石墨烯基复合材料光催化还原二氧化碳研究进展
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摘要
化石燃料的燃烧产生的二氧化碳(CO_2)所引起的温室效应已成为全球性问题。利用太阳光催化还原CO_2,不仅可以降低温室效应的危害,还可以提供碳氢燃料,缓解能源短缺问题。石墨烯作为一种新型的光催化剂载体材料,近年来受到越来越多人的关注。综述了近年来石墨烯基复合材料光催化还原CO_2的研究进展,并对今后的研究重点做出了展望。
The greenhouse effect caused by carbon dioxide(CO_2) from the burning of fossil fuels has become a global problem. Using sunlight to photocatalytic CO_2 reduction, it can not only reduce the harm of the greenhouse effect, but also provide hydrocarbon fuels and alleviate energy shortage problem. In recent years, as a new kind of photocatalyst carrier materials, graphene is caught the attention of more and more people. The research progress on photocatalytic CO_2 reduction over composites based on graphene in recent years was reviewed in this paper, and the focus of future research prospects was made.
The greenhouse effect caused by carbon dioxide(CO_2) from the burning of fossil fuels has become a global problem. Using sunlight to photocatalytic CO_2 reduction, it can not only reduce the harm of the greenhouse effect, but also provide hydrocarbon fuels and alleviate energy shortage problem. In recent years, as a new kind of photocatalyst carrier materials, graphene is caught the attention of more and more people. The research progress on photocatalytic CO_2 reduction over composites based on graphene in recent years was reviewed in this paper, and the focus of future research prospects was made.
引文
[1] 彭辉,吴志红,张建林,等. 基于能带匹配理论设计CO2光催化还原催化剂的研究进展[J]. 化工进展,2014,11(33): 3 007-3 012Peng Hui, Wu Zhihong, Zhang Jianlin, et al. Progress in designing CO2 photocatalyst based on energy band match theory[J].Chemical Industry and Engineering Progress, 2014, 11(33): 3 007-3 012(in Chinese)
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[2] 蓝奔月,史海峰. 光催化CO2转化为碳氢燃料体系的综述[J]. 物理化学学报,2014,30(22): 2 177-2 196Lan Benyue, Shi Haifeng. Review of systems for photocatalytic conversion of CO2 to hydrocarbon fuels[J]. Acta Physico-Chimica Sinica, 2014, 30(22): 2 177-2 196(in Chinese)
[3] Halmann M.Photoelectrochemical reduction of aqueous carbon-dioxide on p-type gallium-phosphide in liquid junction solar-cells[J]. Nature, 1978, 275(5 676): 115-116
[4] 李娜.石墨烯基半导体纳米复合材料的制备及其在光催化还原CO2中的应用[D]. 太原: 中北大学,2015Li Na. Preparation of graphene based semiconductor nanocomposites for photocatalytic reduction of CO2 [D]. Taiyuan: North University of China, 2015(in Chinese)
[5] Chen X, Zhou Y, Liu Q, et al. Ultrathin, single-crystal WO3 nanosheets by two-dimensional oriented attachment toward enhanced photocatalystic reduction of CO2 into hydrocarbon fuels under visible light[J]. ACS Applied Materials & Interfaces, 2012, 4(7): 3 372-3 377
[6] Li X, Chen J, Li H, et al. Photoreduction of CO2 to methanol over Bi2S3/CdS photocatalyst under visible light irradiation[J]. Journal of Natural Gas Chemistry, 2011, 20(4): 413-417
[7] Liu Y, Huang B, Dai Y, et al. Selective ethanol formation from photocatalytic reduction of carbon dioxide in water with BiVO4 photocatalyst[J]. Catalysis Communications, 2009, 11(3): 210-213
[8] 陈小康.石墨烯基复合材料用于CO2光催化还原的第一性原理研究[D].哈尔滨:哈尔滨工业大学,2013Chen Xiaokang. A first-principles study of graphene-based composite materials in photocatalytic reduction of CO2[D]. Harbin: Harbin Institute of Technology, 2013(in Chinese)
[9] Wang W, Serp P, Kalck P, et al. Preparation and characterization of nanostructured MWCNT-TiO2 composite materials for photocatalytic water treatment applications[J]. Materials Research Bulletin, 2008, 43: 958-967
[10] Wang W, Serp P, Kalck P, et al. Visible light photodegradation of phenol on MWNT-TiO2 composite catalysts prepared by a modified sol-gel method[J]. Journal of Molecular Catalysis A Chemical, 2005, 235: 194-199
[11] Wang W, Serp P, Kalck P, et al. Photocatalytic degradation of phenol on MWNT and titania composite catalysts prepared by a modified sol-gel method[J]. Applied Catalysis B: Environmental, 2005, 56: 305-312
[12] Ou Y, Lin J, Fang S, et al. MWNT-TiO2: Ni composite catalyst: A new class of catalyst for photocatalytic H2 evolution from water under visible light illumination[J]. Chemical Physics Letters, 2006, 429: 199-203
[13] Oh W C, Ko W B. Characterization and photonic properties for the Pt-fullerene/TiO2 composites derived from titanium (IV) n-butoxide and C60[J]. Journal of Industrial and Engineering Chemistry, 2009, 15: 791-797
[14] Krishna V, Noguchi N, Koopman B, et al. Enhancement of titanium dioxide photocatalysis by water-soluble fullerenes[J]. Journal of Colloid and Interface Science, 2006, 304: 166-171
[15] Mu S, Long Y, Kang S, et al. Surface modification of TiO2 nanoparticles with a C60 derivative and enhanced photocatalytic activity for the reduction of aqueous Cr(VI) ions[J]. Catalysis Communications, 2010, 11: 741-744
[16] 李长南,陈佩,孙毅男,等. 石墨烯基材料的制备及应用研究进展[J]. 淮北师范大学学报:自然科学版,2015, 36(3): 53-62Li Changnan, Chen Pei, Sun Yinan, et al. Research progress on the preparation and application of composite materials based on grapheme[J]. Journal of Huaibei Normal University:Natural Science, 2015, 36(3): 53-62(in Chinese)
[17] Wang W, Yu J, Xiang Q, et al. Enhanced photocatalytic activity of hierarchical macro/mesoporous TiO2-graphene composites for photodegradation of acetone in air[J]. Applied Catalysis B: Environmental, 2012, (119/120): 109-116
[18] Yoo D, Cuong T, Luan V, et al. Photocatalytic performance of a Ag/ZnO/CCG multidimensional heterostructure prepared by a solution-based method[J]. The Journal of Physical Chemistry C, 2012, 116: 7 180-7 184
[19] Ren Z, Kim E, Pattinson S W, et al. Hybridizing photoactive zeolites with graphene: A powerful strategy towards superior photocatalytic properties[J]. Chemical Science, 2012, 3: 209-216
[20] Chen J, Shi J, Wang X, et al. Recent progress in the preparation and application of semiconductor/graphene composite photocatalysts[J]. Chinese Journal of Catalysis, 2013, 34(4): 621-640
[21] 牛英华. 石墨烯负载TiO2和Cu2O催化剂的制备及CO2资源化中的应用[D]. 哈尔滨:哈尔滨工业大学,2012Niu Yinghua. Synthesis of TiO2/Cu2O-graphene catalysts and their application in the resources of carbon dioxide[D]. Harbin: Harbin Institute of Technology, 2012(in Chinese)
[22] Tan L, Ong W, Chai S, et al. Reduced graphene oxide-TiO2 nanocomposite as a promising visible-light-active photocatalyst for the conversion of carbon dioxide[J]. Nanoscale Research Letters, 2013, 8: 465-474
[23] 李娜,张立新,黄云杰,等. 还原氧化石墨烯-TiO2纳米管复合光催化剂的制备及其对CO2的光催化还原性能[J]. 化工环保,2015,35(2): 199-203Li Na, Zhang Lixin, Huang Yunjie, et al. Preparation of reduced graphene oxide-TiO2 nanotube photocatalyst and its photocatalytic activity on reduction of CO2[J]. Environmental Protection of Chemical Industry, 2015, 35(2): 199-203(in Chinese)
[24] Tu W, Zhou Y, Liu Q, et al. An in situ simultaneous reduction-hydrolysis technique for fabrication of TiO2-graphene 2D sandwich-like hybrid nanosheets: Graphene-Promoted selectivity of photocatalytic-driven hydrogenation and coupling of CO2 into methane and ethane[J]. Adv Funct Mater, 2013, 23(14): 1 743-1 749
[25] Tan L, Ong W, Chai S, et al. Photocatalytic reduction of CO2 with H2O over graphene oxidesupported oxygen-rich TiO2 hybrid photocatalyst under visible light irradiation: Process and kinetic studies[J]. Chemical Engineering Journal, 2017, 308: 248-255
[26] Liu C, Han X, Xie S, et al. Enhancing the photocatalytic activity of anatase TiO2 by improving the specific facet-induced spontaneous separation of photogenerated electrons and holes[J]. Chemistry-An Asian Journal, 2013, 8: 282-289
[27] Du Y, Feng Q, Chen C, et al. Photocatalytic and dye-sensitized solar cell performances of {010}-faceted and [111]-faceted anatase TiO2 nanocrystals synthesized from tetratitanate nanoribbons[J]. ACS Applied Materials & Interfaces, 2014, 6: 16 007-16 019
[28] Xiong Z, Lou Y, Zhao Y, et al. Synthesis, characterization and enhanced photocatalytic CO2 reduction activity of graphene supported TiO2 nanocrystals with coexposed {001} and {101} facets[J]. Physical Chemistry Chemical Physics, 2016, 18: 13 186-13 196
[29] Li X, Wang Q, Zhao Y, et al. Green synthesis and photo-catalytic performances for ZnO-reduced graphene oxide nanocomposites[J]. Journal of Colloid and Interface Science, 2013, 411: 69-75
[30] Zhang L, Li N, Jiu H, et al. ZnO-Reduced graphene oxide nanocomposites as efficient photocatalysts for photocatalytic reduction of CO2[J]. Ceramics International, 2015, 41(5): 6 256-6 262
[31] Gusain R, Kumar P, Sharma P O, et al. Reduced graphene oxide-CuO nanocomposites for photocatalytic conversion of CO2 into methanol under visible light irradiation[J]. Applied Catalysis B: Environmental, 2016, 181: 352-362
[32] An X, Li K, Tang J. Cu2O/reduced graphene oxide composites for the photocatalytic conversion of CO2[J]. Chem Sus Chem, 2014, 7: 1 086-1 093
[33] Wang A, Li X, Zhao Y, et al. Preparation and characterizations of Cu2O/reduced graphene oxide nanocomposites with high photo-catalytic performance[J]. Powder Technology, 2014, 261(7): 42-48
[34] Yu J, Jin J, Cheng B, et al. A noble metal-free reduced graphene oxide-CdS nanorod composite for the enhanced visible-light photocatalytic reduction of CO2 to solar fuel[J]. Journal of Materials Chemistry A, 2014, 2(10): 3 407-3 416
[35] Wang P, Bai Y, Luo P, et al. Graphene-WO3 nanobelt composite: Elevated conduction band toward photocatalytic reduction of CO2 into hydrocarbon fuels[J]. Catalysis Communications, 2013, 38(110): 82-85
[36] Liu L, Jin F. Hybrid ZnO nanorod arrays@graphene through a facile room-temperature bipolar solution route towards advanced CO2 photocatalytic reduction properties[J]. Chemical Engineering Journal, 2017, 43: 860-865
[37] Kumar P, Mungse P H, Cordier S, et al. Hexamolybdenum clusters supported on graphene oxide: Visible-light induced photocatalytic reduction of carbon dioxide into methanol[J]. Carbon, 2015, 94: 91-100
[38] Liu H, Zhang H, Shen P, et al. Synergistic effects in nanoengineered HNb3O8/graphene hybrids with improved photocatalytic conversion ability of CO2 into renewable fuels[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2016, 32(1): 254-264
[39] Jain S L, Kumar P, Labhsetwar N, et al. Visible light assisted photocatalytic reduction of CO2 using a graphene oxide supported heteroleptic ruthenium complex[J]. Green Chemistry, 2015, 17(3): 1 605-1 609
[40] Shown I, Hsu H C, Chang Y, et al. Highly efficient visible light photocatalytic reduction of CO2 to hydrocarbon fuels by cu-nanoparticle decorated graphene oxide[J]. Nano Letters, 2014, 14(11): 6 097-6 103
[41] Piao M, Liu N, Wang Y, et al. Efficiently converting CO2 into C2H4 using a porphyrin-graphene composite photocatalyst[J]. Australian Journal of Chemistry, 2016, 69(1): 27-32
[42] Xu Y, Yang M, Chen B, et al. A CsPbBr3 perovskite quantum dotgraphene oxide composite for photocatalytic CO2 reduction[J]. Journal of the American Chemical Society, 2017, 139: 5 660-5 663
[43] Zhang W, Li Y, Zhang X, et al. Facile synthesis of highly active reduced graphene oxide-CuI catalyst through a simple combustion method for photocatalytic reduction of CO2 to methanol[J]. Journal of Solid State Chemistry, 2017, 253: 47-51
[44] Liang Y, Vijayan B K, Gray K A, et al. Minimizing graphene defects enhances titania nanocomposite-based photocatalytic reduction of CO2 for improved solar fuel production[J]. Nano Letters, 2011, 11(7): 2 865-2 870
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