植物基活性炭前驱体及制备方法研究进展
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摘要
活性炭以其发达的孔隙结构、高比表面积、高吸附率、良好的化学稳定性等优点而备受关注。综述了植物基活性炭前驱体的主要种类和研究进展,详细介绍了制备活性炭的主要方法,即物理活化法、化学活化法和物理化学耦合法。通过比较不同活化方法、不同活化剂所制备的活性炭性能,分析了不同活化方法的优势和不足,并展望了植物基活性炭未来的研究方向。
Activated carbon has attracted much attention due to its advantages such as high porosity,high specific surface area,high adsorption rate and good chemical stability.The precursors of plant-based activated carbon and its research progress were reviewed.And the main preparing methods were introduced.The advantages and disadvantages were introduced by comparing the properties of activated carbon prepared by different activators and different activation methods.Future research directions were predicted.
Activated carbon has attracted much attention due to its advantages such as high porosity,high specific surface area,high adsorption rate and good chemical stability.The precursors of plant-based activated carbon and its research progress were reviewed.And the main preparing methods were introduced.The advantages and disadvantages were introduced by comparing the properties of activated carbon prepared by different activators and different activation methods.Future research directions were predicted.
引文
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[8]王玉新,苏伟,刘聪敏,等.椰壳活性炭作为电极材料和吸附剂的应用研究[J].林产化学与工业,2008,28(5):60-64.
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[16]张志柏,朱义年,刘辉利,等.ZnCl2活化法制备甘蔗渣活性炭吸附剂[J].化工环保,2009,29(1):62-66.
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[18]孙金菊,高建民,郝新敏,等.KOH活化法制备汉麻秆活性炭及其微孔结构的研究[J].功能材料,2014,45(21):21136-21139.
[19]谢志刚,吉芳英,邱雪敏,等.柑橘皮中孔活性炭的制备及性能表征[J].功能材料,2009,40(4):645-649.
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[21]王力,张传祥,张亚飞,等.丝瓜络基活性炭电极材料的制备及其电化学性能表征[J].化工新型材料,2015,43(8):57-59.
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[24]王国栋,邓先伦,朱光真,等.KOH活化高比表面积椰壳活性炭的制备及其性质研究[J].林产化学与工业,2013,33(2):108-112.
[25]王秀芳,张会平,肖新颜,等.高比表面积活性炭研制进展[J].功能材料,2005,36(7):975-977.
[26]褚衍秋,张淮浩,陈进富,等.低活化比富微孔炭质天然气吸附剂的制备工艺条件研究[J].石油与天然气化工,2003,32(6):329-332.
[27]Dobele G,Dizhbite T,Rossinskaja G,et al.Pre-treatment of biomass with phosphoric acid prior to fast pyrolysis,apromising method for obtaining anhydrosaccharides in high yields[J].Anal.Applied Pyrolysis,2003(68/69):197-211.
[28]Liou Tzonghorng.Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chlorideactivation[J].Chemical Engineering Journal,2010(158):129-142.
[29]Sun Yuanyuan,Xu Xing,Li Qian,et al.Comparative study on characterization and adsorption properties of activated carbons with H3PO4and H4P2O7activation employing cyperus alternifolius as precursor[J].Chemical Engineering Journal,2012(181/182):790-797.
[30]胡志杰,左宋林.H3PO4活化法制备稻壳活性炭的研究[J].林业科技开发,2007,21(4):83-85.
[31]徐涛,刘晓勤.H3PO4活化法制备花生壳活性炭工艺[J].化学工程,2009,37(11):70-74.
[32]司崇殿,郭庆杰.活性炭活化机理与再生研究进展[J].中国粉体技术,2008,14(5):48-52.
[33]卢辛成,蒋剑春,孙康,等.ZnCl2法制备杉木屑活性炭的研究[J].林产化学与工业,2013,33(3):59-63.
[34]苑守瑞,朱义年,梁美娜.ZnCl2活化法制备柚子皮活性炭[J].环境科学与技术,2010(s1):22-25.
[35]代晓东,刘欣梅,钱岭,等.物理化学耦合活化法制备活性炭[J].炭素技术,2008,27(4):30-34.
[2]Kalderis D,Bethanis S,Paraskeva P,et al.Production of activated carbon from bagasse and rice husk by a single-stage chemical activation method at low retention times[J].Bioresource Technology,2008,99(15):6809-6816.
[3]Deiana C,Granados D,Venturini R,et al.Activated carbons obtained from rice husk:influence of leaching on textural parameters[J].Industrial&Engineering Chemistry Research,2008,47(14):4754-4757.
[4]厉悦,李湘洲,刘敏.氢氧化钠法稻壳基活性炭制备及表征[J].安徽农业科学,2010,38(11):5829-5830.
[5]胡志杰,李淳.水蒸气活化法制备稻壳活性炭的研究[J].生物质化学工程,2007,41(5):21-24.
[6]Chen Y,Zhai S R,Liu N,et al.Dye removal of activated carbons prepared from NaOH-pretreated rice husks by low-temperature solution-processed carbonization and H3PO4,activation[J].Bioresource Technology,2013,144C(3):401-409.
[7]廖钦洪,李会合,刘奕清,等.碳酸钾活化剂法制备稻壳活性炭的工艺优化[J].农业工程学报,2015,31(11):256-261.
[8]王玉新,苏伟,刘聪敏,等.椰壳活性炭作为电极材料和吸附剂的应用研究[J].林产化学与工业,2008,28(5):60-64.
[9]魏海博,陈一民,谢凯.高比表面积椰壳活性炭电极材料研究[C].武汉:中国空间科学学会空间材料专业委员会,2012.
[10]付国家,张建社,郭庆杰.核桃壳化学-物理耦合活化法制备活性炭及其表征[J].青岛科技大学学报自然科学版,2012,33(2):126-130.
[11]余筱洁,周存山,王允祥,等.山核桃壳活性炭制备及其吸附苯胺特性[J].过程工程学报,2010,10(1):65-69.
[12]张越,杨晓霞,徐家伟,等.化学活化法制枣核基活性炭研究[J].广州化工,2015(6):102-104.
[13]Sekirifa M L,Hadj-Mahammed M,Pallier S,et al.Preparation and characterization of an activated carbon from a date stones variety by physical activation with carbon dioxide[J].Journal of Analytical&Applied Pyrolysis,2013,99(99):155-160.
[14]莫柳珍,廖炳权,黄向阳,等.甘蔗渣活性炭制备研究进展[J].广西糖业,2015(1):31-35.
[15]周曰,潘卫国,郭瑞堂,等.用H3PO4活化法制备甘蔗渣活性炭及其吸附性能研究[J].上海电力学院学报,2013,29(1):97-100.
[16]张志柏,朱义年,刘辉利,等.ZnCl2活化法制备甘蔗渣活性炭吸附剂[J].化工环保,2009,29(1):62-66.
[17]马承愚,毛宇,徐鹏飞,等.KOH/NaOH活化法辣椒秸秆制备高表面积活性炭与表征[J].功能材料,2013,44(5):704-708.
[18]孙金菊,高建民,郝新敏,等.KOH活化法制备汉麻秆活性炭及其微孔结构的研究[J].功能材料,2014,45(21):21136-21139.
[19]谢志刚,吉芳英,邱雪敏,等.柑橘皮中孔活性炭的制备及性能表征[J].功能材料,2009,40(4):645-649.
[20]刘斌,杨继亮,马叶,等.磷酸活化法制备梧桐叶活性炭及表征[J].林产工业,2013,40(6):35-40.
[21]王力,张传祥,张亚飞,等.丝瓜络基活性炭电极材料的制备及其电化学性能表征[J].化工新型材料,2015,43(8):57-59.
[22]Bouchelta C,Medjram M S,Bertrand O,et al.Preparation and characterization of activated carbon from date stones by physical activation with steam[J].Journal of Analytical&Applied Pyrolysis,2008,82(1):70-77.
[23]Rodríguez-Reinoso F,Molina-Sabio M.Activated carbons from lignocellulosic materials by chemical and/or physical activation:an overview[J].Carbon,1992,30(7):1111-1118.
[24]王国栋,邓先伦,朱光真,等.KOH活化高比表面积椰壳活性炭的制备及其性质研究[J].林产化学与工业,2013,33(2):108-112.
[25]王秀芳,张会平,肖新颜,等.高比表面积活性炭研制进展[J].功能材料,2005,36(7):975-977.
[26]褚衍秋,张淮浩,陈进富,等.低活化比富微孔炭质天然气吸附剂的制备工艺条件研究[J].石油与天然气化工,2003,32(6):329-332.
[27]Dobele G,Dizhbite T,Rossinskaja G,et al.Pre-treatment of biomass with phosphoric acid prior to fast pyrolysis,apromising method for obtaining anhydrosaccharides in high yields[J].Anal.Applied Pyrolysis,2003(68/69):197-211.
[28]Liou Tzonghorng.Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chlorideactivation[J].Chemical Engineering Journal,2010(158):129-142.
[29]Sun Yuanyuan,Xu Xing,Li Qian,et al.Comparative study on characterization and adsorption properties of activated carbons with H3PO4and H4P2O7activation employing cyperus alternifolius as precursor[J].Chemical Engineering Journal,2012(181/182):790-797.
[30]胡志杰,左宋林.H3PO4活化法制备稻壳活性炭的研究[J].林业科技开发,2007,21(4):83-85.
[31]徐涛,刘晓勤.H3PO4活化法制备花生壳活性炭工艺[J].化学工程,2009,37(11):70-74.
[32]司崇殿,郭庆杰.活性炭活化机理与再生研究进展[J].中国粉体技术,2008,14(5):48-52.
[33]卢辛成,蒋剑春,孙康,等.ZnCl2法制备杉木屑活性炭的研究[J].林产化学与工业,2013,33(3):59-63.
[34]苑守瑞,朱义年,梁美娜.ZnCl2活化法制备柚子皮活性炭[J].环境科学与技术,2010(s1):22-25.
[35]代晓东,刘欣梅,钱岭,等.物理化学耦合活化法制备活性炭[J].炭素技术,2008,27(4):30-34.