LaNi_5系储氢合金的研究现状及展望
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摘要
作为一种清洁环保的新型二次能源,氢能已经被越来越多地应用于人们的生活中。氢的有效储存是氢能实用化中的关键步骤。LaNi_5型储氢材料是一种优秀的储氢合金,对LaNi_5型储氢材料进行详细介绍,综述了元素部分取代及合金制备工艺两个方面对合金储氢性能的研究进展。分析了LaNi_5系储氢合金现存的主要问题,对其发展和市场前景做出展望。
As a clean and environmental friendly new secondary energy,hydrogen has been more and more applied in people's life.Effective hydrogen storage is the key for efficient utilization of hydrogen.LaNi_5 material is a kind of excellent hydrogen storage alloy.LaNi_5 hydrogen storage alloys were introduced deeply.In the meantime,the existing main problems of LaNi_5 hydrogen storage alloys were analyzed,and prospected its market prospect and development trend.
As a clean and environmental friendly new secondary energy,hydrogen has been more and more applied in people's life.Effective hydrogen storage is the key for efficient utilization of hydrogen.LaNi_5 material is a kind of excellent hydrogen storage alloy.LaNi_5 hydrogen storage alloys were introduced deeply.In the meantime,the existing main problems of LaNi_5 hydrogen storage alloys were analyzed,and prospected its market prospect and development trend.
引文
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[22]李瑞,胡泽忠,刘永锋,等.La0.7Mg0.3Ni2.65Co0.75-xMn0.1Six储氢电极合金的结构和电化学性能[J].材料科学与工程学报,2013,31(3):372-375,460.
[23]江冰洁,王敬,穆道斌,等.Al对La-Mg-Ni系贮氢合金电极电化学性能的影响[J].中国有色金属学报,2008,18(11):2036-2043.
[24]Wang L,Yan H Z,Xiong W,et al.The influence of boron content on the structural and electrochemical properties of the La15Fe77B8-type hydrogen storage alloy[J].J Power Sources,2014,259(1):213.
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[26]闫慧忠,熊玮,孔繁清,等.La15Fe77B8型储氢合金的结构和电化学性能[J].中国稀土学报,2012,30(5):587-593.
[27]黄显吞.退火对(La0.8Nd0.2)2Mg(Ni0.8-xCo0.1Mn0.1Alx)9合金储氢性能的影响[J].金属热处理,2014,39(2):15-18.
[28]Zhao X Y,Ding Y,Yang M,et al.Effect of surface treatment on electrochemical properties of MmNi3.8Co0.75Mn0.4Al0.2hydrogen storage alloy[J].International Journal of Hydrogen Energy,2008,33(1):81-86.
[29]张森,邓超.新型AB5储氢合金表面修饰方法及机理研究[J].物理化学学报,2005,21(10):1146-1150.
[30]吕燕.储氢合金粉表面电化学修饰镍磷合金的研究[J].唐山学院学报,2014,27(6):42-44,50.
[2]Shi H,Han S M,Jia Y H,et al.In-vestigations on hydrogen storage properties of LaMg8.52Ni2.23M0.15(M=Ni,Cu,Cr)alloys[J].J Rare Earths,2013,31(1):79.
[3]Zhu X L,Han S M,Zhao X,et al.Effect of lan-thanum hydride on microstructures and hydrogen storage performances of2LiNH2-MgH2system[J].Rare Earths,2014,32(5):429.
[4]Schlapbach L,Züttel A.Hydrogen-storage materials for mobile applications[J].Nature,2001,414(6861):353.
[5]Schur D V,Zaginaichenko S Y,Matysina Z A,et al.Hydrogen in lanthan-nickel storage alloys[J].Journal of Alloys&Compounds,2002,s330-332(1):70-75.
[6]Willems J J,Buschow K H.From permanent magnets to rechargeable hydride electrodes[J].J Less Comm Met,1987,129(1):12.
[7]肖玲玲,王一菁,刘毅,等.储氢合金La0.7-xCexMg0.3Ni2.4Co0.6(x=0~0.4)电化学性能研究[J].电化学,2007,13(1):40-43.
[8]罗永春,刘刚,康龙.稀土Ce对无Co过计量比CaCu5型合金贮氢和电化学性能的影响[J].兰州理工大学学报,2009,35(5):17-22.
[9]李宝犬,熊玮,王利,等.La15-xCexFe14Ni64Mn5B2(x=0~6)储氢合金结构及电化学性能研究[J].稀土,2014(2):1-6.
[10]苏泉榕,王凤,黄贺伟,等.La1-xPrxNi4.2Mn0.3Al0.3Cu0.15Fe0.05储氢合金结构及电化学性能[J].电工材料,2014(2):8-12.
[11]Pan H,Ma S,Shen J,et al.Effect of the substitution of PR for LA on the microstructure and electrochemical properties of La0.7-xPrxMg0.3Ni2.45Cu0.75Mn0.1Al0.2(x=0.0-0.3)hydrogen storage electrode alloys[J].International Journal of Hydrogen Energy,2007,32(14):2949-2956.
[12]Zhang Yanghuan,Wang Haitao,Yang Tai.Electrochemical hydrogen storage performances of the nanocrystalline and amorphous(Mg24Ni10Cu2)100-xNdx(x=0-20)alloy applied to Ni-MH battery[J].Journal of Rare Earths,2013,31(12):1175-1182.
[13]Zhang F L,Luo Y C.Structure and electrochemical properties of La2-xMgxNi7.0(x=0.3~0.6)hydrogen storage alloys[J].Journal of Alloys and Compounds,2007,439(1-2):181-188.
[14]Asano K,Yamazaki Y,Iijima Y.Hydrogen and dehydriding processes of LaNi5-xCox(x=0~2)alloys under hydrogen pressure of 1~5MPa[J].Inter Metallic,2003,11(9):911.
[15]李斯,邓健秋,唐莹,等.Co部分替代Ni对La0.4Er0.4Mg0.2Ni3.3-xCoxAl0.2(0.1≦x≦0.4)储氢合金结构和电化学性能的影响[J].桂林电子科技大学学报,2014,34(3):254-258.
[16]Liu J,Yang Y,Shao H.Rapid evaluation of LaNi5-xMnx(x=0.1~0.5)by X-ray diffraction and powder microelectrode(PME)techniques[J].J Alloy Compd,2007,429(1):285.
[17]Kong L,Chen Be,Young K,et al.Effect of Al and Mn contents in the negative MH alloy on the self-discharge and long term storage properties of Ni-MH battery[J].Journal of Power Sources,2012,213:128-139.
[18]Wu Jianmin,Li Jun,Zhang Wenpeng,et al.The study on the hydrogen storage properties of MmNiCoMnAl compounds[J].Journal of Alloys and Compounds,1997,248(1-2):180-184.
[19]Jiang Long,Li Guangxu,Xu Liqin,et al.Effect of substituting Mn for Ni on the hydrogen storage electrochemical properties of RENi2.6-xMnxCo0.9alloy[J].International Journal of Hydrogen Energy,2010,35:204-209.
[20]Yang Shouqin,Han Shumin,Li Yuan,et al.Study on the microstructure and electrochemical kineric properties of MmNi4.5-x MnxCo0.45Al0.30(0.25≤x≤0.45)hydrogen storage alloys[J].Materials Science and Engineering:B,2013,178(1):39-44.
[21]彭雯琦,戴豪,邓年进,等.Fe部分取代Co对La0.7Zr0.1Mg0.2Ni2.75Co0.75-xFex合金储氢性能的影响[J].材料导报,2014,28(2):25-29,33.
[22]李瑞,胡泽忠,刘永锋,等.La0.7Mg0.3Ni2.65Co0.75-xMn0.1Six储氢电极合金的结构和电化学性能[J].材料科学与工程学报,2013,31(3):372-375,460.
[23]江冰洁,王敬,穆道斌,等.Al对La-Mg-Ni系贮氢合金电极电化学性能的影响[J].中国有色金属学报,2008,18(11):2036-2043.
[24]Wang L,Yan H Z,Xiong W,et al.The influence of boron content on the structural and electrochemical properties of the La15Fe77B8-type hydrogen storage alloy[J].J Power Sources,2014,259(1):213.
[25]Lei Y Q,Zhang S K,LüG L,et al.Influence of the material processing on the electrochemical properties of cobalt-free Ml(NiMnAlFe)5,alloy[J].Journal of Alloys&Compounds,2002,330(2):861-865.
[26]闫慧忠,熊玮,孔繁清,等.La15Fe77B8型储氢合金的结构和电化学性能[J].中国稀土学报,2012,30(5):587-593.
[27]黄显吞.退火对(La0.8Nd0.2)2Mg(Ni0.8-xCo0.1Mn0.1Alx)9合金储氢性能的影响[J].金属热处理,2014,39(2):15-18.
[28]Zhao X Y,Ding Y,Yang M,et al.Effect of surface treatment on electrochemical properties of MmNi3.8Co0.75Mn0.4Al0.2hydrogen storage alloy[J].International Journal of Hydrogen Energy,2008,33(1):81-86.
[29]张森,邓超.新型AB5储氢合金表面修饰方法及机理研究[J].物理化学学报,2005,21(10):1146-1150.
[30]吕燕.储氢合金粉表面电化学修饰镍磷合金的研究[J].唐山学院学报,2014,27(6):42-44,50.