激光刻蚀法制备仿生超疏水表面的研究进展
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摘要
超疏水表面因具有滑移减阻、防腐蚀、防摩擦等良好的性能,获得广泛的关注。激光刻蚀超疏水表面具有可控、简单、稳定、环保等优点,有望实现工业化生产。首先梳理了超疏水表面的理论模型与影响因素,概述了国内外激光刻蚀超疏水表面的方法,讨论了飞秒、皮秒和纳秒激光制备超疏水表面的优缺点,最后提出了激光刻蚀超疏水表面技术的展望。今后的研究应该坚持以降低生产成本、减少工艺步骤、提高生产效率、绿色节能环保等为基础,着重提高表面微结构的稳定性与持久性。超疏水表面将朝着多功能化与智能化的方向发展。
Superhydrophobic surfaces have gained wide attention due to their good properties such as slip resistance, corrosion resistance, and anti-friction. Superhydrophobic surfaces etched by laser have advantages of controllability, simplicity, stability, environmental protection, etc. It is expected to achieve industrial production. Firstly, theoretical models and influencing factors of superhydrophobic surfaces are reviewed. Also, the methods of laser etching superhydrophobic surfaces at home and abroad are summarized. The advantages and disadvantages of femtosecond, picosecond and nanosecond lasers for superhydrophobic surfaces are discussed. Finally, the prospect of laser etching superhydrophobic surface technology is put forward. Future research should insist on reducing the production cost, reducing the process steps, improving production efficiency, saving energy and keeping environmental protection, etc. It is important to improve the stability and durability of surface microstructure. Superhydrophobic surfaces will move towards multi-functionality and intelligence.
Superhydrophobic surfaces have gained wide attention due to their good properties such as slip resistance, corrosion resistance, and anti-friction. Superhydrophobic surfaces etched by laser have advantages of controllability, simplicity, stability, environmental protection, etc. It is expected to achieve industrial production. Firstly, theoretical models and influencing factors of superhydrophobic surfaces are reviewed. Also, the methods of laser etching superhydrophobic surfaces at home and abroad are summarized. The advantages and disadvantages of femtosecond, picosecond and nanosecond lasers for superhydrophobic surfaces are discussed. Finally, the prospect of laser etching superhydrophobic surface technology is put forward. Future research should insist on reducing the production cost, reducing the process steps, improving production efficiency, saving energy and keeping environmental protection, etc. It is important to improve the stability and durability of surface microstructure. Superhydrophobic surfaces will move towards multi-functionality and intelligence.
引文
[1] LI J Y,LU Sh X,XU W G,et al.Fabrication of stable Ni-AlNi-AlO superhydrophobic surface on aluminum substrate for self-cleaning,anti-corrosive and catalytic performance[J].Journal of Materials Science,2018,53(2):1097-1109.
[2] SHASHANK S,YUNG C S.Superhydrophobic contoured surfaces created on metal and polymer using a femtosecond laser [J].Applied Surface Science,2017,405(2):465-475.
[3] MORADI S,KAMAI S,ENGLEZOS P,et al.Femtosecond laser irradiation of metallic surfaces:effects of laser parameters on super hydrophobicity [J].Nanotechnology,2013,24(41):1-12.
[4] LI J,ZHAO Sh C,DU F,et al.Study on superhydrophobic and corrosion resistant surfaces constructed by laser grooves and grid structures[J].Journal of Materials Engineering,2018,46(5):86-91(in Ch-inese).
[5] LI B J,LI H,HUANG L J,et al.Femtosecond pulsed laser textured titanium surfaces with stable superhydrophilicity and superhydrophobicity [J].Applied Surface Science,2016,389(7):585-593.
[6] HUANG Ch,YE X,YANG X H,et al.Preparation of a superhydrophobic aluminium alloy surface by UV laser [J].Surface Engineering,2017,28(6):1-7.
[7] MAURER J A,MILLER M J,BARTOLUCCI S F.Self-cleaning superhydrophobic nanocomposite surfaces generated by laser pulse heating[J].Journal of Colloid and Interface Science,2018,524 (6):204-208.
[8] XUE L,YU J Y,MA X Sh,et al.Femtosecond laser fabricated wetting copper surfaces and their anti-icing properties [J].Aeronautical Ma-nufacturing Technology,2018,61(12):74-79 (in Chinese).
[9] FARSHCHIAN B,GATABI J R,BERNICK S M,et al.Scaling and mechanism of droplet array formation on a laser-ablated superhydrophobic grid[J].Colloids and Surfaces,2018,A547(6):49-55.
[10] HILL D.Laser treatment creates superhydrophobic metals[J].Civil Engineering,2015,85(3):38-39.
[11] CARDOSO J T,AGUILAR-MORALES A I,ALAMRI S,et al.Superhydrophobicity on hierarchical periodic surface structures fabricated via direct laser writing and direct laser interference patterning on an aluminium alloy[J].Optics and Lasers in Engineering,2018,111(4):193-200.
[12] BAI W B,LAI N Sh,GUAN M Q,et al.Petal-effect super hydrophobic surface self-assembled from poly (p-phenylene)s[J].European Polymer Journal,2018,101(2):12-17.
[13] CHEN X H,CHEN M J,MIN Y L,et al.Preparation and electro- chemical properties of superhydrophobic surface of aluminum alloy by hydrothermal method[J].Journal of Electrochemistry,2018,24(1):28-35(in Chinese).
[14] YAN Zh P,LIANG X D,SHEN H,et al.Preparation and basic pro-perties of superhydrophobic silicone rubber with micro-nano hierarchical structures formed by picosecond laser-ablated template [J].IEEE Transactions on Dielectrics and Electrical Insulation,2017,24(3):1743-1750.
[15] MOHAMMED MUSTAFA ALJUMAILY,MOHAMMED ABDULHA-KIM ALSAADI,RASEL DAS,et al.Optimization of the synthesis of superhydrophobic carbon nano-materials by chemical vapor deposition[J].Scientific Reports,2018,8(1):2778-2779.
[16] ZHAO Sh G,CHEN Y,MA N,et al.Preparation of superhydrophobic surface and wettability transition of aluminum alloy by electrochemical etching[J].Surface Technology,2018,47(3):115-120(in Ch-inese).
[17] SHO W,HIROYA M,KOJI F.Drag-reducing performance of obliquely aligned super hydrophobic surface in turbulent channel flow [J].Fluid Dynamics Research,2017,49(2):1-20.
[18] ZHENG J Y,ZHONG M Q,FENG J.Research progress and industrialization status of self-cleaning surface based on superhydrophobic principle [J].Chemical Industry and Engineering Progress,2010,29(2):281-288(in Chinese).
[19] LONG J Y,WU Y Ch,GONG D W,et al.Preparation of super hydrophobic copper surface by femtosecond laser and its anti-icing performance [J].Chinese Journal of Lasers,2015,42(7):07060002(in Chinese).
[20] UROS T,MATEJ H,GREGORCIC P.Transition from superhydrophilic to superhydrophobic state of laser textured stainless steel surface and its effect on corrosion resistance[J].Corrosion Science,2017,123(10):21-26.
[21] MODESTOV A D,EMELYANENKO K A,EMELYANENKO A M,et al.Application of laser micro- and nano-texturing for the fabrication of superhydrophobic corrosion resistant coatings on aluminum[J].Russian Chemical Bulletin,2016,65(11):2607-2611.
[22] WU H,ZHU L N,YUE W,et al.Research status of tribological properties and hydrophobicity of PTFE composite coatings [J].Materials Review,2018,A48(1):284-288(in Chinese).
[23] ZHANG Y J,DONG L Q,ZHANG Y J,et al.Drag reduction performance of superhydrophobic materials based on numerical simulation[J].Surface Technology,2016,45(11):173-179(in Chinese).
[24] CAO J Y,ZHANG H Y,LI J H,et al.Research progress and application of superhydrophobic coatings in aerospace field[J].Chemical Engineer,2017,31(1):57-60(in Chinese).
[25] CAO L R.Study on super-hydrophobic and weather resistant surface of radome [J].Electronics Process Technology,2016,37(4):239-242(in Chinese).
[26] YE X,WANG Z,ZHOU M,et al.Research of surface micro-structure and anti-coagulant property of pyrolytic carbon induced by laser[J].Laser Technology,2013,37(5):696-699(in Chinese).
[27] JIANG L,YANG B,LI T J,et al.Binary cooperative complementary nano-scale interfacial materials[J].Pure and Applied Chemistry,2000,72(1/2):73-81.
[28] GUO Sh H,YU Zh J,LUO B M,et al.Research progress on wetting theory of superhydrophobic surface[J].Materials Review:A Review Rrticle,2012,A26(3):74-77(in Chinese).
[29] LONG J Y,PAN L,FAN P X,et al.Cassie-state stability of metallic superhydrophobic surfaces with various micro/nanostructures produced by a femtosecond laser[J].Langmuir,2016,32(4):1065-1072.
[30] WU B.Fabrication and research of metal bionic functional micro-structures by laser[D].Zhenjiang:Jiangsu University,2011:73-81(in Chinese).
[31] PAN H H,WANG Zh,FAN Zh W,et al.Micro nano structure of superhydrophobic titanium surface induced by femtosecond laser[J].Chinese Journal of Lasers,2016,43(8):08020002(in Chinese).
[32] WU B,ZHOU M,LI J B,et al.Fabrication of highly adherent stainless steel super hydrophobic surfaces by femtosecond laser combined with hydrothermal method[J].Functional Materials,2013,24(4):3658-3662(in Chinese).
[33] SONG Y X,WANG C,DONG X R,et al.Controllable superhydrophobic aluminum surfaces with tunable adhesion fabricated by femtosecond laser[J].Optics and Laser Technology,2018,102(5):25-31.
[34] ELISABETH K,SANDRA S,STEPHAN K,et al.Fabrication of biomimetic fog-collecting superhydrophilic-superhydro phobic surface micropatterns using femtosecond lasers[J].Langmuir,2018,34 (9):2933-2941.
[35] SANDRA S,STEPHAN K,MATTHIAS D,et al.Transparent superhydrophobic surfaces with high adhesion generated by the combination of femtosecond laser structuring and wet oxidation[J].Applied Surface Science,2017,420(9):550-557.
[36] LIU D,WU Y G,HU Y T,et al.Preparation of aluminum based superhydrophobic surface by picosecond laser[J].Laser & Optoelectronics Progress,2016,53(10):101408(in Chinese).
[37] XIE Zh W,DONG Sh Y,YAN Sh X,et al.Experimental study on morphology control of stainless steel with picosecond laser micro nano processing[J].Laser & Optoelectronics Progress,2018,55(3):031402(in Chinese).
[38] SUN K,YANG H,XUE W,et al.Anti-biofouling super-hydrophobic surface fabricated by picosecond laser texturing of stainless steel[J].Applied Surface Science,2018,436(6):263-267.
[39] FATEMA H R,CHISTOPHER M L,BENSON P S,et al.Picosecond laser treatment production of hierarchical structured stainless steel to reduce bacterial fouling[J].Food and Bioproducts Processing,2018,109(7):29-40.
[40] LAWRENCE J,WAUGH D G.Creating superhydrophobic surface structures via the rose petal effect on stainless steel with a picosecond laser [J].Lasers in Engineering (Old City Publishing),2017,37(1/3):125-134.
[41] YANG Q B,LIU Sh J,WANG Y T,et al.Nanosecond laser induced super hydrophobic micro nano-structure on aluminum sheet[J].Laser & Optoelectronics Progress,2017,55(3):091406(in Chinese).
[42] van TA D,DUNN A,WASLEY T J,et al.Laser textured superhydrophobic surfaces and their applications for homogeneous spot deposition[J].Applied Surface Science,2016,365(10):153-159.
[43] EMELYANENKO A M,SHAGIEVA F M,DOMANTO-VXKY A G,et al.Nanosecond laser micro- and nanotexturing for the design of a superhydrophobic coating robust against long-term contact with water,cavitation,and abrasion[J].Applied Surface Science,2015,332(8):513-517.
[44] RICO S D,EDWARDSON S P,DEARDEN G.Laser surface texturing of titanium with thermal post-processing for improved wettability properties[J].Procedia CIRP,2018,74(6):362-366.
[45] OCANA J L,JAGDHEESH R,GARCIA B J J.Direct generation of super-hydrophobic microstructures in metals by UV laser sources in the nanosecond regime[J].Advanced Optical Technologies,2016,5(1):87-93.
[46] FU X,ZHANG F,JIANG M,et al.Study on technology and quality of etching copper clad laminate with 1064nm and 355nm laser[J].Laser Technology,2014,38(4):435-440(in Chinese).
[47] HOU T J,AI J,LIU J G,et al.Selective preparation of metal copper layer on silicate glass by laser surface modification[J].Laser Technology,2018,42(2):176-180(in Chinese).
[48] YANG Y,WEI X,XIE X Zh,et al.Study on etching process of composite grooves on micro heat pipes with infrared laser[J].Laser Technology,2018,42(2):276-281(in Chinese).
[49] SHANG X Ch,CAO X K,ZHANG R Zh,et al.Influence of laser wavelength and pulse duration threshold on laser-induced optical damage[J].High Power Laser and Particle Beams,2008,20(7):1071-1075(in Chinese).
[50] YUAN Ch H,LI X H,TANG D Ch,et al.Influence of wavelength and atmosphere on laser induced microstructure of silicon surface[J].Laser Technology,2010,34(5):647-649(in Chinese).
[2] SHASHANK S,YUNG C S.Superhydrophobic contoured surfaces created on metal and polymer using a femtosecond laser [J].Applied Surface Science,2017,405(2):465-475.
[3] MORADI S,KAMAI S,ENGLEZOS P,et al.Femtosecond laser irradiation of metallic surfaces:effects of laser parameters on super hydrophobicity [J].Nanotechnology,2013,24(41):1-12.
[4] LI J,ZHAO Sh C,DU F,et al.Study on superhydrophobic and corrosion resistant surfaces constructed by laser grooves and grid structures[J].Journal of Materials Engineering,2018,46(5):86-91(in Ch-inese).
[5] LI B J,LI H,HUANG L J,et al.Femtosecond pulsed laser textured titanium surfaces with stable superhydrophilicity and superhydrophobicity [J].Applied Surface Science,2016,389(7):585-593.
[6] HUANG Ch,YE X,YANG X H,et al.Preparation of a superhydrophobic aluminium alloy surface by UV laser [J].Surface Engineering,2017,28(6):1-7.
[7] MAURER J A,MILLER M J,BARTOLUCCI S F.Self-cleaning superhydrophobic nanocomposite surfaces generated by laser pulse heating[J].Journal of Colloid and Interface Science,2018,524 (6):204-208.
[8] XUE L,YU J Y,MA X Sh,et al.Femtosecond laser fabricated wetting copper surfaces and their anti-icing properties [J].Aeronautical Ma-nufacturing Technology,2018,61(12):74-79 (in Chinese).
[9] FARSHCHIAN B,GATABI J R,BERNICK S M,et al.Scaling and mechanism of droplet array formation on a laser-ablated superhydrophobic grid[J].Colloids and Surfaces,2018,A547(6):49-55.
[10] HILL D.Laser treatment creates superhydrophobic metals[J].Civil Engineering,2015,85(3):38-39.
[11] CARDOSO J T,AGUILAR-MORALES A I,ALAMRI S,et al.Superhydrophobicity on hierarchical periodic surface structures fabricated via direct laser writing and direct laser interference patterning on an aluminium alloy[J].Optics and Lasers in Engineering,2018,111(4):193-200.
[12] BAI W B,LAI N Sh,GUAN M Q,et al.Petal-effect super hydrophobic surface self-assembled from poly (p-phenylene)s[J].European Polymer Journal,2018,101(2):12-17.
[13] CHEN X H,CHEN M J,MIN Y L,et al.Preparation and electro- chemical properties of superhydrophobic surface of aluminum alloy by hydrothermal method[J].Journal of Electrochemistry,2018,24(1):28-35(in Chinese).
[14] YAN Zh P,LIANG X D,SHEN H,et al.Preparation and basic pro-perties of superhydrophobic silicone rubber with micro-nano hierarchical structures formed by picosecond laser-ablated template [J].IEEE Transactions on Dielectrics and Electrical Insulation,2017,24(3):1743-1750.
[15] MOHAMMED MUSTAFA ALJUMAILY,MOHAMMED ABDULHA-KIM ALSAADI,RASEL DAS,et al.Optimization of the synthesis of superhydrophobic carbon nano-materials by chemical vapor deposition[J].Scientific Reports,2018,8(1):2778-2779.
[16] ZHAO Sh G,CHEN Y,MA N,et al.Preparation of superhydrophobic surface and wettability transition of aluminum alloy by electrochemical etching[J].Surface Technology,2018,47(3):115-120(in Ch-inese).
[17] SHO W,HIROYA M,KOJI F.Drag-reducing performance of obliquely aligned super hydrophobic surface in turbulent channel flow [J].Fluid Dynamics Research,2017,49(2):1-20.
[18] ZHENG J Y,ZHONG M Q,FENG J.Research progress and industrialization status of self-cleaning surface based on superhydrophobic principle [J].Chemical Industry and Engineering Progress,2010,29(2):281-288(in Chinese).
[19] LONG J Y,WU Y Ch,GONG D W,et al.Preparation of super hydrophobic copper surface by femtosecond laser and its anti-icing performance [J].Chinese Journal of Lasers,2015,42(7):07060002(in Chinese).
[20] UROS T,MATEJ H,GREGORCIC P.Transition from superhydrophilic to superhydrophobic state of laser textured stainless steel surface and its effect on corrosion resistance[J].Corrosion Science,2017,123(10):21-26.
[21] MODESTOV A D,EMELYANENKO K A,EMELYANENKO A M,et al.Application of laser micro- and nano-texturing for the fabrication of superhydrophobic corrosion resistant coatings on aluminum[J].Russian Chemical Bulletin,2016,65(11):2607-2611.
[22] WU H,ZHU L N,YUE W,et al.Research status of tribological properties and hydrophobicity of PTFE composite coatings [J].Materials Review,2018,A48(1):284-288(in Chinese).
[23] ZHANG Y J,DONG L Q,ZHANG Y J,et al.Drag reduction performance of superhydrophobic materials based on numerical simulation[J].Surface Technology,2016,45(11):173-179(in Chinese).
[24] CAO J Y,ZHANG H Y,LI J H,et al.Research progress and application of superhydrophobic coatings in aerospace field[J].Chemical Engineer,2017,31(1):57-60(in Chinese).
[25] CAO L R.Study on super-hydrophobic and weather resistant surface of radome [J].Electronics Process Technology,2016,37(4):239-242(in Chinese).
[26] YE X,WANG Z,ZHOU M,et al.Research of surface micro-structure and anti-coagulant property of pyrolytic carbon induced by laser[J].Laser Technology,2013,37(5):696-699(in Chinese).
[27] JIANG L,YANG B,LI T J,et al.Binary cooperative complementary nano-scale interfacial materials[J].Pure and Applied Chemistry,2000,72(1/2):73-81.
[28] GUO Sh H,YU Zh J,LUO B M,et al.Research progress on wetting theory of superhydrophobic surface[J].Materials Review:A Review Rrticle,2012,A26(3):74-77(in Chinese).
[29] LONG J Y,PAN L,FAN P X,et al.Cassie-state stability of metallic superhydrophobic surfaces with various micro/nanostructures produced by a femtosecond laser[J].Langmuir,2016,32(4):1065-1072.
[30] WU B.Fabrication and research of metal bionic functional micro-structures by laser[D].Zhenjiang:Jiangsu University,2011:73-81(in Chinese).
[31] PAN H H,WANG Zh,FAN Zh W,et al.Micro nano structure of superhydrophobic titanium surface induced by femtosecond laser[J].Chinese Journal of Lasers,2016,43(8):08020002(in Chinese).
[32] WU B,ZHOU M,LI J B,et al.Fabrication of highly adherent stainless steel super hydrophobic surfaces by femtosecond laser combined with hydrothermal method[J].Functional Materials,2013,24(4):3658-3662(in Chinese).
[33] SONG Y X,WANG C,DONG X R,et al.Controllable superhydrophobic aluminum surfaces with tunable adhesion fabricated by femtosecond laser[J].Optics and Laser Technology,2018,102(5):25-31.
[34] ELISABETH K,SANDRA S,STEPHAN K,et al.Fabrication of biomimetic fog-collecting superhydrophilic-superhydro phobic surface micropatterns using femtosecond lasers[J].Langmuir,2018,34 (9):2933-2941.
[35] SANDRA S,STEPHAN K,MATTHIAS D,et al.Transparent superhydrophobic surfaces with high adhesion generated by the combination of femtosecond laser structuring and wet oxidation[J].Applied Surface Science,2017,420(9):550-557.
[36] LIU D,WU Y G,HU Y T,et al.Preparation of aluminum based superhydrophobic surface by picosecond laser[J].Laser & Optoelectronics Progress,2016,53(10):101408(in Chinese).
[37] XIE Zh W,DONG Sh Y,YAN Sh X,et al.Experimental study on morphology control of stainless steel with picosecond laser micro nano processing[J].Laser & Optoelectronics Progress,2018,55(3):031402(in Chinese).
[38] SUN K,YANG H,XUE W,et al.Anti-biofouling super-hydrophobic surface fabricated by picosecond laser texturing of stainless steel[J].Applied Surface Science,2018,436(6):263-267.
[39] FATEMA H R,CHISTOPHER M L,BENSON P S,et al.Picosecond laser treatment production of hierarchical structured stainless steel to reduce bacterial fouling[J].Food and Bioproducts Processing,2018,109(7):29-40.
[40] LAWRENCE J,WAUGH D G.Creating superhydrophobic surface structures via the rose petal effect on stainless steel with a picosecond laser [J].Lasers in Engineering (Old City Publishing),2017,37(1/3):125-134.
[41] YANG Q B,LIU Sh J,WANG Y T,et al.Nanosecond laser induced super hydrophobic micro nano-structure on aluminum sheet[J].Laser & Optoelectronics Progress,2017,55(3):091406(in Chinese).
[42] van TA D,DUNN A,WASLEY T J,et al.Laser textured superhydrophobic surfaces and their applications for homogeneous spot deposition[J].Applied Surface Science,2016,365(10):153-159.
[43] EMELYANENKO A M,SHAGIEVA F M,DOMANTO-VXKY A G,et al.Nanosecond laser micro- and nanotexturing for the design of a superhydrophobic coating robust against long-term contact with water,cavitation,and abrasion[J].Applied Surface Science,2015,332(8):513-517.
[44] RICO S D,EDWARDSON S P,DEARDEN G.Laser surface texturing of titanium with thermal post-processing for improved wettability properties[J].Procedia CIRP,2018,74(6):362-366.
[45] OCANA J L,JAGDHEESH R,GARCIA B J J.Direct generation of super-hydrophobic microstructures in metals by UV laser sources in the nanosecond regime[J].Advanced Optical Technologies,2016,5(1):87-93.
[46] FU X,ZHANG F,JIANG M,et al.Study on technology and quality of etching copper clad laminate with 1064nm and 355nm laser[J].Laser Technology,2014,38(4):435-440(in Chinese).
[47] HOU T J,AI J,LIU J G,et al.Selective preparation of metal copper layer on silicate glass by laser surface modification[J].Laser Technology,2018,42(2):176-180(in Chinese).
[48] YANG Y,WEI X,XIE X Zh,et al.Study on etching process of composite grooves on micro heat pipes with infrared laser[J].Laser Technology,2018,42(2):276-281(in Chinese).
[49] SHANG X Ch,CAO X K,ZHANG R Zh,et al.Influence of laser wavelength and pulse duration threshold on laser-induced optical damage[J].High Power Laser and Particle Beams,2008,20(7):1071-1075(in Chinese).
[50] YUAN Ch H,LI X H,TANG D Ch,et al.Influence of wavelength and atmosphere on laser induced microstructure of silicon surface[J].Laser Technology,2010,34(5):647-649(in Chinese).