碱蓬籽油强化提取方法对比研究
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摘要
采用微波强化提取法、超声强化提取法及超声-微波协同法提取碱蓬籽油,从最佳提取工艺条件、出油率、主要脂肪酸种类及相对含量三个方面对三种强化提取方法加以对比分析。结果表明,协同法的出油率为20.34%±0.23%,略低于超声法,提取时间仅为6 min,是超声法提取时间的11.54%,且为微波法的一半。协同法所含四种主要脂肪酸(亚油酸(C18:2)、油酸(C18:1)、棕榈酸(C16:0)及硬脂酸(C18:0))的相对含量的总量最高,达98.51%,优于其他两种强化提取方法。证明超声-微波协同法是碱蓬籽油比较理想的强化提取方法。
Microwave-assisted extraction(MAE), ultrasound-assisted extraction(UAE) and ultrasonic-microwave synergistic extraction(UMSE) were respectively adopted to extract Suaeda salsa seed oil. The three improved extraction methods were compared and analyzed from the aspects of optimal extraction conditions, oil yield, composition and relative content of main fatty acid. The results showed that the oil yield of UMSE was 20.34%±0.23%, which was slightly lower than the UAE;The extraction time of UMSE was 6 min, which was 11.54% of UAE and half of MAE. In the oil extracted by UMSE,the total content of four kinds of main fatty acids(linoleic acid(C18:2), oleic acid(C18:1), palmitic acid(C16:0) and stearic acid(C18:0)) was 98.51%, which was all superior to other improved extraction methods. These all showed that UMSE was the ideal improved extraction method of Suaeda salsa seed oil.
Microwave-assisted extraction(MAE), ultrasound-assisted extraction(UAE) and ultrasonic-microwave synergistic extraction(UMSE) were respectively adopted to extract Suaeda salsa seed oil. The three improved extraction methods were compared and analyzed from the aspects of optimal extraction conditions, oil yield, composition and relative content of main fatty acid. The results showed that the oil yield of UMSE was 20.34%±0.23%, which was slightly lower than the UAE;The extraction time of UMSE was 6 min, which was 11.54% of UAE and half of MAE. In the oil extracted by UMSE,the total content of four kinds of main fatty acids(linoleic acid(C18:2), oleic acid(C18:1), palmitic acid(C16:0) and stearic acid(C18:0)) was 98.51%, which was all superior to other improved extraction methods. These all showed that UMSE was the ideal improved extraction method of Suaeda salsa seed oil.
引文
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[2]Atabani A E,Silitonga A S,Badruddin I A,et al.A comprehensive review on biodiesel as an alternative energy resource and its characteristics[J].Renewable&Sustainable Energy Reviews,2012,16(4):2070-2093.
[3]Mahmudul H M,Hagos F Y,Mamat R,et al.Production,characterization and performance of biodiesel as an alternative fuel in diesel engines-Areview[J].Renewable&Sustainable Energy Reviews,2017,72:497-509.
[4]Ashraful A M,Masjuki H H,Kalam M A,et al.Production and comparison of fuel properties,engine performance,and emission characteristics of biodiesel from various non-edible vegetable oils:Areview[J].Energy Conversion&Management,2014,80:202-228.
[5]Silitonga A S,Atabani A E,Mahlia T M I,et al.A review on prospect of Jatropha curcas for biodiesel in Indonesia[J].Renewable&Sustainable Energy Reviews,2011,15(8):3733-3756.
[6]Mofijur M,Masjuki H H,Kalam M A,et al.Properties and use of Moringa oleifera,biodiesel and diesel fuel blends in a multi-cylinder diesel engine[J].Energy Conversion&Management,2014,82(6):169-176.
[7]Mofijur M,Masjuki H H,Kalam M A,et al.Prospects of biodiesel from Jatropha in Malaysia[J].Renewable&Sustainable Energy Reviews,2012,16(7):5007-5020.
[8]S.S.Zhao,Y.X.Liu,M.C.Li,C.Sun,M.X.Zhou,H.X.Zhang,Analysis of Jiangsu tidal flats reclamation from 1974 to 2012 using remote sensing[J].China Ocean Eng.,2015,29:143-154.
[9]杨庆利,朱凤,张初署,等.盐地碱蓬油制备生物柴油工艺条件研究[J].现代化工,2008,28(s2):43-46.
[10]Wang L,Weller C L.Recent advances in extraction of nutraceuticals from plants[J].Trends in Food Science&Technology,2006,17(6):300-312.
[11]Gibbins R D,Aksoy H A,Ustun G.Enzyme-assisted aqueous extraction of safflower oil:optimisation by response surface methodology[J].International Journal of Food Science&Technology,2012,47(5):1055-1062.
[12]张爱军,沈继红,石书河.碱蓬籽油萃取和精炼中试研究[J].中国油脂,2005,30(1):57-58.
[13]牟书勇,程争鸣,包群,等.GC/MS法分析囊果碱蓬种子油中脂肪酸组成[J].干旱区研究,2006,23(3):475-477.
[14]李洪山,范艳霞.盐地碱蓬籽油的提取及特性分析[J].中国油脂,2010,35(1):74-76.
[15]柳仁民,张坤.碱蓬籽油的超临界CO2流体萃取及其GC/MS分析[J].中国油脂,2003,28(2):42-45.
[16]陈然然,邵荣,杨剑,等.碱蓬籽油脂的超临界CO2提取工艺优化[J].化学工程师,2015,29(1):61-64.
[17]金丽珠,许伟,邵荣,等.微波法辅助提取碱蓬籽油的工艺研究[J].食品工业科技,2016,37(5):232-237.
[18]Xu W,Ge X D,Yan X H,et al.Optimization of methyl ricinoleate synthesis with ionic liquids as catalysts using the response surface methodology[J].Chemical Engineering Journal,2015,275:63-70.
[19]Chemat S,A?t-Amar H,Lagha A,et al.Microwave-assisted extraction kinetics of terpenes from caraway seeds[J].Chemical Engineering and Processing:Process Intensification,2005,44(12):1320-1326.
[20]杨静,聂炎炎,陈遂,等.响应曲面优化-微波辅助法对葛根中葛根素的提取及测定[J].当代化工,2018,47(1):64-67.
[21]马晓燕.枸杞籽油的超临界萃取及其微胶囊化技术的研究[D].济南:齐鲁工业大学,2014.
[22]王华.超声波法提取长柄扁桃仁油脂的工艺优化[J].当代化工,2018,47(6):1185-1187.
[23]Liu R-L,Song S-H,Wu M,et al.Rapid analysis of fatty acid profiles in raw nuts and seeds by microwave-ultrasonic synergistic in situ extraction-derivatisation and gas chromatography-mass spectrometry[J].Food Chemistry,2013,141:4269-4277.
[24]朱国胜,刘作易,雷邦星,等.温度和高糖驯化对拟青霉3#B产生亚油酸的影响[J].武汉大学学报(理学版),2004,50(S2):67-70.
[25]李波.棉籽油生物柴油制备工艺及燃烧排放特性研究[D].石河子大学,2013.