煤间接液化技术的发展现状及工程化转化
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摘要
介绍了煤间接液化技术及其核心技术——费托合成,重点分析了影响费托合成反应的合成催化剂和反应器等因素,综述了煤间接液化技术的发展现状及其工程化转化现状,指出我国煤间接液化技术已经成熟,达到了国际领先水平,具有完全自主知识产权,商业示范装置项目已成功实施,中国特色能源转化产业正在形成。
The indirect coal liquefaction technology, and its core technology Fischer-Tropsch synthesis including the effects of synthesis catalyst and reactor and other factors were introduced. The development status of indirect coal liquefaction technology and its engineering transformation were summarized. It is pointed out that China's indirect coal liquefaction technology with independent intellectual property rights has matured and reached the international advanced level; commercial demonstration plant project has been successfully implemented; energy conversion industry of Chinese characteristics is forming.
The indirect coal liquefaction technology, and its core technology Fischer-Tropsch synthesis including the effects of synthesis catalyst and reactor and other factors were introduced. The development status of indirect coal liquefaction technology and its engineering transformation were summarized. It is pointed out that China's indirect coal liquefaction technology with independent intellectual property rights has matured and reached the international advanced level; commercial demonstration plant project has been successfully implemented; energy conversion industry of Chinese characteristics is forming.
引文
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[11]任相坤,房鼎业,金嘉璐,等.煤直接液化技术开发新进展[J].化工进展,2010,29(2):198-204.
[12]王野,康金灿,张庆红.费托合成催化剂的研究进展[J].石油化工,2009,38(12):1 255-1 263.
[13]苏海全,张晓红,丁宁,等.费托合成催化剂的研究进展[J].内蒙古大学学报(自然版),2009,40(4):499-513.
[14]孙予罕,陈建刚,王俊刚,等.费托合成钴基催化剂的研究进展[J].催化学报,2010,31(8):919-927.
[15]徐振刚,罗伟,王乃继,等.费托合成催化剂载体的研究进展[J].煤炭转化,2008,31(3):92-95.
[16]李加波,林泉.费托合成钴催化剂载体改性研究进展[J].洁净煤技术,2015,21(1):65-68.
[17]石勇.费托合成反应器的进展[J].化工技术与开发,2008,37(5):31-38.
[18]杜冰,刘潇,王涛,等.费托合成反应器应用研究进展及展望[J].洁净煤技术,2016,22(5):35-40.
[19]徐志新.费托合成反应器的技术进展[J].科技创新导报,2014(24):47-50.
[20]许毅.煤间接液化产品结构的发展方向[J].大氮肥,2015,38(3):145-150.
[21]屈革荣.浅析我国煤间接液化技术开发现状及其发展前景[J].硅谷,2010(24):11-11.
[2]付长亮,张爱民编.现代煤化工生产技术[M].北京:化学工业出版社,2009.
[3]王礼,徐志新,马芳伟.煤间接液化技术分析和前景展望[J].内蒙古石油化工,2011(11):103-104.
[4]Steynberg A P,Espinoza R L,Jager B,et al.High temperature Fischer-Tropsch synthesis in commercial practice[J].Applied Catalysis A General,1999,186(1-2):41-54.
[5]Espinoza R L,Steynberg A P,Jager B,et al.Low temperature Fischer-Tropsch synthesis from a Sasol perspective[J].Applied Catalysis A General,1999,186(1-2):13-26.
[6]Sie S T.Process development and scale upⅣ:Case history of the development of a Fischer-Tropsch synthesis process[J].Rev Chem Eng,1998,14(21):109-157.
[7]武靖为.煤制油技术概述与展望[J].中国化工贸易,2012(4):5-5.
[8]谢云辉.兖矿榆林100万t/a煤间接液化示范项目进展顺利[DB/OL].[2014].http://www.ccin.com.cn/ccin/news/2014/08/13/302012.shtml.
[9]曹谊.伊泰200万t/a煤炭间接液化示范项目开工[DB/OL].[2017].http://www.northnews.cn/2017/0609/2528449.shtml.
[10]李贺.中国煤间接液化技术及未来前景概述[J].内蒙古石油化工,2014,2(7):97-98.
[11]任相坤,房鼎业,金嘉璐,等.煤直接液化技术开发新进展[J].化工进展,2010,29(2):198-204.
[12]王野,康金灿,张庆红.费托合成催化剂的研究进展[J].石油化工,2009,38(12):1 255-1 263.
[13]苏海全,张晓红,丁宁,等.费托合成催化剂的研究进展[J].内蒙古大学学报(自然版),2009,40(4):499-513.
[14]孙予罕,陈建刚,王俊刚,等.费托合成钴基催化剂的研究进展[J].催化学报,2010,31(8):919-927.
[15]徐振刚,罗伟,王乃继,等.费托合成催化剂载体的研究进展[J].煤炭转化,2008,31(3):92-95.
[16]李加波,林泉.费托合成钴催化剂载体改性研究进展[J].洁净煤技术,2015,21(1):65-68.
[17]石勇.费托合成反应器的进展[J].化工技术与开发,2008,37(5):31-38.
[18]杜冰,刘潇,王涛,等.费托合成反应器应用研究进展及展望[J].洁净煤技术,2016,22(5):35-40.
[19]徐志新.费托合成反应器的技术进展[J].科技创新导报,2014(24):47-50.
[20]许毅.煤间接液化产品结构的发展方向[J].大氮肥,2015,38(3):145-150.
[21]屈革荣.浅析我国煤间接液化技术开发现状及其发展前景[J].硅谷,2010(24):11-11.