硅氧烷封端聚醚的研究进展
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摘要
综述了硅烷改性聚醚化合物的结构、制备方法、交联固化机理及硅烷改性聚醚密封胶研究进展及其在装配式建筑、土木工程及工业领域中的应用,并对硅烷改性聚醚基础聚合物制备路线及硅烷改性聚醚密封胶未来的发展方向进行了展望.
The molecule structure, preparation method and vulcanization mechanism of silane modified polyether compounds, and the research progress of sealants initiated from these compounds were briefly introduced, together with the application of those sealants used in assembly building, civil engineering and other industrial areas. A prospect was provided for synthetic routes of silane modified polyether matrix and the future development of silane modified polyether sealants.
The molecule structure, preparation method and vulcanization mechanism of silane modified polyether compounds, and the research progress of sealants initiated from these compounds were briefly introduced, together with the application of those sealants used in assembly building, civil engineering and other industrial areas. A prospect was provided for synthetic routes of silane modified polyether matrix and the future development of silane modified polyether sealants.
引文
[1] 郭济中.建筑用硅橡胶密封剂的制备与应用[J].中国建材科技,1995,4(6):40-42.
[2] 张同标,倪雅,田明明,等.硅烷改性聚合物密封剂的研究进展[J].化工时刊,2010,24(12):51-55.
[3] FENG T M,WALDMAN B A.Silyated urethane polymer enhance properties of construction sealants[J].Adhesives Age,1995,38(4):30-32.
[4] 陈洋庆,陈建军,龙飞,等.环保型硅烷改性聚醚免钉胶的制备及研究[J].广东化工,2017,44(12):131-132.
[5] 李小童,姜娜,尚丙坤,等.建筑密封胶用有机硅改性聚醚的研究进展[J].聚氨酯工业,2004,19(4):1-4.
[6] HASHIMOTO K,IMAYA K.Silyl-terminated polyethers for sealant use:performance updates[J].Adhesives Age,1998,41(8):18-22.
[7] 张同标,倪雅,李建军,等.硅烷改性聚醚密封剂的制备及应用[J].中国建材科技,2011(1):24-27.
[8] 赵苗,吴玉昆,高之香,等.硅烷改性聚醚密封胶的研究进展[J].粘接,2016(12):59-62.
[9] 孙全吉,赵艳芬,黄艳华,等.端烷氧基有机硅改性聚醚的初步研究[J].粘接,2010(3):30-32.
[10] 李小童.聚醚端烯丙基化及其硅烷化技术研究[D].洛阳:河南科技大学,2004.
[11] TAKASHI W.Curable composition:JP05-059267[P].1991-09-04.
[12] TOSHIHIKO H.Room temperature curing composition:JP07-090170[P].1993-09-22.
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[15] 蔡海涛,赵瑞,王翠花,等.高强度硅烷改性聚醚密封胶的制备及性能研究[J].粘接,2016(8):43-45.
[16] 于美超,章谏正,吴松华,等.硫化条件对聚硫密封胶硫化性能的影响[J].中国胶粘剂,2016,25(7):15-17.
[17] 刘金花,周春艳.快速硫化硬度可调型聚氨酯密封胶的研制[J].中国胶粘剂,2010,19(7):42-44.
[18] 何业明,张银华,苏少军.高强度耐湿热老化室温硫化硅橡胶的研制[J].有机硅材料,2012,26(4):242-247.
[19] 张虎极,王翠花,赵瑞.单组分硅烷改性聚醚密封胶的研制[J].粘接,2011(3):55-57.
[20] 杨静,毛旭华,陈世龙,等.单组分透明型有机硅改性聚醚密封胶的制备[J].中国建筑防水,2011(10):18-21.
[21] 王翠花,刘鹏,赵瑞,等.双组分硅烷改性聚醚密封胶的制备及研究[J].粘接,2014(9):50-52.
[22] HELMUT M.Adhesion promoters[J].Adhesives Age,2000,43(8):28-31.
[23] JOHN F T.Silicon modified polyethers enhance construction sealants[J].Adhesives Age,1991,34(2):26-31.
[24] JOHN F T.Silicon modified polyethers find use as intermediates for adhesives[J].Adhesives Age,1992,35(7):30-33.
[25] 李正梅,钱志国,翟剑峰,等.硅烷改性聚醚密封剂的应用和制备进展[C]//北京粘接学会第二十三届学术年会暨粘接剂、密封剂技术发展研讨会.北京:[s.n.],2014:216-221.
[26] 倪雅,卫丽娟,孟凡浩,等.MS密封剂在钢结构桥梁防护中的应用[J].工业建筑,2010,40(s):832-834.
[27] SONI S S,SASTRY N V,ASWAL V K,et al.Micellar structure of silicone surfactants in water from surface activity,SANS and viscosity studies[J].Journal of Physical Chemistry B,2002,106(10):2606-2617.
[28] SONI S S,SASTRY N V,GEORGE J.Dynamic light scattering and viscosity studies on the association behavior of silicone surfactants in aqueous solutions[J].Journal of Physical Chemistry B,2003,107(22):5382-5390.
[2] 张同标,倪雅,田明明,等.硅烷改性聚合物密封剂的研究进展[J].化工时刊,2010,24(12):51-55.
[3] FENG T M,WALDMAN B A.Silyated urethane polymer enhance properties of construction sealants[J].Adhesives Age,1995,38(4):30-32.
[4] 陈洋庆,陈建军,龙飞,等.环保型硅烷改性聚醚免钉胶的制备及研究[J].广东化工,2017,44(12):131-132.
[5] 李小童,姜娜,尚丙坤,等.建筑密封胶用有机硅改性聚醚的研究进展[J].聚氨酯工业,2004,19(4):1-4.
[6] HASHIMOTO K,IMAYA K.Silyl-terminated polyethers for sealant use:performance updates[J].Adhesives Age,1998,41(8):18-22.
[7] 张同标,倪雅,李建军,等.硅烷改性聚醚密封剂的制备及应用[J].中国建材科技,2011(1):24-27.
[8] 赵苗,吴玉昆,高之香,等.硅烷改性聚醚密封胶的研究进展[J].粘接,2016(12):59-62.
[9] 孙全吉,赵艳芬,黄艳华,等.端烷氧基有机硅改性聚醚的初步研究[J].粘接,2010(3):30-32.
[10] 李小童.聚醚端烯丙基化及其硅烷化技术研究[D].洛阳:河南科技大学,2004.
[11] TAKASHI W.Curable composition:JP05-059267[P].1991-09-04.
[12] TOSHIHIKO H.Room temperature curing composition:JP07-090170[P].1993-09-22.
[13] FUJII M.Moisture-curable composition:JP03-195768[P].1989-12-22.
[14] 姚晓宁.SPU密封胶的制备及结构与力学性能关系的研究[D].北京:北京化工大学,2007.
[15] 蔡海涛,赵瑞,王翠花,等.高强度硅烷改性聚醚密封胶的制备及性能研究[J].粘接,2016(8):43-45.
[16] 于美超,章谏正,吴松华,等.硫化条件对聚硫密封胶硫化性能的影响[J].中国胶粘剂,2016,25(7):15-17.
[17] 刘金花,周春艳.快速硫化硬度可调型聚氨酯密封胶的研制[J].中国胶粘剂,2010,19(7):42-44.
[18] 何业明,张银华,苏少军.高强度耐湿热老化室温硫化硅橡胶的研制[J].有机硅材料,2012,26(4):242-247.
[19] 张虎极,王翠花,赵瑞.单组分硅烷改性聚醚密封胶的研制[J].粘接,2011(3):55-57.
[20] 杨静,毛旭华,陈世龙,等.单组分透明型有机硅改性聚醚密封胶的制备[J].中国建筑防水,2011(10):18-21.
[21] 王翠花,刘鹏,赵瑞,等.双组分硅烷改性聚醚密封胶的制备及研究[J].粘接,2014(9):50-52.
[22] HELMUT M.Adhesion promoters[J].Adhesives Age,2000,43(8):28-31.
[23] JOHN F T.Silicon modified polyethers enhance construction sealants[J].Adhesives Age,1991,34(2):26-31.
[24] JOHN F T.Silicon modified polyethers find use as intermediates for adhesives[J].Adhesives Age,1992,35(7):30-33.
[25] 李正梅,钱志国,翟剑峰,等.硅烷改性聚醚密封剂的应用和制备进展[C]//北京粘接学会第二十三届学术年会暨粘接剂、密封剂技术发展研讨会.北京:[s.n.],2014:216-221.
[26] 倪雅,卫丽娟,孟凡浩,等.MS密封剂在钢结构桥梁防护中的应用[J].工业建筑,2010,40(s):832-834.
[27] SONI S S,SASTRY N V,ASWAL V K,et al.Micellar structure of silicone surfactants in water from surface activity,SANS and viscosity studies[J].Journal of Physical Chemistry B,2002,106(10):2606-2617.
[28] SONI S S,SASTRY N V,GEORGE J.Dynamic light scattering and viscosity studies on the association behavior of silicone surfactants in aqueous solutions[J].Journal of Physical Chemistry B,2003,107(22):5382-5390.