镨(Ⅲ)、镝(Ⅲ)与1,6-双(苯并三氮唑)己烷配合物的抑菌性研究
|
摘要
采用传统回流法,以苯并三氮唑和1,6-二溴己烷为原料,合成了1,6-双(苯并三氮唑)己烷化合物.以自制的1,6-双(苯并三氮唑)己烷作为配体,分别与Pr(NO3)3·6H2O和Dy(NO3)3·5H2O采用溶剂挥发法合成了两种稀土金属配合物,通过红外光谱和热重分析等手段对所合成的配合物进行了性能表征.还利用菌落直径法研究了配体及其配合物对腐皮镰刀真菌生长的抑制作用,结果表明配体及其配合物都具有抑菌性,且配合物的抑菌活性强于配体.
This experiment,using benzotriazole and 1,6-dibromohexane as raw material,under reflux method produces 1,6-bis(benzotriazole)hexane.The self-assembly of Pr(NO3)3·6H2O or Dy(NO3)3·5H2O with 1,6-bis(benzotriazole)hexane ligand by slow evaporation at room temperature produces two rare earth complexes,which are characterized by IR and TGA.Furthermore,the antibacterial activity of ligand and their complexes on the growth of fusarium solani have been studied using the colony diameter method.The results show that they all have antimicrobial properties,and complexes have relatively better antibacterial activity than the ligand.
This experiment,using benzotriazole and 1,6-dibromohexane as raw material,under reflux method produces 1,6-bis(benzotriazole)hexane.The self-assembly of Pr(NO3)3·6H2O or Dy(NO3)3·5H2O with 1,6-bis(benzotriazole)hexane ligand by slow evaporation at room temperature produces two rare earth complexes,which are characterized by IR and TGA.Furthermore,the antibacterial activity of ligand and their complexes on the growth of fusarium solani have been studied using the colony diameter method.The results show that they all have antimicrobial properties,and complexes have relatively better antibacterial activity than the ligand.
引文
[1]何跃君,薛立.稀土元素对植物的生物效应及其作用机理[J].应用生态学报,2005,16(10):1983-1989.
[2]张健,郑长征,张利勤,等.酰腙类化合物及其稀土金属配合物的研究进展[J].化工技术与开发,2011,40(1):23-27.
[3]赵国良,李彬,那崇武,等.稀土与邻香兰素二胺类双Schiff碱配合物合成及其性质的研究[J].化学学报,1991,49(4):365-370.
[4]姚克敏,李冬成,沈联芳,等.镧系与邻氨基苯甲酸型Schiff配合物的合成、表征及催化活性[J].化学学报,1993,51(7):677-682.
[5]杨锐,何水样,武望婷,等.镝(Ⅲ)与酰腙及1,10-菲啰啉多元配合物的晶体结构及荧光性质[J].化学学报,2004,62(20):2040-2044.
[6]刘建风,陈吉妃,赵国良.基于对羟基苯乙酸及邻菲咯啉的稀土配合物的合成、晶体结构和荧光光谱[J].无机化学学报,2011,27(1):100-106.
[7]单凝,王彬彬,连文慧,等.稀土金属尾式组氨酸卟啉配合物的合成及光电性质[J].高等学校化学学报,2012,33(8):1651-1656.
[8]王新苗,吴威平,蒋亚辉.六例2-氟异烟酸稀土配位聚合物的合成、晶体结构及其荧光和磁学性质研究[J].无机化学学报,2014,30(1):192-203.
[9]李佳佳,李睿,马雪,等.2-磺酸对苯二甲酸铕配合物的发光性质及对苯甲醛的检测[J].光谱学与光谱分析,2016,36(2):345-368.
[10]黄远,王书改,李雯雯,等.多酸基金属——有机框架的构筑及其催化性能[J].化学研究,2016,27(1):62-68.
[11]那立艳,张丽影,张伟,等.稀土金属有机配位聚合物的绿色合成及发光性能[J].材料导报,2015,29(9):28-31.
[12]HOU H W,MENG X R,SONG Y L,et al.TwoDimensional Rhombohedral Grid Coordination Polymers[M(bbbt)2(NCS)2]n(M=Co,Mn,or Cd;bbbt=1,1′-(1,4-butanediyl)bis-1H-benzotriazole):Synthesis,Crystal Structures,and Third-Order Nonlinear Optical Properties[J].Inorg Chem,2002,41:4068-4075.
[13]MENG X R,SONG Y L,HOU H W,et al.Novel Pb and Zn Coordination Polymers:Synthesis,Molecular Structures,and Third-Order Nonlinear Optical Properties[J].Inorg Chem,2003,42:1306-1315.
[14]ZHOU J H,PENG Y F,ZHANG Y P,et al.Synthesis,Crystal Structure and Luminescent Properties of a Novel Cadmium Coordination Polymer with Unprecedented One-Dimensional Hetero-TripleStranded Chain[J].Inorg Chem Commun,2004,7:1181-1183.
[15]BRSTING P,STEEL P J.Synthesis and X-ray Crystal Structures of Cobalt and Copper Complexes of 1,3-Bis(benzotriazolyl)propanes[J].Eur J Inorg Chem,2004,2004(2):376-380.
[16]ZHOU J H,LIU X G,ZHANG Y P,et al.Synthesis,Structures and Luminescent Properties of Two Silver Supramolecular Isomers with One-Dimensional Concavo-Convex Chain and Dimer Metallacycle[J].Inorg Chem Commun,2006,9:216-219.
[17]ZHOU X L,MENG X R,CHENG W,et al.Crystal Structural,Electrochemical and Computational Studies of Two Cu(II)Complexes Formed by Benzotriazole Derivatives[J].Inorg Chim Acta,2007,360:3467-3474.
[18]MENG X R,LI J P,HOU H W,et al.Double Helix Chain Frameworks Constructed from Bis-Benzotriazole Building Blocks:Syntheses,Crystal Structures and Third-Order Nonlinear Optical Properties[J].J Mol Struct,2008,891:305-311.
[19]GAO X,ZHAI Q G,DUI X J,et al.Synthesis,Crystal Structure,and Characterizations of a 3DCu(I)Organic-Inorganic Hybrid Solid with 1,6-Bi(benzotriazole)hexane Ligand[J].J Coord Chem,2010,63:214-222.
[20]HU M C,WANG Y,ZHAI Q G,et al.Synthesis,Crystal Structures,and Photoluminescence Properties of the Cu(I)/X/α,ω-Bis(benzotriazole)alkane Hybrid Family(X=Cl,Br,I,and CN)[J].Inorg Chem,2009,8:1449-1468.
[21]GAO X,ZHAI Q G,LI S N,et al.Two Anionic[CuI6X7]nn-(X=Br and I)Chain-Based OrganicInorganic Hybrid Solids with N-substituted Benzotriazole Ligands[J].J Solid State Chem,2010,183:1150-1158.
[22]高霞,张国春.1,5-双(苯并三氮唑)戊烷的合成和抑菌性研究[J].陕西科技大学学报,2016,34(2),107-111.
[2]张健,郑长征,张利勤,等.酰腙类化合物及其稀土金属配合物的研究进展[J].化工技术与开发,2011,40(1):23-27.
[3]赵国良,李彬,那崇武,等.稀土与邻香兰素二胺类双Schiff碱配合物合成及其性质的研究[J].化学学报,1991,49(4):365-370.
[4]姚克敏,李冬成,沈联芳,等.镧系与邻氨基苯甲酸型Schiff配合物的合成、表征及催化活性[J].化学学报,1993,51(7):677-682.
[5]杨锐,何水样,武望婷,等.镝(Ⅲ)与酰腙及1,10-菲啰啉多元配合物的晶体结构及荧光性质[J].化学学报,2004,62(20):2040-2044.
[6]刘建风,陈吉妃,赵国良.基于对羟基苯乙酸及邻菲咯啉的稀土配合物的合成、晶体结构和荧光光谱[J].无机化学学报,2011,27(1):100-106.
[7]单凝,王彬彬,连文慧,等.稀土金属尾式组氨酸卟啉配合物的合成及光电性质[J].高等学校化学学报,2012,33(8):1651-1656.
[8]王新苗,吴威平,蒋亚辉.六例2-氟异烟酸稀土配位聚合物的合成、晶体结构及其荧光和磁学性质研究[J].无机化学学报,2014,30(1):192-203.
[9]李佳佳,李睿,马雪,等.2-磺酸对苯二甲酸铕配合物的发光性质及对苯甲醛的检测[J].光谱学与光谱分析,2016,36(2):345-368.
[10]黄远,王书改,李雯雯,等.多酸基金属——有机框架的构筑及其催化性能[J].化学研究,2016,27(1):62-68.
[11]那立艳,张丽影,张伟,等.稀土金属有机配位聚合物的绿色合成及发光性能[J].材料导报,2015,29(9):28-31.
[12]HOU H W,MENG X R,SONG Y L,et al.TwoDimensional Rhombohedral Grid Coordination Polymers[M(bbbt)2(NCS)2]n(M=Co,Mn,or Cd;bbbt=1,1′-(1,4-butanediyl)bis-1H-benzotriazole):Synthesis,Crystal Structures,and Third-Order Nonlinear Optical Properties[J].Inorg Chem,2002,41:4068-4075.
[13]MENG X R,SONG Y L,HOU H W,et al.Novel Pb and Zn Coordination Polymers:Synthesis,Molecular Structures,and Third-Order Nonlinear Optical Properties[J].Inorg Chem,2003,42:1306-1315.
[14]ZHOU J H,PENG Y F,ZHANG Y P,et al.Synthesis,Crystal Structure and Luminescent Properties of a Novel Cadmium Coordination Polymer with Unprecedented One-Dimensional Hetero-TripleStranded Chain[J].Inorg Chem Commun,2004,7:1181-1183.
[15]BRSTING P,STEEL P J.Synthesis and X-ray Crystal Structures of Cobalt and Copper Complexes of 1,3-Bis(benzotriazolyl)propanes[J].Eur J Inorg Chem,2004,2004(2):376-380.
[16]ZHOU J H,LIU X G,ZHANG Y P,et al.Synthesis,Structures and Luminescent Properties of Two Silver Supramolecular Isomers with One-Dimensional Concavo-Convex Chain and Dimer Metallacycle[J].Inorg Chem Commun,2006,9:216-219.
[17]ZHOU X L,MENG X R,CHENG W,et al.Crystal Structural,Electrochemical and Computational Studies of Two Cu(II)Complexes Formed by Benzotriazole Derivatives[J].Inorg Chim Acta,2007,360:3467-3474.
[18]MENG X R,LI J P,HOU H W,et al.Double Helix Chain Frameworks Constructed from Bis-Benzotriazole Building Blocks:Syntheses,Crystal Structures and Third-Order Nonlinear Optical Properties[J].J Mol Struct,2008,891:305-311.
[19]GAO X,ZHAI Q G,DUI X J,et al.Synthesis,Crystal Structure,and Characterizations of a 3DCu(I)Organic-Inorganic Hybrid Solid with 1,6-Bi(benzotriazole)hexane Ligand[J].J Coord Chem,2010,63:214-222.
[20]HU M C,WANG Y,ZHAI Q G,et al.Synthesis,Crystal Structures,and Photoluminescence Properties of the Cu(I)/X/α,ω-Bis(benzotriazole)alkane Hybrid Family(X=Cl,Br,I,and CN)[J].Inorg Chem,2009,8:1449-1468.
[21]GAO X,ZHAI Q G,LI S N,et al.Two Anionic[CuI6X7]nn-(X=Br and I)Chain-Based OrganicInorganic Hybrid Solids with N-substituted Benzotriazole Ligands[J].J Solid State Chem,2010,183:1150-1158.
[22]高霞,张国春.1,5-双(苯并三氮唑)戊烷的合成和抑菌性研究[J].陕西科技大学学报,2016,34(2),107-111.