石墨烯防腐涂料研究进展
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摘要
介绍了石墨烯的结构、性能及制备方法,概述了石墨烯防腐涂料的防腐机理,并从石墨烯薄膜防腐涂料和石墨烯复合防腐涂料两个方向对石墨烯防腐涂料的研究进展进行论述,同时对石墨烯防腐涂料研究上存在的问题进行总结,并对石墨烯防腐涂料未来发展方向进行了展望。
This review firstly presents a brief description of graphene in terms of the structure, properties and preparation methods, then discusses the anticorrosion mechanism of graphene anticorrosive coating, followed by a detailed discussion on the peculiarity of graphene anticorrosive coatings, such as the single layer graphene anticorrosive coating and graphene composite anticorrosive coating. The existing problems in applications and scientific research areas related with graphene anticorrosive coating have also been summarized. Hopefully, this review will offer a perspective and guidelines for the future research and development of graphene anticorrosive coating.
This review firstly presents a brief description of graphene in terms of the structure, properties and preparation methods, then discusses the anticorrosion mechanism of graphene anticorrosive coating, followed by a detailed discussion on the peculiarity of graphene anticorrosive coatings, such as the single layer graphene anticorrosive coating and graphene composite anticorrosive coating. The existing problems in applications and scientific research areas related with graphene anticorrosive coating have also been summarized. Hopefully, this review will offer a perspective and guidelines for the future research and development of graphene anticorrosive coating.
引文
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[15]Cai Z,Wang S L,Chen L,et al.Progress in graphene/epoxy resin composite coatings[J].Paint Coat.Ind.,2018,48(4):83(才政,王树立,陈磊等.石墨烯/环氧树脂复合涂料研究进展[J].涂料工业,2018,48(4):83)
[16]Chen S S,Brown L,Levendorf M,et al.Oxidation resistance of graphene-coated Cu and Cu/Ni alloy[J].ACS Nano,2011,5:1321
[17]Chi J H,Chen S,Chen X F,et al.Research progress and application of graphene anticorrosive coatings[J].Equip.Environ.Eng.,2018,15(5):56(迟钧瀚,陈珊,陈晓飞等.石墨烯在防腐涂料中的研究进展及应用[J].装备环境工程,2018,15(5):56)
[18]Raman R K S,Banerjee P C,Lobo D E,et al.Protecting copper from electrochemical degradation by graphene coating[J].Carbon,2012,50:4040
[19]Prasai D,Tuberquia J C,Harl R R,et al.Graphene:corrosion-inhibiting coating[J].ACS Nano,2012,6:1102
[20]Mi?kovi?-Stankovi?V,Jevremovi?I,Jung I,et al.Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution[J].Carbon,2014,75:335
[21]Ambrosi A,Pumera M.The structural stability of graphene anticorrosion coating materials is compromised at low potentials[J].Chemistry,2015,21A:7896
[22]Kim H,Kobayashi S,Abdurrahim M A,et al.Graphene/polyethylene nanocomposites:Effect of polyethylene functionalization and blending methods[J].Polymer,2011,52:1837
[23]Zhu D Y,Rong M Z,Zhang M Q.Self-healing polymeric materials based on microencapsulated healing agents:from design to preparation[J].Prog.Polym.Sci.,2015,49/50:175
[24]Zhang K,Zhang L L,Zhao X S,et al.Graphene/polyaniline nanofiber composites as supercapacitor electrodes[J].Chem.Mater.,2010,22:1392
[25]Qiu S H,Liu G,Li W,et al.Noncovalent exfoliation of graphene and its multifunctional composite coating with enhanced anticorrosion and tribological performance[J].J.Alloy.Compd.,2018,747:60
[26]Liu C B,Qiu S H,Du P,et al.An ionic liquid-graphene oxide hybrid nanomaterial:Synthesis and anticorrosive applications[J].Nanoscale,2018,10:8115
[27]Zhou N,Chen H,Ding J H,et al.Efficient dispersion of graphene and its application in anticorrosion coatings[J].China Coat.,2017,32(2):6(周楠,陈浩,丁纪恒等.石墨烯的分散及其在防腐涂层中的应用[J].中国涂料,2017,32(2):6)
[28]Sheng X X,Cai W X,Zhong L,et al.Synthesis of functionalized graphene/polyaniline nanocomposites with effective synergistic reinforcement on anticorrosion[J].Ind.Eng.Chem.Res.,2016,55:8576
[29]Kim S,Le T H,Park C S,et al.A solution-processable,nanostructured,and conductive graphene/polyaniline hybrid coating for metal-corrosion protection and monitoring[J].Sci.Rep.,2017,7:15184
[30]Ramezanzadeh B,Moghadam M H M,Shohani N,et al.Effects of highly crystalline and conductive polyaniline/graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating[J].Chem.Eng.J.,2017,320:363
[31]Ding R,Zheng Y,Yu H B,et al.Study of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings[J].J.Alloy.Compd.,2018,748:481
[32]Liu J R,Liu T,Guo Z W,et al.Promoting barrier performance and cathodic protection of zinc-rich epoxy primer via single-layer graphene[J].Polymers,2018,10:591
[33]Zhang S H,Yang B,Kong G,et al.Research progress of graphenecontaining zinc-rich epoxy coatings[J].Electroplat.Finish.,2018,37:656(张双红,杨波,孔纲等.石墨烯环氧富锌涂层的研究进展[J].电镀与涂饰,2018,37:656)
[2]Sheng Q,Silveira K C D,Tian W,et al.Simultaneous hydrate and corrosion inhibition with modified poly(vinyl caprolactam)polymers[J].Energy Fuels,2017,31:6724
[3]Hayatdavoudi H,Rahsepar M.A mechanistic study of the enhanced cathodic protection performance of graphene-reinforced zinc rich nanocomposite coating for corrosion protection of carbon steel substrate[J].J.Alloy.Compd.,2017,727:1148
[4]Kirkland N T,Schiller T,Medhekar N,et al.Exploring graphene as a corrosion protection barrier[J].Corros.Sci.,2012,56:1
[5]Chang C H,Huang T C,Peng C W,et al.Novel anticorrosion coatings prepared from polyaniline/graphene composites[J].Carbon,2012,50:5044
[6]Berman D,Erdemir A,Sumant A V.Few layer graphene to reduce wear and friction on sliding steel surfaces[J].Carbon,2013,54:454
[7]Zhao S H,Chen Y,Wang S L,et al.Research progress in anti-corrosion coatings containing graphene[J].J.Changzhou Univ.(Nat.Sci.Ed.),2017,29(2):23(赵书华,陈玉,王树立等.石墨烯防腐涂料研究进展[J].常州大学学报(自然科学版),2017,29(2):23)
[8]Luo J,Wang J H,Wen S G,et al.Research progress in graphene for anticorrosive coatings[J].Paint Coat.Ind.,2017,47(11):69(罗健,王继虎,温绍国等.石墨烯在防腐涂料中的研究进展[J].涂料工业,2017,47(11):69)
[9]Geim A K,Novoselov K S.The rise of graphene[J].Nat.Mater.,2007,6:183
[10]Liu Y Q.Graphene:from Basics to Applications[M].Beijing:Chemical Industry Press,2017:6(刘云圻.石墨烯:从基础到应用[M].北京:化学工业出版社,2017:6)
[11]Bolotin K I,Sikes K J,Jiang Z,et al.Ultrahigh electron mobility in suspended graphene[J].Solid State Commun.,2008,146:351
[12]Balandin A A,Ghosh S,Bao W Z,et al.Superior thermal conductivity of single-layer graphene[J].Nano Lett.,2008,8:902
[13]Wang Q H,Wang X J,Fang J J.Application of graphene in epoxy zinc rich primer[J].Paint Coat.Ind.,2016,46(12):42(王清海,王秀娟,方健君.石墨烯在环氧富锌底漆中的应用[J].涂料工业,2016,46(12):42)
[14]Huang G J,Chen Z G,Li M D,et al.Surface functional modification of graphene and graphene oxide[J].Acta Chim.Sin.,2016,74:789(黄国家,陈志刚,李茂东等.石墨烯和氧化石墨烯的表面功能化改性[J].化学学报,2016,74:789)
[15]Cai Z,Wang S L,Chen L,et al.Progress in graphene/epoxy resin composite coatings[J].Paint Coat.Ind.,2018,48(4):83(才政,王树立,陈磊等.石墨烯/环氧树脂复合涂料研究进展[J].涂料工业,2018,48(4):83)
[16]Chen S S,Brown L,Levendorf M,et al.Oxidation resistance of graphene-coated Cu and Cu/Ni alloy[J].ACS Nano,2011,5:1321
[17]Chi J H,Chen S,Chen X F,et al.Research progress and application of graphene anticorrosive coatings[J].Equip.Environ.Eng.,2018,15(5):56(迟钧瀚,陈珊,陈晓飞等.石墨烯在防腐涂料中的研究进展及应用[J].装备环境工程,2018,15(5):56)
[18]Raman R K S,Banerjee P C,Lobo D E,et al.Protecting copper from electrochemical degradation by graphene coating[J].Carbon,2012,50:4040
[19]Prasai D,Tuberquia J C,Harl R R,et al.Graphene:corrosion-inhibiting coating[J].ACS Nano,2012,6:1102
[20]Mi?kovi?-Stankovi?V,Jevremovi?I,Jung I,et al.Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution[J].Carbon,2014,75:335
[21]Ambrosi A,Pumera M.The structural stability of graphene anticorrosion coating materials is compromised at low potentials[J].Chemistry,2015,21A:7896
[22]Kim H,Kobayashi S,Abdurrahim M A,et al.Graphene/polyethylene nanocomposites:Effect of polyethylene functionalization and blending methods[J].Polymer,2011,52:1837
[23]Zhu D Y,Rong M Z,Zhang M Q.Self-healing polymeric materials based on microencapsulated healing agents:from design to preparation[J].Prog.Polym.Sci.,2015,49/50:175
[24]Zhang K,Zhang L L,Zhao X S,et al.Graphene/polyaniline nanofiber composites as supercapacitor electrodes[J].Chem.Mater.,2010,22:1392
[25]Qiu S H,Liu G,Li W,et al.Noncovalent exfoliation of graphene and its multifunctional composite coating with enhanced anticorrosion and tribological performance[J].J.Alloy.Compd.,2018,747:60
[26]Liu C B,Qiu S H,Du P,et al.An ionic liquid-graphene oxide hybrid nanomaterial:Synthesis and anticorrosive applications[J].Nanoscale,2018,10:8115
[27]Zhou N,Chen H,Ding J H,et al.Efficient dispersion of graphene and its application in anticorrosion coatings[J].China Coat.,2017,32(2):6(周楠,陈浩,丁纪恒等.石墨烯的分散及其在防腐涂层中的应用[J].中国涂料,2017,32(2):6)
[28]Sheng X X,Cai W X,Zhong L,et al.Synthesis of functionalized graphene/polyaniline nanocomposites with effective synergistic reinforcement on anticorrosion[J].Ind.Eng.Chem.Res.,2016,55:8576
[29]Kim S,Le T H,Park C S,et al.A solution-processable,nanostructured,and conductive graphene/polyaniline hybrid coating for metal-corrosion protection and monitoring[J].Sci.Rep.,2017,7:15184
[30]Ramezanzadeh B,Moghadam M H M,Shohani N,et al.Effects of highly crystalline and conductive polyaniline/graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating[J].Chem.Eng.J.,2017,320:363
[31]Ding R,Zheng Y,Yu H B,et al.Study of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings[J].J.Alloy.Compd.,2018,748:481
[32]Liu J R,Liu T,Guo Z W,et al.Promoting barrier performance and cathodic protection of zinc-rich epoxy primer via single-layer graphene[J].Polymers,2018,10:591
[33]Zhang S H,Yang B,Kong G,et al.Research progress of graphenecontaining zinc-rich epoxy coatings[J].Electroplat.Finish.,2018,37:656(张双红,杨波,孔纲等.石墨烯环氧富锌涂层的研究进展[J].电镀与涂饰,2018,37:656)