稀土氟化物纳米材料的应用研究进展
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摘要
氟化物纳米材料由于其独特的光、电、磁等性质,在光学器件、生物标记等领域具有广泛的应用,已成为材料科学领域研究的热点之一,尤其是稀土金属氟化物。合成氟化物纳米材料的方法多种多样,已成功制备出了球形纳米颗粒、纳米线、纳米花、复合结构纳米晶、核壳结构纳米材料等。本文主要列举了几种常见的稀土氟化物,重点对其合成以及应用进行了综述,并结合其特点,进行了展望。
Due to their special optical,electrical,magnetic and other properties,fluoride nanomaterials has become one of the hot spots in the field of materials science and has been widely used in the fields of optical devices,biological marker,especially the rare earth metal fluoride nanoparticles.Various methods have been successfuly synthesised fluoride nanoparticles,such as nanowires,nano flowers,nanocrystalline composite structure,core-shell structure nanomaterials.In this paper,we mainly listed some common rare earth fluorides,the synthesis and application were also reviewed.And combined with its characteristics,prospects was also carried on.
Due to their special optical,electrical,magnetic and other properties,fluoride nanomaterials has become one of the hot spots in the field of materials science and has been widely used in the fields of optical devices,biological marker,especially the rare earth metal fluoride nanoparticles.Various methods have been successfuly synthesised fluoride nanoparticles,such as nanowires,nano flowers,nanocrystalline composite structure,core-shell structure nanomaterials.In this paper,we mainly listed some common rare earth fluorides,the synthesis and application were also reviewed.And combined with its characteristics,prospects was also carried on.
引文
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[3]Tomasz G,Dominika P.Formation mechanism,structural,and upconversion properties of alkaline rare-earth fluoride nanocrystals doped with Yb3+/Er3+ ions[J].Inorg Chem,2018,57(11):6410-6420.
[4]Gustavo G,Silvia H S,Younes M,et al.Rare-earth doped fluoride phosphate glasses:structural foundations of their luminescence properties[J].Phys Chem Chem Phys,2017,19(32):21612-21624.
[5]Rahul K S,Anja V M,Pushpal G.Recent trends in binary and ternary rare-earth fluoride nanophosphors:How structural and physical properties influence optical behavior[J].J Lumin,2017,189(3):44-63.
[6]Zhang P,Rogelj S,Nguyen K,et al.Design of a highly sensitive and specific nucleotide sensor based on photon upconverting particles[J].J Am Chem Soc,2006,128(38):12410-12411.
[7]Wang F,Han Y,Lim C S,et al.Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping[J].Nature,2010,463(7284):1061-1065.
[8]Hu H,Xiong L Q,Zhou J,et al.Multimodal-luminescence core-shell nanocomposites for targeted imaging of tumor cells[J].Chem Eur J,2009,15(14):3577-3584.
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[10]Hilderbrand S A,Shao F W,Salthouse C,et al.Upconverting luminescent nanomaterials:application to in vivo bioimaging[J].Chem Commun,2009,28(28):4188-4190.
[11]Lim S F,Riehn R,Tung C K,et al.Upconverting nanophosphors for bioimaging[J].Nanotechnology,2009,20(40):5701-405706.
[12]Kobayashi H,Kosaka N,Ogawa M,et al.In vivo multiple color lymphatic imaging using upconverting nanocrystals[J].Mater Chem,2009,19(36):6481-6484.
[13]Bouzigues C,Gacoin T,Alexandrou A.Biological applications of rare-earth based nanoparticles[J].ACS Nano,2011,5(11):8488-8505.
[14]He H,Chen Z G,Cao T Y,et al.Hydrothermal synthesis of hexagonal lanthanide-doped LaF3 nanoplates with bright upconversion luminescence[J].Nanotechnology,2008,19(37):375702-375710.
[15]Li F F,Li C G,Liu X M,et al.Microwave-assisted synthesis and up–down conversion luminescent properties of multicolor hydrophilic LaF3:Ln3+ nanocrystals[J].Dalton Trans,2012,42(6):2015-2022.
[16]Diamente P R,Burke R D,Veggel F V.Bioconjugation of Ln3+-doped LaF3 nanoparticles to avidin[J].Langmuir,2006,22(4):1782-1788.
[17]Wang F,Zhang Y,Fan X P,et al.One-pot synthesis of chitosan/LaF3:Eu3+nanocrystals for bio-applications[J].Nanotechnology,2006,17(5):1527-1532.
[18]Wang L Y,Yang Z H,Zhang Y,et al.Bifunctional nanoparticles with magnetization and luminescence[J].J Phys Chem C,2009,113(10):3955-3959.
[19]Wang L,Li P,Wang L Y.Luminescent and hydrophilic LaF3-polymer nanocomposite for DNA detection[J].Luminescence,2009,24(1):39-44.
[20]Cu X X,She J B,Gao C,et al.Luminescent properties of Nd3+-doped LaF3 core/shell nanoparticles with enhanced near infrared(NIR)emission[J].Chem Phy Lett,2010,494(1):60-63.
[21]Zhang X T,Hayakawa T,Nogami M,et al.Selective synthesis and luminescence properties of nanocrystalline GdF3:Eu3+with hexagonal and orthorhombic structures[J].J Nanomater,2010,11(7):68-75.
[22]Sayed F N,V Grover,Sudarsan V,et al.Multicolored and white-light phosphors based on doped GdF3 nanoparticles and their potential bio-applications[J].J Colloid Interface Sci,2012,367(1):161-170.
[23]Evanics F,Diamente P R,Veggel F V,et al.Water-soluble GdF3 and GdF3/LaF3 nanoparticless physical characterization and NMR relaxation properties[J].Chem Mater,2006,18(10):2499-2505.
[24]Cheung E N M,Alvares R DA,OakdenW,et al.Polymer-stabilized lanthanide fluoride nanoparticle aggregates as contrast agents for magnetic resonance imaging and computed tomography[J].Chem Mater,2010,22(16):4728-4739.
[25]Runowski M,Grzyb T,Lis S.Bifunctional luminescent and magnetic core/shell type nanostructures Fe3O4@CeF3:Tb3+/SiO2[J].J Rare Earth,2011,29(12):1117-1122.
[26]Kong D Y,Wang Z L,LinC K,et al.Biofunctionalization of CeF3:Tb3+ Nanoparticles[J].Nanotechnology,2007,18(17):75601-75607.
[27]Vu Y H,Li Y,Zhao D,et al.Uniform YF3 nanorods:Synthesis,luminescent properties and cytotoxicity study[J].J Rare Earth,2011,29(11):1036-1039.
[28]Xiong L Q,Shen B,Behera D.Synthesis of ligand-functionalized water-soluble[18F]YF3 nanoparticles for PET imaging[J].Nanoscale,2013,5(8):3253-3256.
[29]Zhu L,Liu X M,Meng J,et al.Facile sonochemical synthesis of single-crystalline europium fluorine with novel nanostructure[J].Cryst Growth Des,2007,7(12):2505-2511.
[30]Safronikhin A,Shcherba T,Ehrlich H,et al Preparation and colloidal behaviour of surface-modified EuF3[J].Appl Sur Sci,2009(18),255:7990-7994.
[31]万垂铭,孟建新,邓小玲.ScF3的水热法制备及掺Ce3+光谱性质研究[J].稀土,2009,30(6):22-25.
[32]Feng B,Wang Y S,Cheng Y,et al.Self-assembly of mono-crystalline NdF3 nanostructures during hydrothermal process[J].Mater Lett,2006,60(3):389-392.
[33]Anees A,Ansari S P,Singh N,et al.Synthesis of optically active silica-coated NdF3 core–shell nanoparticles[J].Spectrochim Acta Part A,2012,86(4):432-436.
[34]Yu X F,Chen L D,Li M,et al.Highly efficient fluorescence of NdF3/SiO2 core/shell nanoparticles and the applications for in vivo NIR detection[J].Adv Mater,2008,20(21):4118-4123.
[35]Nyk M,Kumar R,Ohulchanskyy T Y,et al.High contrast in vitro and in vivo photoluminescence bioimaging using near infrared to near infrared up-conversion in Tm3+ and Yb3+doped fluoride nanophosphors[J].Nano Lett,2008,8(11):3834-3838.
[36]Zhou J,Sun Y,Du X X,et al.Dual-modality in vivo imaging using rare-earth nanocrystals with near-infrared to near-infrared(NIR-to-NIR)upconversion luminescence and magnetic resonance properties[J].Biomaterials,2010,31(12):3287-3295.
[37]Jiang S,Zhang Y,Lim K M,et al.NIR-to-visible upconversion nanoparticles for fluorescent labeling and targeted delivery of si RNA[J].Nanotechnology,2009,20(15):155101-155109.
[38]Wang M,Shi Y J,Jiang G Q,et al.Room temperature synthesis and characterization of different morphological TbF3 nano/microcrystals[J].Mater Lett,2011,65(12):1945-1948.
[39]Dong C H,Raudsepp M,Veggel C F V.Kinetically determined crystal structures of undoped and La3+-doped LnF3[J].J Phys Chem C,2009,113(1):472-478.
[40]Yi G S,Chow G M.Water-soluble NaYF4:Yb,Er(Tm)/NaYF4/polymer core/shell/shell nanoparticles with significant enhancement of upconversion fluorescence[J].Chem Mater,2007,19(3):341-343.
[41]Jian B Q,Qing J,Da C Z,Zheng W Y.Recent progress on upconversion luminescence enhancement in rare-earth doped transparent glass-ceramics[J].J Rare Earth,2016,34(4):341-367.
[42]Pushpal G,Rahul K S,Yogendra N C.Size of the rare-earth ions:a key factor in phase tuning and morphology control of binary and ternary rare-earth fluoride materials[J].RSC Advances,2017,7(53):33467-33476.
[43]Mai H X,Zhang Y W,Sun L D,et al.Size-and phase-controlled synthesis of monodisperse NaYF4:Yb,Er nanocrystals from a unique delayed nucleation pathway monitored with ipconversion spectroscopy[J].J Phys Chem C,2007,111(37):13730-13739.
[44]Chen Z G,Chen H L,Hu H,et al.Versatile synthesis strategy for carboxylic acid-functionalized upconverting nanophosphors as biological labels[J].J Am Chem Soc,2008,130(10):3023-3029.
[45]Wang F,Liu X G.Upconversion multicolor fine-tuning:visible to near-infrared emission from lanthanide-doped NaYF4 nanoparticles[J].J Am Chem Soc,2008,130(17):5642-5643.
[46]Zhou H P,Xu C H,Sun W,et al.Clean and flexible modification strategy for carboxyl/aldehyde-functionalized upconversion nanoparticles and their optical applications[J].Adv Funct Mater,2009,19(24):3892-3900.
[47]Gai S L,Yang P P,Li C X,et al.Synthesis of magnetic,up-conversion luminescent,and mesoporous core–shell-structured nanocomposites as drug carriers[J].Adv Funct Mater,2010,20(7):1-7.
[48]Cao T Y,Yang T S,Gao Y,et al.Water-soluble NaYF4:Yb/Er upconversion nanophosphors:synthesis,characteristics and application in bioimaging[J].Chem Commun,2010,13(3):392-394.
[49]Yu M X,Li F Y,Chen Z G,et al.Laser scanning up-conversion luminescence microscopy for imaging cells labeled with rare-earth nanophosphors[J].Anal Chem,2009,81(3):930-935.
[50]Idris N M,Li Z Q,Ye L,et al.Tracking transplanted cells in live animal using upconversion fluorescent nanoparticles[J].Biomaterials,2009,30(28):5104-5113.
[51]Rufaihah A J,Zhang Y.Biocompatibility of silica coated NaYF4 upconversion fluorescent nanocrystals[J].Biomaterials,2008,29(30):4122-4128.
[52]Xiong L Q,Chen Z G,Yu M X,et al.Synthesis,characterization,and in vivo targeted imaging of amine-functionalized rare-earth up-converting nanophosphors[J].Biomaterials,2009,30(29):5592-5600.
[53]Hu H,Yu M X,Li F Y,et al.Facile epoxidation strategy for producing amphiphilic up-converting rare-earth nanophosphors as biological labels[J].Chem Mater,2008,20(22):7003-7009.
[54]Wang M,Mi C C,Wang W X,et al.Immunolabeling and NIR-excited fluorescent imaging of HeLa cells by using NaYF4:Yb,Er upconversion nanoparticles[J].ACS Nano,2009,3(6):1580-1586.
[55]Misiak M,Str?k W,Arabasz S,et al.The effect of intentional potassium co-doping on the luminescent properties of Yb3+ and Tm3+doped α-NaYF4 core and core–shell nanoparticles[J].J Lumin,2016,178:34-42.
[56]Dong X B,You F T,Peng H S,et al.Ultraviolet to near-infrared energy transfer in NaYF4:Nd3+,Yb3+crystals[J].J Rare Earth,2016,34(9):863-867.
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