生物活性炭技术在水处理中的研究与应用进展
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摘要
介绍了生物活性炭技术的原理、生物再生机理以及形成方法、间歇期保存方法和微生物泄漏控制措施,综述了该技术在微污染原水、工业废水、生活污水处理中的研究与应用进展。认为今后的主要研究内容包括活性炭的生物再生机理,建立污染物去除的吸附、解吸、生物降解、传质等过程的数学模型,活性炭自身的材质、孔径分布、表面性状以及吸附能力对生物膜的形成、有机物去除效果的影响,以及生物膜厚度的控制措施等。
The principle of biological activated carbon technology, the mechanism of biological regeneration, the method of formation, the method of intermission preservation and the control measures for microorganism leakage were introduced, the research and application progress of this technology in the treatment of micro-polluted raw water, industrial wastewater and domestic sewage were reviewed. The biological regeneration mechanism of activated carbon, mathematic model of adsorption, desorption, biodegration and mass transfer process of pollutant removal, the effect of material, pore size distribution, surface character of activated carbon, adsorption performance on membrane formation and organic matter removal efficiency, controlling of biological membrane thickness were considered as the main research content in the future.
The principle of biological activated carbon technology, the mechanism of biological regeneration, the method of formation, the method of intermission preservation and the control measures for microorganism leakage were introduced, the research and application progress of this technology in the treatment of micro-polluted raw water, industrial wastewater and domestic sewage were reviewed. The biological regeneration mechanism of activated carbon, mathematic model of adsorption, desorption, biodegration and mass transfer process of pollutant removal, the effect of material, pore size distribution, surface character of activated carbon, adsorption performance on membrane formation and organic matter removal efficiency, controlling of biological membrane thickness were considered as the main research content in the future.
引文
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[2]NATH K, BHAKHAR M S. Microbial regeneration of spent activated carbon dispersed with organic contaminants:mechanism, efficiency,and kinetic models[J].Environmental Science and Pollution Research,2011,18(4):534-546.
[3]马放,时双喜,杨基先,等.固定化生物活性炭的形成及功能研究[J].哈尔滨建筑大学学报,2000,33(1):46-50.
[4]MOCHIDZUKI K, TAKEUCHI Y. The effects of some inhibitory components on biological activated carbon processes[J].Water Research,1999,33(11):2609-2616.
[5]孔令宇,张晓健,王占生.生物活性炭内吸附与生物降解协同去除有机污染物[J].环境科学,2007,28(4):777-780.
[6]田晴,陈季华.BAC生物活性炭法及其在水处理中的应用[J].环境工程,2006,24(1):84-86.
[7]符乃创,刘静.生物活性炭技术在水处理中的作用机理及应用现状[J].皮革与化工,2014,31(2):13-18.
[8]ZHANG X J, WANG Z S, GU X S. Simple combination of biodegradation and carbon adsorption-the mechanism of the biological activated carbon process[J].Water Research,1991,25(2):165-172.
[9]KLIMENKO N, WINTHER-NIELSEN M, SMOLIN S, et al. Role of the physico-chemical factors in the purification process of water from surface-active matter by biosorption[J].Water Research,2002,36(20):5132-5140.
[10]Aktas O,Cecen F. Effect of activation type on bioregeneration of various activated carbons loaded with phenol[J].Journal of Chemical Technology and Biotechnology,2006,81(7):1081-1092.
[11]郑璐,高乃云,甘霖,等.固定化生物活性炭快速启动处理微污染水[J].环境工程学报,2015,9(11):5231-5236.
[12]CARVALHO M F, VASCONCELOS I, BULL A T, et al. A GAC biofilm reactor for the continuous degradation of 4-chlorophenol:treatment efficiency and microbial analysis[J].Applied Microbiology and Biotechnology,2001,57(3):419-426.
[13]缪刚,鲍娟,陈云霄,等.臭氧-生物活性炭工艺间歇性运行的生物量保持方法[J].水资源保护,2017,33(6):109-113.
[14]陶辉,文晨,陈卫.臭氧-生物活性炭工艺间歇性运行时保存方法的优化研究[J].水处理技术,2018,44(1):110-113.
[15]陈国强,王剑,张正德,等.臭氧/生物活性炭工艺的微生物泄漏控制研究[J].中国给水排水,2017,33(15):36-41.
[16]KO Y-S, LEE Y-J, NAM S-h. Evaluation of a pilot scale dual media biological activated carbon process for drinking water[J].Korean Journalof Chemical Engineering,2007,24(2):253-260.
[17]张硕,王如华,徐俊.黄浦江微污染原水的臭氧生物活性炭工艺设计探讨[J].净水技术,2016,35(s1):30-32.
[18]郑和辉,卞战强,田向红,等.中国饮用水标准的现状[J].卫生研究,2014,43(1):166-169.
[19]刘玮,武道吉,戚菲菲.生物活性炭技术在水处理中的应用与发展趋势[J].水科学与工程技术,2009(4):74-78.
[20]薛琦,朱光灿,戴小冬,等.臭氧-生物活性炭工艺对微污染长江原水中有机物的去除特性[J].净水技术,2015,34(4):36-41.
[21]郭建宁,陈磊,张锡辉,等.臭氧/陶瓷膜对生物活性炭工艺性能和微生物群落结构影响[J].中国环境科学,2014,34(3):697-704.
[22]LIU H,HE Y H,QUAN X C, et al. Enhancement of organic pollutant biodegradation by ultrasound irradiation in a biological activated carbon membrane reactor[J].Process Biochemistry,2005,40(9):3002-3007.
[23]YAN M, WANG D, MA X, et al. THMs precursor removal by an integrated process of ozonation and biological granular activated carbon for typical Northern China water[J].Separation and Purification Technology,2010,72(3):263-268.
[24]范晓丹,李皓璇,姬海燕,等.生物活性炭法深度处理印染废水及其生物毒性的表征[J].环境工程学报,2015,9(1):188-194.
[25]杨波,魏爽,田晴,等.上流式曝气生物滤池深度处理碱减量印染废水[J].环境工程,2013,31(1):30-34.
[26]生活杂用水水质标准:CJ/T 48-1999[S].
[27]LIN Y H,LEU J Y. Kinetics of reactive azo-dye decolorization by Pseudomonas luteola in a biological activated carbon process[J].Biochemical Engineering Journal,2008,39(3):457-467.
[28]石油炼制工业污染物排放标准:GB 31570-2015[S].
[29]李伟光,李欣,朱文芳.固定化生物活性炭处理含油废水的试验研究[J].哈尔滨商业大学学报(自然科学版),2004,20(2):187-190.
[30]车春波,苏荣军,聂千.采用生物活性炭法对含油污水进行深度处理[J].炼油与化工,2009,20(1):52-53.
[31]冯晋阳,吴小宁.高效原油降解菌的筛选及其在生物活性炭中的应用[J].环境污染与防治,2011,33(6):39-43.
[32]李亚峰,高颖.制药废水处理技术研究进展[J].水处理技术,2014,40(5):1-4.
[33]程雪敏,陈超,樊占国.抗生素制药废水的混凝和生化处理研究[J].环境保护科学,2010,36(2):34-37.
[34]毛定坤,庞金钊,李斌水.精氨酸生物制药废水的中试处理研究[J].安徽农业科学,2010,38(4):1979-1980.
[35]生物工程类制药工业水污染物排放标准:GB 21907-2008[S].
[36]MISEREZ K, PHILIPS S, VERSTRAETE W. New biology for advanced wastewater treatment[J].Water Science and Technology,1999,40(4):137-144.
[37]RENOU S, GIVAUDAN J G, POULAIN S, et al. Landfill leachate treatment:Review and opportunity[J].Journal of Hazardous Materials,2008,150(3):468-493.
[38]崔延瑞,郭焱,吴青,等.生物活性炭投加量对垃圾渗滤液处理效果的影响[J].环境科学,2014,35(8):3206-3211.
[39]尉然,赵庆良,丁晶,等.曝气生物活性炭滤池深度处理垃圾渗滤液的效能研究[J].环境保护科学,2017,43(2):30-34.
[40]生活垃圾填埋场污染控制标准:GB 16889-2008[S].
[41]唐国卿,邱家洲,沈燕,等.臭氧高级氧化组合技术处理垃圾渗滤液浓缩液[J].中国给水排水,2016,32(8):88-91.
[42]AZIZ S Q, AZIZ H A, YUSOFF M S. Powdered activated carbon augmented double react-settle sequencing batch reactor process for treatment of landfill leachate[J].Desalination,2011,277(1):313-320.
[43]刘寅,赵庆,杜兵.某酱香型白酒生产企业废水处理工程设计[J].给水排水,2017,43(2):63-67.
[44]廖雷,师杰峰,彭娟,等.固定化生物活性炭处理糖蜜酒精废水[J].环境工程学报,2017,11(2):727-732.
[45]HOU B, HAN H, ZHUANG H, et al. A novel integration of threedimensional electro-Fenton and biological activated carbon and its application in the advanced treatment of biologically pretreated Lurgi coal gasification wastewater[J].Bioresource Technology,2015,196:721-725.
[46]城镇污水处理厂污染物排放标准:GB18918-2002[S].
[47]TAMMARO M, SALLUZZO A, PERFETTO R, et al. A comparative evaluation of biological activated carbon and activated sludge processes for the treatment of tannery wastewater[J].Journal of Environmental Chemical Engineering,2014,2(3):1445-1455.
[48]李金波,陶虎春,李绍峰.BAC-FB与传统活性污泥法处理生活污水的对比研究[J].东北农业大学学报,2010,41(4):59-63.
[49]丛俏,肖振林,曲蛟.固定化生物活性炭纤维处理洗浴废水的研究[J].安全与环境学报,2009,9(6):44-46.
[50]生活饮用水卫生标准:GB 5749-2006[S].
[51]城市供水水质标准:CJ/T 206-2005[S].
[2]NATH K, BHAKHAR M S. Microbial regeneration of spent activated carbon dispersed with organic contaminants:mechanism, efficiency,and kinetic models[J].Environmental Science and Pollution Research,2011,18(4):534-546.
[3]马放,时双喜,杨基先,等.固定化生物活性炭的形成及功能研究[J].哈尔滨建筑大学学报,2000,33(1):46-50.
[4]MOCHIDZUKI K, TAKEUCHI Y. The effects of some inhibitory components on biological activated carbon processes[J].Water Research,1999,33(11):2609-2616.
[5]孔令宇,张晓健,王占生.生物活性炭内吸附与生物降解协同去除有机污染物[J].环境科学,2007,28(4):777-780.
[6]田晴,陈季华.BAC生物活性炭法及其在水处理中的应用[J].环境工程,2006,24(1):84-86.
[7]符乃创,刘静.生物活性炭技术在水处理中的作用机理及应用现状[J].皮革与化工,2014,31(2):13-18.
[8]ZHANG X J, WANG Z S, GU X S. Simple combination of biodegradation and carbon adsorption-the mechanism of the biological activated carbon process[J].Water Research,1991,25(2):165-172.
[9]KLIMENKO N, WINTHER-NIELSEN M, SMOLIN S, et al. Role of the physico-chemical factors in the purification process of water from surface-active matter by biosorption[J].Water Research,2002,36(20):5132-5140.
[10]Aktas O,Cecen F. Effect of activation type on bioregeneration of various activated carbons loaded with phenol[J].Journal of Chemical Technology and Biotechnology,2006,81(7):1081-1092.
[11]郑璐,高乃云,甘霖,等.固定化生物活性炭快速启动处理微污染水[J].环境工程学报,2015,9(11):5231-5236.
[12]CARVALHO M F, VASCONCELOS I, BULL A T, et al. A GAC biofilm reactor for the continuous degradation of 4-chlorophenol:treatment efficiency and microbial analysis[J].Applied Microbiology and Biotechnology,2001,57(3):419-426.
[13]缪刚,鲍娟,陈云霄,等.臭氧-生物活性炭工艺间歇性运行的生物量保持方法[J].水资源保护,2017,33(6):109-113.
[14]陶辉,文晨,陈卫.臭氧-生物活性炭工艺间歇性运行时保存方法的优化研究[J].水处理技术,2018,44(1):110-113.
[15]陈国强,王剑,张正德,等.臭氧/生物活性炭工艺的微生物泄漏控制研究[J].中国给水排水,2017,33(15):36-41.
[16]KO Y-S, LEE Y-J, NAM S-h. Evaluation of a pilot scale dual media biological activated carbon process for drinking water[J].Korean Journalof Chemical Engineering,2007,24(2):253-260.
[17]张硕,王如华,徐俊.黄浦江微污染原水的臭氧生物活性炭工艺设计探讨[J].净水技术,2016,35(s1):30-32.
[18]郑和辉,卞战强,田向红,等.中国饮用水标准的现状[J].卫生研究,2014,43(1):166-169.
[19]刘玮,武道吉,戚菲菲.生物活性炭技术在水处理中的应用与发展趋势[J].水科学与工程技术,2009(4):74-78.
[20]薛琦,朱光灿,戴小冬,等.臭氧-生物活性炭工艺对微污染长江原水中有机物的去除特性[J].净水技术,2015,34(4):36-41.
[21]郭建宁,陈磊,张锡辉,等.臭氧/陶瓷膜对生物活性炭工艺性能和微生物群落结构影响[J].中国环境科学,2014,34(3):697-704.
[22]LIU H,HE Y H,QUAN X C, et al. Enhancement of organic pollutant biodegradation by ultrasound irradiation in a biological activated carbon membrane reactor[J].Process Biochemistry,2005,40(9):3002-3007.
[23]YAN M, WANG D, MA X, et al. THMs precursor removal by an integrated process of ozonation and biological granular activated carbon for typical Northern China water[J].Separation and Purification Technology,2010,72(3):263-268.
[24]范晓丹,李皓璇,姬海燕,等.生物活性炭法深度处理印染废水及其生物毒性的表征[J].环境工程学报,2015,9(1):188-194.
[25]杨波,魏爽,田晴,等.上流式曝气生物滤池深度处理碱减量印染废水[J].环境工程,2013,31(1):30-34.
[26]生活杂用水水质标准:CJ/T 48-1999[S].
[27]LIN Y H,LEU J Y. Kinetics of reactive azo-dye decolorization by Pseudomonas luteola in a biological activated carbon process[J].Biochemical Engineering Journal,2008,39(3):457-467.
[28]石油炼制工业污染物排放标准:GB 31570-2015[S].
[29]李伟光,李欣,朱文芳.固定化生物活性炭处理含油废水的试验研究[J].哈尔滨商业大学学报(自然科学版),2004,20(2):187-190.
[30]车春波,苏荣军,聂千.采用生物活性炭法对含油污水进行深度处理[J].炼油与化工,2009,20(1):52-53.
[31]冯晋阳,吴小宁.高效原油降解菌的筛选及其在生物活性炭中的应用[J].环境污染与防治,2011,33(6):39-43.
[32]李亚峰,高颖.制药废水处理技术研究进展[J].水处理技术,2014,40(5):1-4.
[33]程雪敏,陈超,樊占国.抗生素制药废水的混凝和生化处理研究[J].环境保护科学,2010,36(2):34-37.
[34]毛定坤,庞金钊,李斌水.精氨酸生物制药废水的中试处理研究[J].安徽农业科学,2010,38(4):1979-1980.
[35]生物工程类制药工业水污染物排放标准:GB 21907-2008[S].
[36]MISEREZ K, PHILIPS S, VERSTRAETE W. New biology for advanced wastewater treatment[J].Water Science and Technology,1999,40(4):137-144.
[37]RENOU S, GIVAUDAN J G, POULAIN S, et al. Landfill leachate treatment:Review and opportunity[J].Journal of Hazardous Materials,2008,150(3):468-493.
[38]崔延瑞,郭焱,吴青,等.生物活性炭投加量对垃圾渗滤液处理效果的影响[J].环境科学,2014,35(8):3206-3211.
[39]尉然,赵庆良,丁晶,等.曝气生物活性炭滤池深度处理垃圾渗滤液的效能研究[J].环境保护科学,2017,43(2):30-34.
[40]生活垃圾填埋场污染控制标准:GB 16889-2008[S].
[41]唐国卿,邱家洲,沈燕,等.臭氧高级氧化组合技术处理垃圾渗滤液浓缩液[J].中国给水排水,2016,32(8):88-91.
[42]AZIZ S Q, AZIZ H A, YUSOFF M S. Powdered activated carbon augmented double react-settle sequencing batch reactor process for treatment of landfill leachate[J].Desalination,2011,277(1):313-320.
[43]刘寅,赵庆,杜兵.某酱香型白酒生产企业废水处理工程设计[J].给水排水,2017,43(2):63-67.
[44]廖雷,师杰峰,彭娟,等.固定化生物活性炭处理糖蜜酒精废水[J].环境工程学报,2017,11(2):727-732.
[45]HOU B, HAN H, ZHUANG H, et al. A novel integration of threedimensional electro-Fenton and biological activated carbon and its application in the advanced treatment of biologically pretreated Lurgi coal gasification wastewater[J].Bioresource Technology,2015,196:721-725.
[46]城镇污水处理厂污染物排放标准:GB18918-2002[S].
[47]TAMMARO M, SALLUZZO A, PERFETTO R, et al. A comparative evaluation of biological activated carbon and activated sludge processes for the treatment of tannery wastewater[J].Journal of Environmental Chemical Engineering,2014,2(3):1445-1455.
[48]李金波,陶虎春,李绍峰.BAC-FB与传统活性污泥法处理生活污水的对比研究[J].东北农业大学学报,2010,41(4):59-63.
[49]丛俏,肖振林,曲蛟.固定化生物活性炭纤维处理洗浴废水的研究[J].安全与环境学报,2009,9(6):44-46.
[50]生活饮用水卫生标准:GB 5749-2006[S].
[51]城市供水水质标准:CJ/T 206-2005[S].