.J.2006,12,2825.
(16)Zhu,B.Y.;Shi,H.T.;Huang,J.B.;He,X.Acta Chim.Sin.2001,59,913.[朱瑶,石洪涛,黄建滨,何煦.化学学报,2001,59,913.]
(17)Yin,H.Q.;Huang,J.B.;Lin,Y.Y.;Zhang,Y.Y.;Qiu,S.C.;Ye,J.P.J.Phys.Chem.B 2005,109,4104.
(18)Han,X.;Cheng,X.H.;Wang,J.;Huang,J.B.Acta Phys.-Chim.Sin.2012,28,146.[韩霞,程新皓,王江,黄建滨.物理化学学报,2012,28,146.]doi:10.3866/PKU.WHXB201228146
(2)Zhang,L.H.;Qiao,J.;Ding,H.J.;Zhao,G.X.Acta Phys.-Chim.Sin.1993,9,478.[张兰辉,谯静,丁慧君,赵国玺.物理化学学报,1993,9,478.]doi:10.3866/PKU.WHXB19930411
(3)Yin,H.Q.;Zhou,Z.K.;Huang,J.B.;Zheng,R.;Zhang,Y.Y.Angew.Chem.Int.Edit.2003,42,2188.doi:10.1002/anie.200350913
(4)Wang,C.Z.;Tang,S.H.;Huang,J.B.;Zhang,X.R.;Fu,H.L.Colloid Polymer Sci.2002,280,770.doi:10.1007/s00396-002-0676-1
(5)Huang,J.B.;Zhao,G.X.Colloid Polymer Sci.1995,273,56.
(6)Cao,X.L.;Lü,K.;Cui,X.H.;Shi,J.;Yuan,S.L.Acta Phys.-Chim.Sin.2010,26,1959.[曹绪龙,吕凯,崔晓红,石静,苑世领.物理化学学报,2010,26,1959.]doi:10.3866/PKU.WHXB20100143
(7)Huang,J.B.;Zhao,G.X.Colloid Polymer Sci.1996,274,747.doi:10.1007/BF00654670
(8)Tang,S.H.;Huang,J.B.;Dai,L.R.;Wang,C.Z.;Fu,H.L.Acta Chim.Sin.2002,60,1331.[唐世华,黄建滨,戴乐蓉,王传忠,付宏兰.化学学报,2002,60,1331.]
(9)Chen,L.;Xiao,J.X.;Ma,J.M.Acta Phys.-Chim.Sin.2003,19,577.[陈莉,肖进新,马季铭.物理化学学报,2003,19,577.]doi:10.3866/PKU.WHXB20030701
(10)Yin,H.Q.;Huang,J.B.;Mao,M.;Fu,H.L.Langmuir 2002,18,9198.doi:10.1021/la025902n
(11)Han,F.;Fu,H.L.;He,X.;Huang,J.B.Acta Chim.Sin.2003,61,1399.[韩峰,付宏兰,何潇,黄建滨.化学学报,2003,61,1399.]
(12)Yan,Y.;Huang,J.B.;Li,Z.C.;Zhao,X.L.;Zhu,B.Y.;Ma,J.M.Colloids and Surfaces A 2003,215,263.doi:10.1016/S0927-7757(02)00486-7
(13)Xiao,J.X.;Zhao,G.X.Chemical Research and Application2001,13(5),502.[肖进新.赵国玺.化学研究与应用,2001,13(5),502.]
(14)Wang,K.;Yin,H.Q.;Sha,W.;Huang,J.B.;Fu,H.L.J.Phys.Chem.B 2007,111,12997.
(15)Yin,H.Q.;Lei,S.;Zhu,S.B.;Huang,J.B.;Ye,J.P.Chem.Eur.J.2006,12,2825.
(16)Zhu,B.Y.;Shi,H.T.;Huang,J.B.;He,X.Acta Chim.Sin.2001,59,913.[朱瑶,石洪涛,黄建滨,何煦.化学学报,2001,59,913.]
(17)Yin,H.Q.;Huang,J.B.;Lin,Y.Y.;Zhang,Y.Y.;Qiu,S.C.;Ye,J.P.J.Phys.Chem.B 2005,109,4104.
(18)Han,X.;Cheng,X.H.;Wang,J.;Huang,J.B.Acta Phys.-Chim.Sin.2012,28,146.[韩霞,程新皓,王江,黄建滨.物理化学学报,2012,28,146.]doi:10.3866/PKU.WHXB201228146