溶液喷射纺纳米纤维制备技术及其应用进展
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摘要
为进一步推广溶液喷射纺丝技术,并为该技术的研究提供理论与实践参考,综述了国内外溶液喷射纺丝技术的制备机制、基础研究及其纳米纤维应用等方面的研究进展。主要从机制、工艺研究等角度将溶液喷射纺丝技术与熔喷、静电纺丝技术进行对比,溶液纺丝技术具有原料适用性广、生产效率高等特点;从纤维形貌、结构控制等方面,阐述了通过溶液喷射纺丝新工艺开发加工制备具有特殊形态结构的纳米纤维。介绍了溶液喷射纺纳米纤维在医用、过滤、电极、隔膜等材料领域的应用,并对溶液喷射纺丝技术当前发展的不足及未来发展前景进行了总结与展望。
In order to further promote the solution blowing process,and provide valuable theoretical and practical reference to many researchers,preparation mechanisms and fundamental research of solution blowing process and the applications of solution blown nanofibers home and abroad were reviewed. The preparation mechanism and process research of solution blowing process were compared with those of melt blowing and electrospinning,and it is shown that the solution blowing process has the characteristics of wide application and high production efficiency. Furthermore,nanofibers with some special morphological structures could be prepared by the development of novel solution blowing process,which was reviewed based on the perspective of fiber morphology and structure control. Finally,the application prospects of solution blown nanofibers including medical materials,filter materials,electrode materials and diaphragm materials were introduced. Meanwhile,the shortage of current development and the future perspectives for solution blowing process were prospected.
In order to further promote the solution blowing process,and provide valuable theoretical and practical reference to many researchers,preparation mechanisms and fundamental research of solution blowing process and the applications of solution blown nanofibers home and abroad were reviewed. The preparation mechanism and process research of solution blowing process were compared with those of melt blowing and electrospinning,and it is shown that the solution blowing process has the characteristics of wide application and high production efficiency. Furthermore,nanofibers with some special morphological structures could be prepared by the development of novel solution blowing process,which was reviewed based on the perspective of fiber morphology and structure control. Finally,the application prospects of solution blown nanofibers including medical materials,filter materials,electrode materials and diaphragm materials were introduced. Meanwhile,the shortage of current development and the future perspectives for solution blowing process were prospected.
引文
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[6]GUAN Yingshi,QIN Yueke,SUN Yuanhui,et al.Donor-acceptor co-assembled supramolecular nanofibers with high and well-balanced ambipolar charge transport properties under ambient conditions[J].Chemical Communication,2016(52):4648-4651.
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[9]ZHUANG Xupin,YANG Xiaocan,SHI Lei,et al.Solution blowing of submicron-scale cellulose fibers[J].Carbohydrate Polymers,2012,90(2):982-987.
[10]JIA Kaifei,ZHUANG Xupin,CHENG Bowen,et al.Solution blown aligned carbon nanofiber yarn as supercapacitor electrode[J].Journal of Materials Science:Materials in Electronics,2013,24(12):4769-4773.
[11]POLAT Y,PAMPAL E S,STOJANOVSKA E,et al.Solution blowing of thermoplastic polyurethane nanofibers:a facile method to produce flexible porous materials[J].Journal of Applied Polymer Science,2016,133(9):43025.
[12]TUTAK W,SARKAR S,LIN Gibson S,et al.The support of bone marrow stromal cell differentiation by airbrushed nanofiber scaffolds[J].Biomaterials,2013,34(10):2389-2398.
[13]BEHRENS A,LEE N G,CASEY B J,et al.Biodegradable-polymer-blend-based surgical sealant with body-temperature-mediated adhesion[J].Advanced Materials,2015,27(48):8056-8061.
[14]YUAN S,LI Z,SONG L,SHI H,et al.Liquid-Infused poly(styrene-b-isobutylene-b-styrene)microfiber coating prevents bacterial attachment and thrombosis[J].ACS Applied Materials&Interfaces,2016,8(33):21214-21220.
[15]HAN W,XIE S,SUN X,et al.Optimization of airflow field via solution blowing for chitosan/PEO nanofiber formation[J].Fibers and Polymers,2017,18(8):1554-1560.
[16]石磊.溶液喷射纳米纤维成形机理及其应用研究[D].天津:天津工业大学,2010:6-26SHI Lei.Study on the forming mechanism and application of solution blown nanofibers[D].Tianjin:Tianjin Polytechnic University,2010:6-26
[17]SINHA Sumit,SINHA Suman,YARIN L,et al.Theoretical and experimental investigation of physical mechanisms responsible for polymer nanofiber formation in solution blowing[J].Polymer,2015,56:452-463.
[18]唐定友.感应静电辅助溶液喷射纺丝技术及纳米纤维应用研究[D].天津:天津工业大学,2015:4-15.TANG Dingyou.Study on the generation and applications of nanofibers via electrostatic-inductionassisted solution blow spinning[D].Tianjin:Tianjin Polytechnic University,2015:4-15.
[19]GRASSLEY W.Polymer chain dimensions and the dependence of viscoelastic properties on concentration,molecular weight and solvent power[J].Polymer,1980,21(3):258-262.
[20]FLORY P,VOLKENSTEIN M.Statistical mechanics of chain molecules[J].Biopolymers,1969,23(5):699-700.
[21]SRINIVASAN Siddarth,CHHATRE Shreerang S,MABRY Joseph M.Solution spraying of poly(methyl meth-acrylate)blends to fabricate microtextured,superoleophobic surfaces[J].Polymer,2011,14(52):3209-3218.
[22]ZHUANG X,SHI L,ZHANG B,et al.Coaxial solution blown core-shell structure nanofibers for drug delivery[J].Macromolecular Research,2013,21(4):346-348.
[23]BENAVIDES R E,JANA S C,RENEKER D H.Role of liquid jet stretching and bending instability in nanofiber formation by gas jet method[J].Macromolecules,2013,46(15):6081-6090.
[24]LIANG F,FANG F,ZENG J,et al.Fabrication of three-dimensional micro-nanofiber structures by a novel solution blow spinning device[J].AIP Advances,2017,7(2):25002.
[25]焦晓宁,庄旭品,程博闻,等.一种聚合物纳微纤维非织造布的制备方法.201110041792.3[P]:2011-05-25.JIAO Xiaoning,ZHUANG Xupin,CHENG Bowen,et al.A preparation method of polymer nano/micro fiber nonwovens.201110041792.3[P]:2011-05-25.
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