MOFs材料研究进展
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摘要
金属有机框架化合物MOFs材料,由金属中心与桥连配体构成。构成框架的金属中心及有机配体同简单的配合物、高分子聚合物相比,有着非常显著的差异,因此,MOFs材料的物理化学性质根据金属中心和有机配体的变化而具有明显的多样性。概述了MOFs材料的产生过程,总结了MOFs材料的多孔性、大的比表面积、结构的多样性及具有不饱和金属配位点的特点,综述了其在燃气存储、荧光性能方面的研究进展,并概述了其在其他领域的研究进展。
Metal-organic frameworks, MOFs materials are composed of metal centers and bridged ligands. The metal centers and organic ligands in the frameworks are significantly different from those of simple inorganic complexes or organic polymers, therefore, the physical and chemical properties of MOFs materials have obvious diversity according to the change of metal centers and organic ligands. In this paper, the production process of MOFs materials was outlined. Characteristics of MOFs materials were summarized, such as porous property, large specific surface area, the diversity of structure and unsaturated metal coordination sites. The research progress of MOFs materials in gas storage,fluorescence property and other application areas was reviewed.
Metal-organic frameworks, MOFs materials are composed of metal centers and bridged ligands. The metal centers and organic ligands in the frameworks are significantly different from those of simple inorganic complexes or organic polymers, therefore, the physical and chemical properties of MOFs materials have obvious diversity according to the change of metal centers and organic ligands. In this paper, the production process of MOFs materials was outlined. Characteristics of MOFs materials were summarized, such as porous property, large specific surface area, the diversity of structure and unsaturated metal coordination sites. The research progress of MOFs materials in gas storage,fluorescence property and other application areas was reviewed.
引文
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[6] Li HL, Eddaoudi M, Groy TL, et al. Establishing Microporosity in Open Metal-Organic Frame works:Gas Sorption Isotherms for Zn(BDC)(BDC=1,4-Benzenediicarboxylate)[J]. J. Am. Chem. Soc.,1998, 120(33):8571-8572.
[7] Pachfule P,Das R,Poddar P, et al. Structural, magnetic, and gas adsorption study of a series of partially fluorinated metal-organic frameworks(HF-MOFs)[J]. Inorg. Chem.,2011, 50(9):3855-3865.
[8] Mihalcik DJ, Zhang T, M LQ,et al. Highly Porous 4,8-Connected Metal-Organic Frameworks:Synthesis, Characterization, and Hydrogen Uptake[J]. Inorg. Chem., 2012, 51(4):2503-2508.
[9] Zhao TT, Jing XM, Wang J, et al. Assembly of Two 3D PorousMetal-Organic FrameworksBased on 1,2,3-Triazole-4,5-dicarboxylate Exhibiting Novel CoordinationModes[J]. Cryst.Growth Des. 2012, 12(11):5456-5461.
[10]王海洋,马蕊英,赵亮,等.金属有机骨架材料用于气体吸附分离的研究进展[J].当代化工,2014(10):2061-2064.
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[12] Furukawa H, Ko N, Go YB et al. Ultrahigh porosity in metal-organic frameworks[J]. Science, 2010, 329:424-428.
[13] Chen ZX, Xiang SC, Liao TB, et al. A New Multidentate Hexacarboxylic Acid for the Construction of Porous Metal-Organic Frameworks of Diverse Structures and Porosities[J]. Cryst. Growth Des. 2010, 10(6):2775-2779.
[14] Tong ML, Wu YM, Zheng SL, et al. A three-dimensional hone ycomb-like network constructed with novel one-dimensional S-s haped chains via hydrogen bonding andπ-πinteractions[J]. Ne w J. Chem.,2001,25:1482-1485.
[15] Fernandez M, Barnard AS. Geometrical Properties Can Predict CO_2and N2 Adsorption Performance of Metal-organic Frameworks(MOFs)at Low Pressure[J]. ACS Comb. Sci., 2016, 18(5):243-252
[16]徐来,傅仰河,孙龙,等.MOFs材料催化氧化苯乙烯的研究进展[J].广东化工,2015,42(12):75-76.
[17] Corma A, Garcia H, Llabres i Xamena F. X. ChemInform Abstract:Engineering Metal Organic Frameworks for Heterogeneous Catalysis[J]. Chem. Rev., 2010, 110(8):4606-4655.
[18]许炜,陶占良,陈军等.储氢研究进展[J].化学进展,2006,18(2):200-210.
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[24] Getman RB, Bae YS, Wilmer CE, et al. Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal-Organic Frameworks[J]. Chem. Rev., 2012, 112(2):703-723.
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[26] Ma SQ, Sun DF, Simmons JM,et al. Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane up take[J]. J. Am. Chem. Soc., 2008, 130(3):1012-1016.
[27] Lin XM, He CT, Liu Y et al. A Metal-Organic Framework with a Pore Size/Shape Suitable for Strong Binding and Close Packing of Methane[J]. Angew. Chem. Int. Ed., 2016, 55(15), 4674-4678.
[28] Llewellyn PL,Bourrelly S,Serre C, et al. High uptakes of CO_2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101[J]. Langmuir, 2008, 24(14):7245-7250.
[29]武鹏彦.光功能金属有机骨架的构筑及其性能研究[D].大连理工大学,2013.
[30] Bordiga S, Lamberti C, Ricchiardi G, et al. Electronic and vibrational properties of a MOF-5 metal-organic framework:ZnO quantum dot behavior[J]. Chem. Comm., 2004,(20):2300-2301.
[31] Fang QR,Zhu GS, Xue M,et al. Structure, Luminescence, and Adsorption Properties of Two Chiral Microporous Metal-Organic Frame wo rks[J]. Inorg. Chem, 2006, 45(9):3582-3587.
[32] Wei YQ, Yu YF, Wu KC. Highly Stable Five-Coordinated Mn(II)Polymer[Mn(Hbidc)]n(Hbidc=lH-Benzimidazole-5,6-dicarboxylate):Crystal Structure, Antiferromegnetic Property, and Strong Long-Lived Luminescence[J]. Cryst. Growth Des., 2008, 8(7):2087-2089.
[33] Li MX, Miao ZX, Shao M, et al. Metal-Organic Frameworks Constructed from 2,4,6-Tris(4-pyridyl)-1, 3,5-triazine[J]. Inorg.Chem., 2008,47(11):4481-4489.
[34] Sava Gallis DF, Rohwer LES, Rodriguez MA, et al. Efficient Photoluminescence via Metal-Ligand Alteration in a New MOFs Family[J]. Chem. Mater, 2014, 26(9):2943-2951.
[35] Chandler BD, Cramb DT, Shimizu GKH. Microporous metal-organic frameworks formed in a stepwise manner from luminescent building blocks[J]. J. Am. Chem. Soc., 2006, 128(32):10403-10412.
[36] Sun YQ, Yang GY. Organic-inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic4,5-imidazoledicarboxylic acid[J]. Dalton Trans., 2007(34):3771-3781.
[37] Song XQ, Liu WS, Dou W, et al. Structure variation and luminescence properties of lanthanide complexes incorporating a naphthalenederived chromophore featuring salicylamide pendant arms[J].Eru. J.Inorg.Chem,. 2008, 11:1908-1912.
[38] Cheng JW, Zheng ST, Yang GY. Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction[J]. Dalton Trans., 2007,(36):4059-4066.
[39] Douvali A, Papaefstathiou GS, Gullo MP, et al. Alkaline Earth Metal Ion/Dihydroxy-Terephthalate MOFs:Structural Diversity and Unusual Luminescent Properties[J]. Inorg. Chem., 2015, 54(12):5813-5826.
[40] Chen BL, Yang Y, Zapata F, et al. Enhanced near-infraredluminescence in an erbium tetrafluoroterephthalate framework[J].Inorg. Chem., 2006, 45(22):8882-8886.
[41] Binnemans K. Lanthanide-based luminescent hybrid materials[J].Chem. Rev., 2009,109(9):4283-4374.
[42] Fang QR, Zhu GS, Jin Z, et al. Mesoporous Metal-Organic Framework with Rare etb Topology for Hydrogen Storage and Dye Assembly[J]. Angew. Chem. Int. Ed., 2007,46(35):6638-6642.
[43] Luo F, Batten SR. Metal-organic framework(MOF):lanthanide(Ⅲ)-doped approach for luminescence modulation and luminescent sensing[J]. Dalton Trans., 2010, 39(19):4485-4488.
[44] Zhang LJ,Jian Y,Wang J,et al. Post-modification of a MOF through a fluorescent-labeling technology for the selective sensing and adsorption of Ag~+in aqueous solution[J]. Dalton Trans., 2012,41(34):10153-10155.
[45] Jung S, Kim Y, Kim S-J, et al. Bio-functionalization of metal-organic frameworks by covalent protein conjugation[J]. Chem. Common.,2011,47(10):2904-2906.
[46] Shiga T, Okawa H, Kitagawa S, et al. Stepwise synthesis and magnetic control of trimetallic magnets[Co_2Ln(L)_2(H_2O)_4][Cr(CN)_6]·nH_2O(Ln=La,Gd; H2L=2,6-Di(acetoacetyl)pyridine)with 3-D pillared-layer structure[J]. J. Am. Chem. Soc., 2006, 128(51):16426-16427.
[47] Cheng XN, Zhang WX, Chen XM. Single crystal-to-single crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer[J]. J. Am. Chem. Soc., 2007,129(51):15738-15739.
[48] Zheng YZ, Xue w, Tong ML, et al. A two-dimensional iron(Ⅱ)carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition[J].Inorg. Chem.,2008, 47(10):4077-4087.
[49] Yoon M,Srirambalaji R,Kim K. Homochiral Metal-Organic Frameworks for Asymmetric Heterogeneous Catalysis[J]. Chem.Rev., 2012, 112(2):1196-1231.
[50] Yang D,Han Y, Xu W, et al. A Series of Lanthanide-Based Metal-Organic Frameworks:Synthesis, Structures, and Multicolor Tuning of Single Component[J]. Inorg. Chem., 2017,56:2345-2353.
[51] Kreno Le, Leong K, Farha OK, et al. Metal-organic framework materials as chemical sensors[J]. Chem. Rev., 2012, 112(2):1105-1125.
[52] Li H Y, Wei Y L, Dong X Y, et al. Novel Tb-MOF Embedded with Viologen Species for Multi-Photofunctionality:Photochromism,Photomodulated Fluorescence, and Luminescent pH Sensing[J].Chem. Mater., 2015, 27(4):1327-1331.
[53] Horcajada P, Serre C, Maurin G, et al. Flexible porous metal-organic frameworks for a controlled drug delivery[J]. J. Am. Chem. Soc.,2008, 130(21):6774-678.
[2] Rayner JH, Powell HM. J. Structure of molecular compounds. Part X.Crystal structure of the compound of benzene with an ammonia-nickel cyanide complex[J]. Chem. Soc.,1952,6(6):433-438.
[3] Iwamoto T, Miyoshi T, Sasaki Y. The Metal Cyanide Aromatic Clathrates.ⅩⅢ. The Crystal Structure of the Hofmann-type Biphenyl Clathrate, Diammineickel(Ⅱ)Te tracy anoni ckel ate(Ⅱ)Di-biphenyl:Ni(NH_3)_2Ni(CN)_4·-2C_(12)H_(10)[J]. Acta. Cryst., 1974, B30:292-295.
[4] Hoskins BF, Robson R. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments[J]. J. Am. Chem. Soc.,1989, 111(15):5962-5964.
[5] Kondo M, Yoshitomi T, Seki K, et;al. Three-Dimensional Framework with Channeling Cavities for Small Molecules:{[M2(4, 4'-bpy)_3(NO_3)_4]·xH_2On(M Co, Ni, Zn)[J]. Angew. Chem., Int. Ed.Engl., 1997, 36(16):1725-1727.
[6] Li HL, Eddaoudi M, Groy TL, et al. Establishing Microporosity in Open Metal-Organic Frame works:Gas Sorption Isotherms for Zn(BDC)(BDC=1,4-Benzenediicarboxylate)[J]. J. Am. Chem. Soc.,1998, 120(33):8571-8572.
[7] Pachfule P,Das R,Poddar P, et al. Structural, magnetic, and gas adsorption study of a series of partially fluorinated metal-organic frameworks(HF-MOFs)[J]. Inorg. Chem.,2011, 50(9):3855-3865.
[8] Mihalcik DJ, Zhang T, M LQ,et al. Highly Porous 4,8-Connected Metal-Organic Frameworks:Synthesis, Characterization, and Hydrogen Uptake[J]. Inorg. Chem., 2012, 51(4):2503-2508.
[9] Zhao TT, Jing XM, Wang J, et al. Assembly of Two 3D PorousMetal-Organic FrameworksBased on 1,2,3-Triazole-4,5-dicarboxylate Exhibiting Novel CoordinationModes[J]. Cryst.Growth Des. 2012, 12(11):5456-5461.
[10]王海洋,马蕊英,赵亮,等.金属有机骨架材料用于气体吸附分离的研究进展[J].当代化工,2014(10):2061-2064.
[11] Chae HK, Siberio-Perez DY, Kim J,et al. route to high surface area,porosity and inclusion of large molecules in crystals[J]. Nature, 2004,427:523-527.
[12] Furukawa H, Ko N, Go YB et al. Ultrahigh porosity in metal-organic frameworks[J]. Science, 2010, 329:424-428.
[13] Chen ZX, Xiang SC, Liao TB, et al. A New Multidentate Hexacarboxylic Acid for the Construction of Porous Metal-Organic Frameworks of Diverse Structures and Porosities[J]. Cryst. Growth Des. 2010, 10(6):2775-2779.
[14] Tong ML, Wu YM, Zheng SL, et al. A three-dimensional hone ycomb-like network constructed with novel one-dimensional S-s haped chains via hydrogen bonding andπ-πinteractions[J]. Ne w J. Chem.,2001,25:1482-1485.
[15] Fernandez M, Barnard AS. Geometrical Properties Can Predict CO_2and N2 Adsorption Performance of Metal-organic Frameworks(MOFs)at Low Pressure[J]. ACS Comb. Sci., 2016, 18(5):243-252
[16]徐来,傅仰河,孙龙,等.MOFs材料催化氧化苯乙烯的研究进展[J].广东化工,2015,42(12):75-76.
[17] Corma A, Garcia H, Llabres i Xamena F. X. ChemInform Abstract:Engineering Metal Organic Frameworks for Heterogeneous Catalysis[J]. Chem. Rev., 2010, 110(8):4606-4655.
[18]许炜,陶占良,陈军等.储氢研究进展[J].化学进展,2006,18(2):200-210.
[19] Rowsell JLC, Millward AR, Park KS, et al. Hydrogen Sorption in Functionalized Metal-Organic Frameworks[J]. J. Am. Chem. Soc.,2004, 126(18):5666-5667.
[20]Rowsell JLC, Yaghi OM. Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal-Organic Frameworks[J]. J. Am. Chem. Soc., 2006, 128(4):1304-1315.
[21] Zhou W, Wu H, Yildirim T. Enhanced H_2 adsorption in isostructural metal-organic frameworks with open metal sites:strong dependence of the binding strength on metal ions[J]. J. Am. Chem. Soc., 2008,130(46):15268-15269.
[22] Li YW, Yang RT. Hydrogen storage in metal-organic frameworks by bridged hydrogen spillover[J]. J. Am. Chem. Soc., 2008, 128(25):8136-8137.
[23] Mulfort KL, Hupp JT. Alkali metal cation effects on hydrogen uptake and binding in metal-organic frameworks[J]. Inorg. Chem.,2008,47(18):7936-7938.
[24] Getman RB, Bae YS, Wilmer CE, et al. Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal-Organic Frameworks[J]. Chem. Rev., 2012, 112(2):703-723.
[25] Duren T, Sarkisov L, Yaghi OM, et al. Design of New Materials for Methane Storage[J]. Langmuir, 2004, 20(7):2683-2689.
[26] Ma SQ, Sun DF, Simmons JM,et al. Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane up take[J]. J. Am. Chem. Soc., 2008, 130(3):1012-1016.
[27] Lin XM, He CT, Liu Y et al. A Metal-Organic Framework with a Pore Size/Shape Suitable for Strong Binding and Close Packing of Methane[J]. Angew. Chem. Int. Ed., 2016, 55(15), 4674-4678.
[28] Llewellyn PL,Bourrelly S,Serre C, et al. High uptakes of CO_2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101[J]. Langmuir, 2008, 24(14):7245-7250.
[29]武鹏彦.光功能金属有机骨架的构筑及其性能研究[D].大连理工大学,2013.
[30] Bordiga S, Lamberti C, Ricchiardi G, et al. Electronic and vibrational properties of a MOF-5 metal-organic framework:ZnO quantum dot behavior[J]. Chem. Comm., 2004,(20):2300-2301.
[31] Fang QR,Zhu GS, Xue M,et al. Structure, Luminescence, and Adsorption Properties of Two Chiral Microporous Metal-Organic Frame wo rks[J]. Inorg. Chem, 2006, 45(9):3582-3587.
[32] Wei YQ, Yu YF, Wu KC. Highly Stable Five-Coordinated Mn(II)Polymer[Mn(Hbidc)]n(Hbidc=lH-Benzimidazole-5,6-dicarboxylate):Crystal Structure, Antiferromegnetic Property, and Strong Long-Lived Luminescence[J]. Cryst. Growth Des., 2008, 8(7):2087-2089.
[33] Li MX, Miao ZX, Shao M, et al. Metal-Organic Frameworks Constructed from 2,4,6-Tris(4-pyridyl)-1, 3,5-triazine[J]. Inorg.Chem., 2008,47(11):4481-4489.
[34] Sava Gallis DF, Rohwer LES, Rodriguez MA, et al. Efficient Photoluminescence via Metal-Ligand Alteration in a New MOFs Family[J]. Chem. Mater, 2014, 26(9):2943-2951.
[35] Chandler BD, Cramb DT, Shimizu GKH. Microporous metal-organic frameworks formed in a stepwise manner from luminescent building blocks[J]. J. Am. Chem. Soc., 2006, 128(32):10403-10412.
[36] Sun YQ, Yang GY. Organic-inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic4,5-imidazoledicarboxylic acid[J]. Dalton Trans., 2007(34):3771-3781.
[37] Song XQ, Liu WS, Dou W, et al. Structure variation and luminescence properties of lanthanide complexes incorporating a naphthalenederived chromophore featuring salicylamide pendant arms[J].Eru. J.Inorg.Chem,. 2008, 11:1908-1912.
[38] Cheng JW, Zheng ST, Yang GY. Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction[J]. Dalton Trans., 2007,(36):4059-4066.
[39] Douvali A, Papaefstathiou GS, Gullo MP, et al. Alkaline Earth Metal Ion/Dihydroxy-Terephthalate MOFs:Structural Diversity and Unusual Luminescent Properties[J]. Inorg. Chem., 2015, 54(12):5813-5826.
[40] Chen BL, Yang Y, Zapata F, et al. Enhanced near-infraredluminescence in an erbium tetrafluoroterephthalate framework[J].Inorg. Chem., 2006, 45(22):8882-8886.
[41] Binnemans K. Lanthanide-based luminescent hybrid materials[J].Chem. Rev., 2009,109(9):4283-4374.
[42] Fang QR, Zhu GS, Jin Z, et al. Mesoporous Metal-Organic Framework with Rare etb Topology for Hydrogen Storage and Dye Assembly[J]. Angew. Chem. Int. Ed., 2007,46(35):6638-6642.
[43] Luo F, Batten SR. Metal-organic framework(MOF):lanthanide(Ⅲ)-doped approach for luminescence modulation and luminescent sensing[J]. Dalton Trans., 2010, 39(19):4485-4488.
[44] Zhang LJ,Jian Y,Wang J,et al. Post-modification of a MOF through a fluorescent-labeling technology for the selective sensing and adsorption of Ag~+in aqueous solution[J]. Dalton Trans., 2012,41(34):10153-10155.
[45] Jung S, Kim Y, Kim S-J, et al. Bio-functionalization of metal-organic frameworks by covalent protein conjugation[J]. Chem. Common.,2011,47(10):2904-2906.
[46] Shiga T, Okawa H, Kitagawa S, et al. Stepwise synthesis and magnetic control of trimetallic magnets[Co_2Ln(L)_2(H_2O)_4][Cr(CN)_6]·nH_2O(Ln=La,Gd; H2L=2,6-Di(acetoacetyl)pyridine)with 3-D pillared-layer structure[J]. J. Am. Chem. Soc., 2006, 128(51):16426-16427.
[47] Cheng XN, Zhang WX, Chen XM. Single crystal-to-single crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer[J]. J. Am. Chem. Soc., 2007,129(51):15738-15739.
[48] Zheng YZ, Xue w, Tong ML, et al. A two-dimensional iron(Ⅱ)carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition[J].Inorg. Chem.,2008, 47(10):4077-4087.
[49] Yoon M,Srirambalaji R,Kim K. Homochiral Metal-Organic Frameworks for Asymmetric Heterogeneous Catalysis[J]. Chem.Rev., 2012, 112(2):1196-1231.
[50] Yang D,Han Y, Xu W, et al. A Series of Lanthanide-Based Metal-Organic Frameworks:Synthesis, Structures, and Multicolor Tuning of Single Component[J]. Inorg. Chem., 2017,56:2345-2353.
[51] Kreno Le, Leong K, Farha OK, et al. Metal-organic framework materials as chemical sensors[J]. Chem. Rev., 2012, 112(2):1105-1125.
[52] Li H Y, Wei Y L, Dong X Y, et al. Novel Tb-MOF Embedded with Viologen Species for Multi-Photofunctionality:Photochromism,Photomodulated Fluorescence, and Luminescent pH Sensing[J].Chem. Mater., 2015, 27(4):1327-1331.
[53] Horcajada P, Serre C, Maurin G, et al. Flexible porous metal-organic frameworks for a controlled drug delivery[J]. J. Am. Chem. Soc.,2008, 130(21):6774-678.