二氧化铅阳极改性及电化学氧化性能研究进展
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摘要
介绍了PbO_2阳极的性质以及优缺点,并从基体、中间层、表面层三方面对PbO_2阳极的改性方法进行了概述。总结、分析了不同改性方法改性后阳极的电化学氧化性能与其他主要性能,提出了现阶段PbO_2阳极应用中存在的主要问题,并对今后PbO_2阳极改性研究方向提出了建议。
The paper introduces the property of lead dioxide anode and analyzes the advantages and disadvantages of lead dioxide anode. Matrix, Interlayer and Surface layer can be reviewed from the points of lead dioxide anode to change property. The electrochemical oxidation properties and other main properties of the electrode plate modified by each modification method are reviewed after modification. The current main application problems are pointed out and the modified method research direction of lead dioxide anode is forecasted.
The paper introduces the property of lead dioxide anode and analyzes the advantages and disadvantages of lead dioxide anode. Matrix, Interlayer and Surface layer can be reviewed from the points of lead dioxide anode to change property. The electrochemical oxidation properties and other main properties of the electrode plate modified by each modification method are reviewed after modification. The current main application problems are pointed out and the modified method research direction of lead dioxide anode is forecasted.
引文
[1] 李晓良,徐浩,延卫,等.钛基二氧化铅电极的制备及其改性的研究进展[J].电镀与涂饰,2016(7):378-382.
[2] 李月婵,余培锴.石墨烯基二氧化铅复合材料的一锅法制备及电学性能[J].湖北师范大学学报(自然科学版),2018(2):65-71.
[3] 张杰磊,陈步明,郭忠诚,等.一种新型Al基PbO2电极的性能研究[J].材料保护,2018(9):30-34.
[4] 王瑞祥,陈芳会,张斌,等.电化学阳极氧化构建Pb/3D-PbO2结构[J].有色金属(冶炼部分),2019(1):1-6.
[5] 周涛,姚颖悟,顿朋.二氧化铅电极电催化降解对氯苯酚的研究[J].电镀与精饰,2012(10):32-34.
[6] MENG D F,LI G,LIU Z H,et al.Study of depolymerization of cotton cellulose by Pb/PbO2 anode electrochemical catalysis in sulfuric acid solution[J].Polymer Degradation & Stability,2011(7):1173-1178.
[7] ZHAO W,XING J T,CHEN D H,et al.Study on the performance of an improved Ti/SnO2-Sb2O3/PbO2 based on porous titanium substrate compared with planar titanium substrate[J].RSC Advances,2015,5:26530-26539.
[8] 陈步明,郭忠诚.α-PbO2-CeO2-TiO2复合电极材料的耐蚀性研究[J].电镀与精饰,2011(4):1-4.
[9] 王炼,张钱丽,王东田,等.改性金属氧化物电极用于降解邻甲酚的性能研究[J].化学研究与应用,2015(5):612-616.
[10] 卓琼芳,罗梅清,李永铭,等.新型钛基二氧化铅电极的制备及其对全氟辛酸的降解[J].工业水处理,2019(3):30-34.
[11] XING J T,CHEN D H,ZHAO W,et al.Preparation and characterization of a novel porous Ti/SnO2-Sb2O3-CNT/PbO2 electrode for the anodic oxidation of phenol wastewater[J].Rsc Advances,2015(66):53504-53513.
[12] 褚秋霞,梁镇海,孙颜发,等.稀土Y掺杂Ti/SnO2+MnOx/PbO2电极的电化学性能研究[J].稀有金属材料与工程,2009(5):821-825.
[13] 唐长斌,郑超,于丽花,等.电镀镍中间层对钛基二氧化铅阳极性能的影响[J].稀有金属材料与工程,2019(1):143-151.
[14] 周键,王三反.钛基二氧化铅阳极去除有机污染物的研究进展[J].环境工程,2014(12):1-4.
[15] 王鸿辉,马明洁,冯婕,等.钕掺杂二氧化铅复合阳极的电化学性能研究[J].电化学,2018(4):367-374.
[16] 郑辉,戴启洲,王家德,等.La/Ce掺杂钛基二氧化铅电极的制备及电催化性能研究[J].环境科学,2012(3):857-865.
[17] XIE T T,HU H T,CHEN D H,et al.Electrochemical Degradation of Tetracycline Hydrochloride in Aqueous Medium by (B4C/C)‐β‐PbO2 Electrode[J].Bulletin of the Korean Chemical Society,2017,38:756-762.
[18] 杨丽娟,魏杰,胡翔.Ce-PbO2/C电极的制备及其去除水中酸性红B[J].环境工程学报,2014(3):941-947.
[19] 张博文,汤莎莎,宋爽.碳纳米点掺杂二氧化铅电极电催化降解2,4-D[J].水处理技术,2018(7):21-25.
[20] 王炼,张钱丽,王东田,等.高性能二氧化铅电极制备及降解邻甲酚[J].环境工程学报,2016(4):1657-1664.
[21] 雷佳妮,李晓良,袁孟孟,等.脉冲电化学氧化降解亚甲基蓝[J].中国环境科学,2018(5):1767-1773.
[22] YAO Y W,LI M Y,YANG Y,et al.Electrochemical degradation of insecticide hexazinone with Bi-doped PbO2 electrode:Influencing factors,intermediates and degradation mechanism[J].Chemosphere,2019,216:812-822.
[23] SUN P Z,CHEN D H.Electrochemical degradation of reactive brilliant red X-3B with the (CeO2/C)-β-PbO2-PTFE composite electrode[J].Journal of Rare Earths,2016(5):507-520.
[24] 徐迈,王凤武,梁铣,等.Pr-PVP掺杂Ti/PbO2电极制备及其在有机物降解中的应用[J].电化学,2017(3):340-346.
[25] BARBARI K,DELIMI R,BENREDJEM Z,et al.Photocatalytically-assisted electrooxidation of herbicide fenuron using a new bifunctional electrode PbO2/SnO2-Sb2O3/Ti//Ti/TiO2[J].Chemosphere,2018,203:1-10.
[26] KANNAN K,MUTHURAMAN G,CHO G,et al.Fabrication of a nano-structured PbO2 electrode by using printing technology:Surface characterization and application[J].Journal of the Korean Physical Society,2014(3):372-376.
[27] Li X L,LI X M,YANG W J,et al.Preparation of 3D PbO2 nanospheres SnO2 nanowires/Ti Electrode and Its Application in Methyl Orange Degradation[J].Electrochimica Acta,2014,146:15-22.
[28] 毛雨路,张西,徐迈,等.Ti/TiO2纳米管阵列/PbO2-Pr电极制备及在电氧化有机废水中应用[J].应用化学,2018(5):582-588.
[29] 邢俊涛,周秉武.多孔Ti/SnO2-Sb2O5/CNT-PbO2电极的制备及其电催化氧化有机染料废水的研究[J].上海化工,2018(6):15-22.
[2] 李月婵,余培锴.石墨烯基二氧化铅复合材料的一锅法制备及电学性能[J].湖北师范大学学报(自然科学版),2018(2):65-71.
[3] 张杰磊,陈步明,郭忠诚,等.一种新型Al基PbO2电极的性能研究[J].材料保护,2018(9):30-34.
[4] 王瑞祥,陈芳会,张斌,等.电化学阳极氧化构建Pb/3D-PbO2结构[J].有色金属(冶炼部分),2019(1):1-6.
[5] 周涛,姚颖悟,顿朋.二氧化铅电极电催化降解对氯苯酚的研究[J].电镀与精饰,2012(10):32-34.
[6] MENG D F,LI G,LIU Z H,et al.Study of depolymerization of cotton cellulose by Pb/PbO2 anode electrochemical catalysis in sulfuric acid solution[J].Polymer Degradation & Stability,2011(7):1173-1178.
[7] ZHAO W,XING J T,CHEN D H,et al.Study on the performance of an improved Ti/SnO2-Sb2O3/PbO2 based on porous titanium substrate compared with planar titanium substrate[J].RSC Advances,2015,5:26530-26539.
[8] 陈步明,郭忠诚.α-PbO2-CeO2-TiO2复合电极材料的耐蚀性研究[J].电镀与精饰,2011(4):1-4.
[9] 王炼,张钱丽,王东田,等.改性金属氧化物电极用于降解邻甲酚的性能研究[J].化学研究与应用,2015(5):612-616.
[10] 卓琼芳,罗梅清,李永铭,等.新型钛基二氧化铅电极的制备及其对全氟辛酸的降解[J].工业水处理,2019(3):30-34.
[11] XING J T,CHEN D H,ZHAO W,et al.Preparation and characterization of a novel porous Ti/SnO2-Sb2O3-CNT/PbO2 electrode for the anodic oxidation of phenol wastewater[J].Rsc Advances,2015(66):53504-53513.
[12] 褚秋霞,梁镇海,孙颜发,等.稀土Y掺杂Ti/SnO2+MnOx/PbO2电极的电化学性能研究[J].稀有金属材料与工程,2009(5):821-825.
[13] 唐长斌,郑超,于丽花,等.电镀镍中间层对钛基二氧化铅阳极性能的影响[J].稀有金属材料与工程,2019(1):143-151.
[14] 周键,王三反.钛基二氧化铅阳极去除有机污染物的研究进展[J].环境工程,2014(12):1-4.
[15] 王鸿辉,马明洁,冯婕,等.钕掺杂二氧化铅复合阳极的电化学性能研究[J].电化学,2018(4):367-374.
[16] 郑辉,戴启洲,王家德,等.La/Ce掺杂钛基二氧化铅电极的制备及电催化性能研究[J].环境科学,2012(3):857-865.
[17] XIE T T,HU H T,CHEN D H,et al.Electrochemical Degradation of Tetracycline Hydrochloride in Aqueous Medium by (B4C/C)‐β‐PbO2 Electrode[J].Bulletin of the Korean Chemical Society,2017,38:756-762.
[18] 杨丽娟,魏杰,胡翔.Ce-PbO2/C电极的制备及其去除水中酸性红B[J].环境工程学报,2014(3):941-947.
[19] 张博文,汤莎莎,宋爽.碳纳米点掺杂二氧化铅电极电催化降解2,4-D[J].水处理技术,2018(7):21-25.
[20] 王炼,张钱丽,王东田,等.高性能二氧化铅电极制备及降解邻甲酚[J].环境工程学报,2016(4):1657-1664.
[21] 雷佳妮,李晓良,袁孟孟,等.脉冲电化学氧化降解亚甲基蓝[J].中国环境科学,2018(5):1767-1773.
[22] YAO Y W,LI M Y,YANG Y,et al.Electrochemical degradation of insecticide hexazinone with Bi-doped PbO2 electrode:Influencing factors,intermediates and degradation mechanism[J].Chemosphere,2019,216:812-822.
[23] SUN P Z,CHEN D H.Electrochemical degradation of reactive brilliant red X-3B with the (CeO2/C)-β-PbO2-PTFE composite electrode[J].Journal of Rare Earths,2016(5):507-520.
[24] 徐迈,王凤武,梁铣,等.Pr-PVP掺杂Ti/PbO2电极制备及其在有机物降解中的应用[J].电化学,2017(3):340-346.
[25] BARBARI K,DELIMI R,BENREDJEM Z,et al.Photocatalytically-assisted electrooxidation of herbicide fenuron using a new bifunctional electrode PbO2/SnO2-Sb2O3/Ti//Ti/TiO2[J].Chemosphere,2018,203:1-10.
[26] KANNAN K,MUTHURAMAN G,CHO G,et al.Fabrication of a nano-structured PbO2 electrode by using printing technology:Surface characterization and application[J].Journal of the Korean Physical Society,2014(3):372-376.
[27] Li X L,LI X M,YANG W J,et al.Preparation of 3D PbO2 nanospheres SnO2 nanowires/Ti Electrode and Its Application in Methyl Orange Degradation[J].Electrochimica Acta,2014,146:15-22.
[28] 毛雨路,张西,徐迈,等.Ti/TiO2纳米管阵列/PbO2-Pr电极制备及在电氧化有机废水中应用[J].应用化学,2018(5):582-588.
[29] 邢俊涛,周秉武.多孔Ti/SnO2-Sb2O5/CNT-PbO2电极的制备及其电催化氧化有机染料废水的研究[J].上海化工,2018(6):15-22.