铜尾矿在水泥基材料中应用的研究进展
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摘要
综述了铜尾矿的物理、化学性质,对铜尾矿在水泥基材料中的应用进行了分析与展望。铜尾矿含有丰富的矿物成分,可作为矿化剂、铁质原料、代替粘土生产水泥熟料,铜尾矿可降低水泥熟料烧成温度,提高熟料质量和产量。铜尾矿具有与火山灰质材料相似的矿物物相,用作混合材可降低水泥生产成本。铜尾矿作为细集料或掺合料用于混凝土,具有较好的强度特性和耐久性能。利用铜尾矿制备加气混凝土、蒸压灰砂砖、蒸养标准砖等新型墙体材料,可节约大量能源与资源。
The physical and chemical properties of copper tailing were introduced,as well as the application of copper tailing in cement-based materials was analyzed and prospected. Copper tailing contains rich mineral compositions,which can be used as mineralizer,iron raw materials and clay replacement of cement clinker production. Copper tailing can reduce sintering temperature of cement clinker,and improve its quality and output. Copper tailing has similar mineral properties to pozzolanic materials,which can reduce the cost of cement production as mineral admixture. When taking copper tailing as fine aggregate or admixtures in concrete, which has better strength characteristics and durability. It can save a lot of energy and resources to take copper tailings to prepare new wall materials such as aerated concrete,autoclaved sand-line brick and steamed standard brick.
The physical and chemical properties of copper tailing were introduced,as well as the application of copper tailing in cement-based materials was analyzed and prospected. Copper tailing contains rich mineral compositions,which can be used as mineralizer,iron raw materials and clay replacement of cement clinker production. Copper tailing can reduce sintering temperature of cement clinker,and improve its quality and output. Copper tailing has similar mineral properties to pozzolanic materials,which can reduce the cost of cement production as mineral admixture. When taking copper tailing as fine aggregate or admixtures in concrete, which has better strength characteristics and durability. It can save a lot of energy and resources to take copper tailings to prepare new wall materials such as aerated concrete,autoclaved sand-line brick and steamed standard brick.
引文
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[6] Rico M,Benito G,Salgueiro A R,et al. Reported tailings dam failures. a review of the european incidents in the world wide context[J]. Journal of Hazardous Materials,2008,152(2):846-852.
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[8]徐飞,褚洪涛,刘晓亮.某铜矿全尾砂充填体强度研究[J].金属矿山,2013,42(12):37-39.
[9]兰青,马洪坤,沈卫国,等.尾矿混合砂混凝土的性能研究[J].武汉理工大学学报,2012,34(12):19-23.
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[11] Lam E J,Gálvez M E,Cánovas M,et al. Evaluation of metal mobility from copper mine tailings in northern chile[J]. Environmental Science and Pollution Research,2016,23(12):11901-11915.
[12] Zheng J R,Zhu Y L,Zhao Z B. Utilization of limestone powder and water-reducing admixture in cemented paste backfill of coarse copper mine tailings[J]. Construction and Building Materials,2016,124:31-36.
[13] Lv C,Wen S M,Bai S J,et al. Recovery Cu from a copper oxide ore by flotation and leaching[J]. Applied Mechanics and Materials,2014,522-524:1484-1487.
[14]周婷婷,张长森,魏宁,等.铜尾渣替代粘土制备水泥熟料的试验研究[J].硅酸盐通报,2014,33(3):691-696.
[15]施正伦,骆仲泱,林细光,等.尾矿作水泥矿化剂和铁质原料的试验研究[J].浙江大学学报(工学版),2008,42(3):506-510.
[16] Oluwasola E A,Hainin M R,Aziz M M A. Evaluation of asphalt mixtures incorporating electric arc furnace steel slag and copper mine tailings forroad construction[J]. Construction and Building Material,2013,49(6):611-617.
[17] Thomas B S,Damare A,Gupta R C. Strength and durability characteristics of copper tailing concrete[J]. Construction and Building Materials,2013,48(11):894-900.
[18] Ahmari S,Zhang L Y. Production of eco-friendly bricks from copper mine tailings through geopolymerization[J]. Construction and Building Materials,2012,29(4):323-331.
[19]赵晶,郑秀华,彭永恒.铜尾矿煅烧水泥的试验研究[J].哈尔滨建筑大学学报,1996(6):75-78.
[20]饶春如,肖国先,郜志海,等.铜尾矿替代粘土煅烧硅酸盐水泥熟料的研究[J].苏州科技学院学报(工程技术版),2009,22(4):37-40.
[21] Onuaguluchi O,ErenO. Recycling of copper tailings as an additive in cement mortars[J]. Construction and Building Materials,2012,37(12):723-727.
[22] Onuaguluchi O,ErenO. Rheology,strength and durability properties of mortars containing copper tailings as a cement replacement material[J].European Journal of Environmental and Civil Engineering,2013,17(1):19-31.
[23]林细光.铜铅锌尾矿应用于水泥原料的试验研究[D].杭州:浙江大学,2006.
[24] Kolovos K,Loutsi P,Tsivilis S,et,al. The effect of foreign ions on the reactivity of the CaO-SiO2-Al2O3-Fe2O3system part I anions[J]. Cement and Concrete Research,2001,31(3):425-429.
[25] Kolovos K,Tsivilis S,Kakali G. The effect of foreign ions on the reactivity of the CaO-SiO2-Al2O3-Fe2O3system part II anions[J]. Cement and Concrete Research,2002,32(3):463-469.
[26] Qiu G H,Luo Z Y,Shi Z L,et al. Utilization of coal gangue and copper tailings as clay for cement clinker calcinations[J]. Journal of Wuhan University of Technology-Materials Science Edition,2011,26(6):1205-1210.
[27]郑秀华,赵晶,王金忠.铜尾矿对水泥生料易烧性及水泥强度的影响[J].房材与应用,1999(2):8-9,15.
[28]奚新国,张长森,周婷婷,等.铜尾渣对水泥生料易烧性及熟料性能的影响[J].建筑材料学报,2014,17(6):1102-1107,1114.
[29]唐达高.铜尾矿在水泥生产中的应用研究[J].中国资源综合利用,2005(10):17-20.
[30]王志强,吕宪俊,褚会超,等.尾矿的火山灰活性及其在水泥混合材料中的应用[J].硅酸盐通报,2017,36(1):97-103.
[31] Cheng Y H,Huang F,Li W C,et al. Test research on the effects of mechanochemically activated iron tailings on the compressive strength of concrete[J]. Construction and Building Materials,2016,118:164-170.
[32] Souri A,Kazemi-Kamyab H,Snellings R,et al. Pozzolanic activity of mechanochemically and thermally activated kaolins in cement[J]. Cement and Concrete Research,2015,77:47-59.
[33]倪明江,焦有宙,骆仲泱,等.金属尾矿作水泥混合材活性试验研究[J].环境科学学报,2007,27(5):868-872.
[34]许小荣,张月.铜尾矿作混合材在水泥生产中的应用[J].青海科技,2001,8(4):36-37.
[35]刘数华,严军伟,邢婕,等.矿物掺合料对水泥石抗酸性侵蚀性能的影响[J].混凝土与水泥制品,2012(6):19-21.
[36]宋军伟,方坤河,朱街禄,等.铜矿渣混凝土强度与脆性试验研究[J].武汉理工大学学报,2013,35(10):33-37.
[37]朱街禄,宋军伟,王露,等.铜矿渣在水泥混凝土应用的研究进展[J].硅酸盐通报,2017,36(11):3676-3682.
[38] Gupta R C,Mehra P,Thomas B S. Utilization of copper tailing in developing sustainable and durable concrete[J]. Journal of Materials in Civil Engineering,2016,29(5):04016274.
[39] Onuaguluchi O,ErenO. Copper tailings as a potential additive in concrete:consistency,strength and toxic metal immobilization properties[J].Indian Journal of Engineering and Materials Sciences,2012,19(2):79-86.
[40] Kundu S,Aggarwal A,Mazumdar S,et al. Stabilization characteristics of copper mine tailings through its utilization as a partial substitute for cement in concrete:preliminary investigations[J]. Environmental Earth Sciences,2016,75(3):1-9.
[41]邹先杰,刘道斌,卢自立,等.机制砂-铜尾矿复合砂商品混凝土性能研究[J].武汉理工大学学报,2014,36(12):27-31.
[42]朱永祥,林祖宏,梁冠军.铜矿尾砂绿色混凝土的力学性能及耐久性试验研究[J].延安大学学报(自然科学版),2014(4):31-35.
[43] Onuaguluchi O,ErenO. Durability-related properties of mortar and concrete containing copper tailings as a cement replacement material[J].Magazine of Concrete Research,2012,64(11):1015-1023.
[44]沈荣熹,徐洛屹.中国墙体材料可持续发展技术途径探讨[J].建筑材料学报,2001,4(3):203-210.
[45] Huang X Y,Ni W,Cui W H,et al. Preparation of autoclaved aerated concrete using copper tailings and blast furnace slag[J]. Construction and Building Materials,2012,27(1):1-5.
[46]方永浩,庞二波,王锐,等.用低硅铜尾矿制备蒸压灰砂砖[J].硅酸盐学报,2010,38(4):559-563.
[47]赵风清,倪文,王会君.利用铜尾矿制蒸养标准砖[J].矿业快报,2006,25(4):34-36.
[48] Un8ík S,Struharova A,Hlavinkova M,et al. Effect of bulk density and moisture content on the properties of autoclaved aerated concrete[J].Cement Wapno Beton,2013. 18(4):189-196.
[49]黄晓燕,倪文,王中杰,等.铜尾矿制备无石灰加气混凝土的试验研究[J].材料科学与工艺,2012,20(1):11-15.
[50]钱嘉伟,倪文,许国东,等.天然石膏对铜尾矿加气混凝土强度的影响研究[J].硅酸盐通报,2013,32(1):117-120,125.
[51] Zhao F Q,Zhao J,Liu H J. Autoclaved brick from low-silicon tailings[J]. Construction and Building Materials,2009,23(1):538-541.
[52] Fang Y H,Gu Y M,Kang Q B,et al. Utilization of copper tailing for autoclaved sand-lime brick[J]. Construction and Building Materials,2011,25(2):867-872.
[2]余良晖,贾文龙,薛亚洲.我国铜尾矿资源调查分析[J].金属矿山,2009,39(8):179-181.
[3] Jia T,Cao M W,Jing J H,et al. Endophytic fungi and soil microbial community characteristics over different years of phytoremediation in a copper tailings dam of Shanxi,China[J]. Science of the Total Environment,2017,574:881-888.
[4] Guo Y G,Huang P,Zhang W G,et al. Leaching of heavy metals from dexing copper mine tailings pond[J]. Transactions of Nonferrous Metals Society of China,2013,23(10):3068-3075.
[5] Shen Z J,Wang Y P,Chen Y S,et al. Transfer of heavy metals from the polluted rhizosphere soil to celosia argentea L. in copper mine tailings[J].Horticulture,Environment,and Biotechnology,2017,58(1):93-100.
[6] Rico M,Benito G,Salgueiro A R,et al. Reported tailings dam failures. a review of the european incidents in the world wide context[J]. Journal of Hazardous Materials,2008,152(2):846-852.
[7]杜淑华.铜尾矿有价元素资源化应用基础研究[D].北京:中国矿业大学,2013.
[8]徐飞,褚洪涛,刘晓亮.某铜矿全尾砂充填体强度研究[J].金属矿山,2013,42(12):37-39.
[9]兰青,马洪坤,沈卫国,等.尾矿混合砂混凝土的性能研究[J].武汉理工大学学报,2012,34(12):19-23.
[10]潘含江,程志中,杨榕,等.德兴铜矿尾矿地球化学特征[J].物探与化探,2013,37(4):627-632.
[11] Lam E J,Gálvez M E,Cánovas M,et al. Evaluation of metal mobility from copper mine tailings in northern chile[J]. Environmental Science and Pollution Research,2016,23(12):11901-11915.
[12] Zheng J R,Zhu Y L,Zhao Z B. Utilization of limestone powder and water-reducing admixture in cemented paste backfill of coarse copper mine tailings[J]. Construction and Building Materials,2016,124:31-36.
[13] Lv C,Wen S M,Bai S J,et al. Recovery Cu from a copper oxide ore by flotation and leaching[J]. Applied Mechanics and Materials,2014,522-524:1484-1487.
[14]周婷婷,张长森,魏宁,等.铜尾渣替代粘土制备水泥熟料的试验研究[J].硅酸盐通报,2014,33(3):691-696.
[15]施正伦,骆仲泱,林细光,等.尾矿作水泥矿化剂和铁质原料的试验研究[J].浙江大学学报(工学版),2008,42(3):506-510.
[16] Oluwasola E A,Hainin M R,Aziz M M A. Evaluation of asphalt mixtures incorporating electric arc furnace steel slag and copper mine tailings forroad construction[J]. Construction and Building Material,2013,49(6):611-617.
[17] Thomas B S,Damare A,Gupta R C. Strength and durability characteristics of copper tailing concrete[J]. Construction and Building Materials,2013,48(11):894-900.
[18] Ahmari S,Zhang L Y. Production of eco-friendly bricks from copper mine tailings through geopolymerization[J]. Construction and Building Materials,2012,29(4):323-331.
[19]赵晶,郑秀华,彭永恒.铜尾矿煅烧水泥的试验研究[J].哈尔滨建筑大学学报,1996(6):75-78.
[20]饶春如,肖国先,郜志海,等.铜尾矿替代粘土煅烧硅酸盐水泥熟料的研究[J].苏州科技学院学报(工程技术版),2009,22(4):37-40.
[21] Onuaguluchi O,ErenO. Recycling of copper tailings as an additive in cement mortars[J]. Construction and Building Materials,2012,37(12):723-727.
[22] Onuaguluchi O,ErenO. Rheology,strength and durability properties of mortars containing copper tailings as a cement replacement material[J].European Journal of Environmental and Civil Engineering,2013,17(1):19-31.
[23]林细光.铜铅锌尾矿应用于水泥原料的试验研究[D].杭州:浙江大学,2006.
[24] Kolovos K,Loutsi P,Tsivilis S,et,al. The effect of foreign ions on the reactivity of the CaO-SiO2-Al2O3-Fe2O3system part I anions[J]. Cement and Concrete Research,2001,31(3):425-429.
[25] Kolovos K,Tsivilis S,Kakali G. The effect of foreign ions on the reactivity of the CaO-SiO2-Al2O3-Fe2O3system part II anions[J]. Cement and Concrete Research,2002,32(3):463-469.
[26] Qiu G H,Luo Z Y,Shi Z L,et al. Utilization of coal gangue and copper tailings as clay for cement clinker calcinations[J]. Journal of Wuhan University of Technology-Materials Science Edition,2011,26(6):1205-1210.
[27]郑秀华,赵晶,王金忠.铜尾矿对水泥生料易烧性及水泥强度的影响[J].房材与应用,1999(2):8-9,15.
[28]奚新国,张长森,周婷婷,等.铜尾渣对水泥生料易烧性及熟料性能的影响[J].建筑材料学报,2014,17(6):1102-1107,1114.
[29]唐达高.铜尾矿在水泥生产中的应用研究[J].中国资源综合利用,2005(10):17-20.
[30]王志强,吕宪俊,褚会超,等.尾矿的火山灰活性及其在水泥混合材料中的应用[J].硅酸盐通报,2017,36(1):97-103.
[31] Cheng Y H,Huang F,Li W C,et al. Test research on the effects of mechanochemically activated iron tailings on the compressive strength of concrete[J]. Construction and Building Materials,2016,118:164-170.
[32] Souri A,Kazemi-Kamyab H,Snellings R,et al. Pozzolanic activity of mechanochemically and thermally activated kaolins in cement[J]. Cement and Concrete Research,2015,77:47-59.
[33]倪明江,焦有宙,骆仲泱,等.金属尾矿作水泥混合材活性试验研究[J].环境科学学报,2007,27(5):868-872.
[34]许小荣,张月.铜尾矿作混合材在水泥生产中的应用[J].青海科技,2001,8(4):36-37.
[35]刘数华,严军伟,邢婕,等.矿物掺合料对水泥石抗酸性侵蚀性能的影响[J].混凝土与水泥制品,2012(6):19-21.
[36]宋军伟,方坤河,朱街禄,等.铜矿渣混凝土强度与脆性试验研究[J].武汉理工大学学报,2013,35(10):33-37.
[37]朱街禄,宋军伟,王露,等.铜矿渣在水泥混凝土应用的研究进展[J].硅酸盐通报,2017,36(11):3676-3682.
[38] Gupta R C,Mehra P,Thomas B S. Utilization of copper tailing in developing sustainable and durable concrete[J]. Journal of Materials in Civil Engineering,2016,29(5):04016274.
[39] Onuaguluchi O,ErenO. Copper tailings as a potential additive in concrete:consistency,strength and toxic metal immobilization properties[J].Indian Journal of Engineering and Materials Sciences,2012,19(2):79-86.
[40] Kundu S,Aggarwal A,Mazumdar S,et al. Stabilization characteristics of copper mine tailings through its utilization as a partial substitute for cement in concrete:preliminary investigations[J]. Environmental Earth Sciences,2016,75(3):1-9.
[41]邹先杰,刘道斌,卢自立,等.机制砂-铜尾矿复合砂商品混凝土性能研究[J].武汉理工大学学报,2014,36(12):27-31.
[42]朱永祥,林祖宏,梁冠军.铜矿尾砂绿色混凝土的力学性能及耐久性试验研究[J].延安大学学报(自然科学版),2014(4):31-35.
[43] Onuaguluchi O,ErenO. Durability-related properties of mortar and concrete containing copper tailings as a cement replacement material[J].Magazine of Concrete Research,2012,64(11):1015-1023.
[44]沈荣熹,徐洛屹.中国墙体材料可持续发展技术途径探讨[J].建筑材料学报,2001,4(3):203-210.
[45] Huang X Y,Ni W,Cui W H,et al. Preparation of autoclaved aerated concrete using copper tailings and blast furnace slag[J]. Construction and Building Materials,2012,27(1):1-5.
[46]方永浩,庞二波,王锐,等.用低硅铜尾矿制备蒸压灰砂砖[J].硅酸盐学报,2010,38(4):559-563.
[47]赵风清,倪文,王会君.利用铜尾矿制蒸养标准砖[J].矿业快报,2006,25(4):34-36.
[48] Un8ík S,Struharova A,Hlavinkova M,et al. Effect of bulk density and moisture content on the properties of autoclaved aerated concrete[J].Cement Wapno Beton,2013. 18(4):189-196.
[49]黄晓燕,倪文,王中杰,等.铜尾矿制备无石灰加气混凝土的试验研究[J].材料科学与工艺,2012,20(1):11-15.
[50]钱嘉伟,倪文,许国东,等.天然石膏对铜尾矿加气混凝土强度的影响研究[J].硅酸盐通报,2013,32(1):117-120,125.
[51] Zhao F Q,Zhao J,Liu H J. Autoclaved brick from low-silicon tailings[J]. Construction and Building Materials,2009,23(1):538-541.
[52] Fang Y H,Gu Y M,Kang Q B,et al. Utilization of copper tailing for autoclaved sand-lime brick[J]. Construction and Building Materials,2011,25(2):867-872.