Ti-6Al-4V合金热浸铝涂层对磨GCr15钢干滑动的磨损行为（英文）
|
摘要
Ti-6Al-4V合金经热浸铝并在650℃下进行高温扩散退火处理,获得TiAl_3涂层。采用销-盘式磨损试验机研究铝化后的Ti-6Al-4V合金与GCr15钢对磨的干滑动磨损行为。通过SEM、XRD、EDS和XPS等手段分析热浸镀铝涂层磨面的形貌、物相和成分,并且探讨其磨损机制。研究结果表明:随着滑动速度的增加,当滑动速度为0.75 m/s时,铝化后的Ti-6Al-4V合金的磨损量先减小到最小值,然后在2.68 m/s时增加到最高值,最后在4 m/s时降至最低值。在不同的滑动速度下,磨损量随着载荷的增加而增加。研究发现,摩擦层结构对磨损的行为和机制有显著的影响。在4m/s时,含氧的摩擦层(TiO和TiO_2)具有明显的减磨性能;相反地,在2.68m/s时,没有氧化物的摩擦层并未对磨损显示出保护作用。与未经热浸镀处理的Ti-6Al-4V合金相比,在不同工况下,铝化后的涂层提高了钛合金的耐磨性,尤其速度为4 m/s。耐磨性得到提高是由Ti-Al涂层和摩擦氧化物层所引起的。
An aluminized coating of TiAl_3 was prepared on Ti-6Al-4V alloy by hot-dip aluminizing(HDA) and subsequent high-temperature diffusion at 650 °C. Dry sliding wear behavior for the aluminized Ti-6Al-4V alloy against GCr15 steel was investigated by a pin-on-disc wear tester. The morphology, phase and composition of worn surface of the HDA coatings were characterized by SEM, XRD, EDS and XPS. The wear mechanism was also explored. The result demonstrates that with an increase of sliding velocity, the wear loss of the aluminized Ti-6Al-4V alloy decreases to a lower value at 0.75 m/s, then increases to the highest value at 2.68 m/s, and finally decreases to the lowest at 4 m/s. At different sliding velocities, the wear loss increases with the increase of load. Tribo-layers notably affect the wear behavior and mechanism. At 4 m/s, oxide-containing tribo-layers(TiO and TiO_2) possess an obvious wear-reduced function; conversely, at 2.68 m/s, no-oxide layers show no protection from wear. Compared with uncoated Ti-6Al-4V alloy, the aluminized coating improves the wear resistance of the titanium alloy under various conditions, especially 4 m/s. The improved wear performance is attributed to Ti-Al coating and tribo-oxide layer.
An aluminized coating of TiAl_3 was prepared on Ti-6Al-4V alloy by hot-dip aluminizing(HDA) and subsequent high-temperature diffusion at 650 °C. Dry sliding wear behavior for the aluminized Ti-6Al-4V alloy against GCr15 steel was investigated by a pin-on-disc wear tester. The morphology, phase and composition of worn surface of the HDA coatings were characterized by SEM, XRD, EDS and XPS. The wear mechanism was also explored. The result demonstrates that with an increase of sliding velocity, the wear loss of the aluminized Ti-6Al-4V alloy decreases to a lower value at 0.75 m/s, then increases to the highest value at 2.68 m/s, and finally decreases to the lowest at 4 m/s. At different sliding velocities, the wear loss increases with the increase of load. Tribo-layers notably affect the wear behavior and mechanism. At 4 m/s, oxide-containing tribo-layers(TiO and TiO_2) possess an obvious wear-reduced function; conversely, at 2.68 m/s, no-oxide layers show no protection from wear. Compared with uncoated Ti-6Al-4V alloy, the aluminized coating improves the wear resistance of the titanium alloy under various conditions, especially 4 m/s. The improved wear performance is attributed to Ti-Al coating and tribo-oxide layer.
引文
1 Mehdi M,Farokhzadeh K,Edrisy A et al.Wear[J],2016,350-351:10
2 Fu Pengfei,Mao Zhiyong,Wang Yajun et al.Rare Metal Materials and Engineering[J],2011,40(S4):74
3 Bruschi Stefania,Bertolini Rachele,Ghiotti Andrea et al.Tribology International[J],2017,116:58
4 Meng Qingwu,Geng Lin,Wang Chunhua.Daqing Petroleum Institute[J],2006,30(4):46
5 Molinari A,Straffelini G,Tesi B et al.Wear[J],1997,203-204:447
6 Straffelini G,Molinari A,Tesi B.Wear[J],1999,236(1-2):328
7 Jeng Shiang-Cheng.Surface and Coatings Technology[J],2013,235:867
8 Zhang Z G,Wang Y J,Xiao L J et al.Corrosion Science[J],2012,64:137
9 Wang Yuansheng,Xiong Ji,Yan Jing et al.Surface and Coatings Technology[J],2011,206:1277
10 Karimi Zarchi H R,Soltanieh M,Aboutalebi M R et al.Transactions of Nonferrous Metals Society of China[J],2014,24(6):1959
11 Zhang Z G,Peng Y P,Mao Y L et al.Corrosion Science[J],2012,55:187
12 Li X X,Zhou Y,Ji X L et al.Tribol Int[J],2015,91:228
13 Rigney D A.Wear[J],2000,245(1-2):1
14 Pauschitz A,Roy M,Franek F.Tribol Int[J],2008,41(7):584
2 Fu Pengfei,Mao Zhiyong,Wang Yajun et al.Rare Metal Materials and Engineering[J],2011,40(S4):74
3 Bruschi Stefania,Bertolini Rachele,Ghiotti Andrea et al.Tribology International[J],2017,116:58
4 Meng Qingwu,Geng Lin,Wang Chunhua.Daqing Petroleum Institute[J],2006,30(4):46
5 Molinari A,Straffelini G,Tesi B et al.Wear[J],1997,203-204:447
6 Straffelini G,Molinari A,Tesi B.Wear[J],1999,236(1-2):328
7 Jeng Shiang-Cheng.Surface and Coatings Technology[J],2013,235:867
8 Zhang Z G,Wang Y J,Xiao L J et al.Corrosion Science[J],2012,64:137
9 Wang Yuansheng,Xiong Ji,Yan Jing et al.Surface and Coatings Technology[J],2011,206:1277
10 Karimi Zarchi H R,Soltanieh M,Aboutalebi M R et al.Transactions of Nonferrous Metals Society of China[J],2014,24(6):1959
11 Zhang Z G,Peng Y P,Mao Y L et al.Corrosion Science[J],2012,55:187
12 Li X X,Zhou Y,Ji X L et al.Tribol Int[J],2015,91:228
13 Rigney D A.Wear[J],2000,245(1-2):1
14 Pauschitz A,Roy M,Franek F.Tribol Int[J],2008,41(7):584