熔盐电解制备镝合金及其电化学机理研究现状与发展趋势
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摘要
综述了金属Dy及几类典型Dy合金的应用、熔盐电解制备方法及其电化学机理研究现状,分析了目前国内外在Dy金属和Dy-Al、Dy-Mg、Dy-Ni、Dy-Fe、Dy-Cu等合金制备技术方面的研究进展,对熔盐电解法制备Dy合金的发展方向进行了展望。
Research status is reviewed on the application,the preparation method of molten salt electrolysis and the electrochemical mechanism of Dy metal and some typical Dy alloys.The current research progress is analyzed in preparation technology of Dy metal and Dy-Al,Dy-Mg,Dy-Ni,Dy-Fe,Dy-Cu alloys at home and abroad.The development trend of Dy alloy preparation by molten salt electrolysis is prospected.
Research status is reviewed on the application,the preparation method of molten salt electrolysis and the electrochemical mechanism of Dy metal and some typical Dy alloys.The current research progress is analyzed in preparation technology of Dy metal and Dy-Al,Dy-Mg,Dy-Ni,Dy-Fe,Dy-Cu alloys at home and abroad.The development trend of Dy alloy preparation by molten salt electrolysis is prospected.
引文
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[21]孙婷婷.熔盐体系中Dy(Ⅲ)和Ho(Ⅲ)的电化学行为及镝镍、钬镍和镁锂镝钬合金的制备[D].哈尔滨:哈尔滨工程大学,2014:1-58.
[22]杨育圣.熔盐电解共沉积镁锂镝合金的研究[D].哈尔滨:哈尔滨工程大学,2009:1-80.
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[26]TONG Yexiang,LIU guankun,YANG Qiqin,et al.Electroreduction of Dy3+on Ni cathode in molten chloeides[J].Journal of Rare Earths,1996,14(4):271-274.
[27]CLARK A E,BELSON H S.Giant room-temperature magneto-strictions in TbFe2 and DyFe2[J].Physical Review B,1972,5(9):193-205.
[28]黄文莉.镝铁合金熔铸试验研究[J].江西有色金属,2003,17(4):25-27.
[29]刘冠昆,童叶翔,洪惠婵,等.氯化物熔体中镝铁合金形成的电化学研究[J].中国稀土学报,1997,15(4):300-304.
[30]KONISHI H,NOHIRA T,ITO Y.Formation of Dy-Fe alloy films by molten salt electrochemical process[J].Electrochimica Acta,2003,47(21):3 533-3 539.
[31]谢宏伟,王锦霞,金炳勋,等.CaCl2熔盐中直接电化学还原制备铽-镝-铁合金机制[J].稀有金属材料与工程,2012,41(12):2 233-2 237.
[32]王中磊,唐惠庆,郭占成,等.熔盐电脱氧法制取镝铁合金阴极还原过程的研究[J].中国稀土学报,2010,4(28):171-176.
[33]SHI Y,LIU X,GAO Y,et al.Electrochemical behavior of Dy(Ⅲ)and Dy-Fe alloys preparation by Co-reduction in molten fluoride salts[J].Journal of the Electrochemical Society,2017,164(4):263-268.
[34]李炜.熔盐电解法制取镝铁合金的研究[J].江西有色金属,1999,13(1):29-33.
[35]史文范,黄平,李雅民,等.一种氧化物熔盐电解制备镝铁合金的方法:CN102140656A[P].2011-08-03.
[36]NARAYANA M V,KOTNANA G,JAMMALAMADAKA S N.Magnetocaloric effect and nature of magnetic transition in low dimensional DyCu2[J].Journal of Alloys&Compounds,2016,683:56-61.
[37]唐定骧,刘余九,张洪杰,等.稀土金属材料[M].北京:冶金工业出版社,2011.
[38]PALUMBO M,BATTEZZATI L,PASTUREL A,et al.Thermodynamic and ab initio investigation of the Cu-Dy system[J].Calphad—Computer Coupling of Phase Diagrams&Thermochemistry,2009,33(3):511-516.
[39]ZHANG Y,XU X,YANG Y,et al.Study of the magnetic phase transitions and magnetocaloric effect in Dy2Cu2In compound[J].Journal of Alloys&Compounds,2016,667:130-133.
[40]WANG Z,JU J,WANG J,et al.Near-surface microstructure improvement for die-upset Nd-Fe-B magnets with an enhanced maximum energy product[J].Journal of Alloys&Compounds,2017,710:66-71.
[41]KABLOV E N,PETRAKOV A F,PISKORSKII V P,et al.Effect of dysprosium and cobalt on the temperature dependence of magnetization and phase composition of a material of the Nd-Dy-Fe-Co-B system[J].Metal Science&Heat Treatment,2007,49(3/4):159-166.
[42]王伟,罗伟,文玉华,等.二级回火对(NdDy)FeCoCu磁体磁性能和微结构的影响[J].稀土金属材料与工程,2005,34(10):1 633-1 636.
[43]庄虹,刘勇健.稀土对铜及铜合金性能的影响[J].有色金属,1995,42(2):40-44.
[44]YANG S,WANG J,WANG H,et al.The electrochemical behavior of Dy(Ⅲ)in eutectic LiF-DyF3,at W electrode[J].Ionics,2016,22(8):1 337-1 342.
[45]GUO X,SUN Z H I,SIETSMA J,et al.A semi-empirical model for the solubility of rare earth oxides in molten fluorides[J].Industrial&Engineering Chemistry Research,2016,55(16):4 773-4 781.
[46]ABBASALIZADEH A,MALFLIET A,SEETHARAMAN S,et al.Electrochemical extraction of rare earth metals in molten fluorides:Conversion of rare earth oxides into rare earth fluorides using fluoride additives[J].Journal of Sustainable Metallurgy,2017,3(3):627-637.
[47]陈国华,刘玉宝.稀土熔盐电解技术研究进展[J].稀土信息,2015,379(10):12-15.
[2]潘树明.添加元素Dy对Nd-Fe-B永磁合金性能的影响[J].中国有色金属学报,1998,8(3):459-462.
[3]ZHANG G B,ZHENG W G,CUI Y,et al.Structural,magnetic,and magentostrictive properties of Dy1-x(Tb0.2Pr0.8)xFe1.93(0≤x≤0.5)compounds[J].Journal of Superconductivity and Novel Magnetism,2018,31(7):2 217-2 220.
[4]ALHO B P,RIBEIRO P O,ALVARENGA T S T,et al.Magnetocaloric effect in Gd(1-y)Dy Al2[J].International Journal of Refrigeration,2014,37(1):297-302.
[5]CAREY R,NEWMAN D M,SNELLING J P,et al.The magnetic properties of DyFeCo thin films[J].Journal of Magnetism&Magnetic Materials,1995,148(148):491-496.
[6]吴文远.稀土冶金学[M].北京:化学工业出版社,2005:198-232.
[7]LUCAS J,LUCAS P,MERCIER T L,et al.Rare earths:Science,technology,production and use[M].Elsevier,2015:181-189.
[8]潘思明,颜世宏,李宗安,等.我国熔盐电解法制备稀土金属及其合金工艺技术进展[J].稀土金属,2011,35(3):440-450.
[9]郭探,王世栋,叶秀深,等.熔盐电解法制备稀土合金研究进展[J].中国科学:化学,2012,42(9):1 328-1 336.
[10]CASTRILLEJO Y,BERMEJO M R,BARRADO A I,et al.Electrochemical behavior of dysprosium in the eutectic LiCl-KCl at W and Al electrodes[J].Electrochimica Acta,2005,50:2 047-2 057.
[11]SU Lingling,LIU Kui,LAN Ya,et al.Electrochemical behaviors of Dy(Ⅲ)and its co-reduction with Al(Ⅲ)in molten LiCl-KCl salts[J].Electrochimica Acta,2014,147:87-95.
[12]CHANG Kaiguo,LU Xiangping,DU Fuying,et al.Determination of the apparent standard potential of the Dy/Dy(Ⅲ)system in the LiCl-KCl eutectic[J].Chinese Journal of Chemistry,1994,12(9):509-515.
[13]苏明忠,宋丕莹,邹连清,等.熔盐电解制备Al-Dy合金[J].稀土,1995,16(5):61-63.
[14]王渠东,吕宜振,曾小勤,等.稀土在铸造镁合金中的应用[J].特种铸造及有色合金,1999(1):40-44.
[15]YANG Lei,MA Liangong,HUANG Yuanding,et al.Influence of Dy in solid solution on the degradation behavior of binary Mg-Dy alloys in cell culture medium[J].Materials Science and Engineering,2017,75:1 351-1 358.
[16]BI Guangli,LI Yuandong,ZANG Shijun,et al.Microstructure,mechanical and corrosion properties of Mg-2Dy-xZn(x=0,0.1,0.5and 1at.%)alloys[J].Journal of Magnesium and Alloys,2014,2(1):875-882.
[17]LI Dehui,DONG Jie,ZENG Xiaoqin,et al.Transmission electron microscopic investigation of theβ→βphase transformation in a Mg-Dy-Nd alloy[J].Materials Characterization,2010,61(8):818-823.
[18]ZHANG Jinghuai,LENG Zhe,LIU Shujuan,et al.Microstructure and mechanical properties of Mg-Gd-DyZn alloy with long period stacking ordered structure or stacking faults[J].Journal of Alloys and Compounds,2011,509(29):7 717-7 722.
[19]ZHANG Milin,YANG Yusheng,HAN Wei,et al.Electrodeposition of magnesium-lithium-dysprosium ternary alloys with controlled components from dysprosium oxide assisted by magnesium chloride in molten chlorides[J].J Solid State Electrochem,2013,17(10):2 671-2 678.
[20]YANG Yusheng,ZHANG Milin,HAN Wei,et al.Selective electrodeposition of dysprosium in LiCl-KClGdCl3-DyCl3-melts at magnesium electrodes:Application to separation of nuclear wastes[J].Electrochimica Acta,2014,118(2):150-156.
[21]孙婷婷.熔盐体系中Dy(Ⅲ)和Ho(Ⅲ)的电化学行为及镝镍、钬镍和镁锂镝钬合金的制备[D].哈尔滨:哈尔滨工程大学,2014:1-58.
[22]杨育圣.熔盐电解共沉积镁锂镝合金的研究[D].哈尔滨:哈尔滨工程大学,2009:1-80.
[23]潘顺康.Dy-Ni-Ti三元系合金相图500℃等温截面[D].南宁:广西大学,1999:1-45.
[24]YASUDA Kouji,KOBAYASHI Seitaro,NOHIRA Toshiyuki,et al.Electrochemical formation of Dy-Ni alloys in molten NaCl-KCl-DyCl3[J].Electrochimica Acta,2013,106(12):293-300.
[25]SAILA A,GIBILARO M,MASSOT L,et al.Electrochemical behaviour of dysprosium(Ⅲ)in LiF-CaF2,on Mo,Ni and Cu electrodes[J].Journal of Electroanalytical Chemistry,2010,642(2):150-156.
[26]TONG Yexiang,LIU guankun,YANG Qiqin,et al.Electroreduction of Dy3+on Ni cathode in molten chloeides[J].Journal of Rare Earths,1996,14(4):271-274.
[27]CLARK A E,BELSON H S.Giant room-temperature magneto-strictions in TbFe2 and DyFe2[J].Physical Review B,1972,5(9):193-205.
[28]黄文莉.镝铁合金熔铸试验研究[J].江西有色金属,2003,17(4):25-27.
[29]刘冠昆,童叶翔,洪惠婵,等.氯化物熔体中镝铁合金形成的电化学研究[J].中国稀土学报,1997,15(4):300-304.
[30]KONISHI H,NOHIRA T,ITO Y.Formation of Dy-Fe alloy films by molten salt electrochemical process[J].Electrochimica Acta,2003,47(21):3 533-3 539.
[31]谢宏伟,王锦霞,金炳勋,等.CaCl2熔盐中直接电化学还原制备铽-镝-铁合金机制[J].稀有金属材料与工程,2012,41(12):2 233-2 237.
[32]王中磊,唐惠庆,郭占成,等.熔盐电脱氧法制取镝铁合金阴极还原过程的研究[J].中国稀土学报,2010,4(28):171-176.
[33]SHI Y,LIU X,GAO Y,et al.Electrochemical behavior of Dy(Ⅲ)and Dy-Fe alloys preparation by Co-reduction in molten fluoride salts[J].Journal of the Electrochemical Society,2017,164(4):263-268.
[34]李炜.熔盐电解法制取镝铁合金的研究[J].江西有色金属,1999,13(1):29-33.
[35]史文范,黄平,李雅民,等.一种氧化物熔盐电解制备镝铁合金的方法:CN102140656A[P].2011-08-03.
[36]NARAYANA M V,KOTNANA G,JAMMALAMADAKA S N.Magnetocaloric effect and nature of magnetic transition in low dimensional DyCu2[J].Journal of Alloys&Compounds,2016,683:56-61.
[37]唐定骧,刘余九,张洪杰,等.稀土金属材料[M].北京:冶金工业出版社,2011.
[38]PALUMBO M,BATTEZZATI L,PASTUREL A,et al.Thermodynamic and ab initio investigation of the Cu-Dy system[J].Calphad—Computer Coupling of Phase Diagrams&Thermochemistry,2009,33(3):511-516.
[39]ZHANG Y,XU X,YANG Y,et al.Study of the magnetic phase transitions and magnetocaloric effect in Dy2Cu2In compound[J].Journal of Alloys&Compounds,2016,667:130-133.
[40]WANG Z,JU J,WANG J,et al.Near-surface microstructure improvement for die-upset Nd-Fe-B magnets with an enhanced maximum energy product[J].Journal of Alloys&Compounds,2017,710:66-71.
[41]KABLOV E N,PETRAKOV A F,PISKORSKII V P,et al.Effect of dysprosium and cobalt on the temperature dependence of magnetization and phase composition of a material of the Nd-Dy-Fe-Co-B system[J].Metal Science&Heat Treatment,2007,49(3/4):159-166.
[42]王伟,罗伟,文玉华,等.二级回火对(NdDy)FeCoCu磁体磁性能和微结构的影响[J].稀土金属材料与工程,2005,34(10):1 633-1 636.
[43]庄虹,刘勇健.稀土对铜及铜合金性能的影响[J].有色金属,1995,42(2):40-44.
[44]YANG S,WANG J,WANG H,et al.The electrochemical behavior of Dy(Ⅲ)in eutectic LiF-DyF3,at W electrode[J].Ionics,2016,22(8):1 337-1 342.
[45]GUO X,SUN Z H I,SIETSMA J,et al.A semi-empirical model for the solubility of rare earth oxides in molten fluorides[J].Industrial&Engineering Chemistry Research,2016,55(16):4 773-4 781.
[46]ABBASALIZADEH A,MALFLIET A,SEETHARAMAN S,et al.Electrochemical extraction of rare earth metals in molten fluorides:Conversion of rare earth oxides into rare earth fluorides using fluoride additives[J].Journal of Sustainable Metallurgy,2017,3(3):627-637.
[47]陈国华,刘玉宝.稀土熔盐电解技术研究进展[J].稀土信息,2015,379(10):12-15.