自由基产生剂在阻燃塑料中的应用
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摘要
综述了2,3-二甲基-2,3-二苯基丁烷、N-烷氧基受阻胺、偶氮烷烃等自由基产生剂在阻燃塑料中作为阻燃协效剂或阻燃剂的应用及研究进展,并对自由基产生剂的应用前景进行了展望,建议应更加重视自由基产生剂作为阻燃协效剂和阻燃剂的研究,设计和开发一些化学结构简单、热稳定更高、阻燃效果更好、使用范围更宽的品种。
Application and research progress of radical generators such as 2,3-dimethyl-2,3-diphenylbutane,N-alkoxy hindered amine,azoalkane as flame retarded synergists or flame retardants in plastics were summarized,and the application prospect of radical generators was raised.It was suggested that more attention should be paid to the study of free radical producing agents for designing and developing some varieties with simple chemical structure,higher heat stability and flame retardancy as well as wider application.
Application and research progress of radical generators such as 2,3-dimethyl-2,3-diphenylbutane,N-alkoxy hindered amine,azoalkane as flame retarded synergists or flame retardants in plastics were summarized,and the application prospect of radical generators was raised.It was suggested that more attention should be paid to the study of free radical producing agents for designing and developing some varieties with simple chemical structure,higher heat stability and flame retardancy as well as wider application.
引文
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[2]IDUMAH C I,HASSAN A A,AUGUSTINE C.A review of recent developments in flammability of polymer nanocomposites[J].Reviews in Chemical Engineering,2015,31(2):149-177.
[3]LIAGKOURIDIS L,COUSINS A P,COUSINS I T.Physical-chemical properties and evaluative fate modelling of‘emerging’and‘novel’brominated and organophosphorus flame retardants in the indoor and outdoor environment[J].Science of the Total Environment,2015,(524-525):416-426.
[4]曹堃,吴水良,李彦,等.N-取代烷氧基受阻胺类阻燃剂及其在聚烯烃中的应用[J].化学进展,2011,23(6):1189-1195.
[5]沈晓东,王建新.二甲基二苯基丁烷的应用[J].中国塑料,2001,15(2):65-67.
[6]高山俊,张林,杨吟,等.一种阻燃PP/ABS复合材料及其制备方法:CN 102911436A[P].2013-02-06.
[7]HOGT A H,SPIJKERMAN G K,TONNAER H.Flame retardant polyolefin composition:WO 2010/023236A1[P].2010-03-04.
[8]HOGT A H,SPIJKERMAN G K,TONNAER H.Flame retardant polyolefin composition:WO 2010/023235A1[P].2010-03-04.
[9]ANTONIO P,DARIO G,ATTILIO A,et al.Compositions of self-extinguishing expandable vinyl aromatic(co)polymers and process for their preparation:US 2013/0225703A1[P].2013-08-29.
[10]LORENZI M,ZAMBOTTI S F.Novel flame-retardant compostion for polystyenic compounds:EP 2 557 115A1[P].2013-02-13.
[11]雷自强,马德龙,张哲,等.一种用于制备聚乙烯材料的无卤阻燃剂:CN 105418975A[P].2016-03-23.
[12]张哲,刘清华,马德龙,等.一种用于制备聚丙烯材料的无卤抑烟阻燃剂:CN105385036A[P].2016-03-09.
[13]姚坤,艾细如.一种耳机导线专用阻燃外壳料及其制备方法:CN 104845458A[P].2015-08-19.
[14]王良民,李建业,王德强,等.低卤阻燃增强共聚聚丙烯的制备[J].广东化工,2015,42(18):43-44.
[15]李艳.一种低卤聚丙烯阻燃材料及其制备方法:CN104004270A[P].2014-08-27.
[16]彭维礼.一种阻燃PP/ABS复合材料及其制备方法:CN101880420A[P].2010-11-10.
[17]周良,陈志强.一种阻燃可膨胀聚苯乙烯聚合物组合物及其制造方法:CN 105175917A[P].2015-12-23.
[18]ZUCCHELLI U,BENIGNO S.Flame retarded extruded polystyrene foams:US 20140303294A1[P].2014-10-09.
[19]KILIARIS P,PAPASPYRIDES C D.Polymer Green Flame Retardants[M].Amsterdam:Elsevier Science Ltd edited,2014:267-288.
[20]NICOLAS R,WILEN C-E,ROTH M,et al.Azoalkanes:A novel class of flame retardants[J].Macromol Rapid Commun,2006,27:976-981.
[21]AUBERT M,NICOLAS R,PAWELEC W,et al.Azoalkanes-novel flame retardants and their structure-property relationship[J].Polym Adv Technol,2011,22:1529-1538.
[22]AUBERT M,TIRRI T,WILEN C-E,et al.Versatile bis(1-alkoxy-2,2,6,6-tetramethyl-piperidin-4-yl)-diazenes(AZONORs)and related structures and their utilization as flame retardants in polypropylene,low density polyethylene and high-impact polystyrene[J].Polym Degr Stab,2012,97:1438-1446.
[23]AUBERT M,WILEN C-E,PFAENDNER R,et al.Bis(1-propyloxy-2,2,6,6-tetramethyl-piperidin-4-yl)-diazene-An innovative multifunctional radical generator providing flame retardancy to polypropylene even after extended artificial weathering[J].Polym Degr Stab,2011,96:328-333.
[24]TIRRI T,AUBERT M,WILEN C-E,et al.Novel tetrapotassium azo diphosphonate(INAZO)as flame retardant for polyurethane adhesives[J].Polym Degr Stab,2012,97:375-82.
[25]TIRRI T,AUBERT M,PAWELEC W,et al.Preparation and characterization of bis-[1,3,5]triazinyl diazenes and their utilization as flame retardants in polypropylene films[J].J Appl Polym Sci,2014,131:404-413.
[26]PAWELEC W,AUBERT M,PFAENDNER R,et al.Triazene compounds as a novel and effective class of flame retardants for polypropylene[J].Polym Degr Stab,2012,97:948-954.