高聚物玻璃化转变温度的测量技术
摘要
玻璃化转变温度(T_g)是非晶态高聚物一个重要表征参数,准确测量高聚物的T_g具有很重要意义。文章介绍了T_g测量技术的现状,对DMA、TMA和DSC测量T_g的原理及其定义进行详细介绍、阐述了三种技术的优缺点及应用,并提出了建立T_g测量溯源体系等的建议。
引文
[1]高家武.高分子材料近代测试技术[M].北京:北京航空航天大学出版社,1994:114-125.
[2]李健丰,徐亚娟.测试方法对聚合物玻璃化温度的影响[J].塑料科技,2009,37(2):65-67.
[3]过梅丽.高聚物与复合材料的动态力学热分析[M].北京:化学工业出版社,2002:22-23.
[4]许建中,许晨.动态机械热分析技术及其在高分子中的表征应用[J].化学工程与装备,2008,6(4):22-25.
[5]American Society Testing and Materials.ASTM D7028-07 Standard Test Method for Glass Transition.Temperature of Polymer Matrix Composites by Dynamic Mechanical Analysis[S].United States:A-merican Society Testing and Materials.2008.
[6]International Organization for Standardization.ISO 6721-11-2012Plastics-Determination of dynamic mechanical properties[S].Switzerland:International Organization for Standardization.2012.
[7]徐颖,张勇.测量玻璃化转变温度的几种热分析技术[J].分析仪器,2010(3):57-60.
[8]Ana Pinheiro.Study of the glass transition on viscous-forming and powder materials using dynamic mechanical analysis[J].Polymer Testing,2009,28:89-95.
[9]Wei Sun.Effect of thermal lag on glass transition temperature of polymers measured by DMA[J].International Journal of Adhesion&Adhesives,2014,52:31-39.
[10]吕珏,冯捷敏.测试条件对环氧树脂损耗因子和玻璃化转变温度的影响[J].上海塑料,2016(2):25-29.
[11]丁国芳,王建华,罗世凯.丁基橡胶阻尼材料相容性的DSC与DMA研究[J].化学研究与应用,2004,16(1):113-114.
[12]International Organization for Standardization.ISO 11359-2-1999:Plastics-Thermomechanical analysis(TMA)-Part 2:Determination of coefficient of linear thermalexpansion and glass transition temperature[S].Switzerland:International Organization for Standardization,1991.
[13]American Society Testing and Materials.ASTM E1545-00 Standard Test Method for Assignment of the Glass Transition Temperature by Thermomechanical Analysis[S].United States:American Society Testing and Materials,2000.
[14]古松,赵维忠,李锦平.有机玻璃玻璃化转变温度影响因素的研究[J].塑料工业,2012,40(12):93-111.
[15]付蕾,陈立贵,王忠,等.热机械分析仪测定PMMA玻璃化温度测定条件的研究[J].塑料科技,2012,40(3):89-91.
[16]刘振海,徐国华,张洪林,等.热分析与量热仪与其应用[M].北京:化学工业出版社,2012:190-191.
[17]American Society Testing and Materials.ASTM D1356-2008Standard Test Method for Assignment of the Glass Transition Temperatures by Differential Scanning Calorimetry[S].United States:American Society Testing and Materials,2008.
[18]International Organization for Standardization.ISO 11357-2-1999:Plastics-Differential Scanning Calorimetry(DSC)-Part 2:Determination of glass transition temperature[S].Switzerland:International Organization for Standardization,1999.
[19]GB/T 19466.2-2004塑料-差示扫描量热法(DSC)第2部分:玻璃化转变温度的测定[S].北京:中国标准出版社,2004.
[20]Matthias Wagner著,陆立明编译.热分析应用基础[M].上海:东华大学出版社,2010:174.
[21]Deutsches Institut für Normung e.V.DIN 65467 Differenzthermoanalyse[S].Berlin:Beulth Verlag Gmb H,1999.
[22]郭健.浅析差示扫描量热法测定材料的比热容[J].高分子材料研究,2007(10):19-20.
[23]Yongli Mi,Sixun Zheng.A new study of glass transition of polymers by high pressure DSC[J].Polymer,1998,39(16):3709-3712.
[24]Peng Liu,Long Yu,Hongsheng Liu.Glass transition temperature of starch studied by a high-speed DSC[J].Carbohydrate Polymers,2009,77:250-253.
[25]李守超.差示扫描量热法测定橡胶玻璃化温度[J].分析仪器,2012(3):26-30.
[26]朱梦冰.聚酰亚胺薄膜热形变及杂化研究[D].南京:南京工业大学,2008.
[2]李健丰,徐亚娟.测试方法对聚合物玻璃化温度的影响[J].塑料科技,2009,37(2):65-67.
[3]过梅丽.高聚物与复合材料的动态力学热分析[M].北京:化学工业出版社,2002:22-23.
[4]许建中,许晨.动态机械热分析技术及其在高分子中的表征应用[J].化学工程与装备,2008,6(4):22-25.
[5]American Society Testing and Materials.ASTM D7028-07 Standard Test Method for Glass Transition.Temperature of Polymer Matrix Composites by Dynamic Mechanical Analysis[S].United States:A-merican Society Testing and Materials.2008.
[6]International Organization for Standardization.ISO 6721-11-2012Plastics-Determination of dynamic mechanical properties[S].Switzerland:International Organization for Standardization.2012.
[7]徐颖,张勇.测量玻璃化转变温度的几种热分析技术[J].分析仪器,2010(3):57-60.
[8]Ana Pinheiro.Study of the glass transition on viscous-forming and powder materials using dynamic mechanical analysis[J].Polymer Testing,2009,28:89-95.
[9]Wei Sun.Effect of thermal lag on glass transition temperature of polymers measured by DMA[J].International Journal of Adhesion&Adhesives,2014,52:31-39.
[10]吕珏,冯捷敏.测试条件对环氧树脂损耗因子和玻璃化转变温度的影响[J].上海塑料,2016(2):25-29.
[11]丁国芳,王建华,罗世凯.丁基橡胶阻尼材料相容性的DSC与DMA研究[J].化学研究与应用,2004,16(1):113-114.
[12]International Organization for Standardization.ISO 11359-2-1999:Plastics-Thermomechanical analysis(TMA)-Part 2:Determination of coefficient of linear thermalexpansion and glass transition temperature[S].Switzerland:International Organization for Standardization,1991.
[13]American Society Testing and Materials.ASTM E1545-00 Standard Test Method for Assignment of the Glass Transition Temperature by Thermomechanical Analysis[S].United States:American Society Testing and Materials,2000.
[14]古松,赵维忠,李锦平.有机玻璃玻璃化转变温度影响因素的研究[J].塑料工业,2012,40(12):93-111.
[15]付蕾,陈立贵,王忠,等.热机械分析仪测定PMMA玻璃化温度测定条件的研究[J].塑料科技,2012,40(3):89-91.
[16]刘振海,徐国华,张洪林,等.热分析与量热仪与其应用[M].北京:化学工业出版社,2012:190-191.
[17]American Society Testing and Materials.ASTM D1356-2008Standard Test Method for Assignment of the Glass Transition Temperatures by Differential Scanning Calorimetry[S].United States:American Society Testing and Materials,2008.
[18]International Organization for Standardization.ISO 11357-2-1999:Plastics-Differential Scanning Calorimetry(DSC)-Part 2:Determination of glass transition temperature[S].Switzerland:International Organization for Standardization,1999.
[19]GB/T 19466.2-2004塑料-差示扫描量热法(DSC)第2部分:玻璃化转变温度的测定[S].北京:中国标准出版社,2004.
[20]Matthias Wagner著,陆立明编译.热分析应用基础[M].上海:东华大学出版社,2010:174.
[21]Deutsches Institut für Normung e.V.DIN 65467 Differenzthermoanalyse[S].Berlin:Beulth Verlag Gmb H,1999.
[22]郭健.浅析差示扫描量热法测定材料的比热容[J].高分子材料研究,2007(10):19-20.
[23]Yongli Mi,Sixun Zheng.A new study of glass transition of polymers by high pressure DSC[J].Polymer,1998,39(16):3709-3712.
[24]Peng Liu,Long Yu,Hongsheng Liu.Glass transition temperature of starch studied by a high-speed DSC[J].Carbohydrate Polymers,2009,77:250-253.
[25]李守超.差示扫描量热法测定橡胶玻璃化温度[J].分析仪器,2012(3):26-30.
[26]朱梦冰.聚酰亚胺薄膜热形变及杂化研究[D].南京:南京工业大学,2008.