皮革中全氟化合物检测技术研究进展
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摘要
全氟化合物应用广泛,作为防水整理剂加入皮革及皮革制品中,可赋予防水性,并改善其他物理化学性能,提升穿着舒适性。然而,全氟化合物已被证实为难以降解的持久性有机污染物,且能够随食物链传播,具有一定的生殖毒性,对环境和人体危害严重。本文主要综述了皮革及其制品中全氟化合物(PFCs)检测过程中样品的前处理技术和检测方法,指出了皮革中PFCs现有检测技术存在的问题,并对其发展趋势进行了展望。
Perfluorinated compounds are widely used as waterproof finishing agents in leather and leather products,which can give waterproof, improve other physical and chemical properties, and improve wearing comfort. However,perfluorinated compounds have been proved to be persistent organic pollutants that are difficult to degrade, and can be transmitted along the food chain. They have certain reproductive toxicity and serious harm to the environment and human body. In this paper, the pretreatment and detection methods of samples in the detection of perfluorinated compounds(PFCs) in leather and its products were discussed. The existing problems in the detection technology of PFCs in leather were pointed out, and the development trend was prospected.
Perfluorinated compounds are widely used as waterproof finishing agents in leather and leather products,which can give waterproof, improve other physical and chemical properties, and improve wearing comfort. However,perfluorinated compounds have been proved to be persistent organic pollutants that are difficult to degrade, and can be transmitted along the food chain. They have certain reproductive toxicity and serious harm to the environment and human body. In this paper, the pretreatment and detection methods of samples in the detection of perfluorinated compounds(PFCs) in leather and its products were discussed. The existing problems in the detection technology of PFCs in leather were pointed out, and the development trend was prospected.
引文
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[2] Olsen G W, Burris J M, Ehresman D J, et al.Half-life of serum elimination of perfluorooctanesulfonate, perfluorohexanesulfonate, and perfluorooctanoate in retired fluorochemical production workers[J].Environmental Health Perspectives, 2007, 115(9):1298-1305.
[3] LehmLer, H J.Synthesis of environmentally relevant fluorinated surfactants-A review.Chemosphere, 2005, 58(11):1471-1496.
[4] Chaemfa C, Barber L J, Huber S, et al.Screening for PFOS and PFOA in European air using passive samplers[J].Journal of Environmental Monitoring, 2010, 12(5):1100-1109.
[5] Lu Z B, Song L N, Zhao Z, et al.Occurrence and trends in concentrations of perfluoroalkyl substances(PFASs)in surface waters of eastern China[J].Chemosphere, 2015, 119:820-827.
[6]张鸿,赵亮,何龙,等.不同功能区表层土中全氟化合物污染指纹及其来源解析[J].环境科学,2014,35(7):2698-2704.
[7] Higgins C P, Field J A, Criddle C S, et al.Quantitative determination of perfluorochemicals in sediments and domestic sludge[J].Environmental Science&Technology, 2005, 39(11):3946-3956.
[8] JP Giesy, Kannan K.Global Distribution of Perfluorooctane Sulfonate in Wildlife[J].Environmental Science&Technology,2001, 35(7):1339.
[9] Rotander A, Karrman A, van Bavel B, et al.Increasing levels of long-chain perfluorocarboxylic acids(PFCAs)in Arctic and North Atlantic marine mammals, 1984-2009[J].Chemosphere, 2012, 86(3):278-285.
[10] Lau C, Anitole K, Hodes C, et al.Perfluoroalkyl acids:A review of monitoring and toxicological findings[J].Toxicological Sciences, 2007, 99(2):366-394.
[11] Mariussen E.Neurotoxic effects of perfluoroalkylated compounds:Mechanisms of action and environmental relevance[J].Archives of Toxicology, 2012, 86(9):1349-1367.
[12] Knox S S, Jackson T, Javins B, et al.Implications of early menopause in women exposed to perfluorocarbons[J].Journal of Clinical Endocrinology&Metabolism, 2011, 96(6):1747-1753.
[13] The commission of the European Communities.On establishing the ecological criteria for the award of the Community eco-label for footwear(2009/563/EC)[S].
[14] Candidate List of substances of very high concern for authorization[EB/OL].https://echa.europa.eu/candidate-list-table,2018-06/2018-12-24.
[15] Oeko-texRStandard 100 General and special conditions for the authorization to use the Oeko-texRStandard100 mark(Edition 01/2017)[S].
[16] CEN/TS 16968:2010[DB/OL]http://www.doc88.com/p-3377640314124.html,2010-08/2018-12-24.
[17]中华人民共和国国家质量监督检验检疫总局.SN/T2449-2010.中华人民共和国出入境检验检疫行业标准-皮革及其制品中全氟辛烷磺酸的测定液相色谱-质谱/质谱法[S].北京:中国标准出版社,2010.
[18]中华人民共和国国家质量监督检验检疫总局.SN/T3694.11-2013.中华人民共和国出入境检验检疫行业标准-进出口工业品中全氟烷基化合物测定第11部分:皮革液相色谱-串联质谱法[S].北京:中国标准出版社,2014.
[19]中华人民共和国工业和信息化部.QB/T 4554-2013.中华人民共和国轻工业行业标准-鞋类化学试验方法全氟辛酸盐和全氟辛酸的测定液相色谱—串联质谱法[S].北京:中国轻工业出版社,2013.
[20]浙江省技术质量监督局.DB33/T 749-2009.浙江省地方标准-纺织品、皮革中全氟辛烷磺酸盐(PFOS)和全氟辛酸盐(PFOA)的测定液相色谱-串联质谱法[S].
[21]马贺伟,黄丽英,廖上富.液相色谱-串联质谱法测定皮革中PFOS及PFOA盐类[J].皮革科学与工程,2009,19(6):49-52.
[22]陈小珍,黄丽英,廖上富.超高效液相色谱-串联质谱法测定皮革中全氟辛烷磺酸和全氟辛酸[J].理化检验(化学分册),2011,47(2):160-162,165.
[23]严龙.纺织品、皮革及纺织助剂中有害物质的检测方法研究[D].浙江大学,2010:1-63.
[24]盛华栋.纺织品和皮革中PFOS、PFOA检测方法研究[D].浙江大学,2011:1-47.
[25]付寒鸣,黄玢珲,陆展鹏,等.高效液相色谱-质谱法测定皮革及皮革处理剂中全氟辛酸和全氟辛烷磺酸的浓度[J].工业卫生与职业病,2011,37(4):247-249.
[26]刘文莉,李春霞.纺织品、皮革制品中全氟辛酸(PFOA)和全氟辛烷磺酸盐(PFOS)的测定方法初探[J].中国纤检,2010,(10):60-62.
[27]刘志红,邹春海,刘丽,等.高效液相色谱-串联质谱法测定皮革中全氟辛烷磺酸[J].理化检验(化学分册),2010,46(10):1216-1217.
[28]王华,任祥祥,严洪连,等.液相色谱质谱法测定皮革中残留PFOA、PFOS和PFOSA[J].广东化工,2016,43(24):142-143,148.
[29]程群,林碧芬,童玉贵,等.LC-MS/MS测定鞋材中的全氟辛烷磺酸盐[J].皮革科学与工程,2009,19(4):65-67.
[30]卢利军,周晓,韩大川,等.液相色谱串联质谱法测定纺织品和皮革中PFOS含量[J].印染助剂,2009,26(10):50-53.
[31]刘慧婷.食品接触材料及纺织品、皮革中全氟化合物的检测方法研究[D].浙江大学,2011:1-66.
[32]张锋,桑军,俞凌云,等.高效液相色谱-荧光法测定皮革中全氟辛酸残留量[J].中国皮革,2016,45(2):4-8.
[33]黄晓兰,吴惠勤,黄芳,等.液相色谱-质谱法测定纺织品和皮革制品中痕量全氟辛烷磺酸盐[J].分析化学,2017,35(11):1591-1595.
[34]贺文彬,张海煊,林紫威,等.皮革中全氟辛烷磺酸盐和全氟辛酸盐测定方法的优化[J].中国皮革,2012,41(19):30-33.
[35]牛增元,罗忻,叶曦雯.色谱质谱技术在消费品安全检测中的应用进展[J].检验检疫学刊,2011,21(4):1-5.
[36]林泳峰,阮挺,江桂斌.新型全氟和多氟烷基化合物的分析、行为与效应研究进展[J].科学通报,2017,62(24):2724-2733.
[2] Olsen G W, Burris J M, Ehresman D J, et al.Half-life of serum elimination of perfluorooctanesulfonate, perfluorohexanesulfonate, and perfluorooctanoate in retired fluorochemical production workers[J].Environmental Health Perspectives, 2007, 115(9):1298-1305.
[3] LehmLer, H J.Synthesis of environmentally relevant fluorinated surfactants-A review.Chemosphere, 2005, 58(11):1471-1496.
[4] Chaemfa C, Barber L J, Huber S, et al.Screening for PFOS and PFOA in European air using passive samplers[J].Journal of Environmental Monitoring, 2010, 12(5):1100-1109.
[5] Lu Z B, Song L N, Zhao Z, et al.Occurrence and trends in concentrations of perfluoroalkyl substances(PFASs)in surface waters of eastern China[J].Chemosphere, 2015, 119:820-827.
[6]张鸿,赵亮,何龙,等.不同功能区表层土中全氟化合物污染指纹及其来源解析[J].环境科学,2014,35(7):2698-2704.
[7] Higgins C P, Field J A, Criddle C S, et al.Quantitative determination of perfluorochemicals in sediments and domestic sludge[J].Environmental Science&Technology, 2005, 39(11):3946-3956.
[8] JP Giesy, Kannan K.Global Distribution of Perfluorooctane Sulfonate in Wildlife[J].Environmental Science&Technology,2001, 35(7):1339.
[9] Rotander A, Karrman A, van Bavel B, et al.Increasing levels of long-chain perfluorocarboxylic acids(PFCAs)in Arctic and North Atlantic marine mammals, 1984-2009[J].Chemosphere, 2012, 86(3):278-285.
[10] Lau C, Anitole K, Hodes C, et al.Perfluoroalkyl acids:A review of monitoring and toxicological findings[J].Toxicological Sciences, 2007, 99(2):366-394.
[11] Mariussen E.Neurotoxic effects of perfluoroalkylated compounds:Mechanisms of action and environmental relevance[J].Archives of Toxicology, 2012, 86(9):1349-1367.
[12] Knox S S, Jackson T, Javins B, et al.Implications of early menopause in women exposed to perfluorocarbons[J].Journal of Clinical Endocrinology&Metabolism, 2011, 96(6):1747-1753.
[13] The commission of the European Communities.On establishing the ecological criteria for the award of the Community eco-label for footwear(2009/563/EC)[S].
[14] Candidate List of substances of very high concern for authorization[EB/OL].https://echa.europa.eu/candidate-list-table,2018-06/2018-12-24.
[15] Oeko-texRStandard 100 General and special conditions for the authorization to use the Oeko-texRStandard100 mark(Edition 01/2017)[S].
[16] CEN/TS 16968:2010[DB/OL]http://www.doc88.com/p-3377640314124.html,2010-08/2018-12-24.
[17]中华人民共和国国家质量监督检验检疫总局.SN/T2449-2010.中华人民共和国出入境检验检疫行业标准-皮革及其制品中全氟辛烷磺酸的测定液相色谱-质谱/质谱法[S].北京:中国标准出版社,2010.
[18]中华人民共和国国家质量监督检验检疫总局.SN/T3694.11-2013.中华人民共和国出入境检验检疫行业标准-进出口工业品中全氟烷基化合物测定第11部分:皮革液相色谱-串联质谱法[S].北京:中国标准出版社,2014.
[19]中华人民共和国工业和信息化部.QB/T 4554-2013.中华人民共和国轻工业行业标准-鞋类化学试验方法全氟辛酸盐和全氟辛酸的测定液相色谱—串联质谱法[S].北京:中国轻工业出版社,2013.
[20]浙江省技术质量监督局.DB33/T 749-2009.浙江省地方标准-纺织品、皮革中全氟辛烷磺酸盐(PFOS)和全氟辛酸盐(PFOA)的测定液相色谱-串联质谱法[S].
[21]马贺伟,黄丽英,廖上富.液相色谱-串联质谱法测定皮革中PFOS及PFOA盐类[J].皮革科学与工程,2009,19(6):49-52.
[22]陈小珍,黄丽英,廖上富.超高效液相色谱-串联质谱法测定皮革中全氟辛烷磺酸和全氟辛酸[J].理化检验(化学分册),2011,47(2):160-162,165.
[23]严龙.纺织品、皮革及纺织助剂中有害物质的检测方法研究[D].浙江大学,2010:1-63.
[24]盛华栋.纺织品和皮革中PFOS、PFOA检测方法研究[D].浙江大学,2011:1-47.
[25]付寒鸣,黄玢珲,陆展鹏,等.高效液相色谱-质谱法测定皮革及皮革处理剂中全氟辛酸和全氟辛烷磺酸的浓度[J].工业卫生与职业病,2011,37(4):247-249.
[26]刘文莉,李春霞.纺织品、皮革制品中全氟辛酸(PFOA)和全氟辛烷磺酸盐(PFOS)的测定方法初探[J].中国纤检,2010,(10):60-62.
[27]刘志红,邹春海,刘丽,等.高效液相色谱-串联质谱法测定皮革中全氟辛烷磺酸[J].理化检验(化学分册),2010,46(10):1216-1217.
[28]王华,任祥祥,严洪连,等.液相色谱质谱法测定皮革中残留PFOA、PFOS和PFOSA[J].广东化工,2016,43(24):142-143,148.
[29]程群,林碧芬,童玉贵,等.LC-MS/MS测定鞋材中的全氟辛烷磺酸盐[J].皮革科学与工程,2009,19(4):65-67.
[30]卢利军,周晓,韩大川,等.液相色谱串联质谱法测定纺织品和皮革中PFOS含量[J].印染助剂,2009,26(10):50-53.
[31]刘慧婷.食品接触材料及纺织品、皮革中全氟化合物的检测方法研究[D].浙江大学,2011:1-66.
[32]张锋,桑军,俞凌云,等.高效液相色谱-荧光法测定皮革中全氟辛酸残留量[J].中国皮革,2016,45(2):4-8.
[33]黄晓兰,吴惠勤,黄芳,等.液相色谱-质谱法测定纺织品和皮革制品中痕量全氟辛烷磺酸盐[J].分析化学,2017,35(11):1591-1595.
[34]贺文彬,张海煊,林紫威,等.皮革中全氟辛烷磺酸盐和全氟辛酸盐测定方法的优化[J].中国皮革,2012,41(19):30-33.
[35]牛增元,罗忻,叶曦雯.色谱质谱技术在消费品安全检测中的应用进展[J].检验检疫学刊,2011,21(4):1-5.
[36]林泳峰,阮挺,江桂斌.新型全氟和多氟烷基化合物的分析、行为与效应研究进展[J].科学通报,2017,62(24):2724-2733.