X射线荧光光谱在铜矿石分析中的应用文献评介
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摘要
作者收集了我国用X射线荧光光谱(XRF)分析技术进行铜矿石(含铜精矿)分析的文献共计51篇,其中野外现场分析文献21篇,实验室内分析文献30篇。实验室内方法文献包括熔融制样法12篇,粉末压片制样的15篇,其他方法3篇。文章用列表方式对文献要点进行了介绍,对其中的多元素分析方法文献进行了重点评介,也特别讨论了X射线荧光光谱分析的技术条件、制样方法选取、标准物质与标准方法等问题。文献表明:XRF已成为铜矿石主次痕量分析最强有力的技术方法之一,并随着社会对环境需求的增长,直接粉末压片制样的XRF方法必将具有更广阔的发展前景。全篇引文89篇。
Total 51 literatures about the analysis of copper ore(including copper concentrate)by X-ray fluorescence spectrometry(XRF)were collected,including 21 literatures about analysis in the field and 30 literatures about laboratory analysis.Among the literatures about laboratory analysis,12 of them were involved in fusion sample preparation,15 of them were involved pressed powder pellet sample preparation and 3 of them were involved in other methods.The key points of literatures were introduced in a list,wherein the multi-element analysis methods were emphasized.Some other issues such as the technical conditions,the selection of sample preparation method,the certified reference material and standard method of XRF were also discussed.The results indicated that XRF had become one of most powerful technologies for the analysis of major,minor and trace elements in copper ore.With the increasing requirements of environment,XRF with direct pressed powder pellet sample preparation would have broader development prospect.Total 89 references were cited.
Total 51 literatures about the analysis of copper ore(including copper concentrate)by X-ray fluorescence spectrometry(XRF)were collected,including 21 literatures about analysis in the field and 30 literatures about laboratory analysis.Among the literatures about laboratory analysis,12 of them were involved in fusion sample preparation,15 of them were involved pressed powder pellet sample preparation and 3 of them were involved in other methods.The key points of literatures were introduced in a list,wherein the multi-element analysis methods were emphasized.Some other issues such as the technical conditions,the selection of sample preparation method,the certified reference material and standard method of XRF were also discussed.The results indicated that XRF had become one of most powerful technologies for the analysis of major,minor and trace elements in copper ore.With the increasing requirements of environment,XRF with direct pressed powder pellet sample preparation would have broader development prospect.Total 89 references were cited.
引文
[1]周平,唐金荣,施俊法,等.铜资源现状与发展态势分析[J].岩石矿物学杂志,2012,31(5):750-756.ZHOU Ping,TANG Jin-rong,SHI Jun-fa,et al.Analysis on current situation and development trend of copper resources[J].Petromineralogy,2012,31(5):750-756.
[2]陈甲斌,梁振杰,高鹏.中国铜资源现状与发展战略研究[J].世界有色金属,2005(12):8-11.CHEN Jia-bin,LIANG Zhen-jie,GAO Peng.A study on the current situation and development strategy of copper resources in China[J].World Nonferrous Metals,2005(12):8-11.
[3]陈四箴.安徽铜陵狮子山含铜钙钨矿之发现及分析[J].地质论评,1951(1):63-64.CHEN Si-zhen.Discovery and analysis of copper-bearing calcium-tungsten deposit in Shizishan,Tongling,Anhui province[J].GeoReview,1951(1):63-64.
[4]陈四箴.用氢氧化铵及氯化铵分离铜与铁[J].化学学报,1952(1):29-32.CHEN Si-zhen.Separation of copper and iron with ammonium hydroxide and ammonium chloride[J].Chinese Journal of Chemistry,1952(1):29-32.
[5]冶金部地质研究所.铜矿石中铜和铁的简易测定[J].地质与勘探,1958(22):18.Institute of Geology,Ministry of Metallurgy.Sample determination of copper and iron in copper ores[J].Geology and Exploration,1958(22):18.
[6]郑大中,张立成,赖明森.铜锌连续测定[J].化学通报,1966(4):53-55.ZHENG Da-zhong,ZHANG Li-cheng,LAI Ming-sen.Continuous determination of copper and zinc[J].Chemistry Bulletin,1966(4):53-55.
[7]肖慈林.原子吸收法测定矿石中铜、镍、钴[J].分析化学,1975,3(1):81-82.XIAO Ci-lin.Determination of copper,nickel and cobalt in ores by atomic absorption spectrometry[J].Analytical Chemistry,1975,3(1):81-82.
[8]路庆详.铜矿石中氧化铜总量的快速示波极谱测定[J].分析化学,1975,3(2):142-143.LU Qing-xiang.Rapid oscillopolarographic determination of total copper oxide in copper ores[J].Analytical Chemistry,1975,3(2):142-143.
[9]柳延极.水平电极在极谱分析中的应用—矿石中铜铅锌的测定[J].分析化学,1977,5(3):210-212.LIU Yan-ji.Application of horizontal electrode in polarographic analysis-Determination of copper,lead and zinc in ores[J].Analytical Chemistry,1977,5(3):210-212.
[10]陈建华,徐楚华,吴杭春.氢化物ICP-AES法测定铜精矿中砷和锑[J].检验检疫科学,1993(4):17-21.CHEN Jian-hua,XU Chu-hua,WU Hang-chun.Determination of arsenic and antimony in copper concentrate by hydride ICP-AES[J].Inspection and Quarantine Science,1993(4):17-21.
[11]高建文,董淑珍,张春田,等.ICP-AES方法同时测定铜精矿中十三种成份[J].光谱实验室,1998,15(1):47-55.GAO Jian-wen,DONG Shu-zhen,ZHANG Chun-tian,et al.Determination of 13components in copper concentrates by ICP-AES method[J].Chinese Journal of Spectroscopy Laboratory,1998,15(1):47-55.
[12]地质部矿物原料研究所.矿物原料分析[M].北京:地质出版社,1959:253-265.
[13]岩石矿物编写组.岩石矿物分析[M].2版.北京:地质出版社,1974:331-346.
[14]李连仲.岩石矿物分析:第1分册[M].3版.北京:地质出版社,1991:409-421.
[15]尹明,李家熙.岩石矿物分析:第3分册[M].4版.北京:地质出版社,2013:17-53,42-44.
[16]于力,符斌.有色冶金分析手册[M].北京:冶金工业出版社,2004:1-805.
[17]北京矿冶研究总院分析室.矿石及有色金属分析手册[M].北京:冶金工业出版社,1990:1-385.
[18]中华人民共和国国家质量监督检验检疫总局.SN/T4365—2015铜精矿中铜、铅、铬、砷、银、锑、铋、镍、铁、铝元素含量的测定波长色散X射线荧光光谱法[S].北京:中国标准出版社,2016.
[19]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 14263—2010散装浮选铜精矿取样、制样方法[S].北京:中国标准出版社,2011.
[20]全国标准物质管理委员会,中华人民共和国标准物质目录[S].北京:中国计量出版社,2010:54-216.
[21]王毅民,顾铁新,王晓红,等.实用地质分析标准物质手册(汉-英对照)[M].2版.北京:地质出版社,2013:589.
[22]侯晋,窦怀智,吕翔.我国进口铜精矿检验方法的研究进展[J].理化检验:化学分册,2010,46(10):1229-1232.HOU Jin,DOU Huai-zhi,LXiang.Recent progress on analytical methods for imported copper concentrates[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2010,46(10):1229-1232.
[23]许德娟,朱佩思,陈永欣,等.中国铜矿分析文献评介[J].大众科技,2013,15(7):58-63.XU De-juan,ZHU Pei-si,CHEN Yong-xin,et al.A review on literatures of copper ores analysis in China[J].Popular Science &Technology,2013,15(7):58-63.
[24]梁亚平.铜矿石化学分析方法概述与评价[J].甘肃科技,2015,31(18):52-53.LIANG Ya-ping.Overview and evaluation of chemical analysis methods for copper ore[J].Gansu Science and Technology,2015,31(18):52-53.
[25]蒋晓光,周蕾,褚宁,等.X射线荧光光谱分析硫化铜矿及其精矿的进展[J].冶金分析,2017,37(7):23-30.JIANG Xiao-guang,ZHOU Lei,CHU Ning,et al.Progress on X-ray fluorescence spectrometric analysis of copper sulfide ore and its concentrate[J].Metallurgical Analysis,2017,37(7):23-30.
[26]北京矿冶研究院放射性同位素X射线荧光分析专题组.实验室台式放射性同位素X射线荧光分析仪的研制[J].有色金属:冶炼部分,1975(7):10-16,41.Beijing Institute of Mining and Metallurgy Radioisotope X-ray Fluorescence Analysis Group.Development of laboratory bench radioisotope X-ray fluorescence analyzer[J].Non-ferrous Metals:Smelting Part,1975(7):10-16,41.
[27]河北铜矿化验室,国营二六一厂三室,北京矿冶研究院自动化室.台式放射性同位素X射线荧光分析仪的实验[J].有色金属:冶炼部分,1977(4):11-16,19.Hebei Copper Mine Laboratory,State-run 261-3,Beijing Institute of Mining and Metallurgy Automation Room.Experiment of bench-type radioisotope X-ray fluorescence analyzer[J].Non-ferrous Metals:Smelting Part,1977(4):11-16,19.
[28]河北铜矿龙潭分矿,国营二六一厂三室,北京矿冶研究院自动化室.放射性同位素X射线荧光分析仪的现场实验[J].有色金属:采矿部分,1977(3):9-15.Hebei Copper Mine Laboratory,State-run 261-3,Beijing Institute of Mining and Metallurgy Automation Room.Field experiment of radioisotope X-ray fluorescence analyzer[J].Non-ferrous Metals:Mining,1977(3):9-15.
[29]吉林大学物理系原子核物理教研室.XY-1型便携式放射性同位素X射线荧光分析仪[J].吉林大学学报:自然科学版,1977(3):43-48.Faculty of Atomic Nuclear Physics,Department of Physics,Jilin University.Model XY-1portable radioisotope X-ray fluorescence analyzer[J].Journal of Jilin University:Natural Science Edition,1977(3):43-48.
[30]河北铜矿化验室.用源靶组合体法测定铜精矿中的铁[J].有色金属:冶炼部分,1978(3):16-19.Hebei Copper Mine Laboratory.Determination of iron in copper concentrate by source-target combination method[J].Non-ferrous Metals:Smelting Part,1978(3):16-19.
[31]张光华,赖章生,常立志.放射性同位素X射线荧光分析仪在中条山铜矿的应用[J].核技术,1986(6):35-37,60.ZHANG Guang-hua,LAI Zhang-sheng,CHANG Li-zhi.Application of radioisotope X-ray fluorescence analyzer in Zhongtiaoshan Copper Mine[J].Nuclear Techniques,1986(6):35-37,60.
[32]章哗.X射线荧光技术现场原位测铜量上的应用[J].矿产与地质,1992(3):238-241.ZHANG Ye.Application of X-ray fluorescence in situ measurement of copper content[J].Mineral Resources and Geology,1992(3):238-241.
[33]许春林.X射线荧光探矿技术在福建紫金山铜矿区的应用效果[J].物探与化探,1993(2):116-119.XU Chu-lin.Application effect of X-ray fluorescence prospecting technology in Zijinshan copper mine,Fujian province[J].Geophysical and Geochemical Exploration,1993(2):116-119.
[34]方同秀,周道玉.狮子山铜矿岩壁X取样研究与应用[J].物探化探计算技术,1996(S1):118-121.FANG Tong-xiu,ZHOU Dao-yu.Research and applications of X-sampling on rock surface at Shizishan copper deposit[J].Computing Techniques for Geophysical and Geochemical Exploration,1996(S1):118-121.
[35]郑建安,庹先国.X射线荧光快速分析多类型铜精矿品位[J].分析试验室,1998,17(3):84-86.ZHENG Jian-an,TUO Xian-guo.The rapid analysis of defferent types of copper concentrate by XRF[J].Analytical Laboratory,1998,17(3):84-86.
[36]周四春.携带式X荧光仪监控金铜矿石选矿应用研究[J].核技术,2001,24(6):515-520.ZHOU Si-chun.A study on benefiting Cu-bearing gold ore by monitoring the ore-dressing process with a portable XRF analyzer[J].Nuclear Techniques,2001,24(6):515-520.
[37]周四春,王德明,侯克功,等.X荧光取样技术在铜矿山的应用研究[J].有色矿山,2001,30(2):4-11.ZHOU Si-chun,WANG De-ming,HOU Ke-gong,et al.Study and application of XRF sampling technique on copper mines[J].Nonferrous Mines,2001,30(2):4-11.
[38]庹先国,任家富,郭海,等.X荧光现场取样技术在大红山铜矿的应用[J].金属矿山,2003(10):43-45.TUO Xian-guo,REN Jia-fu,GUO Hai,et al.Application of XRF in-situ sampling at Dahongshan copper mine[J].Metal Mine,2003(10):43-45.
[39]黄进初,喻东,吴永红,等.高精度XRF技术在新疆某铜镍矿的应用[J].金属矿山,2010(6):137-138,146.HUANG Jin-chu,YU Dong,WU Yong-hong,et al.Application of high precision XRF technology to a copper-nickel mine in Xinjiang[J].Metal Mine,2010(6):137-138,146.
[40]郑兴国,陈方强,葛良全,等.钻孔岩芯多元素原位X荧光分析技术及应用[J].金属矿山,2011(4):104-107,161.ZHENG Xing-guo,CHEN Fang-qiang,GE Liang-quan,et al.Research on multi-element in-situ XRF technique on drilling cores and its application[J].Metal Mine,2011(4):104-107,161.
[41]徐巧,杨新雨,付水兴,等.便携式X荧光分析仪在智利科皮亚波泥沟铜矿勘查中的应用[J].矿产勘查,2012,3(4):545-548.XU Qiao,YANG Xin-yu,FU Shui-xing,et al.Application of the portable XRF instrument in Nigou copper exploration,Copiapo,Chile[J].Mineral Exploration,2012,3(4):545-548.
[42]李吉生,鞠青海,邢谦,等.整装勘查区铜铅锌矿现场快速分析技术的发展现状及思考[J].光谱实验室,2013,30(4):1618-1621.LI Ji-sheng,JU Qing-hai,XING Qian,et al.Development status and thinking of quickly analysis technology with mineral(copper,lead and zinc)in the equipped erambulation area[J].Chinese Journal of Spectroscopy Laboratory,2013,30(4):1618-1621.
[43]马德锡,杨进,陈孝强,等.便携式X荧光仪在多金属矿区的应用[J].物探与化探,2013,37(1):63-66.MA De-xi,YANG Jin,CHEN Xiao-qiang,et al.Application of portable X-ray fluorescence instrument in polymetallic mining area[J].Geophysical &Geochemical Exploration,2013,37(1):63-66.
[44]曹发明,赖万昌,贾雪辉,等.XRF分析仪在青海某铜矿的应用研究[J].广东微量元素科学,2014,21(3):29-32.CAO Fa-ming,LAI Wan-chang,JIA Xue-hui,et al.Application of the XRF technology to analyze a copper ore in Qinghai[J].Guangdong Weiliang Yuansu Kexue,2014,21(3):29-32.
[45]梁爽,陈洋,刘龙利.手持式X射线荧光光谱仪在江西某铜矿中的应用[J].中国矿业,2017,26(S2):312-314.LIANG Shuang,CHEN Yang,LIU Long-li.Application of handheld X-ray fluorescence spectrometer in a copper ore in Jiangxi province[J].China Mining Magazine,2017,26(S2):312-314.
[46]郑正华.XRF矿石分析仪在紫金山铜矿生产中的应用探讨[J].世界有色金属,2018(11):271-272.ZHENG Zheng-hua.Discussion on application of XRF ore analyzer in production of Zijinshan copper mine[J].World Non-ferrous Metals,2018(11):271-272.
[47]袁汉章,吴长存,卜赛斌,等.铜矿选矿流程中铜、铁、硫、硅、铝、钼和钛的X射线荧光光谱直接测定[J].分析化学,1981,9(2):146-152.YUAN Han-zhang,WU Chang-cun,PU Sai-bin,et al.Determination of copper,iron,sulfur,silicon,aluminum,molybdenum and titanium in the ore-dressing process of copper ores by X-ray fluorescence spectroscopy[J].Analytical Chemistry,1981,9(2):146-152.
[48]曹慧君.Panalytical Magix(PW2403)型波长色散X射线荧光光谱仪测定铜矿石中的Pb、As、Zn、Mn、Na2O、TiO2[J].铝镁通讯,2010(4):40-42.CAO Hui-jun.Determination of Pb,As,Zn,Mn,Na2O,TiO2in copper ores by Panalytical Magix(PW2403)wavelength dispersive X-ray fluorescence spectrometer[J].LVMei Tongxun,2010(4):40-42.
[49]龙昌玉,李小莉,张勤,等.能量色散X射线荧光光谱仪现场快速测定多金属矿中17种组分[J].岩矿测试,2010,29(3):313-315.LONG Chang-yu,LI Xiao-li,ZHANG Qin,et al.Onsite determination of 17components in polymetallic ores by energy dispersive X-ray fluorescence spectrometry[J].Rock and Mineral Analysis,2010,29(3):313-315.
[50]刘江斌,黄兴华,武永芝,等.X射线荧光光谱法同时快速测定多金属矿样品中的铜、铅、锌、钼、钨和硫等元素[J].光谱实验室,2012,29(3):1555-1558.LIU Jiang-bin,HUANG Xing-hua,WU Yong-zhi,et al.Simultaneous and rapid determination of Cu,Pb,Zn,Mo,W and S in polymetallic ore samples by X-ray fluorescence spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2012,29(3):1555-1558.
[51]夏鹏超,李明礼,王祝,等.粉末压片制样-波长色散X射线荧光光谱法测定斑岩型钼铜矿中主次量元素钼铜铅锌砷镍硫[J].岩矿测试,2012,31(3):468-472.XIA Peng-chao,LI Ming-li,WANG Zhu,et al.Determination of major and minor elements of Mo,Cu,Pb,Zn,As,Ni and S in the porphyry type lindgrenite by wavelength dispersive X-ray fluorescence spectrometry with pressed-powder pellets[J].Rock and Mineral Analysis,2012,31(3):468-472.
[52]张二平.X射线荧光光谱仪测定铜精矿中多种元素[J].铜业工程,2013(1):41-42,50.ZHANG Er-ping.X ray fluorescence spectrometer for determination of a variety of elements in copper concentrate[J].Copper Engineering,2013(1):41-42,50.
[53]刘建平.X射线荧光光谱法测定铜钼矿石样品中的Cu、Mo[J].世界有色金属,2016(8):157-159.LIU Jian-ping.Determination of Cu,Mo in Cu-Mo ore samples by X-ray fluorescence spectrometry[J].World Non-ferrous Metals,2016(8):157-159.
[54]卢卫星,李广汉.丰山铜矿X射线荧光光谱分析法与传统滴定法的对比研究[J].采矿技术,2016,16(3):70-71,96.LU Wei-xing,LI Guang-han.Comparative study of Xray fluorescence spectrophotometry and traditional titration in Fengshan copper mine[J].Mining Technology,2016,16(3):70-71,96.
[55]吕新明,田延河,宁海龙,等.波长色散X射线荧光光谱仪和多晶X射线衍射仪联用技术鉴定进口铜矿和含铜物料[J].中国无机分析化学,2018,8(4):21-25.LXin-ming,TIAN Yan-he,NING Hai-dong,et al.Identification of imports of copper and copper materials by wavelength dispersive X-ray fluorescence(XRF)spectrometer and polycrsstalline X-ray diffraction(XRD)spectrometry[J].Inorganic Analytical Chemistry in China,2018,8(4):21-25.
[56]郑厚琳,吴名剑.X射线荧光光谱薄膜法测定多金属矿样中常量Pb、Zn、Cu、Fe、Mn[J].分析试验室,1994,13(1):74-77.ZHENG Hou-lin,WU Ming-jian.Determination of Pb,Zn,Cu,Fe,Mn in ores by thin film X-ray fluorescence spectrometry[J].Analytical Laboratory,1994,13(1):74-77.
[57]赵耀,王再田.XRF熔融制样法测定铜精矿中的Cu、Fe、S、Pb、Zn、As、Bi、Mo[J].分析试验室,1999,18(1):19-22.ZHAO Yao,WANG Zai-tian.XRF analysis of sulphide copper ores by fusion method[J].Analytical Laboratory,1999,18(1):19-22.
[58]郝丽萍,王再田.熔融制样法对硫铁矿、铜精矿和方铅矿主量元素的XRF光谱测定[J].兵器材料科学与工程,2002(5):58-59,72.HAO Li-ping,WANG Zai-tian.X-ray fluorescent spectrum determination of main elements in samples of copper concentrate troilite,galena prepared by smelting method[J].Ordnance Material Science and Engineering,2002(5):58-59,72.
[59]田琼,黄健,钟志光,等.波长色散X射线荧光光谱法测定铜精矿中铜铅锌硫镁砷[J].岩矿测试,2009,28(4):382-384.TIAN Qiong,HUANG Jian,ZHONG Zhi-guang,et al.Determination of Cu,Pb,Zn,S,Mg and As in copper concentrates by wavelength dispersive X-ray fluorescence spectrometry[J].Rock and Mineral Analysis,2009,28(4):382-384.
[60]曹慧君,张爱芬,马慧侠,等.X射线荧光光谱法测定铜矿中主次成分[J].冶金分析,2010,30(10):20-24.CAO Hui-jun,ZHANG Ai-fen,MA Hui-xia,et al.Determination of major and minor components in copper ore by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2010,30(10):20-24.
[61]李小莉,唐力君,黄进初.X射线荧光光谱熔融片法测定铜矿中的主次元素[J].冶金分析,2012,32(7):67-70.LI Xiao-li,TANG Li-jun,HUANG Jin-chu.Determination of major and minor elements in copper ore by Xray fluorescence spectrometry[J].Metallurgical Analysis,2012,32(7):67-70.
[62]杨小丽,刘昱恒.XRF法测定以Cu、Pb、Zn为主的多金属矿中的主次元素[J].现代仪器,2012,18(4):18-21.YANG Xiao-li,LIU Yu-heng.Determination of major and minor elements in Cu,Pb,Zn primarily polymetallic ore by X fluorescence spectrometry[J].Modern Instrument,2012,18(4):18-21.
[63]史梨花,袁长生.X射线荧光光谱熔融片法测定铜矿中的主次元素[J].江西建材,2013(3):251-252.SHI Li-hua,YUAN Chang-sheng.Determination of primary and secondary elements in copper ore by X-ray fluorescence spectroscopic melting sheet method[J].Jiangxi Building Materials,2013(3):251-252.
[64]李可及.熔融制样-X射线荧光光谱法测定硫化铜钼矿中主成分[J].冶金分析,2014,34(4):6-10.LI Ke-ji.Determination of major components in sulfide copper-molybdenum ore by X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2014,34(4):6-10.
[65]罗学辉,苏建芝,鹿青,等.熔融制样X射线荧光光谱法测定铜矿石中16种主次量元素[J].岩矿测试,2014,33(2):230-235.LUO Xue-hui,SU Jian-zhi,LU Qing,et al.Determination of 16elements in copper ores by X-ray fluorescence spectrometry with fused sample preparation[J].Rock and Mineral Analysis,2014,33(2):230-235.
[66]李先和,万双,刘子健,等.X射线荧光光谱法测定铜精矿中10种元素[J].冶金分析,2016,36(6):55-59.LI Xian-he,WAN Shuang,LIU Zi-jian,et al.Determination of ten elements in copper concentrate by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2016,36(6):55-59.
[67]李禄宏,赵淑宏.基于X荧光光谱分析法测定铅锌铜矿石中的主次组分[J].世界有色金属,2017(1):110-111.LI Lu-hong,ZHAO Shu-hong.Determination of major and minor components in lead zinc copper ore based on X-ray[J].World Non-ferrous Metals,2017(1):110-111.
[68]窦怀智,蒋晓光,张晓冬,等.熔融制样-波长色散X射线荧光光谱法测定铜精矿中主次成分[J].冶金分析,2018,38(1):29-35.DOU Huai-zhi,JIANG Xiao-guang,ZHANG Xiao-dong,et al.Determination of major and minor components in copper concentrate by wavelength dispersive X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2018,38(1):29-35.
[69]谢琼心.X射线荧光光谱分析法测定多金属矿中的铅锌铜[J].分析试验室,1997,16(5):76-78.XIE Qiong-xin.Determination of Pb,Zn,Cu in polymetal mineral by XRFA[J].Analytical Laboratory,1997,16(5):76-78.
[70]郭芬,宋义,谷松海,等.X射线荧光光谱法测定铜精矿中砷、铅和镉[J].理化检验:化学分册,2011,47(8):984-985.GUO Fen,SONG Yi,GU Song-hai,et.al.Determination of As,Pb and Cd in copper concentrate by X-ray fluorescence spectrometry[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2011,47(8):984-985.
[71]龙海珍,孔会民,马富超,等.粉末压片制样-X射线荧光光谱法在监控铜选矿流程中的应用[J].光谱实验室,2013,30(1):141-144.LONG Hai-zhen,KONG Hui-min,MA Fu-chao,et al.Application of powder compacting sample preparationX-ray fluorescence spectrometry in monitoring copper dressing process[J].Chinese Journal of Spectroscopy Laboratory,2013,30(1):141-144.
[72]唐梦奇,刘顺琼,袁焕明,等.粉末压片制样-波长色散X射线荧光光谱法测定进口铜矿石中的氟[J].岩矿测试,2013,32(2):254-257.TANG Meng-qi,LIU Shun-qiong,YUAN Huan-ming,et al.Determination of fluorine in import copper ores by wavelength dispersive X-ray fluorescence spectrometry with pressed powder preparation[J].Rock and Mineral Analysis,2013,32(2):254-257.
[73]杨发旺,谈建安,刘江斌,等.X射线荧光光谱法测定多金属矿石中的铜和钼[J].光谱实验室,2013,30(3):1371-1375.YANG Fa-wang,TAN Jian-an,LIU Jiang-bin,et al.Determination of copper and molybdenum in polymetallic ore by X-ray fluorescence spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2013,30(3):1371-1375.
[74]陈法荣.X射线荧光光谱分析铜精矿中的铜和铁[J].岩矿测试,1989,8(2):145-146.CHEN Fa-rong.Analysis of copper and iron in copper concentrate by X-ray fluorescence spectrometry[J].Rock and Mineral Analysis,1989,8(2):145-146.
[75]毛振伟,张巽,李凡庆,等.X射线荧光光谱滤纸片法测定矿石中的铜[J].分析试验室,1997,16(2):48-50.MAO Zhen-wei,ZHANG Xun,LI Fan-qing,et al.Determination of copper in ores by X-ray fluorescence spectrum filter paper method[J].Analytical Laboratory,1997,16(2):48-50.
[76]蒯丽君,樊兴涛,詹秀春,等.酸消解-车载偏振能量色散X射线荧光法现场测定祁曼塔格多金属矿中高品位铜铅锌[J].岩矿测试,2013,32(4):538-546.KUAI Li-jun,FAN Xing-tao,ZHAN Xiu-chun,et al.On-site analysis of Cu,Pb and Zn in polymetallic ores from Qimantage area by vehicle-loaded polarized energy dispersive X-ray fluorescence spectrometer with acid digestion[J].Rock and Mineral Analysis,2013,32(4):538-546.
[77]高新华,宋武元,邓赛文,等.实用X射线荧光光谱分析[M].北京:化学工业出版社,2016:1-365.
[78]罗立强,詹秀春,李国会.X射线荧光光谱仪[M].北京:化学工业出版社,2008:1-188.
[79]刘尚华,陶光仪,吉昂.X射线荧光光谱分析中的粉末压片制样法[J].光谱实验室,1998,15(6):9-15.LIU Shang-hua,TAO Guang-yi,JI Ang.Powder pellets preparation for X-ray fluorescence analysis[J].Chinese Journal of Spectroscopy Laboratory,1998,15(6):9-15.
[80]邓赛文,王祎亚,王毅民.中国磷矿石分析文献评介[J].岩矿测试,2011,30(3):384-390.DENG Sai-wen,WANG Yi-ya,WANG Yi-min.A review on literatures of phosphate ores analysis in China[J].Rock and Mineral Analysis,2011,30(3):384-390.
[81]胥成民,刘邦杰.X射线荧光光谱粉末直接压片法测定哈默斯雷铁矿中的主次元素含量[J].光谱实验室,1998(2):80-83.XU Cheng-min,LIU Bang-jie.Determination of primary and minor elements in Hammersley iron ore by X-ray fluorescence spectrometric method[J].Chinese Journal of Spectroscopy Laboratory,1998(2):80-83.
[82]王晓红,高玉淑,王毅民.超细地质标准物质及其应用[J].自然科学进展,2006,16(3):309-315.WANG Xiao-hong,GAO Yu-shu,WANG Yi-min.Ultra-fine geological reference material and its application[J].Advances in Natural Sciences,2006,16(3):309-315.
[83]王晓红,何红蓼,王毅民,等.超细样品的地质分析应用[J].分析测试学报,2010,29(6):578-583.WANG Xiao-hong,HE Hong-liao,WANG Yi-min,et al.Geoanalytical techniques using ultra-fine samples[J].Journal of Analytical Testing,2010,29(6):578-583.
[84]王毅民,王晓红.我国地质分析中X射线光谱技术的回顾与发展[J].岩矿测试,2000,19(4):275-285.WANG Yi-min,WANG Xiao-hong.The review and prospect on X-ray spectrometry in geoanalysis in China[J].Rock and Mineral Analysis,2000,19(4):275-285.
[85]佡云,贾丽娜.粉末压片制样X-射线荧光光谱法测定铁矿石中主次元素[J].有色矿冶,2017,33(4):52-56,65.NAO Yun,JIA Li-na.Analysis of iron ore component using XRF with powder pressured sample method[J].Non-ferrous Mining and Metallurgy,2017,33(4):52-56,65.
[86]宁艳,蓝恩洪,黄义伟,等.X荧光光谱仪在锰矿分析中的应用拓展[J].轻工科技,2012,28(10):25-26.NING Yan,LAN En-hong,HUANG Yi-wei,et al.Application of X-ray fluorescence spectrometer in manganese ore analysis[J].Light Industry Science and Technology,2012,28(10):25-26.
[87]熊刚.X荧光光谱仪在锰矿分析中的应用前景[J].中国化工贸易,2013(1):152.XIONG Gang.Application prospect of X-ray fluorescence spectrometer in manganese ore analysis[J].China Chemical Trade,2013(1):152.
[88]铁生年,俞径保,麻鑫,等.X荧光光谱法测铬铁矿中Cr、Fe、Si、Mg、Al、Ca的含量[J].冶金标准化与质量,1998(12):16.TIE Sheng-nian,YU Jing-bao,MA Xin,et al.Determination of Cr,Fe,Si,Mg,Al,Ca in chromite by X-ray fluorescence spectrometry[J].Metallurgical Standardization and Quality,1998(12):16.
[89]卜兆杰,王晓旋,黄健强,等.粉末压片制样-X射线荧光光谱法测定铬矿砂中6种氧化物[J].理化检验:化学分册,2017,53(8):978-980.BU Zhao-jie,WANG Xiao-xuan,HUANG Jian-qiang,et al.Determination of six oxides in chromium ore by powder compression preparation sample and X-ray fluorescence spectrometry[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2017,53(8):978-980.
[2]陈甲斌,梁振杰,高鹏.中国铜资源现状与发展战略研究[J].世界有色金属,2005(12):8-11.CHEN Jia-bin,LIANG Zhen-jie,GAO Peng.A study on the current situation and development strategy of copper resources in China[J].World Nonferrous Metals,2005(12):8-11.
[3]陈四箴.安徽铜陵狮子山含铜钙钨矿之发现及分析[J].地质论评,1951(1):63-64.CHEN Si-zhen.Discovery and analysis of copper-bearing calcium-tungsten deposit in Shizishan,Tongling,Anhui province[J].GeoReview,1951(1):63-64.
[4]陈四箴.用氢氧化铵及氯化铵分离铜与铁[J].化学学报,1952(1):29-32.CHEN Si-zhen.Separation of copper and iron with ammonium hydroxide and ammonium chloride[J].Chinese Journal of Chemistry,1952(1):29-32.
[5]冶金部地质研究所.铜矿石中铜和铁的简易测定[J].地质与勘探,1958(22):18.Institute of Geology,Ministry of Metallurgy.Sample determination of copper and iron in copper ores[J].Geology and Exploration,1958(22):18.
[6]郑大中,张立成,赖明森.铜锌连续测定[J].化学通报,1966(4):53-55.ZHENG Da-zhong,ZHANG Li-cheng,LAI Ming-sen.Continuous determination of copper and zinc[J].Chemistry Bulletin,1966(4):53-55.
[7]肖慈林.原子吸收法测定矿石中铜、镍、钴[J].分析化学,1975,3(1):81-82.XIAO Ci-lin.Determination of copper,nickel and cobalt in ores by atomic absorption spectrometry[J].Analytical Chemistry,1975,3(1):81-82.
[8]路庆详.铜矿石中氧化铜总量的快速示波极谱测定[J].分析化学,1975,3(2):142-143.LU Qing-xiang.Rapid oscillopolarographic determination of total copper oxide in copper ores[J].Analytical Chemistry,1975,3(2):142-143.
[9]柳延极.水平电极在极谱分析中的应用—矿石中铜铅锌的测定[J].分析化学,1977,5(3):210-212.LIU Yan-ji.Application of horizontal electrode in polarographic analysis-Determination of copper,lead and zinc in ores[J].Analytical Chemistry,1977,5(3):210-212.
[10]陈建华,徐楚华,吴杭春.氢化物ICP-AES法测定铜精矿中砷和锑[J].检验检疫科学,1993(4):17-21.CHEN Jian-hua,XU Chu-hua,WU Hang-chun.Determination of arsenic and antimony in copper concentrate by hydride ICP-AES[J].Inspection and Quarantine Science,1993(4):17-21.
[11]高建文,董淑珍,张春田,等.ICP-AES方法同时测定铜精矿中十三种成份[J].光谱实验室,1998,15(1):47-55.GAO Jian-wen,DONG Shu-zhen,ZHANG Chun-tian,et al.Determination of 13components in copper concentrates by ICP-AES method[J].Chinese Journal of Spectroscopy Laboratory,1998,15(1):47-55.
[12]地质部矿物原料研究所.矿物原料分析[M].北京:地质出版社,1959:253-265.
[13]岩石矿物编写组.岩石矿物分析[M].2版.北京:地质出版社,1974:331-346.
[14]李连仲.岩石矿物分析:第1分册[M].3版.北京:地质出版社,1991:409-421.
[15]尹明,李家熙.岩石矿物分析:第3分册[M].4版.北京:地质出版社,2013:17-53,42-44.
[16]于力,符斌.有色冶金分析手册[M].北京:冶金工业出版社,2004:1-805.
[17]北京矿冶研究总院分析室.矿石及有色金属分析手册[M].北京:冶金工业出版社,1990:1-385.
[18]中华人民共和国国家质量监督检验检疫总局.SN/T4365—2015铜精矿中铜、铅、铬、砷、银、锑、铋、镍、铁、铝元素含量的测定波长色散X射线荧光光谱法[S].北京:中国标准出版社,2016.
[19]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 14263—2010散装浮选铜精矿取样、制样方法[S].北京:中国标准出版社,2011.
[20]全国标准物质管理委员会,中华人民共和国标准物质目录[S].北京:中国计量出版社,2010:54-216.
[21]王毅民,顾铁新,王晓红,等.实用地质分析标准物质手册(汉-英对照)[M].2版.北京:地质出版社,2013:589.
[22]侯晋,窦怀智,吕翔.我国进口铜精矿检验方法的研究进展[J].理化检验:化学分册,2010,46(10):1229-1232.HOU Jin,DOU Huai-zhi,LXiang.Recent progress on analytical methods for imported copper concentrates[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2010,46(10):1229-1232.
[23]许德娟,朱佩思,陈永欣,等.中国铜矿分析文献评介[J].大众科技,2013,15(7):58-63.XU De-juan,ZHU Pei-si,CHEN Yong-xin,et al.A review on literatures of copper ores analysis in China[J].Popular Science &Technology,2013,15(7):58-63.
[24]梁亚平.铜矿石化学分析方法概述与评价[J].甘肃科技,2015,31(18):52-53.LIANG Ya-ping.Overview and evaluation of chemical analysis methods for copper ore[J].Gansu Science and Technology,2015,31(18):52-53.
[25]蒋晓光,周蕾,褚宁,等.X射线荧光光谱分析硫化铜矿及其精矿的进展[J].冶金分析,2017,37(7):23-30.JIANG Xiao-guang,ZHOU Lei,CHU Ning,et al.Progress on X-ray fluorescence spectrometric analysis of copper sulfide ore and its concentrate[J].Metallurgical Analysis,2017,37(7):23-30.
[26]北京矿冶研究院放射性同位素X射线荧光分析专题组.实验室台式放射性同位素X射线荧光分析仪的研制[J].有色金属:冶炼部分,1975(7):10-16,41.Beijing Institute of Mining and Metallurgy Radioisotope X-ray Fluorescence Analysis Group.Development of laboratory bench radioisotope X-ray fluorescence analyzer[J].Non-ferrous Metals:Smelting Part,1975(7):10-16,41.
[27]河北铜矿化验室,国营二六一厂三室,北京矿冶研究院自动化室.台式放射性同位素X射线荧光分析仪的实验[J].有色金属:冶炼部分,1977(4):11-16,19.Hebei Copper Mine Laboratory,State-run 261-3,Beijing Institute of Mining and Metallurgy Automation Room.Experiment of bench-type radioisotope X-ray fluorescence analyzer[J].Non-ferrous Metals:Smelting Part,1977(4):11-16,19.
[28]河北铜矿龙潭分矿,国营二六一厂三室,北京矿冶研究院自动化室.放射性同位素X射线荧光分析仪的现场实验[J].有色金属:采矿部分,1977(3):9-15.Hebei Copper Mine Laboratory,State-run 261-3,Beijing Institute of Mining and Metallurgy Automation Room.Field experiment of radioisotope X-ray fluorescence analyzer[J].Non-ferrous Metals:Mining,1977(3):9-15.
[29]吉林大学物理系原子核物理教研室.XY-1型便携式放射性同位素X射线荧光分析仪[J].吉林大学学报:自然科学版,1977(3):43-48.Faculty of Atomic Nuclear Physics,Department of Physics,Jilin University.Model XY-1portable radioisotope X-ray fluorescence analyzer[J].Journal of Jilin University:Natural Science Edition,1977(3):43-48.
[30]河北铜矿化验室.用源靶组合体法测定铜精矿中的铁[J].有色金属:冶炼部分,1978(3):16-19.Hebei Copper Mine Laboratory.Determination of iron in copper concentrate by source-target combination method[J].Non-ferrous Metals:Smelting Part,1978(3):16-19.
[31]张光华,赖章生,常立志.放射性同位素X射线荧光分析仪在中条山铜矿的应用[J].核技术,1986(6):35-37,60.ZHANG Guang-hua,LAI Zhang-sheng,CHANG Li-zhi.Application of radioisotope X-ray fluorescence analyzer in Zhongtiaoshan Copper Mine[J].Nuclear Techniques,1986(6):35-37,60.
[32]章哗.X射线荧光技术现场原位测铜量上的应用[J].矿产与地质,1992(3):238-241.ZHANG Ye.Application of X-ray fluorescence in situ measurement of copper content[J].Mineral Resources and Geology,1992(3):238-241.
[33]许春林.X射线荧光探矿技术在福建紫金山铜矿区的应用效果[J].物探与化探,1993(2):116-119.XU Chu-lin.Application effect of X-ray fluorescence prospecting technology in Zijinshan copper mine,Fujian province[J].Geophysical and Geochemical Exploration,1993(2):116-119.
[34]方同秀,周道玉.狮子山铜矿岩壁X取样研究与应用[J].物探化探计算技术,1996(S1):118-121.FANG Tong-xiu,ZHOU Dao-yu.Research and applications of X-sampling on rock surface at Shizishan copper deposit[J].Computing Techniques for Geophysical and Geochemical Exploration,1996(S1):118-121.
[35]郑建安,庹先国.X射线荧光快速分析多类型铜精矿品位[J].分析试验室,1998,17(3):84-86.ZHENG Jian-an,TUO Xian-guo.The rapid analysis of defferent types of copper concentrate by XRF[J].Analytical Laboratory,1998,17(3):84-86.
[36]周四春.携带式X荧光仪监控金铜矿石选矿应用研究[J].核技术,2001,24(6):515-520.ZHOU Si-chun.A study on benefiting Cu-bearing gold ore by monitoring the ore-dressing process with a portable XRF analyzer[J].Nuclear Techniques,2001,24(6):515-520.
[37]周四春,王德明,侯克功,等.X荧光取样技术在铜矿山的应用研究[J].有色矿山,2001,30(2):4-11.ZHOU Si-chun,WANG De-ming,HOU Ke-gong,et al.Study and application of XRF sampling technique on copper mines[J].Nonferrous Mines,2001,30(2):4-11.
[38]庹先国,任家富,郭海,等.X荧光现场取样技术在大红山铜矿的应用[J].金属矿山,2003(10):43-45.TUO Xian-guo,REN Jia-fu,GUO Hai,et al.Application of XRF in-situ sampling at Dahongshan copper mine[J].Metal Mine,2003(10):43-45.
[39]黄进初,喻东,吴永红,等.高精度XRF技术在新疆某铜镍矿的应用[J].金属矿山,2010(6):137-138,146.HUANG Jin-chu,YU Dong,WU Yong-hong,et al.Application of high precision XRF technology to a copper-nickel mine in Xinjiang[J].Metal Mine,2010(6):137-138,146.
[40]郑兴国,陈方强,葛良全,等.钻孔岩芯多元素原位X荧光分析技术及应用[J].金属矿山,2011(4):104-107,161.ZHENG Xing-guo,CHEN Fang-qiang,GE Liang-quan,et al.Research on multi-element in-situ XRF technique on drilling cores and its application[J].Metal Mine,2011(4):104-107,161.
[41]徐巧,杨新雨,付水兴,等.便携式X荧光分析仪在智利科皮亚波泥沟铜矿勘查中的应用[J].矿产勘查,2012,3(4):545-548.XU Qiao,YANG Xin-yu,FU Shui-xing,et al.Application of the portable XRF instrument in Nigou copper exploration,Copiapo,Chile[J].Mineral Exploration,2012,3(4):545-548.
[42]李吉生,鞠青海,邢谦,等.整装勘查区铜铅锌矿现场快速分析技术的发展现状及思考[J].光谱实验室,2013,30(4):1618-1621.LI Ji-sheng,JU Qing-hai,XING Qian,et al.Development status and thinking of quickly analysis technology with mineral(copper,lead and zinc)in the equipped erambulation area[J].Chinese Journal of Spectroscopy Laboratory,2013,30(4):1618-1621.
[43]马德锡,杨进,陈孝强,等.便携式X荧光仪在多金属矿区的应用[J].物探与化探,2013,37(1):63-66.MA De-xi,YANG Jin,CHEN Xiao-qiang,et al.Application of portable X-ray fluorescence instrument in polymetallic mining area[J].Geophysical &Geochemical Exploration,2013,37(1):63-66.
[44]曹发明,赖万昌,贾雪辉,等.XRF分析仪在青海某铜矿的应用研究[J].广东微量元素科学,2014,21(3):29-32.CAO Fa-ming,LAI Wan-chang,JIA Xue-hui,et al.Application of the XRF technology to analyze a copper ore in Qinghai[J].Guangdong Weiliang Yuansu Kexue,2014,21(3):29-32.
[45]梁爽,陈洋,刘龙利.手持式X射线荧光光谱仪在江西某铜矿中的应用[J].中国矿业,2017,26(S2):312-314.LIANG Shuang,CHEN Yang,LIU Long-li.Application of handheld X-ray fluorescence spectrometer in a copper ore in Jiangxi province[J].China Mining Magazine,2017,26(S2):312-314.
[46]郑正华.XRF矿石分析仪在紫金山铜矿生产中的应用探讨[J].世界有色金属,2018(11):271-272.ZHENG Zheng-hua.Discussion on application of XRF ore analyzer in production of Zijinshan copper mine[J].World Non-ferrous Metals,2018(11):271-272.
[47]袁汉章,吴长存,卜赛斌,等.铜矿选矿流程中铜、铁、硫、硅、铝、钼和钛的X射线荧光光谱直接测定[J].分析化学,1981,9(2):146-152.YUAN Han-zhang,WU Chang-cun,PU Sai-bin,et al.Determination of copper,iron,sulfur,silicon,aluminum,molybdenum and titanium in the ore-dressing process of copper ores by X-ray fluorescence spectroscopy[J].Analytical Chemistry,1981,9(2):146-152.
[48]曹慧君.Panalytical Magix(PW2403)型波长色散X射线荧光光谱仪测定铜矿石中的Pb、As、Zn、Mn、Na2O、TiO2[J].铝镁通讯,2010(4):40-42.CAO Hui-jun.Determination of Pb,As,Zn,Mn,Na2O,TiO2in copper ores by Panalytical Magix(PW2403)wavelength dispersive X-ray fluorescence spectrometer[J].LVMei Tongxun,2010(4):40-42.
[49]龙昌玉,李小莉,张勤,等.能量色散X射线荧光光谱仪现场快速测定多金属矿中17种组分[J].岩矿测试,2010,29(3):313-315.LONG Chang-yu,LI Xiao-li,ZHANG Qin,et al.Onsite determination of 17components in polymetallic ores by energy dispersive X-ray fluorescence spectrometry[J].Rock and Mineral Analysis,2010,29(3):313-315.
[50]刘江斌,黄兴华,武永芝,等.X射线荧光光谱法同时快速测定多金属矿样品中的铜、铅、锌、钼、钨和硫等元素[J].光谱实验室,2012,29(3):1555-1558.LIU Jiang-bin,HUANG Xing-hua,WU Yong-zhi,et al.Simultaneous and rapid determination of Cu,Pb,Zn,Mo,W and S in polymetallic ore samples by X-ray fluorescence spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2012,29(3):1555-1558.
[51]夏鹏超,李明礼,王祝,等.粉末压片制样-波长色散X射线荧光光谱法测定斑岩型钼铜矿中主次量元素钼铜铅锌砷镍硫[J].岩矿测试,2012,31(3):468-472.XIA Peng-chao,LI Ming-li,WANG Zhu,et al.Determination of major and minor elements of Mo,Cu,Pb,Zn,As,Ni and S in the porphyry type lindgrenite by wavelength dispersive X-ray fluorescence spectrometry with pressed-powder pellets[J].Rock and Mineral Analysis,2012,31(3):468-472.
[52]张二平.X射线荧光光谱仪测定铜精矿中多种元素[J].铜业工程,2013(1):41-42,50.ZHANG Er-ping.X ray fluorescence spectrometer for determination of a variety of elements in copper concentrate[J].Copper Engineering,2013(1):41-42,50.
[53]刘建平.X射线荧光光谱法测定铜钼矿石样品中的Cu、Mo[J].世界有色金属,2016(8):157-159.LIU Jian-ping.Determination of Cu,Mo in Cu-Mo ore samples by X-ray fluorescence spectrometry[J].World Non-ferrous Metals,2016(8):157-159.
[54]卢卫星,李广汉.丰山铜矿X射线荧光光谱分析法与传统滴定法的对比研究[J].采矿技术,2016,16(3):70-71,96.LU Wei-xing,LI Guang-han.Comparative study of Xray fluorescence spectrophotometry and traditional titration in Fengshan copper mine[J].Mining Technology,2016,16(3):70-71,96.
[55]吕新明,田延河,宁海龙,等.波长色散X射线荧光光谱仪和多晶X射线衍射仪联用技术鉴定进口铜矿和含铜物料[J].中国无机分析化学,2018,8(4):21-25.LXin-ming,TIAN Yan-he,NING Hai-dong,et al.Identification of imports of copper and copper materials by wavelength dispersive X-ray fluorescence(XRF)spectrometer and polycrsstalline X-ray diffraction(XRD)spectrometry[J].Inorganic Analytical Chemistry in China,2018,8(4):21-25.
[56]郑厚琳,吴名剑.X射线荧光光谱薄膜法测定多金属矿样中常量Pb、Zn、Cu、Fe、Mn[J].分析试验室,1994,13(1):74-77.ZHENG Hou-lin,WU Ming-jian.Determination of Pb,Zn,Cu,Fe,Mn in ores by thin film X-ray fluorescence spectrometry[J].Analytical Laboratory,1994,13(1):74-77.
[57]赵耀,王再田.XRF熔融制样法测定铜精矿中的Cu、Fe、S、Pb、Zn、As、Bi、Mo[J].分析试验室,1999,18(1):19-22.ZHAO Yao,WANG Zai-tian.XRF analysis of sulphide copper ores by fusion method[J].Analytical Laboratory,1999,18(1):19-22.
[58]郝丽萍,王再田.熔融制样法对硫铁矿、铜精矿和方铅矿主量元素的XRF光谱测定[J].兵器材料科学与工程,2002(5):58-59,72.HAO Li-ping,WANG Zai-tian.X-ray fluorescent spectrum determination of main elements in samples of copper concentrate troilite,galena prepared by smelting method[J].Ordnance Material Science and Engineering,2002(5):58-59,72.
[59]田琼,黄健,钟志光,等.波长色散X射线荧光光谱法测定铜精矿中铜铅锌硫镁砷[J].岩矿测试,2009,28(4):382-384.TIAN Qiong,HUANG Jian,ZHONG Zhi-guang,et al.Determination of Cu,Pb,Zn,S,Mg and As in copper concentrates by wavelength dispersive X-ray fluorescence spectrometry[J].Rock and Mineral Analysis,2009,28(4):382-384.
[60]曹慧君,张爱芬,马慧侠,等.X射线荧光光谱法测定铜矿中主次成分[J].冶金分析,2010,30(10):20-24.CAO Hui-jun,ZHANG Ai-fen,MA Hui-xia,et al.Determination of major and minor components in copper ore by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2010,30(10):20-24.
[61]李小莉,唐力君,黄进初.X射线荧光光谱熔融片法测定铜矿中的主次元素[J].冶金分析,2012,32(7):67-70.LI Xiao-li,TANG Li-jun,HUANG Jin-chu.Determination of major and minor elements in copper ore by Xray fluorescence spectrometry[J].Metallurgical Analysis,2012,32(7):67-70.
[62]杨小丽,刘昱恒.XRF法测定以Cu、Pb、Zn为主的多金属矿中的主次元素[J].现代仪器,2012,18(4):18-21.YANG Xiao-li,LIU Yu-heng.Determination of major and minor elements in Cu,Pb,Zn primarily polymetallic ore by X fluorescence spectrometry[J].Modern Instrument,2012,18(4):18-21.
[63]史梨花,袁长生.X射线荧光光谱熔融片法测定铜矿中的主次元素[J].江西建材,2013(3):251-252.SHI Li-hua,YUAN Chang-sheng.Determination of primary and secondary elements in copper ore by X-ray fluorescence spectroscopic melting sheet method[J].Jiangxi Building Materials,2013(3):251-252.
[64]李可及.熔融制样-X射线荧光光谱法测定硫化铜钼矿中主成分[J].冶金分析,2014,34(4):6-10.LI Ke-ji.Determination of major components in sulfide copper-molybdenum ore by X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2014,34(4):6-10.
[65]罗学辉,苏建芝,鹿青,等.熔融制样X射线荧光光谱法测定铜矿石中16种主次量元素[J].岩矿测试,2014,33(2):230-235.LUO Xue-hui,SU Jian-zhi,LU Qing,et al.Determination of 16elements in copper ores by X-ray fluorescence spectrometry with fused sample preparation[J].Rock and Mineral Analysis,2014,33(2):230-235.
[66]李先和,万双,刘子健,等.X射线荧光光谱法测定铜精矿中10种元素[J].冶金分析,2016,36(6):55-59.LI Xian-he,WAN Shuang,LIU Zi-jian,et al.Determination of ten elements in copper concentrate by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2016,36(6):55-59.
[67]李禄宏,赵淑宏.基于X荧光光谱分析法测定铅锌铜矿石中的主次组分[J].世界有色金属,2017(1):110-111.LI Lu-hong,ZHAO Shu-hong.Determination of major and minor components in lead zinc copper ore based on X-ray[J].World Non-ferrous Metals,2017(1):110-111.
[68]窦怀智,蒋晓光,张晓冬,等.熔融制样-波长色散X射线荧光光谱法测定铜精矿中主次成分[J].冶金分析,2018,38(1):29-35.DOU Huai-zhi,JIANG Xiao-guang,ZHANG Xiao-dong,et al.Determination of major and minor components in copper concentrate by wavelength dispersive X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2018,38(1):29-35.
[69]谢琼心.X射线荧光光谱分析法测定多金属矿中的铅锌铜[J].分析试验室,1997,16(5):76-78.XIE Qiong-xin.Determination of Pb,Zn,Cu in polymetal mineral by XRFA[J].Analytical Laboratory,1997,16(5):76-78.
[70]郭芬,宋义,谷松海,等.X射线荧光光谱法测定铜精矿中砷、铅和镉[J].理化检验:化学分册,2011,47(8):984-985.GUO Fen,SONG Yi,GU Song-hai,et.al.Determination of As,Pb and Cd in copper concentrate by X-ray fluorescence spectrometry[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2011,47(8):984-985.
[71]龙海珍,孔会民,马富超,等.粉末压片制样-X射线荧光光谱法在监控铜选矿流程中的应用[J].光谱实验室,2013,30(1):141-144.LONG Hai-zhen,KONG Hui-min,MA Fu-chao,et al.Application of powder compacting sample preparationX-ray fluorescence spectrometry in monitoring copper dressing process[J].Chinese Journal of Spectroscopy Laboratory,2013,30(1):141-144.
[72]唐梦奇,刘顺琼,袁焕明,等.粉末压片制样-波长色散X射线荧光光谱法测定进口铜矿石中的氟[J].岩矿测试,2013,32(2):254-257.TANG Meng-qi,LIU Shun-qiong,YUAN Huan-ming,et al.Determination of fluorine in import copper ores by wavelength dispersive X-ray fluorescence spectrometry with pressed powder preparation[J].Rock and Mineral Analysis,2013,32(2):254-257.
[73]杨发旺,谈建安,刘江斌,等.X射线荧光光谱法测定多金属矿石中的铜和钼[J].光谱实验室,2013,30(3):1371-1375.YANG Fa-wang,TAN Jian-an,LIU Jiang-bin,et al.Determination of copper and molybdenum in polymetallic ore by X-ray fluorescence spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2013,30(3):1371-1375.
[74]陈法荣.X射线荧光光谱分析铜精矿中的铜和铁[J].岩矿测试,1989,8(2):145-146.CHEN Fa-rong.Analysis of copper and iron in copper concentrate by X-ray fluorescence spectrometry[J].Rock and Mineral Analysis,1989,8(2):145-146.
[75]毛振伟,张巽,李凡庆,等.X射线荧光光谱滤纸片法测定矿石中的铜[J].分析试验室,1997,16(2):48-50.MAO Zhen-wei,ZHANG Xun,LI Fan-qing,et al.Determination of copper in ores by X-ray fluorescence spectrum filter paper method[J].Analytical Laboratory,1997,16(2):48-50.
[76]蒯丽君,樊兴涛,詹秀春,等.酸消解-车载偏振能量色散X射线荧光法现场测定祁曼塔格多金属矿中高品位铜铅锌[J].岩矿测试,2013,32(4):538-546.KUAI Li-jun,FAN Xing-tao,ZHAN Xiu-chun,et al.On-site analysis of Cu,Pb and Zn in polymetallic ores from Qimantage area by vehicle-loaded polarized energy dispersive X-ray fluorescence spectrometer with acid digestion[J].Rock and Mineral Analysis,2013,32(4):538-546.
[77]高新华,宋武元,邓赛文,等.实用X射线荧光光谱分析[M].北京:化学工业出版社,2016:1-365.
[78]罗立强,詹秀春,李国会.X射线荧光光谱仪[M].北京:化学工业出版社,2008:1-188.
[79]刘尚华,陶光仪,吉昂.X射线荧光光谱分析中的粉末压片制样法[J].光谱实验室,1998,15(6):9-15.LIU Shang-hua,TAO Guang-yi,JI Ang.Powder pellets preparation for X-ray fluorescence analysis[J].Chinese Journal of Spectroscopy Laboratory,1998,15(6):9-15.
[80]邓赛文,王祎亚,王毅民.中国磷矿石分析文献评介[J].岩矿测试,2011,30(3):384-390.DENG Sai-wen,WANG Yi-ya,WANG Yi-min.A review on literatures of phosphate ores analysis in China[J].Rock and Mineral Analysis,2011,30(3):384-390.
[81]胥成民,刘邦杰.X射线荧光光谱粉末直接压片法测定哈默斯雷铁矿中的主次元素含量[J].光谱实验室,1998(2):80-83.XU Cheng-min,LIU Bang-jie.Determination of primary and minor elements in Hammersley iron ore by X-ray fluorescence spectrometric method[J].Chinese Journal of Spectroscopy Laboratory,1998(2):80-83.
[82]王晓红,高玉淑,王毅民.超细地质标准物质及其应用[J].自然科学进展,2006,16(3):309-315.WANG Xiao-hong,GAO Yu-shu,WANG Yi-min.Ultra-fine geological reference material and its application[J].Advances in Natural Sciences,2006,16(3):309-315.
[83]王晓红,何红蓼,王毅民,等.超细样品的地质分析应用[J].分析测试学报,2010,29(6):578-583.WANG Xiao-hong,HE Hong-liao,WANG Yi-min,et al.Geoanalytical techniques using ultra-fine samples[J].Journal of Analytical Testing,2010,29(6):578-583.
[84]王毅民,王晓红.我国地质分析中X射线光谱技术的回顾与发展[J].岩矿测试,2000,19(4):275-285.WANG Yi-min,WANG Xiao-hong.The review and prospect on X-ray spectrometry in geoanalysis in China[J].Rock and Mineral Analysis,2000,19(4):275-285.
[85]佡云,贾丽娜.粉末压片制样X-射线荧光光谱法测定铁矿石中主次元素[J].有色矿冶,2017,33(4):52-56,65.NAO Yun,JIA Li-na.Analysis of iron ore component using XRF with powder pressured sample method[J].Non-ferrous Mining and Metallurgy,2017,33(4):52-56,65.
[86]宁艳,蓝恩洪,黄义伟,等.X荧光光谱仪在锰矿分析中的应用拓展[J].轻工科技,2012,28(10):25-26.NING Yan,LAN En-hong,HUANG Yi-wei,et al.Application of X-ray fluorescence spectrometer in manganese ore analysis[J].Light Industry Science and Technology,2012,28(10):25-26.
[87]熊刚.X荧光光谱仪在锰矿分析中的应用前景[J].中国化工贸易,2013(1):152.XIONG Gang.Application prospect of X-ray fluorescence spectrometer in manganese ore analysis[J].China Chemical Trade,2013(1):152.
[88]铁生年,俞径保,麻鑫,等.X荧光光谱法测铬铁矿中Cr、Fe、Si、Mg、Al、Ca的含量[J].冶金标准化与质量,1998(12):16.TIE Sheng-nian,YU Jing-bao,MA Xin,et al.Determination of Cr,Fe,Si,Mg,Al,Ca in chromite by X-ray fluorescence spectrometry[J].Metallurgical Standardization and Quality,1998(12):16.
[89]卜兆杰,王晓旋,黄健强,等.粉末压片制样-X射线荧光光谱法测定铬矿砂中6种氧化物[J].理化检验:化学分册,2017,53(8):978-980.BU Zhao-jie,WANG Xiao-xuan,HUANG Jian-qiang,et al.Determination of six oxides in chromium ore by powder compression preparation sample and X-ray fluorescence spectrometry[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2017,53(8):978-980.