高温锂电池氧化物正极材料研究现状与展望
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摘要
高温锂电池是热电池向中低温度范围的拓展和延伸,在石油、天然气及地热探测等领域有很好的应用前景。相对于具有大比容量和接近纯锂电极电位的锂合金负极材料,正极材料还有不小的发展潜力。因此,正极材料是提升高温锂电池性能的关键材料。而在正极材料中,氧化物材料表现出高电压特性以及高热稳定性,可以推动高温锂电池小型化发展,满足特定条件下的电流电压供给。目前,并没有针对高温锂电池氧化物正极材料的系统性综述。为了促进本领域的快速发展,优化能源结构,本文系统总结了高温锂电池过渡族金属氧化物正极材料的研究进展,包括其物理特性、电化学特性及合成与制备方法,对材料的可利用特性以及不足之处加以说明;进而对氧化物正极材料在高温锂电池领域的应用做出展望。
High temperature lithium battery is the development of low temperature applications of thermal batteries,and has large potential development and utilization in the oil/gas and geothermal field.Compared with the lithium alloy anode materials with large specific capacity and close to the pure lithium electrode potential,the cathode materials are pivotal section of high temperature lithium battery and have large potential space.In the cathode materials,the oxide materials exhibit high voltage characteristics and high thermal stability,and the high-temperature lithium battery can be miniaturized to meet the current voltage supply under the specific conditions.However,there is no systematic overview about the oxide of high-temperature lithium battery currently.In order to make more development in this field and promote the optimal adjustment of energy structure,this paper introduces and summarizes the transition metal oxides used in high-temperature lithium battery,including physical properties,electrochemical properties and synthesis or preparation methods.We describe the excellent properties of various oxide materials in detail,and point out the shortcomings and the existing problems of the material.Moreover,this paper predicts the development of oxide cathode materials,and demonstrates the future direction of development and the work to be done.We hope that this work can provide some reference for the relevant researchers.
High temperature lithium battery is the development of low temperature applications of thermal batteries,and has large potential development and utilization in the oil/gas and geothermal field.Compared with the lithium alloy anode materials with large specific capacity and close to the pure lithium electrode potential,the cathode materials are pivotal section of high temperature lithium battery and have large potential space.In the cathode materials,the oxide materials exhibit high voltage characteristics and high thermal stability,and the high-temperature lithium battery can be miniaturized to meet the current voltage supply under the specific conditions.However,there is no systematic overview about the oxide of high-temperature lithium battery currently.In order to make more development in this field and promote the optimal adjustment of energy structure,this paper introduces and summarizes the transition metal oxides used in high-temperature lithium battery,including physical properties,electrochemical properties and synthesis or preparation methods.We describe the excellent properties of various oxide materials in detail,and point out the shortcomings and the existing problems of the material.Moreover,this paper predicts the development of oxide cathode materials,and demonstrates the future direction of development and the work to be done.We hope that this work can provide some reference for the relevant researchers.
引文
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[2]ZHAO Guang-Bo(赵广波),XU Ying(徐莹),BIAN Ji-Qing(汴纪庆),et al.Journal of Detection&Control(探测与控制学报),2008,30(6):64-68
[3]ZHANG Chun-Xiao(张春晓),MU Shi-Bo(穆仕博).Chin.J.Power Sources(电源技术),2010,34(6):614-615
[4]Guidotti R A.35th Intersociety Energy Conversion Engineering Conference and Exhibit:Vol.2.New York:IEEE,2000:1276-1286
[5]LU Rui-Sheng(陆瑞生),LIU Xiao-Jiang(刘效疆).Thermal Batteries(热电池).Beijing:National Defense Industry Press,2005.
[6]Masset P J,Guidotti R A.J.Power Sources,2008,177(2):595-609
[7]WANG Zhen-Jie(王振杰).Thesis for the Doctorate of University of Chinese Academy of Sciences(中国科学院大学博士论文).2014.
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[17]Soofivand F,Mohandes F,Salavati-Niasari M.Micro Nano Lett.,2012,7(3):283-286
[18]ZHOU Wen-Min(周文敏),HUANG Jian-Feng(黄剑锋),LI Jia-Yin(李嘉胤),et al.J.Synth.Cryst.(人工晶体学报),2015,44(4):954-960
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[23]XIA Yu-Dan(夏玉丹),SONG Hui(宋辉),YANG Bin(杨斌).Guizhou Chemical Industry(贵州化工),2011,36(4):17-18
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[28]CAO Du-Meng(曹笃盟).Thesis for the Doctorate of Central South University(中南大学博士论文).2006.
[29]LI Zhi-You(李志友),CAO Du-Meng(曹笃盟),ZHOU KeChao(周科朝).Trans.Nonferrous Met.Soc.China(中国有色金属学报),2008,18(1):59-66
[30]Mishra K M,Lal A K,Haque F Z.Solid State Ionics,2004,167(1):137-146
[31]CAO Du-Meng(曹笃盟),LI Zhi-You(李志友),ZHOU KeChao(周科朝).Journal of Functional Materials(功能材料),2004,35(z1):1791-1794
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[33]Pistoia G,Pasquali M,Wang G,et al.Cheminform,1990,21(42):2365-2370
[34]QIAO Xiao-Ning(乔晓宁).Thesis for the Doctorate of Shaanxi University of Science and Technology(陕西科技大学博士论文).2016.
[35]SHI Chuan(石钏),REN Xiang-Zhong(任祥忠),ZHANG PeiXin(张培新),et al.The Proceedings of 29th the National Conference on Chemistry and Physics(第29届全国化学与物理电源学术年会论文集).Changsha:[s.n.],2011:98-99
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[39]Gibbard H F.J.Power Sources,1989,26(1/2):81-91
[40]LIU Xiao-Jiang(刘效疆),LU Rui-Sheng(陆瑞生).Chin.J.Power Sources(电源技术),2002,26(1):26-28
[41]De Guibert A,Crepy G,Buchel J,et al.Proceedings of the34th International.New York:IEEE,1990:145-147
[42]SHI Kui(石奎),FENG Yu-Cai(冯玉才),ZHOU Ai(周爱).Chin.J.Power Sources(电源技术),2016,40(9):1833-1835
[43]Hillel T,Ein-Eli Y.J.Power Sources,2013,229:112-116
[44]Guidotti R A,Reinhardt F W.Office of Scientific&Technical Information Technical Reports.Albuquerque:Sandia National Laboratories,1996.
[45]Dai J X,Lai M,Lafollette R M,et al.ECS Trans.,2011,33(27):3-9
[46]Dai J X,Lai M,Mckee J.220th Electrochemical Society Meeting:Vol.41.Honolulu:The Electrochemical Society,2012:11-16
[47]YAN Yan(闫妍),YANG Shao-Hua(杨少华),ZHAO YanLong(赵彦龙).Journal of Shenyang Ligong University(沈阳理工大学学报),2014,33(2):6-8
[48]LUO Jian-Tun(骆柬氽),YANG Shao-Hua(杨少华),BAI Yin-Xiang(白银祥),et al.Chin.J.Power Sources(电源技术),2014,38(8):1516-1518
[49]DING Xiao-Ru(丁晓儒),YUAN Chao-Jun(袁朝军),YANG Shao-Hua(杨少华),et al.Journal of Shenyang Ligong University(沈阳理工大学学报),2016,1(35):102-105
[50]YUAN Chao-Jun(袁朝军),CAO Xiao-Hui(曹晓晖),YANG Shao-Hua(杨少华).Chin.J.Power Sources(电源技术),2015,39(11):2450-2452
[51]YUAN Chao-Jun(袁朝军),YANG Shao-Hua(杨少华),CAO Xiao-Hui(曹晓晖),et al.Chin.J.Power Sources(电源技术),2015,39(7):1479-1481
[52]YUAN Chao-Jun(袁朝军),YANG Shao-Hua(杨少华),CAO Xiao-Hui(曹晓晖).Journal of Functional Materials(功能材料),2015,46(17):17046-17048
[53]Wang F Y,Zhang H C,Liu L,et al.J.Alloys Compd.,2016,672:229-237
[54]SUN Rong(孙榕),YANG Shao-Hua(杨少华).Chin.J.Power Sources(电源技术),2017,41(2):270-271
[55]Cao J Q,Wang X Y,Tang A,et al.J.Alloys Compd.,2009,479(1):875-878
[56]SUN Rong(孙榕),YANG Shao-Hua(杨少华),CAO Xiao-Hui(曹晓晖),et al.Chin.J.Power Sources(电源技术),2016,40(11):2195-2197
[57]GUO Xue-Yi(郭学益),LIU Hai-Han(刘海涵),LI Dong(李栋),et al.Mining and Metallurgical Engineering(矿冶工程),2007,27(1):50-53
[58]Niu Y Q,Wu Z,Du J L,et al.Solid State Ionics,2014,255:80-83
[59]Guidotti R A,Reinhardt F W.IBA-2000 Manganese Oxide Battery Symposium:Vol.1.Albuquerque:Sandia National Laboratories,2001.
[60]Guidotti R A,Reinhardt F W.41st Power Sources Conference.Philadelphia:[s.n.],2004.
[61]Niu Y Q,Wu Z,Du J L,et al.J.Power Sources,2014,245:537-542
[62]Niu Y Q,Wu Z,Du J L,et al.Electrochim.Acta,2014,115:607-611
[63]Zhu S,Zhou H,Hibino M,et al.Adv.Funct.Mater.,2005,15(3):381-386
[64]MA Chun-An(马淳安),LOU Ying-Wei(楼颖伟),ZHAO Feng-Wu(赵峰呜),et al.Trans.Nonferrous Met.Soc.China(中国有色金属学报),2004,14(10):1736-1740
[65]Tarascon J M,Mckinnon W R,Coowar F,et al.J.Electrochem.Soc.,1994,141(6):1421-1431
[66]BAI Liang-Fei(白亮飞).Thesis for the Doctorate of University of Science and Technology of China(中国科学技术大学博士论文).2013.
[67]JIANG Jian-Bing(江剑兵).Thesis for the Doctorate of Central South University(中南大学博士论文).2014.
[68]YAO Yao-Chun(姚耀春).Thesis for the Doctorate of Kunming University of Science and Technology(昆明理工大学博士论文).2005.
[69]ZHENG De-Shan(郑德山),YANG Xiao-Ling(杨晓玲),YAO Xiao-Cui(姚小翠).New Chemical Materals(化工新型材料),2012,4:34-36
[70]Wang Z J,Du J L,Li Z L,et al.Ceram.Int.,2014,40(2):3527-3531