金佛山方竹材的热解及产物性能研究
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摘要
以金佛山方竹材为原料,通过综合热分析仪进行热解特性的测试,经传统砖土窑在炭化最高温度850℃,炭化周期10 d条件下制得方竹炭,对其理化性能、吸附性能、远红外辐射率和微量元素等测试分析;采用自制的小型炭化炉制备竹醋液,并用气相色谱—质谱联用仪(GC/MS)对组分含量测试。结果表明,方竹材热解特征曲线与毛竹材基本相近;方竹炭的基本理化性能指标符合《竹炭》等国家行业相关标准要求;方竹竹炭具有较高的远红外辐射率、富含多种微量元素,且对甲醛、苯、TVOC和氨具有较强的吸附性;方竹醋液有机物主要为有机酸、酚类、酯类、酮类等等。
Chimonobabusa utilis( Keng) Keng f. is chosen as raw material to analyze its pyrolysis characteristics by using a comprehensive thermal analyzer. The bamboo charcoal was prepared in the traditional brick kiln at the maximum carbonization temperature of 850 ℃ for 10 days. The physical and chemical properties,adsorption properties,far infrared radiation and trace elements of the charcoal were tested and analyzed. Bamboo vinegar was prepared in a small-scale carbonization furnace, and the content of components was measured by gas chromatography-mass spectrometry( GC/MS). The results showed that its pyrolysis characteristics was similar to that of Moso bamboo. The basic physical and chemical properties of the charcoal accorded with the standards of bamboo charcoal. The charcoal had strong far infrared radiation performance and was rich in trace elements. Meanwhile,the charcoal had strong adsorption abilities for formaldehyde,benzene,TVOC,and ammonia. Bamboo vinegar organic matter included mainly organic acids,phenols,aldehydes,ketones and so on.
Chimonobabusa utilis( Keng) Keng f. is chosen as raw material to analyze its pyrolysis characteristics by using a comprehensive thermal analyzer. The bamboo charcoal was prepared in the traditional brick kiln at the maximum carbonization temperature of 850 ℃ for 10 days. The physical and chemical properties,adsorption properties,far infrared radiation and trace elements of the charcoal were tested and analyzed. Bamboo vinegar was prepared in a small-scale carbonization furnace, and the content of components was measured by gas chromatography-mass spectrometry( GC/MS). The results showed that its pyrolysis characteristics was similar to that of Moso bamboo. The basic physical and chemical properties of the charcoal accorded with the standards of bamboo charcoal. The charcoal had strong far infrared radiation performance and was rich in trace elements. Meanwhile,the charcoal had strong adsorption abilities for formaldehyde,benzene,TVOC,and ammonia. Bamboo vinegar organic matter included mainly organic acids,phenols,aldehydes,ketones and so on.
引文
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[2]姜树海,张齐生,蒋身学.竹炭材料的有效利用理论与应用研究进展[J].东北林业大学学报,2002,30(4):53-56.
[3]张文标,李文珠,闫国祺.载铜竹炭的制备及电磁屏蔽效能[J].林业工程学报,2016,1(2):59-65.
[4]孙毅,张文标,林启晨,等.焙烧温度对3种竹材焙烧炭性能的影响[J].林业工程学报,2016,1(1):61-67.
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[7]Nithiyadevi K,Ravichandran K. Enhancement of photocatalytic and antibacterial activities of Zn O:Ag nanopowders through the addition of bamboo charcoal:an efficient natural adsorbent[J]. Acta Metallurgica Sinica(English Letters),2017,30(12):1249-1256.
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[14]杨磊,陈清松,赖寿莲,等.竹炭对甲醛的吸附性能研究[J].林产化学与工业,2005,25(1):77-80.
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[16]张文标. Fe3+/Ti O2改性竹炭催化降解甲醛[J].林业科学,2012,48(4):113-118.
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[18]Ihara Y,Aoyama K,Imamura C. Adsorption of p henol and bisp henol from aqueous solution onto bamboo charcoals[R]. Symposium of Yamaguchi Prefectural University. 2006:81-88.
[19]Liao Peng,Zhan Zhengyi,Dai Jing,et al. Adsorption of tetracycline and chloramp Henicol in aqueous solutions by bamboo charcoal:a batch and fixed-bed column study[J]. Chem Eng J,2013,228:496-505.
[20]Liao Peng,Yuan Songhu,Zhang Wenbiao,et al. Mechanistic aspects of nitrogen-heterocyclic compound adsorption on bamboo charcoal[J]. J Coll Interf Sci,2012,382(1):74-81.
[21]Liao Peng,Ismael Z M,Zhang Wenbiao,et al. Adsorption of dyes from aqueous solutions by microwave modified bamboo charcoal[J]. Chem Eng J,2012,195/196:339-346.
[22]张文标,叶良明,张宏,等.竹炭生产和应用[J].竹子研究汇刊,2001,20(2):49-54.
[23]杉浦銀治,鳥羽曙,谷田貝光克.竹炭·竹酢液っくり方生かし方[R].東京:創森社,2004:1-239.
[24]李延军,许斌,张齐生,等.我国竹材加工产业现状与对策分析[J].林业工程学报,2016,1(1):2-7.
[25]李衎.四库全书——竹谱[M].中国书店,2014:180-200.
[26]马师.合江方竹系统发育与栽培技术研究[D].贵州大学,2016.
[27]张宗高.竹中的佼佼者——方竹[J].林业科技,1984,(4).
[28]王礼春.方竹丰产栽培技术要点分析[J].现代园艺,2016,(4):17-18.
[29]徐冲霄.饮用水用竹炭的制备及工艺研究[D].浙江农林大学,2015:11-15.
[30]张文标,陈斌,王伟龙,等.雷竹炭理化性质及H2+吸附性能测定[J].浙江林业科技,2009,29(2):33-37.
[31]张文标,李文珠,周建钟,等.刺竹炭和毛藤竹炭的性能研究[J].世界竹藤通讯,2009,7(5):12-15.
[32]张文标,陈斌,王伟龙,等.雷竹炭理化性质及Hg2+吸附性能测定[J].浙江林业科技,2009,29(2):33-37.
[33]张文标,傅金和,周光益,等. 2种广东丛生竹炭性能的研究[J].竹子研究汇刊,2008,27(1):46-49.
[34]张文标,李文珠,曾凡地.竹炭的红外辐射特性[J].浙江农林大学学报,2008,25(5):573-577.
[35]余养伦,叶良明,于文吉.竹炭理化性能的测试和分析[J].林业科学,2007,43(11):98-102.
[36]冯晓林,亓荣.浅谈如何正确认识及补充微量元素[J].健康必读旬刊,2012,(1):241-242.
[37]张文标,包立根.高纯度竹醋液的生产技术[J].世界竹藤通讯,2004,2(3):19-21.
[38]张文标,叶良明,刘力,等.竹醋液的组分分析[J].竹子研究汇刊,2001,20(4):72-77.
[2]姜树海,张齐生,蒋身学.竹炭材料的有效利用理论与应用研究进展[J].东北林业大学学报,2002,30(4):53-56.
[3]张文标,李文珠,闫国祺.载铜竹炭的制备及电磁屏蔽效能[J].林业工程学报,2016,1(2):59-65.
[4]孙毅,张文标,林启晨,等.焙烧温度对3种竹材焙烧炭性能的影响[J].林业工程学报,2016,1(1):61-67.
[5]Oo A Z,Sudo S,Akiyama H,et al. Effect of dolomite and biochar addition on N2O and CO2emissions from acidic tea field soil[J]. Plos One,2018,13(2):192-235.
[6]Lin H C. Source water purification of bamboo activated carbon prepared from bamboo charcoal by using the multi layer filtration method[J]. JournalFaculty of Agriculture Kyushu University,2017,62(2):459-467.
[7]Nithiyadevi K,Ravichandran K. Enhancement of photocatalytic and antibacterial activities of Zn O:Ag nanopowders through the addition of bamboo charcoal:an efficient natural adsorbent[J]. Acta Metallurgica Sinica(English Letters),2017,30(12):1249-1256.
[8]Vignesh K,Vijayalakshmi K A,Karthikeyan N. Synthesis and surface properties studies on bamboo charcoal/ZnO nanocomposite by using lowtemperature plasma[J]. Surface Review&Letters,2017,24(3):
[9]Sumanatrakul P,Kongsune P,Chotitham L,et al. Utilization of Dendrocalamus Asper Backer,Bamboo Charcoal and Pyroligneous Acid[J]. Energy Procedia,2015,79(1):691-696.
[10],et al. A study on carbonization characteristics of indonesian and korean bamboo for production of bamboo charcoal and vinegar[J].,2010,15(1).
[11]Odoemelam S A,Onwu F K,Sonde C U,et al. Adsorption Kinetics of Cd(Ⅱ)and Pb(Ⅱ)Ions from aqueous solutions by bamboo-based activated charcoal and bamboo dust[J]. Orbital the Electronic Journal of Chemistry,2015,6(4):253-269.
[12]Partey S T,Frith O B,Kwaku M Y,et al. Comparative life cycle analysis of producing charcoal from bamboo,teak,and acacia species in Ghana[J]. International Journal of Life Cycle Assessment,2016:1-9.
[13]池嵨庸元竹炭は效く[M].東京:致知出版社,1999:1-52.
[14]杨磊,陈清松,赖寿莲,等.竹炭对甲醛的吸附性能研究[J].林产化学与工业,2005,25(1):77-80.
[15]张文标,李文珠,张宏,等.竹炭·竹醋液的生产与应用[M].北京:中国林业出版社,2006:23-55.
[16]张文标. Fe3+/Ti O2改性竹炭催化降解甲醛[J].林业科学,2012,48(4):113-118.
[17]Yoshimura T,Tsuchida K,Aoyama Y,et al. Measurement of water purification process of bamboo charcoal by using the multichannel measurement system with seven ion-selective electrodes[J]. Tech Pep IEICE OME,2001,52:43-47.
[18]Ihara Y,Aoyama K,Imamura C. Adsorption of p henol and bisp henol from aqueous solution onto bamboo charcoals[R]. Symposium of Yamaguchi Prefectural University. 2006:81-88.
[19]Liao Peng,Zhan Zhengyi,Dai Jing,et al. Adsorption of tetracycline and chloramp Henicol in aqueous solutions by bamboo charcoal:a batch and fixed-bed column study[J]. Chem Eng J,2013,228:496-505.
[20]Liao Peng,Yuan Songhu,Zhang Wenbiao,et al. Mechanistic aspects of nitrogen-heterocyclic compound adsorption on bamboo charcoal[J]. J Coll Interf Sci,2012,382(1):74-81.
[21]Liao Peng,Ismael Z M,Zhang Wenbiao,et al. Adsorption of dyes from aqueous solutions by microwave modified bamboo charcoal[J]. Chem Eng J,2012,195/196:339-346.
[22]张文标,叶良明,张宏,等.竹炭生产和应用[J].竹子研究汇刊,2001,20(2):49-54.
[23]杉浦銀治,鳥羽曙,谷田貝光克.竹炭·竹酢液っくり方生かし方[R].東京:創森社,2004:1-239.
[24]李延军,许斌,张齐生,等.我国竹材加工产业现状与对策分析[J].林业工程学报,2016,1(1):2-7.
[25]李衎.四库全书——竹谱[M].中国书店,2014:180-200.
[26]马师.合江方竹系统发育与栽培技术研究[D].贵州大学,2016.
[27]张宗高.竹中的佼佼者——方竹[J].林业科技,1984,(4).
[28]王礼春.方竹丰产栽培技术要点分析[J].现代园艺,2016,(4):17-18.
[29]徐冲霄.饮用水用竹炭的制备及工艺研究[D].浙江农林大学,2015:11-15.
[30]张文标,陈斌,王伟龙,等.雷竹炭理化性质及H2+吸附性能测定[J].浙江林业科技,2009,29(2):33-37.
[31]张文标,李文珠,周建钟,等.刺竹炭和毛藤竹炭的性能研究[J].世界竹藤通讯,2009,7(5):12-15.
[32]张文标,陈斌,王伟龙,等.雷竹炭理化性质及Hg2+吸附性能测定[J].浙江林业科技,2009,29(2):33-37.
[33]张文标,傅金和,周光益,等. 2种广东丛生竹炭性能的研究[J].竹子研究汇刊,2008,27(1):46-49.
[34]张文标,李文珠,曾凡地.竹炭的红外辐射特性[J].浙江农林大学学报,2008,25(5):573-577.
[35]余养伦,叶良明,于文吉.竹炭理化性能的测试和分析[J].林业科学,2007,43(11):98-102.
[36]冯晓林,亓荣.浅谈如何正确认识及补充微量元素[J].健康必读旬刊,2012,(1):241-242.
[37]张文标,包立根.高纯度竹醋液的生产技术[J].世界竹藤通讯,2004,2(3):19-21.
[38]张文标,叶良明,刘力,等.竹醋液的组分分析[J].竹子研究汇刊,2001,20(4):72-77.