摘要
联合超声波破解技术、好氧堆肥技术及蚯蚓处理技术,对污水处理厂剩余污泥进行处理,探讨超声波预处理对污泥蚯蚓堆肥有机质降解和重金属的影响.结果表明:超声波预处理技术对污泥腐殖化程度表现出协同效应,最优TOC反应动力学常数为0.0084d~(-1),是对照组的2.1倍;胡敏酸和HA/FA平均增长率分别为97.4%和191.5%,是对照组的1.26倍和1.37倍;可轻度减少污泥堆体重金属含量,同时对蚯蚓处理阶段重金属富集存在缓减效应,但对各阶段重金属形态影响不显著;蚯蚓处理可明显降低重金属生物有效性,至处理结束Zn、Cu、Pb、Ni、Cd、Cr、Hg、As非稳定态平均占比较好氧堆肥结束时下降28.3%、29.5%、29.1%、35.2%、3.3%、25.3%、36.4%、21.9%.
The combination of technologies including ultrasonic disintegration, aerobic composting and earthworm treatment was used to dispose the residual sludge of wastewater treatment plant in order to evaluate the effect of ultrasonic pretreatment on the degradation of organic matter and heavy metals. The results showed that the ultrasonic pretreatment technology had synergistic effect on the degree of sludge humification. The optimal TOC value of kinetic constant was 0.0084 d~(-1), which was 2.1 times higher than that of the control group. The average growth rates of humic acid and HA/FA were 97.4% and 191.5%, respectively, which were 1.26 and1.37 times higher than that of the control group. Meanwhile, it has a mitigating effect on the heavy metals accumulation in earthworm treatment stage and no significant effect on the heavy metals speciation in other stages. At the end of vermicomposting,the average proportion of non-steady state of heavy metals(Zn, Cu, Pb, Ni, Cd, Cr, Hg, As) decreased by 28.3%, 29.5%, 29.1%,35.2%, 3.3%, 25.3%, 36.4%, 21.9% compared with at the end of the aerobic composting stage, respectively.
引文
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