叔碳酸乙烯酯和叔碳酸缩水甘油酯在低VOC、环境友好型涂料中的应用研究
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摘要
可采取类似使用乙酸乙烯、二元醇、丙烯酸羟烷基酯和活性稀释剂的反应方式,用叔碳酸酯制备叔碳聚合物,并将叔碳基团的优异性能引入其中,从而制备高性能的水性、高固体分、光固化和粉末等低VOC排放的环境友好型涂料。
The mode of reaction of vinyl acetate, diol, hydroxy alkyl acrylate and active dilatant can be adopted to prepare versatic polymer and introduce versatic groups' excellent properties, thus producing high-performance low VOC environmentally friendly waterborne, high solids, UV curing and powder coatings.
The mode of reaction of vinyl acetate, diol, hydroxy alkyl acrylate and active dilatant can be adopted to prepare versatic polymer and introduce versatic groups' excellent properties, thus producing high-performance low VOC environmentally friendly waterborne, high solids, UV curing and powder coatings.
引文
[1]于翔,孔红春,孙兰波.叔碳酸酯衍生物在涂料中的应用[J].涂料工业,2002,32(11):38-41,50
[2]GOMES C E M,PELLEGRINO O,FERNANDES MInfluence of Vinyl Acetate-versatic Vinylester Copolymer on the Microstructural Characteristic of Cement Pastes[J].Materials Research,2005,8(1):51-56
[3]BASSETT D R.Hydrophobic Coatings from Emulsion Polymers[J].Journal of Coatings Technology,2001,73(912):43-55
[4]陶氏环球技术公司.疏水单体的乳液聚合:中国200580035276.2[P].2007-09-19
[5]周新华,涂伟萍,夏正斌.叔碳酸乙烯酯改性乙酸乙烯酯乳液的制备[J].粘接,2003,24(6):25-27
[6]朱延安,张心亚,陈焕钦.叔碳酸乙烯酯改性乙酸乙烯酯乳液的研制[J].粘接,2004,25(1):4-7
[7]李学琼,谭海萍.醋酸乙烯酯与叔碳酸乙烯酯共聚乳液(VV乳液)的研制[J].贵州化工,2010,35(5):1-2,12
[8]张小伟,雷自强,罗策,等.叔碳酸乙烯酯改性聚乙酸乙烯酯乳液的制备研究[J].西北师范大学学报:自然科学版,2008,44(4):75-80
[9]孙兰波.叔碳酸乙烯酯和叔碳酸缩水甘油酯在水性工业涂料中的应用[J].现代涂料与涂装,2017,20(5):12-17,52
[10]DECOCQ F,SLINCKX M,NOOTENS C.A New Technology for Environmentally Friendly UV-resistant Water-borne Anticorrosion Paints[J].Journal of Protective Coatings&Linings,2001,18(6):48-56
[11]SIMAL F,HAVAUX N,VANAKEN D.Exterior Wood Coatings[J].Paint&Coating Industry,2010(10)
[12]SHELL.Coating Compositions for Polyalkylene Polymers,WO:0129117A1[P]
[13]洪啸吟,冯汉保.涂料化学[M].北京:科学出版社,2001
[14]张育波,包春磊,王炼石,等.星形超支化聚酯改性丙烯酸酯树脂的制备及其水性涂料性能研究第一部分——星形超支化聚合物的合成及其影响因素[J].电镀与涂饰,2012,31(8):57-61
[15]张育波,包春磊,王炼石,等.星形超支化聚酯改性丙烯酸酯树脂的制备及其水性涂料性能研究第二部分——星形超支化聚酯改性丙烯酸酯水性涂料性能研究[J].电镀与涂饰,2012,31(9):55-58
[16]任娜娜,胡哲辉,刘志平,等.新型聚酯多元醇水分散体的制备[J].涂料工业,2011,41(8):22-26
[2]GOMES C E M,PELLEGRINO O,FERNANDES MInfluence of Vinyl Acetate-versatic Vinylester Copolymer on the Microstructural Characteristic of Cement Pastes[J].Materials Research,2005,8(1):51-56
[3]BASSETT D R.Hydrophobic Coatings from Emulsion Polymers[J].Journal of Coatings Technology,2001,73(912):43-55
[4]陶氏环球技术公司.疏水单体的乳液聚合:中国200580035276.2[P].2007-09-19
[5]周新华,涂伟萍,夏正斌.叔碳酸乙烯酯改性乙酸乙烯酯乳液的制备[J].粘接,2003,24(6):25-27
[6]朱延安,张心亚,陈焕钦.叔碳酸乙烯酯改性乙酸乙烯酯乳液的研制[J].粘接,2004,25(1):4-7
[7]李学琼,谭海萍.醋酸乙烯酯与叔碳酸乙烯酯共聚乳液(VV乳液)的研制[J].贵州化工,2010,35(5):1-2,12
[8]张小伟,雷自强,罗策,等.叔碳酸乙烯酯改性聚乙酸乙烯酯乳液的制备研究[J].西北师范大学学报:自然科学版,2008,44(4):75-80
[9]孙兰波.叔碳酸乙烯酯和叔碳酸缩水甘油酯在水性工业涂料中的应用[J].现代涂料与涂装,2017,20(5):12-17,52
[10]DECOCQ F,SLINCKX M,NOOTENS C.A New Technology for Environmentally Friendly UV-resistant Water-borne Anticorrosion Paints[J].Journal of Protective Coatings&Linings,2001,18(6):48-56
[11]SIMAL F,HAVAUX N,VANAKEN D.Exterior Wood Coatings[J].Paint&Coating Industry,2010(10)
[12]SHELL.Coating Compositions for Polyalkylene Polymers,WO:0129117A1[P]
[13]洪啸吟,冯汉保.涂料化学[M].北京:科学出版社,2001
[14]张育波,包春磊,王炼石,等.星形超支化聚酯改性丙烯酸酯树脂的制备及其水性涂料性能研究第一部分——星形超支化聚合物的合成及其影响因素[J].电镀与涂饰,2012,31(8):57-61
[15]张育波,包春磊,王炼石,等.星形超支化聚酯改性丙烯酸酯树脂的制备及其水性涂料性能研究第二部分——星形超支化聚酯改性丙烯酸酯水性涂料性能研究[J].电镀与涂饰,2012,31(9):55-58
[16]任娜娜,胡哲辉,刘志平,等.新型聚酯多元醇水分散体的制备[J].涂料工业,2011,41(8):22-26