植物源食品中植物生长调节剂检测标准与分析技术研究进展
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摘要
植物生长调节剂是一类可调控植物生长发育的物质,一般为高效、低毒、低残留农药,起到增产、改善品质、缩短生长周期、延长保鲜期的作用。随着植物生长调节剂在农业生产中发挥日趋重要作用,一些种植户受利益驱动而滥用植物生长调节剂,由此引起的食品安全问题成为公众的关注焦点,残留检测技术研究凸显重要性。本文依据我国登记使用的植物生长调节剂种类,分别介绍了食品安全国家标准中规定植物源食品中植物生长调节剂的最大残留限量和相应的检测标准,概述了国内外最新样品制备方法和仪器分析技术,重点关注多残留检测技术的应用,并对植物生长调节剂残留分析技术发展方向进行展望,以期为更新与完善残留限量标准以及检测标准提供参考依据。
Plant growth regulators are a class of substances those regulate the growth and development of plants.Generally, with the features of high-efficiency, low-toxic, low-residue pesticide, they play a role in increasing production, improving quality, shortening the growth cycle, and prolonging the shelf life. With plant growth regulators playing an increasingly important role in agricultural production, some farmers are driven by the benefit to abuse the plant growth regulators, and the food safety problems caused thereby have become the focus of public attention. The research on residue detection technology is of great importance. Based on the kinds of plant growth regulators registered in China, this article introduced the maximum residue limit of plant growth regulators in the national food safety standards and the corresponding detection standards, summarized the latest sample preparation methods and analytical techniques of instruments at home and abroad, focused on the application of multi-residue determination technology, and prospected the development trend of residue analysis of plant growth regulators, so as to provide technical support for updating and perfecting the residue limit standard and detection standard.
Plant growth regulators are a class of substances those regulate the growth and development of plants.Generally, with the features of high-efficiency, low-toxic, low-residue pesticide, they play a role in increasing production, improving quality, shortening the growth cycle, and prolonging the shelf life. With plant growth regulators playing an increasingly important role in agricultural production, some farmers are driven by the benefit to abuse the plant growth regulators, and the food safety problems caused thereby have become the focus of public attention. The research on residue detection technology is of great importance. Based on the kinds of plant growth regulators registered in China, this article introduced the maximum residue limit of plant growth regulators in the national food safety standards and the corresponding detection standards, summarized the latest sample preparation methods and analytical techniques of instruments at home and abroad, focused on the application of multi-residue determination technology, and prospected the development trend of residue analysis of plant growth regulators, so as to provide technical support for updating and perfecting the residue limit standard and detection standard.
引文
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[2]许春爽,姜宙,沈伟,等.植物生长调节剂的毒理作用及其损害雄性生殖健康的研究进展[J].中华男科学杂志,2018,(4):370-375.Xu CS, Jiang Z, Shen W, et al. Toxicological characteristics of plant growth regulators and their impact on male reproductive health[J]. Natl J Androl, 2018,(4):370-375.
[3] Hosseinchi M, Soltanalinejad F, Najafi G, et al. Effect of gibberellic acid on the quality of sperm and in vitro fertilization outcome in adult male rats[J]. Vet Res Forum, 2013,4(4):259-264.
[4] Troudi A, Samet AM, Zeghal N. Hepatotoxicity induced by gibberellic acid in adult rats and their progeny[J]. Exp Toxicol Pathol, 2010, 62(6):637-642.
[5] Sagelsdorff P, Lutz WK, Schlatter C. DNA methylation in rat liver by daminozide, 1,1-dimethylhydrazine, and dimethylnitrosamine[J]. Fundam Appl Toxicol, 1988, 11(4):723-730.
[6] GB2763-2016食品安全国家标准食品中农药最大残留限量[S].GB2763-2016 National food safety standard-Maximum residue limits for pesticides in food[S].
[7] Ruiz DAC, Soloneski S, Larramendy ML. Toxic and genotoxic effects of the 2,4-dichlorophenoxyacetic acid(2,4-D)-based herbicide on the Neotropical fish Cnesterodon decemmaculatus[J]. Ecotoxicol Environ Saf,2016, 128:222-229.
[8] GB/T5009.219-2008粮谷中矮壮素残留量的测定[S].GB/T 5009.219-2008 Determination of the residues of chlorcholine chloride in cereals[S].
[9] SN/T 1477-2012出口食品中多效唑残留量检测方法[S].SN/T 1477-2012 Determination of paclobutrazol residues in food for export[S].
[10] GB/T 20769-2008水果和蔬菜中450种农药及相关化学品残留量的测定液相色谱-串联质谱法[S].GB/T 20769-2008 Determination of 450 pesticides and related chemicals residues in fruits and vegetables LC-MS MS method[S].
[11] GB/T 20770-2008粮谷中486种农药及相关化学品残留量的测定液相色谱-串联质谱法[S].GB/T 20770-2008 Determination of 486 pesticides and related chemicalsresidues in grains-LC-MS-MS method[S].
[12] GB 23200.9-2016食品安全国家标准粮谷中475种农药及相关化学品残留量的测定气相色谱-质谱法[S].GB 23200.9-2016 National food safety standards-Determination of 475pesticides and related chemicals residues in grains Gas chromatography-mass spectrometry[S].
[13] GB 23200.8-2016食品安全国家标准水果和蔬菜中500种农药及相关化学品残留量的测定气相色谱-质谱法[S].GB 23200.8-2016 National food safety standards-Determination of 500pesticides and related chemicals residues in fruits and vegetables-Gas chromatography-mass spectrometry[S].
[14] SN/T0931-2013出口粮谷中调环酸钙残留量检测方法液相色谱法[S].SN/T 0931-2013 Determination of prohexadione calciumresidues incereals for export-LC method[S].
[15] GB 23200.16-2016食品安全国家标准水果和蔬菜中乙烯利残留量的测定气相色谱法[S].GB 23200.16-2016 National food safety standards-Determination of ethephon residue in fruits and vegetables Gas chromatography[S].
[16] SN/T 2228-2008进出口食品中31种酸性除草剂残留量的检测方法气相色谱-质谱法[S].SN/T 2228-2008 Determination of 31 acid pesticide residues in foods for import and export-GC/MS method[S].
[17] GB 23200.24-2016食品安全国家标准粮谷和大豆中11种除草剂残留量的测定气相色谱-质谱法[S].GB 23200.24-2016 National food safety standards-Detemimation of 11herbicide residues in cereals and soybean-Gas chromatography-mass spectrometry[S].
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