湘中龙山大型金锑矿床成矿时代研究——黄铁矿Re-Os和锆石U-Th/He定年
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摘要
龙山金锑矿床是湘中锑-金矿集区最重要的矿床之一,因缺少适合传统放射性同位素定年的矿物,其成矿时代以往未得到很好的限定,制约了对矿床成因的认识。由于分析测试技术的进步,Re-Os同位素定年技术得到了发展,可对热液矿床中形成的低Re、Os含量的硫化物进行较准确可靠的年龄测定,从而可为低温热液矿床的形成时代提供有效制约。锆石U-Th/He同位素定年,也是近年发展和成熟起来的定年技术,对低温热事件极其敏感,同样是约束低温成矿年龄的重要手段之一。本文采用矿床中黄铁矿Re-Os同位素和蚀变围岩中受成矿热事件影响的锆石U-Th/He同位素定年技术,对龙山金锑矿床的成矿时代进行了研究。定年结果显示:热液成因黄铁矿的Re-Os等时线年龄为195±36Ma,对应于印支晚期;锆石U-Th/He年龄为51.2~133.3Ma,经Ft校正后,U-Th/He年龄分布于93.78~258.29Ma之间,平均值为160.7±7.3Ma,对应于燕山早期。该矿床可能发生了200Ma和160Ma的两次成矿作用;或者矿床形成于200Ma左右,但是受到了160Ma左右岩浆热事件的改造,黄铁矿Re-Os年龄代表成矿年龄,而锆石U-Th/He年龄则代表第二期热事件发生的时间。无论是200Ma左右一次成矿,还是另有160Ma左右的成矿作用叠加,这两个年龄分别与区内两期岩浆活动的时间相当,这表明岩浆事件对驱动矿床的形成发挥了重要的作用。
The Longshan deposit is one of the most important Au-Sb deposits in central Hunan Province. However, the mineralization age of this deposit is still not well constrained due to lacking of suitable minerals for conventional radiometric dating,limiting the recognition of its genesis. Pyrite Re-Os isotopic dating has been proved to be a reliable technique to determine the age of hydrothermal sulfides with low contents of Re and Os,which can be thus used to constrain the age of epithermal mineralization. The zircon U-Th/He isotopic dating is a newly developed technique,which can provide a potential constraint on the ages of low-temperature metallogenic events. Re-Os isotopic dating of the hydrothermal pyrites and U-Th/He isotopic dating of the zircons recording metallogenic event were carried out in this paper,aiming to constrain the mineralization age of the Longshan Au-Sb deposit. Dating results show that the Re-Os isochron age of hydrothermal pyrites is 195 ± 36 Ma,corresponding to Late Indosinian,whereas the U-Th/He ages of zircons from altered wallrock are 51. 2 ~ 133. 3Ma. After correction by Ft,the U-Th/He ages are distributing in the range of93. 78 to 258. 29 Ma with an average of 160. 7 ± 7. 3Ma,corresponding to Early Yanshanian. It can be thus concluded that the Longshan Au-Sb deposit may have experienced two episodes of mineralization( i. e., ~ 200 Ma and ~ 160Ma) or the Sb-Au mineralization may have occurred at ~ 200 Ma which was remobilized by magmatic event at ~ 160 Ma. Pyrite Re-Os age represented the timing of Au-Sb mineralization,whereas the zircon U-Th/He age represented the timing of the second thermal event. Thus,whether the Longshan AuSb deposit formed due to the single mineralization event at ~ 200 Ma,or also experienced an overlapping of the mineralization event at~ 160 Ma,the two ages were roughly consistent with those of two magmatic events in the district,indicating that magmatism may have played a vital role in the formation of the Longshan Sb-Au deposit.
The Longshan deposit is one of the most important Au-Sb deposits in central Hunan Province. However, the mineralization age of this deposit is still not well constrained due to lacking of suitable minerals for conventional radiometric dating,limiting the recognition of its genesis. Pyrite Re-Os isotopic dating has been proved to be a reliable technique to determine the age of hydrothermal sulfides with low contents of Re and Os,which can be thus used to constrain the age of epithermal mineralization. The zircon U-Th/He isotopic dating is a newly developed technique,which can provide a potential constraint on the ages of low-temperature metallogenic events. Re-Os isotopic dating of the hydrothermal pyrites and U-Th/He isotopic dating of the zircons recording metallogenic event were carried out in this paper,aiming to constrain the mineralization age of the Longshan Au-Sb deposit. Dating results show that the Re-Os isochron age of hydrothermal pyrites is 195 ± 36 Ma,corresponding to Late Indosinian,whereas the U-Th/He ages of zircons from altered wallrock are 51. 2 ~ 133. 3Ma. After correction by Ft,the U-Th/He ages are distributing in the range of93. 78 to 258. 29 Ma with an average of 160. 7 ± 7. 3Ma,corresponding to Early Yanshanian. It can be thus concluded that the Longshan Au-Sb deposit may have experienced two episodes of mineralization( i. e., ~ 200 Ma and ~ 160Ma) or the Sb-Au mineralization may have occurred at ~ 200 Ma which was remobilized by magmatic event at ~ 160 Ma. Pyrite Re-Os age represented the timing of Au-Sb mineralization,whereas the zircon U-Th/He age represented the timing of the second thermal event. Thus,whether the Longshan AuSb deposit formed due to the single mineralization event at ~ 200 Ma,or also experienced an overlapping of the mineralization event at~ 160 Ma,the two ages were roughly consistent with those of two magmatic events in the district,indicating that magmatism may have played a vital role in the formation of the Longshan Sb-Au deposit.
引文
Betsi TB,Lentz D,Mc Innes B and Evans NJ.2012.Emplacement ages and exhumation rates for intrusion-hosted Cu-Mo-Sb-Au mineral systems at Freegold Mountain(Yukon,Canada):Assessment from U-Pb,Ar-Ar,and(U-Th)/He geochronometer.Canadian Journal of Earth Sciences,49(5):653-670
Bureau of Geology and Mineral Resources of Hunan Province(BGMRH).1988.Regional Geology of the Hunan Province.Beijing:Geological Publishing House,1-718(in Chinese)
Cabral AR,Eugster O,Brauns M,Lehmann B,Rosel D,Zack T,de Abreu FR,Pernicka E and Barth M.2013.Direct dating of gold by radiogenic helium:Testing the method on gold from Diamantina,Minas Gerais,Brazil.Geology,41(2):163-166
Chen L,Wang ZQ,Zhao YY,Liu Y,Cao J,Ding L and Qu WJ.2013.Re-Os isotopic dating of pyrrhotite in the Linghou Cu deposit,Jiande,Zhejiang Province and its geological significance.Acta Geologica Sinica,87(12):1864-1873(in Chinese with English abstract)
Chen MH,Mao JW,Qu WJ,Wu LL,Uttley PJ,Norman T,Zheng JMand Qin YZ.2007.Re-Os dating of arsenian pyrites from the Lannigou gold deposit,Zhenfeng,Guizhou Province,and its geological significances.Geological Review,53(3):371-382(in Chinese with English abstract)
Chen MH,Mao JW,Li C,Zhang ZQ and Dang Y.2015.Re-Os isochron ages for arsenopyrite from Carlin-like gold deposits in the Yunnan-Guizhou-Guangxi“golden triangle”,southwestern China.Ore Geology Reviews,64:316-327
Chen W,He XX,Zhang Y,Li J,Chen Y and Liu XY.2010.A new dating technique for metallic mineral deposit:(U-Th)/He isotopic dating.Mineral Deposits,29(Suppl.):821-822(in Chinese)
Chen WF,Chen PR,Huang HY,Ding X and Sun T.2007.Chronological and geochemical studies of granite and enclave in Baimashan pluton,Hunan,South China.Science in China(Series D),50(11):1606-1627
Chen XL,Jiang YH,Li SY and Liao HZ.1983.A preliminary study on the origin of the Xikuangshan antimony deposit in Hunan.Geological Review,29(5):486-492(in Chinese with English abstract)
Chen YW,Bi XW,Fu SL and Dong SH.2016.Zircon U-Pb dating and Hf isotope of the felsic dykes in the Longshan Au-Sb deposit in Central Hunan Province and their geological significance.Acta Petrologica Sinica,32(11):3469-3488(in Chinese with English abstract)
Cherniak DJ and Watson EB.2001.Pb diffusion in zircon.Chemical Geology,172(1-2):5-24
Chu Y,Lin W,Faure M,Wang QC and Ji WB.2012.Phanerozoic tectonothermal events of the Xuefengshan Belt,central South China:Implications from U-Pb age and Lu-Hf determinations of granites.Lithos,150:243-255
Dai CH.2000a.Deposit-controlled characteristics of NW-trending structure and prospecting significance about Au ores zone of Gutaishan-Gaojiaao.Hunan Geology,19(2):105-110(in Chinese with English abstract)
Dai CH.2000b.The geological feature of Qingjingzhai gold deposit of Xinhua County and the meaning of conducting ore-prospecting there.Gold,21(4):8-10(in Chinese with English abstract)
Danisik M,Pfaff K,Evans NJ,Manoloukos C,Staude S,Mc Donald BJand Markl G.2010.Tectonothermal history of the Schwarzwald ore district(Germany):An apatite triple dating approach.Chemical Geology,278(1-2):58-69
Ding X,Chen PR,Chen WF,Huang HY and Zhou XM.2006.Single zircon LA-ICPMS U-Pb dating of Weishan granite(Hunan,South China)and its petrogenetic significance.Science in China(Series D),49(8):816-827
Du AD,Qu WJ,Li C and Yang G.2009.A review on the development of Re-Os isotopic dating methods and techniques.Rock and Mineral Analysis,28(3):288-304(in Chinese with English abstract)
Evans NJ,Byrne JP,Keegan JT and Dotter LE.2005.Determination of uranium and thorium in zircon,apatite,and fluorite:Application to laser(U-Th)/He thermochronology.Journal of Analytical Chemistry,60(12):1159-1165
Fan DL,Zhang T and Ye J.2004.The Xikuangshan Sb deposit hosted by the Upper Devonian black shale series,Hunan,China.Ore Geology Reviews,24(1-2):121-133
Farley KA,Wolf RA and Silver LT.1996.The effects of long alphastopping distances on(U-Th)/He ages.Geochimica et Cosmochimica Acta,60(21):4223-4229
Farley KA.2002.(U-Th)/He dating:Techniques,calibrations,and applications.Reviews in Mineralogy and Geochemistry,47(1):819-844
Fu SL,Hu RZ,Bi XW,Chen YW,Yang JH and Huang Y.2015.Origin of Triassic granites in central Hunan Province,South China:Constraints from zircon U-Pb ages and Hf and O isotopes.International Geology Review,57(2):97-111
Gu XX,Zhang YM,Schulz O,Vavtar F,Liu JM,Zheng MH and Zheng L.2012.The Woxi W-Sb-Au deposit in Hunan,South China:An example of Late Proterozoic sedimentary exhalative(SEDEX)mineralization.Journal of Asian Earth Sciences,57:54-75
Guenthner WR,Reiners PW,Ketcham RA,Nasdala L and Giester G.2013.Helium diffusion in natural zircon:Radiation damage,anisotropy,and the interpretation of zircon(U-Th)/He thermochronology.American Journal of Science,313(3):145-198
Guenthner WR,Reiners PW and Tian YT.2014.Interpreting date-e Ucorrelations in zircon(U-Th)/He datasets:A case study from the Longmen Shan,China.Earth and Planetary Science Letters,403:328-339
Harris AC,Dunlap WJ,Reiners PW,Allen CM,Cooke DR,White NC,Campbell IH and Golding SD.2008.Multimillion year thermal history of a porphyry copper deposit:Application of U-Pb,40Ar/39Ar and(U-Th)/He chronometers,Bajo de la Alumbrera coppergold deposit,Argentina.Mineralium Deposita,43(3):295-314
Hourigan JK,Reiners PW and Brandon MT,2005.U-Th zonationdependent alpha-ejection in(U-Th)/He chronometry.Geochimica et Cosmochimica Acta,69(13):3349-3365
Hu RZ and Zhou MF.2012.Multiple Mesozoic mineralization events in South China:An introduction to the thematic issue.Mineralium Deposita,47(6):579-588
Hu RZ,Mao JW,Hua RM and Fan WM.2015.Intra-continental Mineralization of South China Craton.Beijing:Science Press,1-903(in Chinese)
Hu XW,Pei RF and Zhou S.1996.Sm-Nd dating for antimony mineralization in the Xikuangshan deposit,Hunan,China.Resource Geology,46(4):227-231
Huang XW,Gao JF,Qi L and Zhou MF.2015.In-situ LA-ICP-MS trace elemental analyses of magnetite and Re-Os dating of pyrite:The Tianhu hydrothermally remobilized sedimentary Fe deposit,NWChina.Ore Geology Reviews,65:900-916
Lee JKW,Williams IS and Ellis DJ.1997.Pb,U and Th diffusion in natural zircon.Nature,390(6656):159-162
Li C,Qu WJ,Du AD and Sun WJ.2009.Comprehensive study on extraction of rhenium with acetone in Re-Os isotopic dating.Rock and Mineral Analysis,28(3):233-238(in Chinese with English abstract)
Li C,Qu WJ,Wang DH,Chen ZH and Du AD.2010.Advances in the study of the Re-Os isotopic system of organic-rich samples.Acta Petrologica et Mineralogica,29(4):421-430(in Chinese with English abstract)
Li GM,Cao MJ,Qin KZ,Evans NJ,Mc Innes BIA and Liu YS.2014.Thermal-tectonic history of the Baogutu porphyry Cu deposit,West Junggar as constrained from zircon U-Pb,biotite Ar/Ar and zircon/apatite(U-Th)/He dating.Journal of Asian Earth Sciences,79:741-758
Li HQ,Wang DH,Chen FW,Mei YP and Cai H.2008.Study on chronology of the Chanziping and Daping gold deposit in Xuefeng Mountains,Hunan Province.Acta Geologica Sinica,82(7):900-905(in Chinese with English abstract)
Li JH,Wu JC and Zhou YJ.2004.Ore-control rules of dome structure in Baimashan-Co-Longshan gold belt,central Hunan.Gold Geology,10(4):32-36(in Chinese with English abstract)
Li JH,Zhang YQ,Xu XB,Li HL,Dong SW and Li TD.2014.SHRIMPU-Pb dating of zircons from the Baimashan Longtan super-unit and Wawutang granites in Hunan Province and its geological implication.Journal of Jilin University(Earth Science Edition),44(1):158-175(in Chinese with English abstract)
Li JX,Qin KZ,Li GM,Cao MJ,Xiao B,Chen L,Zhao JX,Evans NJand Mc Innes BIA.2012.Petrogenesis and thermal history of the Yulong porphyry copper deposit,eastern Tibet:Insights from U-Pb and U-Th/He dating,and zircon Hf isotope and trace element analysis.Mineralogy and Petrology,105(3-4):201-221
Li SS.1996.Evolution of antimony mineralization by the mantle plume of deep fluid in central Hunan.Hunan Geology,15(3):137-142(in Chinese with English abstract)
Li ZM.1993.A discussion on the mechanism of Xikuangshan antimony deposit.Mineral Resources and Geology,7(2):88-93(in Chinese)
Liang HY.1989.Ore material sources of the Longshan gold-antimony deposit.Mineral Deposits,8(4):39-48(in Chinese with English abstract)
Liang HY.1991.Geochemistry of ore fluids and genesis of Longshan AuSb deposit,west Hunan,China.Geochemica,(4):342-350(in Chinese with English abstract)
Lippolt HJ,Leitz M,Wernicke RS and Hagedorn B.1994.(uranium+thorium)/helium dating of apatite:Experience with samples from different geochemical environments.Chemical Geology,112(1-2):179-191
Liu HP,Zhang YL and Hu WQ.1985.On the origin of the stibnite deposit of Shikuangshan mine,Hunan.Hunan Geology,4(1):28-39(in Chinese with English abstract)
Liu J,Wu G,Li Y,Zhu MT and Zhong W.2012.Re-Os sulfide(chalcopyrite,pyrite and molybdenite)systematics and fluid inclusion study of the Duobaoshan porphyry Cu(Mo)deposit,Heilongjiang Province,China.Journal of Asian Earth Sciences,49:300-312
Liu JQ,Xie Y,Zhao Z,Lin JS,Feng WM and Huang XP.2013.The geochronologic characteristics of Baimashan granite in western Hunan Province and its geotectonic significance.Earth Science Frontiers,20(5):25-35(in Chinese with English abstract)
Liu JS.1996.Relationship between felsic dikes and antimony-gold mineralization in central Hunan Province.Geological Exploration for Non-Ferrous Metals,5(6):321-326(in Chinese with English abstract)
Liu K,Mao JR,Zhao XL,Ye HM and Hu Q.2014.Geological and geochemical characteristics and genetic significance of the Ziyunshan pluton in Hunan Province.Acta Geologica Sinica,88(2):208-227(in Chinese with English abstract)
Liu PC,Tang QG and Li HC.2008.Geological characteristics,enrichment laws and prospecting direction of gold-antimony deposit in Longshan deposits of Hunan.Geology and Prospecting,44(4):31-38(in Chinese with English abstract)
Liu WJ.1992.Genesis of some antimony deposits in southern China.Journal of Chengdu College of Geology,19(2):10-19(in Chinese with English abstract)
Liu X,Fan HR,Evans NJ,Batt GE,Mc Innes BIA,Yang KF and Qin KZ.2014.Cooling and exhumation of the Mid-Jurassic porphyry copper systems in Dexing City,SE China:Insights from geo-and thermochronology.Mineralium Deposita,49(7):809-819
Lu XW.1999.Regional ore-controlling characteristics of gold and antimony deposits in central Hunan.Uranium Geology,15(6):344-349(in Chinese with English abstract)
Luo XL.1995.Geological characteristics of the formation of Banxi antimony deposits in Hunan.Journal of Guilin Institute of Technology,15(3):231-242(in Chinese with English abstract)
Ma DS,Pan JY,Xie QL and He J.2002.Ore source of Sb(Au)deposits in Central Hunan:Ⅰ.Evidences of trace elements and experimental geochemistry.Mineral Deposits,21(3):366-376(in Chinese with English abstract)
Ma DS,Pan JY and Xie QL.2003.Ore sources of Sb(Au)deposits in Central Hunan:Ⅱ.Evidence of isotopic geochemistry.Mineral Deposits,22(1):78-87(in Chinese with English abstract)
Mc Innes BIA,Evans NJ,Fu FQ,Garwin S,Belousova E,Griffin WL,Bertens A,Sukarna D,Permanadewi S,Andrew RL and Deckart K.2005a.Thermal history analysis of selected Chilean,Indonesian,and Iranian porphyry Cu-Mo-Au deposits.In:Porter TM(ed.).Supper Porphyry Copper&Gold Deposits:A Global Perspective.Adelaide:PGC Publishing,1-16
Mc Innes BIA,Evans NJ,Fu FQ and Garwin S.2005b.Application of thermochronology to hydrothermal ore deposits.Reviews in Mineralogy and Geochemistry,58(1):467-498
Meesters AGCA and Dunai TJ.2002.Solving the production-diffusion equation for finite diffusion domains of various shapes Part II.Application to cases withα-ejection and nonhomogeneous distribution of the source.Chemical Geology,186(3-4):57-73
Murao S,Sie SH,Hu X and Suter GF.1999.Contrasting distribution of trace elements between representative antimony deposits in southern China.Nuclear Instruments and Methods in Physics Research Section B,150(1-4):502-509
Nasdala L,Reiners PW,Garver JI,Kennedy AK,Stern RA,Balan Eand Wirth R.2004.Incomplete retention of radiation damage in zircon from Sri Lanka.American Mineralogist,89(1):219-231
Pang BC,Yang DS,Zhou Z,Liu YM,Liu PC and Liu YD.2011.Trace elements in pyrites and their implication for hydrothermal ore-forming process in Longshan gold-antimony deposits,Hunan,China.Geoscience,25(5):832-845(in Chinese with English abstract)
Peng B and Frei R.2004.Nd-Sr-Pb isotopic constraints on metal and fluid sources in W-Sb-Au mineralization at Woxi and Liaojiaping(western Hunan,China).Mineralium Deposita,39(3):313-327
Peng JT and Hu RZ.2001a.Metallogenic epoch and metallogenic tectonic environment of antimony deposits,South China.GeologyGeochemistry,29(3):104-108(in Chinese with English abstract)
Peng JT and Hu RZ.2001b.Carbon and oxygen isotope systematics in the Xikuangshan giant antimony deposit,central Hunan.Geological Review,47(1):34-41(in Chinese with English abstract)
Peng JT,Hu RZ,Zou LQ and Liu JX.2002.Isotope tracing of oreforming materials for the Xikuangshan antimony deposit,central Hunan.Acta Mineralogica Sinica,22(2):155-159(in Chinese with English abstract)
Peng JT,Hu RZ and Burnard PG.2003.Samarium-neodymium isotope systematics of hydrothermal calcites from the Xikuangshan antimony deposit(Hunan,China):The potential of calcite as a geochronometer.Chemical Geology,200(1-2):129-136
Qi XX.1998.Discussion on the mechanism of gold metallogeny in the uplift of Ziyunshan,Shuangfeng County,Hunan.Gold Geology,4(1):50-56(in Chinese with English abstract)
Rao JR,Luo JL and Yi ZJ.1999.The mantle-crustal tectonic metallogenic model and ore-prospecting prognosis in the Xikuangshan antimony ore field.Geophysical and Geochemical Exploration,23(4):241-249(in Chinese with English abstract)
Reiners PW,Spell TL,Nicolescu S and Zanetti KA.2004.Zircon(U-Th)/He thermochronometry:He diffusion and comparisons with40Ar/39Ar dating.Geochimica et Cosmochimica Acta,68(8):1857-1887
Reiners PW.2005.Zircon(U-Th)/He thermochronometry.Reviews in Mineralogy and Geochemistry,58(1):151-179
Selby D and Creaser RA.2005.Direct radiometric dating of hydrocarbon deposits using rhenium-osmium isotopes.Science,308(5726):1293-1295
Shao JB,Zhang XY,Wang HT,Chen DY and Ren Q.2014.Geochemistry and pyrite Re-Os dating of the Tadong iron deposit in Jilin Province.Acta Geologica Sinica,88(1):83-98(in Chinese with English abstract)
Shi MK,Fu BQ,Jin XX and Zhou XC.1993.Antimony Metallogeny in Central Part of Hunan Province.Changsha:Hunan Press of Science and Technology,1-151(in Chinese)
Shuster DL,Flowers RM and Farley KA.2006.The influence of natural radiation damage on helium diffusion kinetics in apatite.Earth and Planetary Science Letters,249(3-4):148-161
Shuster DL and Farley KA.2009.The influence of artificial radiation damage and thermal annealing on helium diffusion kinetics in apatite.Geochimica et Cosmochimica Acta,73(1):183-196
Spiegel C,Kohn B,Belton D,Berner Z and Gleadow A.2009.Apatite(U-Th-Sm)/He thermochronology of rapidly cooled samples:The effect of He implantation.Earth and Planetary Science Letters,285(1-2):105-114
Stein HJ,Morgan JW and Scherstén A.2000.Re-Os dating of low-level highly radiogenic(LLHR)sulfides:The Harns gold deposit,Southwest Sweden,records continental-scale tectonic events.Economic Geology,95(8):1657-1671
Tang YY,Bi XW,Wu LY,Wang L,Zou ZC and He LP.2013.Re-Os isotopic dating of pyrite from Jinding Zn-Pb ore deposit and its geological significance.Acta Mineralogica Sinica,3(3):287-294(in Chinese with English abstract)
Vernon E,Holdsworth RE,Selby D,Dempsey E,Finlay AJ and Fallick AE.2014.Structural characteristics and Re-Os dating of quartzpyrite veins in the Lewisian Gneiss Complex,NW Scotland:Evidence of an Early Paleoproterozoic hydrothermal regime during terrane amalgamation.Precambrian Research,246:256-267
Wang BQ.2005.Enrichment pattern and ore-forming mechanism of Lingshan gold deposit in central Hunan Province.Gold,26(3):14-17(in Chinese with English abstract)
Wang JZ,Li JW,Zhao XF,Ma CQ,QU WJ and Du AD.2008.Re-Os dating of pyrrhotite from the Chaoshan gold skarn,eastern Yangtze Craton,eastern China.International Geology Review,50(4):392-406
Wang YJ,Fan WM,Sun M,Liang XQ,Zhang YH and Peng TP.2007.Geochronological,geochemical and geothermal constraints on petrogenesis of the Indosinian peraluminous granites in the South China Block:A case study in Hunan Province.Lithos,96(3-4):475-502
Wang YL,Chen YC,Wang DH,Xu J and Chen ZH.2012.Scheelite Sm-Nd dating of the Zhazixi W-Sb deposit in Hunan and its geological significance.Geology in China,39(5):1339-1344(in Chinese with English abstract)
Wen GZ,Wu Q,Liu HY,Xie GZ and Lei XL.1993.Preliminary study on ore controlling regularities and metallogenic mechanism of super large-sized Sb-deposits in Xikuangshan.Geology and Exploration,(7):20-27(in Chinese with English abstract)
Wolff R,Dunkl I,Kempe U and von Eynatten H.2015.The age of the latest thermal overprint of tin and polymetallic deposits in the Erzgebirge,Germany:Constraints from fluorite(U-Th-Sm)/He thermochronology.Economic Geology,110(8):2025-2040
Wu JC,Wang JR,Ou J,Wang SS,Yang SF and Li JH.2007.Inclusion-isotope geochemistry of the Baimashan-Longshan gold metallogenic belt in Hunan and its ore-forming fluids’characteristics.Mineral Resources and Geology,21(6):673-678(in Chinese with English abstract)
Xiao QM,Zeng DR,Jin FQ,Yang MY and Yang ZF.1992.Time-space distribution feature and exploration guide of China’s Sb-deposits.Geology and Prospecting,(12):9-14(in Chinese with English abstract)
Yakubchuk A,Stein H and Wilde A.2014.Results of pilot Re-Os dating of sulfides from the Sukhoi Log and Olympiada orogenic gold deposits,Russia.Ore Geology Reviews,59:21-28
Yang DS,Shimizu M,Shimazaki H,Li XH and Xie QL.2006.Sulfur isotope geochemistry of the supergiant Xikuangshan Sb deposit,central Hunan,China:Constraints on sources of ore constituents.Resource Geology,56(4):385-396
Yang SH,Qu WJ,Yang G,Du AD and Chen JF.2007.The correction of mass fractionation in the measurement of rhenium and osmium isotope ratios by ICP-MS.Rock and Mineral Analysis,26(1):4-8(in Chinese with English abstract)
Yang SQ.1986.On inquiry about the genesis of Hunan stibnite ore and the direction of ore search.Hunan Geology,5(4):12-25(in Chinese with English abstract)
Yao ZK and Zhu RB.1993.Polygenetic compound model for the Fuzhuxi gold deposit of Hunan Province and its prospecting.Geotectonica et Metallogenia,17(3):199-209(in Chinese with English abstract)
Ying LJ,Wang CS,Tang JX,Wang DH,Qu WJ and Li C.2014.Re-Os systematics of sulfides(chalcopyrite,bornite,pyrite and pyrrhotite)from the Jiama Cu-Mo deposit of Tibet,China.Journal of Asian Earth Sciences,79:497-506
Yu JG.1998.Alteration features and its direction of looking for the deposit in Gutaishan Au-Sb deposit,Xinhua.Hunan Geology,17(3):155-159(in Chinese with English abstract)
Zeng QT,Evans NJ,Mc Innes BIA,Batt GE,Mc Cuaig CT and Bagas L.2013.Geological and thermochronological studies of the Dashui gold deposit,West Qinling Orogen,Central China.Mineralium Deposita,48(3):397-412
Zheng SG.2006.Geological characteristics of Longshan gold antimony deposit and resource forecast.Geology and Mineral Resources of South China,(4):14-21,80(in Chinese with English abstract)
陈雷,王宗起,赵元艺,刘妍,曹洁,定立,屈文俊.2013.浙江建德岭后铜矿磁黄铁矿Re-Os年代学特征及成矿意义.地质学报,87(12):1864-1873
陈懋弘,毛景文,屈文俊,吴六灵,Uttley PJ,Norman T,郑建民,秦运忠.2007.贵州贞丰烂泥沟卡林型金矿床含砷黄铁矿Re-Os同位素测年及地质意义.地质论评,53(3):371-382
谌锡霖,蒋云杭,李世永,廖洪震.1983.湖南锡矿山锑矿成因探讨.地质论评,29(5):486-492
陈文,何学贤,张彦,李洁,陈越,刘新宇.2010.金属矿床年龄测定新技术---(U-Th)/He同位素定年方法.矿床地质,29(增刊):821-822
陈佑纬,毕献武,付山岭,董少花.2016.湘中地区龙山金锑矿床酸性岩脉U-Pb年代学和Hf同位素特征及其地质意义.岩石学报,32(11):3469-3488
戴长华.2000a.古台山-高家坳金矿床带北西向构造控矿特征及其找矿意义.湖南地质.19(2):105-110
戴长华.2000b.新化青京寨金矿地质特征及找矿意义.黄金,21(4):8-10
杜安道,屈文俊,李超,杨刚.2009.铼-锇同位素定年方法及分析测试技术的进展.岩矿测试,28(3):288-304
湖南省地质矿产局.1988.湖南省区域地质志.北京:地质出版社,1-718
胡瑞忠,毛景文,华仁民,范蔚茗.2015.华南陆块陆内成矿作用.北京:科学出版社,1-903
李超,屈文俊,杜安道,孙文静.2009.铼-锇同位素定年法中丙酮萃取铼的系统研究.岩矿测试,28(3):233-238
李超,屈文俊,王登红,陈郑辉,杜安道.2010.富有机质地质样品Re-Os同位素体系研究进展.岩石矿物学杂志,29(4):421-430
李华芹,王登红,陈富文,梅玉萍,蔡红.2008.湖南雪峰山地区铲子坪和大坪金矿成矿作用年代学研究.地质学报,82(7):900-905
李己华,吴继承,周遗军.2004.湘中白马山-龙山金矿带穹隆控矿规律分析.黄金地质,10(4):32-36
李建华,张岳桥,徐先兵,李海龙,董树文,李廷栋.2014.湖南白马山龙潭超单元、瓦屋塘花岗岩锆石SHRIMP U-Pb年龄及其地质意义.吉林大学学报(地球化学版),44(1):158-175
黎盛斯.1996.湘中锑矿深源流体的地幔柱成矿演化.湖南地质,15(3):137-142
李智明.1993.锡矿山锑矿成矿机理的探讨.矿产与地质,7(2):88-93
梁华英.1989.龙山金锑矿床成矿物质来源研究.矿床地质,8(4):39-48
梁华英.1991.龙山金锑矿床成矿流体地球化学和矿床成因研究.地球化学,(4):342-350
刘焕品,张永龄,胡文清.1985.湖南省锡矿山锑矿床的成因探讨.湖南地质,4(1):28-39
刘建清,谢渊,赵瞻,林家善,冯伟明,黄学平.2013.湖南雪峰山地区白马山花岗岩年代学特征及构造意义.地学前缘,20(5):25-35
刘继顺.1996.湘中地区长英质脉岩与锑(金)成矿关系.有色金属矿产与勘查,5(6):321-326
刘凯,毛建仁,赵希林,叶海敏,胡青.2014.湖南紫云山岩体的地质地球化学特征及其成因意义.地质学报,88(2):208-227
刘鹏程,唐清国,李惠纯.2008.湖南龙山矿区金锑矿地质特征、富集规律与找矿方向.地质与勘探,44(4):31-38
刘文均.1992.华南几个锑矿床的成因探讨.成都地质学院学报,19(2):10-19
卢新卫.1999.湘中金、锑矿床区域控矿特征研究.铀矿地质,15(6):344-349
罗献林.1995.湖南板溪锑矿床的成矿地质特征.桂林工学院学报,15(3):231-242
马东升,潘家永,解庆林,何江.2002.湘中锑(金)矿床成矿物质来源-I.微量元素及其实验地球化学证据.矿床地质,21(3):366-376
马东升,潘家永,解庆林.2003.湘中锑(金)矿床成矿物质来源-II.同位素地球化学证据.矿床地质,22(1):78-87
庞保成,杨东生,周志,刘义茂,刘鹏程,刘远栋.2011.湖南龙山金锑矿黄铁矿微量元素特征及其对成矿过程的指示.现代地质,25(5):832-845
彭建堂,胡瑞忠.2001a.华南锑矿带的成矿时代和成矿构造环境.地质地球化学,29(3):104-108
彭建堂,胡瑞忠.2001b.湘中锡矿山超大型锑矿床的碳、氧同位素体系.地质论评,47(1):34-41
彭建堂,胡瑞忠,邹利群,刘建雄.2002.湘中锡矿山锑矿床成矿物质来源的同位素示踪.矿物学报,22(2):155-159
戚学祥.1998.湖南双峰紫云山隆起区金矿成矿机制探讨.黄金地质,4(1):50-56
饶家荣,骆检兰,易志军.1999.锡矿山锑矿田幔-壳构造成矿模型及找矿预测.物探与化探,23(4):241-249
邵建波,张希友,王洪涛,陈殿义,任强.2014.吉林省塔东大型铁矿地球化学特征及黄铁矿Re-Os同位素定年.地质学报,88(1):83-98
史明魁,傅必勤,靳西祥,周雪昌.1993.湘中锑矿.长沙:湖南科学技术出版社,1-151
唐永永,毕献武,武丽艳,王雷,邹志超,何利平.2013.金顶铅锌矿黄铁矿Re-Os定年及其地质意义.矿物学报,3(3):287-294
王滨清.2005.湘中铃山金矿床富集规律与成矿机理研究.黄金,26(3):14-17
王永磊,陈毓川,王登红,徐珏,陈郑辉.2012.湖南渣滓溪W-Sb矿床白钨矿Sm-Nd测年及其地质意义.中国地质,39(5):1339-1344
文国璋,吴强,刘汉元,谢国柱,雷秀柳.1993.锡矿山超大型锑矿床控矿规律及形成机理初步研究.地质与勘探,(7):20-27
吴继承,王金荣,欧健,汪双双,杨淑芬,李己华.2007.湖南白马山-龙山金矿带包裹体-同位素地球化学及成矿流体特征.矿产与地质,21(6):673-678
肖启明,曾笃仁,金富秋,杨明跃,阳志芳.1992.中国锑矿床时空分布规律及找矿方向.地质与勘探,(12):9-14
杨胜洪,屈文俊,杨刚,杜安道,陈江峰.2007.电感耦合等离子体质谱法测量铼和锇同位素比值的质量分馏校正.岩矿测试,26(1):4-8
杨舜全.1986.湖南省锑矿成因及找矿方向的探讨.湖南地质,5(4):12-25
姚振凯,朱蓉斌.1993.湖南符竹溪金矿床多因复成模式及其找矿意义.大地构造与成矿学,17(3):199-209
余建国.1998.新化古台山金锑矿床蚀变特征及其找矿方向.湖南地质,17(3):155-159
郑时干.2006.龙山金锑矿地质特征及深部找矿预测.华南地质与矿产,(4):14-21,80
Bureau of Geology and Mineral Resources of Hunan Province(BGMRH).1988.Regional Geology of the Hunan Province.Beijing:Geological Publishing House,1-718(in Chinese)
Cabral AR,Eugster O,Brauns M,Lehmann B,Rosel D,Zack T,de Abreu FR,Pernicka E and Barth M.2013.Direct dating of gold by radiogenic helium:Testing the method on gold from Diamantina,Minas Gerais,Brazil.Geology,41(2):163-166
Chen L,Wang ZQ,Zhao YY,Liu Y,Cao J,Ding L and Qu WJ.2013.Re-Os isotopic dating of pyrrhotite in the Linghou Cu deposit,Jiande,Zhejiang Province and its geological significance.Acta Geologica Sinica,87(12):1864-1873(in Chinese with English abstract)
Chen MH,Mao JW,Qu WJ,Wu LL,Uttley PJ,Norman T,Zheng JMand Qin YZ.2007.Re-Os dating of arsenian pyrites from the Lannigou gold deposit,Zhenfeng,Guizhou Province,and its geological significances.Geological Review,53(3):371-382(in Chinese with English abstract)
Chen MH,Mao JW,Li C,Zhang ZQ and Dang Y.2015.Re-Os isochron ages for arsenopyrite from Carlin-like gold deposits in the Yunnan-Guizhou-Guangxi“golden triangle”,southwestern China.Ore Geology Reviews,64:316-327
Chen W,He XX,Zhang Y,Li J,Chen Y and Liu XY.2010.A new dating technique for metallic mineral deposit:(U-Th)/He isotopic dating.Mineral Deposits,29(Suppl.):821-822(in Chinese)
Chen WF,Chen PR,Huang HY,Ding X and Sun T.2007.Chronological and geochemical studies of granite and enclave in Baimashan pluton,Hunan,South China.Science in China(Series D),50(11):1606-1627
Chen XL,Jiang YH,Li SY and Liao HZ.1983.A preliminary study on the origin of the Xikuangshan antimony deposit in Hunan.Geological Review,29(5):486-492(in Chinese with English abstract)
Chen YW,Bi XW,Fu SL and Dong SH.2016.Zircon U-Pb dating and Hf isotope of the felsic dykes in the Longshan Au-Sb deposit in Central Hunan Province and their geological significance.Acta Petrologica Sinica,32(11):3469-3488(in Chinese with English abstract)
Cherniak DJ and Watson EB.2001.Pb diffusion in zircon.Chemical Geology,172(1-2):5-24
Chu Y,Lin W,Faure M,Wang QC and Ji WB.2012.Phanerozoic tectonothermal events of the Xuefengshan Belt,central South China:Implications from U-Pb age and Lu-Hf determinations of granites.Lithos,150:243-255
Dai CH.2000a.Deposit-controlled characteristics of NW-trending structure and prospecting significance about Au ores zone of Gutaishan-Gaojiaao.Hunan Geology,19(2):105-110(in Chinese with English abstract)
Dai CH.2000b.The geological feature of Qingjingzhai gold deposit of Xinhua County and the meaning of conducting ore-prospecting there.Gold,21(4):8-10(in Chinese with English abstract)
Danisik M,Pfaff K,Evans NJ,Manoloukos C,Staude S,Mc Donald BJand Markl G.2010.Tectonothermal history of the Schwarzwald ore district(Germany):An apatite triple dating approach.Chemical Geology,278(1-2):58-69
Ding X,Chen PR,Chen WF,Huang HY and Zhou XM.2006.Single zircon LA-ICPMS U-Pb dating of Weishan granite(Hunan,South China)and its petrogenetic significance.Science in China(Series D),49(8):816-827
Du AD,Qu WJ,Li C and Yang G.2009.A review on the development of Re-Os isotopic dating methods and techniques.Rock and Mineral Analysis,28(3):288-304(in Chinese with English abstract)
Evans NJ,Byrne JP,Keegan JT and Dotter LE.2005.Determination of uranium and thorium in zircon,apatite,and fluorite:Application to laser(U-Th)/He thermochronology.Journal of Analytical Chemistry,60(12):1159-1165
Fan DL,Zhang T and Ye J.2004.The Xikuangshan Sb deposit hosted by the Upper Devonian black shale series,Hunan,China.Ore Geology Reviews,24(1-2):121-133
Farley KA,Wolf RA and Silver LT.1996.The effects of long alphastopping distances on(U-Th)/He ages.Geochimica et Cosmochimica Acta,60(21):4223-4229
Farley KA.2002.(U-Th)/He dating:Techniques,calibrations,and applications.Reviews in Mineralogy and Geochemistry,47(1):819-844
Fu SL,Hu RZ,Bi XW,Chen YW,Yang JH and Huang Y.2015.Origin of Triassic granites in central Hunan Province,South China:Constraints from zircon U-Pb ages and Hf and O isotopes.International Geology Review,57(2):97-111
Gu XX,Zhang YM,Schulz O,Vavtar F,Liu JM,Zheng MH and Zheng L.2012.The Woxi W-Sb-Au deposit in Hunan,South China:An example of Late Proterozoic sedimentary exhalative(SEDEX)mineralization.Journal of Asian Earth Sciences,57:54-75
Guenthner WR,Reiners PW,Ketcham RA,Nasdala L and Giester G.2013.Helium diffusion in natural zircon:Radiation damage,anisotropy,and the interpretation of zircon(U-Th)/He thermochronology.American Journal of Science,313(3):145-198
Guenthner WR,Reiners PW and Tian YT.2014.Interpreting date-e Ucorrelations in zircon(U-Th)/He datasets:A case study from the Longmen Shan,China.Earth and Planetary Science Letters,403:328-339
Harris AC,Dunlap WJ,Reiners PW,Allen CM,Cooke DR,White NC,Campbell IH and Golding SD.2008.Multimillion year thermal history of a porphyry copper deposit:Application of U-Pb,40Ar/39Ar and(U-Th)/He chronometers,Bajo de la Alumbrera coppergold deposit,Argentina.Mineralium Deposita,43(3):295-314
Hourigan JK,Reiners PW and Brandon MT,2005.U-Th zonationdependent alpha-ejection in(U-Th)/He chronometry.Geochimica et Cosmochimica Acta,69(13):3349-3365
Hu RZ and Zhou MF.2012.Multiple Mesozoic mineralization events in South China:An introduction to the thematic issue.Mineralium Deposita,47(6):579-588
Hu RZ,Mao JW,Hua RM and Fan WM.2015.Intra-continental Mineralization of South China Craton.Beijing:Science Press,1-903(in Chinese)
Hu XW,Pei RF and Zhou S.1996.Sm-Nd dating for antimony mineralization in the Xikuangshan deposit,Hunan,China.Resource Geology,46(4):227-231
Huang XW,Gao JF,Qi L and Zhou MF.2015.In-situ LA-ICP-MS trace elemental analyses of magnetite and Re-Os dating of pyrite:The Tianhu hydrothermally remobilized sedimentary Fe deposit,NWChina.Ore Geology Reviews,65:900-916
Lee JKW,Williams IS and Ellis DJ.1997.Pb,U and Th diffusion in natural zircon.Nature,390(6656):159-162
Li C,Qu WJ,Du AD and Sun WJ.2009.Comprehensive study on extraction of rhenium with acetone in Re-Os isotopic dating.Rock and Mineral Analysis,28(3):233-238(in Chinese with English abstract)
Li C,Qu WJ,Wang DH,Chen ZH and Du AD.2010.Advances in the study of the Re-Os isotopic system of organic-rich samples.Acta Petrologica et Mineralogica,29(4):421-430(in Chinese with English abstract)
Li GM,Cao MJ,Qin KZ,Evans NJ,Mc Innes BIA and Liu YS.2014.Thermal-tectonic history of the Baogutu porphyry Cu deposit,West Junggar as constrained from zircon U-Pb,biotite Ar/Ar and zircon/apatite(U-Th)/He dating.Journal of Asian Earth Sciences,79:741-758
Li HQ,Wang DH,Chen FW,Mei YP and Cai H.2008.Study on chronology of the Chanziping and Daping gold deposit in Xuefeng Mountains,Hunan Province.Acta Geologica Sinica,82(7):900-905(in Chinese with English abstract)
Li JH,Wu JC and Zhou YJ.2004.Ore-control rules of dome structure in Baimashan-Co-Longshan gold belt,central Hunan.Gold Geology,10(4):32-36(in Chinese with English abstract)
Li JH,Zhang YQ,Xu XB,Li HL,Dong SW and Li TD.2014.SHRIMPU-Pb dating of zircons from the Baimashan Longtan super-unit and Wawutang granites in Hunan Province and its geological implication.Journal of Jilin University(Earth Science Edition),44(1):158-175(in Chinese with English abstract)
Li JX,Qin KZ,Li GM,Cao MJ,Xiao B,Chen L,Zhao JX,Evans NJand Mc Innes BIA.2012.Petrogenesis and thermal history of the Yulong porphyry copper deposit,eastern Tibet:Insights from U-Pb and U-Th/He dating,and zircon Hf isotope and trace element analysis.Mineralogy and Petrology,105(3-4):201-221
Li SS.1996.Evolution of antimony mineralization by the mantle plume of deep fluid in central Hunan.Hunan Geology,15(3):137-142(in Chinese with English abstract)
Li ZM.1993.A discussion on the mechanism of Xikuangshan antimony deposit.Mineral Resources and Geology,7(2):88-93(in Chinese)
Liang HY.1989.Ore material sources of the Longshan gold-antimony deposit.Mineral Deposits,8(4):39-48(in Chinese with English abstract)
Liang HY.1991.Geochemistry of ore fluids and genesis of Longshan AuSb deposit,west Hunan,China.Geochemica,(4):342-350(in Chinese with English abstract)
Lippolt HJ,Leitz M,Wernicke RS and Hagedorn B.1994.(uranium+thorium)/helium dating of apatite:Experience with samples from different geochemical environments.Chemical Geology,112(1-2):179-191
Liu HP,Zhang YL and Hu WQ.1985.On the origin of the stibnite deposit of Shikuangshan mine,Hunan.Hunan Geology,4(1):28-39(in Chinese with English abstract)
Liu J,Wu G,Li Y,Zhu MT and Zhong W.2012.Re-Os sulfide(chalcopyrite,pyrite and molybdenite)systematics and fluid inclusion study of the Duobaoshan porphyry Cu(Mo)deposit,Heilongjiang Province,China.Journal of Asian Earth Sciences,49:300-312
Liu JQ,Xie Y,Zhao Z,Lin JS,Feng WM and Huang XP.2013.The geochronologic characteristics of Baimashan granite in western Hunan Province and its geotectonic significance.Earth Science Frontiers,20(5):25-35(in Chinese with English abstract)
Liu JS.1996.Relationship between felsic dikes and antimony-gold mineralization in central Hunan Province.Geological Exploration for Non-Ferrous Metals,5(6):321-326(in Chinese with English abstract)
Liu K,Mao JR,Zhao XL,Ye HM and Hu Q.2014.Geological and geochemical characteristics and genetic significance of the Ziyunshan pluton in Hunan Province.Acta Geologica Sinica,88(2):208-227(in Chinese with English abstract)
Liu PC,Tang QG and Li HC.2008.Geological characteristics,enrichment laws and prospecting direction of gold-antimony deposit in Longshan deposits of Hunan.Geology and Prospecting,44(4):31-38(in Chinese with English abstract)
Liu WJ.1992.Genesis of some antimony deposits in southern China.Journal of Chengdu College of Geology,19(2):10-19(in Chinese with English abstract)
Liu X,Fan HR,Evans NJ,Batt GE,Mc Innes BIA,Yang KF and Qin KZ.2014.Cooling and exhumation of the Mid-Jurassic porphyry copper systems in Dexing City,SE China:Insights from geo-and thermochronology.Mineralium Deposita,49(7):809-819
Lu XW.1999.Regional ore-controlling characteristics of gold and antimony deposits in central Hunan.Uranium Geology,15(6):344-349(in Chinese with English abstract)
Luo XL.1995.Geological characteristics of the formation of Banxi antimony deposits in Hunan.Journal of Guilin Institute of Technology,15(3):231-242(in Chinese with English abstract)
Ma DS,Pan JY,Xie QL and He J.2002.Ore source of Sb(Au)deposits in Central Hunan:Ⅰ.Evidences of trace elements and experimental geochemistry.Mineral Deposits,21(3):366-376(in Chinese with English abstract)
Ma DS,Pan JY and Xie QL.2003.Ore sources of Sb(Au)deposits in Central Hunan:Ⅱ.Evidence of isotopic geochemistry.Mineral Deposits,22(1):78-87(in Chinese with English abstract)
Mc Innes BIA,Evans NJ,Fu FQ,Garwin S,Belousova E,Griffin WL,Bertens A,Sukarna D,Permanadewi S,Andrew RL and Deckart K.2005a.Thermal history analysis of selected Chilean,Indonesian,and Iranian porphyry Cu-Mo-Au deposits.In:Porter TM(ed.).Supper Porphyry Copper&Gold Deposits:A Global Perspective.Adelaide:PGC Publishing,1-16
Mc Innes BIA,Evans NJ,Fu FQ and Garwin S.2005b.Application of thermochronology to hydrothermal ore deposits.Reviews in Mineralogy and Geochemistry,58(1):467-498
Meesters AGCA and Dunai TJ.2002.Solving the production-diffusion equation for finite diffusion domains of various shapes Part II.Application to cases withα-ejection and nonhomogeneous distribution of the source.Chemical Geology,186(3-4):57-73
Murao S,Sie SH,Hu X and Suter GF.1999.Contrasting distribution of trace elements between representative antimony deposits in southern China.Nuclear Instruments and Methods in Physics Research Section B,150(1-4):502-509
Nasdala L,Reiners PW,Garver JI,Kennedy AK,Stern RA,Balan Eand Wirth R.2004.Incomplete retention of radiation damage in zircon from Sri Lanka.American Mineralogist,89(1):219-231
Pang BC,Yang DS,Zhou Z,Liu YM,Liu PC and Liu YD.2011.Trace elements in pyrites and their implication for hydrothermal ore-forming process in Longshan gold-antimony deposits,Hunan,China.Geoscience,25(5):832-845(in Chinese with English abstract)
Peng B and Frei R.2004.Nd-Sr-Pb isotopic constraints on metal and fluid sources in W-Sb-Au mineralization at Woxi and Liaojiaping(western Hunan,China).Mineralium Deposita,39(3):313-327
Peng JT and Hu RZ.2001a.Metallogenic epoch and metallogenic tectonic environment of antimony deposits,South China.GeologyGeochemistry,29(3):104-108(in Chinese with English abstract)
Peng JT and Hu RZ.2001b.Carbon and oxygen isotope systematics in the Xikuangshan giant antimony deposit,central Hunan.Geological Review,47(1):34-41(in Chinese with English abstract)
Peng JT,Hu RZ,Zou LQ and Liu JX.2002.Isotope tracing of oreforming materials for the Xikuangshan antimony deposit,central Hunan.Acta Mineralogica Sinica,22(2):155-159(in Chinese with English abstract)
Peng JT,Hu RZ and Burnard PG.2003.Samarium-neodymium isotope systematics of hydrothermal calcites from the Xikuangshan antimony deposit(Hunan,China):The potential of calcite as a geochronometer.Chemical Geology,200(1-2):129-136
Qi XX.1998.Discussion on the mechanism of gold metallogeny in the uplift of Ziyunshan,Shuangfeng County,Hunan.Gold Geology,4(1):50-56(in Chinese with English abstract)
Rao JR,Luo JL and Yi ZJ.1999.The mantle-crustal tectonic metallogenic model and ore-prospecting prognosis in the Xikuangshan antimony ore field.Geophysical and Geochemical Exploration,23(4):241-249(in Chinese with English abstract)
Reiners PW,Spell TL,Nicolescu S and Zanetti KA.2004.Zircon(U-Th)/He thermochronometry:He diffusion and comparisons with40Ar/39Ar dating.Geochimica et Cosmochimica Acta,68(8):1857-1887
Reiners PW.2005.Zircon(U-Th)/He thermochronometry.Reviews in Mineralogy and Geochemistry,58(1):151-179
Selby D and Creaser RA.2005.Direct radiometric dating of hydrocarbon deposits using rhenium-osmium isotopes.Science,308(5726):1293-1295
Shao JB,Zhang XY,Wang HT,Chen DY and Ren Q.2014.Geochemistry and pyrite Re-Os dating of the Tadong iron deposit in Jilin Province.Acta Geologica Sinica,88(1):83-98(in Chinese with English abstract)
Shi MK,Fu BQ,Jin XX and Zhou XC.1993.Antimony Metallogeny in Central Part of Hunan Province.Changsha:Hunan Press of Science and Technology,1-151(in Chinese)
Shuster DL,Flowers RM and Farley KA.2006.The influence of natural radiation damage on helium diffusion kinetics in apatite.Earth and Planetary Science Letters,249(3-4):148-161
Shuster DL and Farley KA.2009.The influence of artificial radiation damage and thermal annealing on helium diffusion kinetics in apatite.Geochimica et Cosmochimica Acta,73(1):183-196
Spiegel C,Kohn B,Belton D,Berner Z and Gleadow A.2009.Apatite(U-Th-Sm)/He thermochronology of rapidly cooled samples:The effect of He implantation.Earth and Planetary Science Letters,285(1-2):105-114
Stein HJ,Morgan JW and Scherstén A.2000.Re-Os dating of low-level highly radiogenic(LLHR)sulfides:The Harns gold deposit,Southwest Sweden,records continental-scale tectonic events.Economic Geology,95(8):1657-1671
Tang YY,Bi XW,Wu LY,Wang L,Zou ZC and He LP.2013.Re-Os isotopic dating of pyrite from Jinding Zn-Pb ore deposit and its geological significance.Acta Mineralogica Sinica,3(3):287-294(in Chinese with English abstract)
Vernon E,Holdsworth RE,Selby D,Dempsey E,Finlay AJ and Fallick AE.2014.Structural characteristics and Re-Os dating of quartzpyrite veins in the Lewisian Gneiss Complex,NW Scotland:Evidence of an Early Paleoproterozoic hydrothermal regime during terrane amalgamation.Precambrian Research,246:256-267
Wang BQ.2005.Enrichment pattern and ore-forming mechanism of Lingshan gold deposit in central Hunan Province.Gold,26(3):14-17(in Chinese with English abstract)
Wang JZ,Li JW,Zhao XF,Ma CQ,QU WJ and Du AD.2008.Re-Os dating of pyrrhotite from the Chaoshan gold skarn,eastern Yangtze Craton,eastern China.International Geology Review,50(4):392-406
Wang YJ,Fan WM,Sun M,Liang XQ,Zhang YH and Peng TP.2007.Geochronological,geochemical and geothermal constraints on petrogenesis of the Indosinian peraluminous granites in the South China Block:A case study in Hunan Province.Lithos,96(3-4):475-502
Wang YL,Chen YC,Wang DH,Xu J and Chen ZH.2012.Scheelite Sm-Nd dating of the Zhazixi W-Sb deposit in Hunan and its geological significance.Geology in China,39(5):1339-1344(in Chinese with English abstract)
Wen GZ,Wu Q,Liu HY,Xie GZ and Lei XL.1993.Preliminary study on ore controlling regularities and metallogenic mechanism of super large-sized Sb-deposits in Xikuangshan.Geology and Exploration,(7):20-27(in Chinese with English abstract)
Wolff R,Dunkl I,Kempe U and von Eynatten H.2015.The age of the latest thermal overprint of tin and polymetallic deposits in the Erzgebirge,Germany:Constraints from fluorite(U-Th-Sm)/He thermochronology.Economic Geology,110(8):2025-2040
Wu JC,Wang JR,Ou J,Wang SS,Yang SF and Li JH.2007.Inclusion-isotope geochemistry of the Baimashan-Longshan gold metallogenic belt in Hunan and its ore-forming fluids’characteristics.Mineral Resources and Geology,21(6):673-678(in Chinese with English abstract)
Xiao QM,Zeng DR,Jin FQ,Yang MY and Yang ZF.1992.Time-space distribution feature and exploration guide of China’s Sb-deposits.Geology and Prospecting,(12):9-14(in Chinese with English abstract)
Yakubchuk A,Stein H and Wilde A.2014.Results of pilot Re-Os dating of sulfides from the Sukhoi Log and Olympiada orogenic gold deposits,Russia.Ore Geology Reviews,59:21-28
Yang DS,Shimizu M,Shimazaki H,Li XH and Xie QL.2006.Sulfur isotope geochemistry of the supergiant Xikuangshan Sb deposit,central Hunan,China:Constraints on sources of ore constituents.Resource Geology,56(4):385-396
Yang SH,Qu WJ,Yang G,Du AD and Chen JF.2007.The correction of mass fractionation in the measurement of rhenium and osmium isotope ratios by ICP-MS.Rock and Mineral Analysis,26(1):4-8(in Chinese with English abstract)
Yang SQ.1986.On inquiry about the genesis of Hunan stibnite ore and the direction of ore search.Hunan Geology,5(4):12-25(in Chinese with English abstract)
Yao ZK and Zhu RB.1993.Polygenetic compound model for the Fuzhuxi gold deposit of Hunan Province and its prospecting.Geotectonica et Metallogenia,17(3):199-209(in Chinese with English abstract)
Ying LJ,Wang CS,Tang JX,Wang DH,Qu WJ and Li C.2014.Re-Os systematics of sulfides(chalcopyrite,bornite,pyrite and pyrrhotite)from the Jiama Cu-Mo deposit of Tibet,China.Journal of Asian Earth Sciences,79:497-506
Yu JG.1998.Alteration features and its direction of looking for the deposit in Gutaishan Au-Sb deposit,Xinhua.Hunan Geology,17(3):155-159(in Chinese with English abstract)
Zeng QT,Evans NJ,Mc Innes BIA,Batt GE,Mc Cuaig CT and Bagas L.2013.Geological and thermochronological studies of the Dashui gold deposit,West Qinling Orogen,Central China.Mineralium Deposita,48(3):397-412
Zheng SG.2006.Geological characteristics of Longshan gold antimony deposit and resource forecast.Geology and Mineral Resources of South China,(4):14-21,80(in Chinese with English abstract)
陈雷,王宗起,赵元艺,刘妍,曹洁,定立,屈文俊.2013.浙江建德岭后铜矿磁黄铁矿Re-Os年代学特征及成矿意义.地质学报,87(12):1864-1873
陈懋弘,毛景文,屈文俊,吴六灵,Uttley PJ,Norman T,郑建民,秦运忠.2007.贵州贞丰烂泥沟卡林型金矿床含砷黄铁矿Re-Os同位素测年及地质意义.地质论评,53(3):371-382
谌锡霖,蒋云杭,李世永,廖洪震.1983.湖南锡矿山锑矿成因探讨.地质论评,29(5):486-492
陈文,何学贤,张彦,李洁,陈越,刘新宇.2010.金属矿床年龄测定新技术---(U-Th)/He同位素定年方法.矿床地质,29(增刊):821-822
陈佑纬,毕献武,付山岭,董少花.2016.湘中地区龙山金锑矿床酸性岩脉U-Pb年代学和Hf同位素特征及其地质意义.岩石学报,32(11):3469-3488
戴长华.2000a.古台山-高家坳金矿床带北西向构造控矿特征及其找矿意义.湖南地质.19(2):105-110
戴长华.2000b.新化青京寨金矿地质特征及找矿意义.黄金,21(4):8-10
杜安道,屈文俊,李超,杨刚.2009.铼-锇同位素定年方法及分析测试技术的进展.岩矿测试,28(3):288-304
湖南省地质矿产局.1988.湖南省区域地质志.北京:地质出版社,1-718
胡瑞忠,毛景文,华仁民,范蔚茗.2015.华南陆块陆内成矿作用.北京:科学出版社,1-903
李超,屈文俊,杜安道,孙文静.2009.铼-锇同位素定年法中丙酮萃取铼的系统研究.岩矿测试,28(3):233-238
李超,屈文俊,王登红,陈郑辉,杜安道.2010.富有机质地质样品Re-Os同位素体系研究进展.岩石矿物学杂志,29(4):421-430
李华芹,王登红,陈富文,梅玉萍,蔡红.2008.湖南雪峰山地区铲子坪和大坪金矿成矿作用年代学研究.地质学报,82(7):900-905
李己华,吴继承,周遗军.2004.湘中白马山-龙山金矿带穹隆控矿规律分析.黄金地质,10(4):32-36
李建华,张岳桥,徐先兵,李海龙,董树文,李廷栋.2014.湖南白马山龙潭超单元、瓦屋塘花岗岩锆石SHRIMP U-Pb年龄及其地质意义.吉林大学学报(地球化学版),44(1):158-175
黎盛斯.1996.湘中锑矿深源流体的地幔柱成矿演化.湖南地质,15(3):137-142
李智明.1993.锡矿山锑矿成矿机理的探讨.矿产与地质,7(2):88-93
梁华英.1989.龙山金锑矿床成矿物质来源研究.矿床地质,8(4):39-48
梁华英.1991.龙山金锑矿床成矿流体地球化学和矿床成因研究.地球化学,(4):342-350
刘焕品,张永龄,胡文清.1985.湖南省锡矿山锑矿床的成因探讨.湖南地质,4(1):28-39
刘建清,谢渊,赵瞻,林家善,冯伟明,黄学平.2013.湖南雪峰山地区白马山花岗岩年代学特征及构造意义.地学前缘,20(5):25-35
刘继顺.1996.湘中地区长英质脉岩与锑(金)成矿关系.有色金属矿产与勘查,5(6):321-326
刘凯,毛建仁,赵希林,叶海敏,胡青.2014.湖南紫云山岩体的地质地球化学特征及其成因意义.地质学报,88(2):208-227
刘鹏程,唐清国,李惠纯.2008.湖南龙山矿区金锑矿地质特征、富集规律与找矿方向.地质与勘探,44(4):31-38
刘文均.1992.华南几个锑矿床的成因探讨.成都地质学院学报,19(2):10-19
卢新卫.1999.湘中金、锑矿床区域控矿特征研究.铀矿地质,15(6):344-349
罗献林.1995.湖南板溪锑矿床的成矿地质特征.桂林工学院学报,15(3):231-242
马东升,潘家永,解庆林,何江.2002.湘中锑(金)矿床成矿物质来源-I.微量元素及其实验地球化学证据.矿床地质,21(3):366-376
马东升,潘家永,解庆林.2003.湘中锑(金)矿床成矿物质来源-II.同位素地球化学证据.矿床地质,22(1):78-87
庞保成,杨东生,周志,刘义茂,刘鹏程,刘远栋.2011.湖南龙山金锑矿黄铁矿微量元素特征及其对成矿过程的指示.现代地质,25(5):832-845
彭建堂,胡瑞忠.2001a.华南锑矿带的成矿时代和成矿构造环境.地质地球化学,29(3):104-108
彭建堂,胡瑞忠.2001b.湘中锡矿山超大型锑矿床的碳、氧同位素体系.地质论评,47(1):34-41
彭建堂,胡瑞忠,邹利群,刘建雄.2002.湘中锡矿山锑矿床成矿物质来源的同位素示踪.矿物学报,22(2):155-159
戚学祥.1998.湖南双峰紫云山隆起区金矿成矿机制探讨.黄金地质,4(1):50-56
饶家荣,骆检兰,易志军.1999.锡矿山锑矿田幔-壳构造成矿模型及找矿预测.物探与化探,23(4):241-249
邵建波,张希友,王洪涛,陈殿义,任强.2014.吉林省塔东大型铁矿地球化学特征及黄铁矿Re-Os同位素定年.地质学报,88(1):83-98
史明魁,傅必勤,靳西祥,周雪昌.1993.湘中锑矿.长沙:湖南科学技术出版社,1-151
唐永永,毕献武,武丽艳,王雷,邹志超,何利平.2013.金顶铅锌矿黄铁矿Re-Os定年及其地质意义.矿物学报,3(3):287-294
王滨清.2005.湘中铃山金矿床富集规律与成矿机理研究.黄金,26(3):14-17
王永磊,陈毓川,王登红,徐珏,陈郑辉.2012.湖南渣滓溪W-Sb矿床白钨矿Sm-Nd测年及其地质意义.中国地质,39(5):1339-1344
文国璋,吴强,刘汉元,谢国柱,雷秀柳.1993.锡矿山超大型锑矿床控矿规律及形成机理初步研究.地质与勘探,(7):20-27
吴继承,王金荣,欧健,汪双双,杨淑芬,李己华.2007.湖南白马山-龙山金矿带包裹体-同位素地球化学及成矿流体特征.矿产与地质,21(6):673-678
肖启明,曾笃仁,金富秋,杨明跃,阳志芳.1992.中国锑矿床时空分布规律及找矿方向.地质与勘探,(12):9-14
杨胜洪,屈文俊,杨刚,杜安道,陈江峰.2007.电感耦合等离子体质谱法测量铼和锇同位素比值的质量分馏校正.岩矿测试,26(1):4-8
杨舜全.1986.湖南省锑矿成因及找矿方向的探讨.湖南地质,5(4):12-25
姚振凯,朱蓉斌.1993.湖南符竹溪金矿床多因复成模式及其找矿意义.大地构造与成矿学,17(3):199-209
余建国.1998.新化古台山金锑矿床蚀变特征及其找矿方向.湖南地质,17(3):155-159
郑时干.2006.龙山金锑矿地质特征及深部找矿预测.华南地质与矿产,(4):14-21,80