高导热陶瓷材料的研究现状与前景分析
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摘要
高导热率陶瓷材料因其具备陶瓷的优异性能与高导热率特性而具有重要的研究意义。笔者主要介绍了导热系数概念、陶瓷材料高导热率规律、高导热陶瓷材料分类、高导热陶瓷应用以及热导率的测试方法、机理、影响因素及提高方法,并对高导热陶瓷材料研究现状与专利情况进行了评述,同时分析了高导热陶瓷材料的发展前景。
Ceramic materials with high thermal conductivity have important research significance because of their excellent properties of ceramic and high thermal conductivity characteristics.This paper mainly introduces the concept of thermal conductivity,the high thermal conductivity rule of ceramic materials,the classification of high thermal conductivity ceramic materials,the application of high thermal conductivity ceramics,and the test methods,mechanisms,influencing factors,improving methods of thermal conductivity.Besides,the research status and patents of high thermal conductivity ceramic materials are reviewed.At the same time,the development prospect of high thermal conductivity ceramic materials is also analyzed.
Ceramic materials with high thermal conductivity have important research significance because of their excellent properties of ceramic and high thermal conductivity characteristics.This paper mainly introduces the concept of thermal conductivity,the high thermal conductivity rule of ceramic materials,the classification of high thermal conductivity ceramic materials,the application of high thermal conductivity ceramics,and the test methods,mechanisms,influencing factors,improving methods of thermal conductivity.Besides,the research status and patents of high thermal conductivity ceramic materials are reviewed.At the same time,the development prospect of high thermal conductivity ceramic materials is also analyzed.
引文
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2 Cheng W,Xie B,Zhang R,et al.Effect of thermal conductivities of shape stabilized PCM on under-floor heating system[J].Applied Energy,2015,144:10~18
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6 孙坤,雍岐龙,裴和中.高导热电绝缘陶瓷的研究方向及应用前景[J].昆明理工大学学报(自然科学版),2002,27(6):25 ~28
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13 刘恩科,朱秉升,罗晋生.半导体物理学.第4版[M].北京:国防工业出版社,2010
14 张金升,张银燕,王美婷.陶瓷材料显微结构与性能[M].北京:化学工业出版社,2007
15 Slack G A.Nonmetallic crystals with high thermal conductivity[J].Journal of Physics&Chemistry of Solids,1973,34(2):321~335
16 陈广乐,范仕刚,夏淑琴,等.高导热AlN陶瓷烧结助剂的研究现状[J].现代技术陶瓷,2004,25(1):26~30
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18 Dietrich B,Kind M,Martin H.Axial two-phase thermal conductivity of ceramic sponges-experimental results and correlation[J].International Journal of Heat&Mass Transfer,2011,54(11):2 276~2 282
19 穆瑞雁.建筑材料导热系数的几个影响因素[J].中原文化研究,2008,16(11):232~233
20 Gao Z,Zhao L.Effect of nano-fillers on the thermal conductivity of epoxy composites with micro-Al2O3 particles[J].Materials&Design,2015,66:176~182
21 Gambaryanroisman T,Shapiro M,Shavit A.Effect of double-diffusive heat transfer on thermal conductivity of porous sintered ceramics:macrotransport analysis[J].International Journal of Heat&Mass Transfer,2011,54(23):4 844~4 855
22 马铁成.陶瓷工艺学[M].北京:中国轻工业出版社,2011
23 储章生.高导热性陶瓷的微观结构[J].江苏陶瓷,1989(3):38~41
24 解保生,周挚.复合生物陶瓷导热系数的测定[J].昆明医科大学学报,1996(4):14~17
25 唐国宏.AlN陶瓷导热系数研究[C].首届中国功能材料及其应用学术会议论文集,1992
26 骆祥磊,刘永启,高振强,等.蜂窝陶瓷有效导热系数的试验研究[J].陶瓷学报,2013,34(3):271~276
27 张士昌,刘孝定,李恩江.陶瓷材料的导热机理[J].建材研究院院刊,1980(2):34~39
28 孔令凯,沈建兴,肖凤军.陶瓷材料热传递的影响因素[J].山东陶瓷,2015,38(6):5~9
29 李清涛,吴清仁,孙创奇,等.改善建筑陶瓷墙地砖强度和导热性能的试验研究[J].硅酸盐通报,2007,26(2):277~281
30 García E,Pablos A D,Bengoechea M A,et al.Thermal conductivity studies on ceramic floor tiles[J].Ceramics International,2011,37(1):369~375
31 Yu W,Xie H,Yin L,et al.Exceptionally high thermal conductivity of thermal grease:synergistic effects of graphene and alumina[J].International Journal of Thermal Sciences,2015,91:76~82
32 He Y L,Xie T.Advances of thermal conductivity models of nanoscale silica aerogel insulation material[J].Applied Thermal Engineering,2015,81:28~50
33 Feng W,Zhang L,Liu Y,et al.Increasing the thermal conductivity of 2DSiC/SiC composites by heat-treatment[J].Fusion Engineering&Design,2015,90:110~118
34 Park Y J,Park M J,Kim J M,et al.Sintered reactionbonded silicon nitrides with high thermal conductivity:the effect of the starting Si powder and Si3N4 diluents[J].Journal of the European Ceramic Society,2014,34(5):1 105~1 113
35 Yuan H,Li J,Shen Q,et al.Preparation and thermal conductivity characterization of ZrB2,porous ceramics fabricated by spark plasma sintering[J].International Journal of Refractory Metals&Hard Materials,2013,36:225~231
36 Zhang C,Yao X,Li Y,et al.Effect of AlN addition on the thermal conductivity of pressureless sintered SiC ceramics[J].Ceramics International,2015,41(7):9 107~9 114
37 许昕睿,庄汉锐.添加Y2O3-DY2O3的AlN陶瓷烧结特性及显微结构[J].无机材料学报,1999,14(6):989~994
38 王爱国.一种高导热的陶瓷加热器:CN104853459A[P].2015
39 肖凤军.高导热功能陶瓷薄板及其制备方法:CN104310973A[P].2014
40 宴育权,刘贤香.一种高导热自释釉陶瓷配方及其制备方法:CN104844164A[P].2014
41 单喆恺.一种高导热氧化物陶瓷材料及其制备方法:CN104276815A[P].2013
42 王双喜,张丹,欧阳雪琼.一种电饭锅用高导热陶瓷内胆:,CN106800404A[P].2015
43 张甘霖.一种高导热陶瓷材料及其制造方法:CN105294079A[P].2015
44 孙道明.一种高导热氮化铝陶瓷材料及其制造方法:,CN104072144A[P].2014
45 翁宇飞,张其笑.一种高导热陶瓷基片材料及其制造方法:CN105236942A[P].2015
46 秦明礼,鲁慧峰,何庆等.一种高导热氮化铝陶瓷的制备方法:CN104973865A[P].2015
47 夏云.一种高导热碳化硅陶瓷材料及其制备方法:CN104628388A[P].2015
2 Cheng W,Xie B,Zhang R,et al.Effect of thermal conductivities of shape stabilized PCM on under-floor heating system[J].Applied Energy,2015,144:10~18
3 郁岚.热工基础及流体力学[M].北京:中国电力出版社,2006
4 宋长华.热工基础[M].北京:机械工业出版社,2013
5 张迎新.高压快速制备高导热陶瓷[D].武汉:武汉理工大学,2015
6 孙坤,雍岐龙,裴和中.高导热电绝缘陶瓷的研究方向及应用前景[J].昆明理工大学学报(自然科学版),2002,27(6):25 ~28
7 吴清良,赖燕玲,顾海静,等.导热系数测试方法的综述[J].佛山陶瓷,2011,21(12):20~22
8 吴清仁,文璧璇.陶瓷材料导热系数测量方法[J].佛山陶瓷,1995(2):40~42
9 葛山,尹玉成.激光闪光法测定耐火材料导热系数的原理与方法[J].理化检验-物理分册,2008,44(2):75~78
10 孙建平,刘建庆,邱萍,等.激光闪光法测量材料热扩散率的漏热修正[J].计量技术,2008(1):23~25
11 薛健,张立.激光脉冲法测量热扩散率技术在材料科学中的应用[J].粉末冶金材料科学与工程,1997(3):163~173
12 曾令可,漆小玲,王慧,等.氧化物热电材料热导率的研究[J].硅酸盐通报,2009,28(3):525~530
13 刘恩科,朱秉升,罗晋生.半导体物理学.第4版[M].北京:国防工业出版社,2010
14 张金升,张银燕,王美婷.陶瓷材料显微结构与性能[M].北京:化学工业出版社,2007
15 Slack G A.Nonmetallic crystals with high thermal conductivity[J].Journal of Physics&Chemistry of Solids,1973,34(2):321~335
16 陈广乐,范仕刚,夏淑琴,等.高导热AlN陶瓷烧结助剂的研究现状[J].现代技术陶瓷,2004,25(1):26~30
17 孔令凯,沈建兴,肖凤军.陶瓷材料热传递的影响因素[J].山东陶瓷,2015,38(6):5~9
18 Dietrich B,Kind M,Martin H.Axial two-phase thermal conductivity of ceramic sponges-experimental results and correlation[J].International Journal of Heat&Mass Transfer,2011,54(11):2 276~2 282
19 穆瑞雁.建筑材料导热系数的几个影响因素[J].中原文化研究,2008,16(11):232~233
20 Gao Z,Zhao L.Effect of nano-fillers on the thermal conductivity of epoxy composites with micro-Al2O3 particles[J].Materials&Design,2015,66:176~182
21 Gambaryanroisman T,Shapiro M,Shavit A.Effect of double-diffusive heat transfer on thermal conductivity of porous sintered ceramics:macrotransport analysis[J].International Journal of Heat&Mass Transfer,2011,54(23):4 844~4 855
22 马铁成.陶瓷工艺学[M].北京:中国轻工业出版社,2011
23 储章生.高导热性陶瓷的微观结构[J].江苏陶瓷,1989(3):38~41
24 解保生,周挚.复合生物陶瓷导热系数的测定[J].昆明医科大学学报,1996(4):14~17
25 唐国宏.AlN陶瓷导热系数研究[C].首届中国功能材料及其应用学术会议论文集,1992
26 骆祥磊,刘永启,高振强,等.蜂窝陶瓷有效导热系数的试验研究[J].陶瓷学报,2013,34(3):271~276
27 张士昌,刘孝定,李恩江.陶瓷材料的导热机理[J].建材研究院院刊,1980(2):34~39
28 孔令凯,沈建兴,肖凤军.陶瓷材料热传递的影响因素[J].山东陶瓷,2015,38(6):5~9
29 李清涛,吴清仁,孙创奇,等.改善建筑陶瓷墙地砖强度和导热性能的试验研究[J].硅酸盐通报,2007,26(2):277~281
30 García E,Pablos A D,Bengoechea M A,et al.Thermal conductivity studies on ceramic floor tiles[J].Ceramics International,2011,37(1):369~375
31 Yu W,Xie H,Yin L,et al.Exceptionally high thermal conductivity of thermal grease:synergistic effects of graphene and alumina[J].International Journal of Thermal Sciences,2015,91:76~82
32 He Y L,Xie T.Advances of thermal conductivity models of nanoscale silica aerogel insulation material[J].Applied Thermal Engineering,2015,81:28~50
33 Feng W,Zhang L,Liu Y,et al.Increasing the thermal conductivity of 2DSiC/SiC composites by heat-treatment[J].Fusion Engineering&Design,2015,90:110~118
34 Park Y J,Park M J,Kim J M,et al.Sintered reactionbonded silicon nitrides with high thermal conductivity:the effect of the starting Si powder and Si3N4 diluents[J].Journal of the European Ceramic Society,2014,34(5):1 105~1 113
35 Yuan H,Li J,Shen Q,et al.Preparation and thermal conductivity characterization of ZrB2,porous ceramics fabricated by spark plasma sintering[J].International Journal of Refractory Metals&Hard Materials,2013,36:225~231
36 Zhang C,Yao X,Li Y,et al.Effect of AlN addition on the thermal conductivity of pressureless sintered SiC ceramics[J].Ceramics International,2015,41(7):9 107~9 114
37 许昕睿,庄汉锐.添加Y2O3-DY2O3的AlN陶瓷烧结特性及显微结构[J].无机材料学报,1999,14(6):989~994
38 王爱国.一种高导热的陶瓷加热器:CN104853459A[P].2015
39 肖凤军.高导热功能陶瓷薄板及其制备方法:CN104310973A[P].2014
40 宴育权,刘贤香.一种高导热自释釉陶瓷配方及其制备方法:CN104844164A[P].2014
41 单喆恺.一种高导热氧化物陶瓷材料及其制备方法:CN104276815A[P].2013
42 王双喜,张丹,欧阳雪琼.一种电饭锅用高导热陶瓷内胆:,CN106800404A[P].2015
43 张甘霖.一种高导热陶瓷材料及其制造方法:CN105294079A[P].2015
44 孙道明.一种高导热氮化铝陶瓷材料及其制造方法:,CN104072144A[P].2014
45 翁宇飞,张其笑.一种高导热陶瓷基片材料及其制造方法:CN105236942A[P].2015
46 秦明礼,鲁慧峰,何庆等.一种高导热氮化铝陶瓷的制备方法:CN104973865A[P].2015
47 夏云.一种高导热碳化硅陶瓷材料及其制备方法:CN104628388A[P].2015