火焰燃料电池综述
摘要
火焰燃料电池是一种基于固体氧化物燃料电池的新型电池,他利用燃料的化学能和火焰的热量进行发电,具有清洁高效、结构简单和燃料来源广泛等优点,在能源转化、工业生产等领域有较好的应用前景。文中主要介绍了火焰燃料电池系统,并将他与传统的固体氧化物燃料电池作对比,详述其功能特性,同时还讨论了火焰燃料电池中阴极、阳极和电解质的材料的研究和利用情况,最后详细论述了几种燃料在电池电极表面的反应机理。
引文
[1]江义,李文钊,王世忠.高温固体氧化物燃料电池(SOFC)进展[J].化学进展,1997,(4):387-396.
[2]张中太,黄传勇.固体氧化物燃料电池的研究进展[J].稀有金属材料与工程,2005,34(8):2-9.
[3]BOSSCHE M V D,MCINTOSH S.Direct Hydrocarbon Solid Oxide Fuel Cells[J].Chemical Reviews,2004,35(50):4845-4865.
[4]POMFRET M B.MARDA J,JACKSON G S,et al.Hydrocarbon Fuels in Solid Oxide Fuel Cells:In Situ Raman Studies of Graphite Formation and Oxidation[J].The Journal of Physical Chemistry C,2008,112(13):5232-5240.
[5]SHAO Zongping,CHAN K,HAILE S M.Anode-supported thin-film fuel cells operated in a single chamber configuration 2T-I-12[J].Solid State Ionics,2004,175(1):39-46.
[6]KRONEMAYER H,BARZAN D,Horiuchi M,et al.A direct-flame solid oxide fuel cell(DFFC)operated on methane,propane,and butane[J].Journal of Power Sources,2007,166(1):120-126.
[7]WANG Yuqing,SHI Yixiang,NI Meng,,et al.A micro tri-generation system based on direct flame fuel cells for residential applications[J].International Journal of Hydrogen Energy,2014,39(11):5996-6005.
[8]ZHU Xingbao,WEI Bo,LU Zhe,et al.A direct flame solid oxide fuel cell for potential combined heat and power generation[J].International Journal of Hydrogen Energy,2012,37(10):8621-8629.
[9]WANG Yuguang,SUN Liangliang,LUO Linghong,et al.The study of portable direct-flame solid oxide fuel cell(DF-SOFC)stack with butane fuel[J].Journal of Fuel Chemistry&Technology,2014,42(9):1135-1139.
[10]王雨晴,史翊翔,余先恺,等.直接火焰燃料电池热应力分析及性能研究[J].燃烧科学与技术,2014,20(3):238-244.
[11]ITOH H,MORI M,MORI N,et al.Production cost estimation of solid oxide fuelcells[J].Journal of Power Sources,1994,49(1-3):315-332.
[12]王康.一种高性能火焰燃料电池的研究[D].南京:南京工业大学,2008:10-48.
[13]EYRAUD C,LENOIR J,GERY M.Fuel cells utilizing the electrochemicalproperties ofabsorbates[J].Compt Rend,1961,252(1):599-1.
[14]陈胜洲,董新法,林维明.单室固体氧化物燃料电池的研究进展[J].电源技术,2003,27(2):134-136.
[15]GUO Youmin,BESSAA M,AGUADO S,et al An all porous solid oxide fuel cell(SOFC):a bridging technology between dual and single chamber SOFCs[J].Energy&Environmental Science,2013,6(7):2119-2123.
[16]JACQUES BEDARD X,NAPPORN T W,ROBERGE R,et al.Performance and ageing of an anode-supported SOFC operated in single-chamber conditions[J].Journal of Power Sources,2006,153(1):108-113.
[17]艾刚.单气室固体氧化物燃料电池性能的研究[D].哈尔滨:哈尔滨工业大学,2006:1-65.
[18]吕喆,魏波,田彦婷,等,单气室固体氧化物燃料电池关键材料与微堆系统[J].化学进展,2011,23(z1):449-462.
[19]DYER C K.A novel thin-film electrochemical device for energy conversionCuO[J].Nature,1990,343(6258):547-548.
[20]IWAHARA H.A one-chamber solid electrolyte fuel cell for chemical cogeneration[J].Ionics,1998,4(5):409-414.
[21]JASINSKI P Z,SUZUKI T,BYARS Z,et al.Comparison of anode and electrolyte support configuration of single chamber solid oxide fuel cell[J].2003,(7):1101-1108.
[22]HORIUCHI M,SUGANUMA S,WATANABE M.Electrochemical Power Generation Directly from Combustion Flame of Gases,Liquids,and Solids[J].Journal of the Electrochemical Society,2004,151(9):A1402-A1405.
[23]SUN Liangliang,HAO Yong,ZHANG Chunming,et al.Coking-free direct-methanol-flame fuel cell with traditional nickel cermet anode[J].International Journal ofHydrogen Energy,2010,35(15):7971-7981.
[24]HORICHI M,KATAGIRI F,YOSHIIKE J,et al.Performance of a solid oxide fuelcell couple operated via in situ catalytic partial oxidation of n-butane[J].Joumal of Power Sources,2009,189(2):950-957.
[25]韩敏芳.固体氧化物燃料电池材料及制备[M].北京:中国科学出版社,2004.
[26]黄贤良,赵海雷,吴卫江,等.固体氧化物燃料电池阳极材料的研究进展[J].硅酸盐学报,2005,3(11):1407-1413.
[27]BIEBERLE A,GAUCKLER L J.Reaction mechanism of Ni pattern anodes for solid oxide fuel cells[J].Solid State Ionics,2000,135(1-4):337-345.
[28]王其艮.YSZ粉体的制备与表征及其在燃料电池中的应用[D].合肥:中国科学技术大学,2007:4.
[29]WANG Shizhong,JIANG Yi,ZHANG Yahong,et al.Electrochemical performance of mixed ionic electronic conducting oxides as anodes for solid oxide fuel cell[J].Solid State Ionics,1999,120(1-4):75-84.
[30]CHEN Min,KIM B H,XU Qing,et al.Synthesis and perfor mances of Ni SDC cermets for IT-SOFC anode[J].Journal of the European Ceramic Society,2008,28(15):2947-2953.
[31]MARINA O A,BAGGER C,PRIMDAHL S,et al.A solid oxide fuel cell with a gadolinia-doped ceria anode:preparation and performance[J].Solid State Ionics,1999,123(1-4):199-208.
[32]TAO Shanwen,IRVINE J T.A redox-stable efficient anode for solid-oxide fuelcells[J].Nature Materials,2003,2(5):320-323.
[33]郑尧,周嵬,冉然,等.钙钛矿型固体氧化物燃料电池阳极材料[J].化学进展,2008,20(z1):413-421.
[34]SHAO Zongping,HAILE S M.A high-performance cathode for the next generationof solid-oxide fuel cells[J].Cheminform,2004,35(47):170-173.
[35]张士军,魏亦军.固体氧化物燃料电池的研究进展[J].淮南师范学院学报,2006,8(3):53-56.
[36]孙帆,郑勇,高小龙,等.固体氧化物燃料电池电解质和电极材料的研究进展[J].金属功能材料,2010,17(4):75-80.
[37]JIANG Sanping.Issue on Development of(La,Sr)MnO3 cathode for Solid Oxide Fuel Cell[J].Journal of Power Sources,2003,124(2):390-402.
[38]SHAO Zonping,HAILE S M,AHN J,et al.A thermally self-sustained micro solid-oxide fuel-cell stack with high power density[J].Nature,2005,435(7043):795.
[39]KIM S G,YOON S P,NAM S W,et al.Fabrication and characterization of a YSZ/YDC composite electrolyte by a sol-gel coating method[J].Journal of Power Sources,2002,110(1):222-228.
[40]于兴文,黄学杰,陈立泉.固体氧化物燃料电池研究进展[J].电池,2002,32(2):110-112.
[41]梁广川,刘文西.复合掺杂CeO2基电解质性能与烧结温度关系[J].河北工业大学学报,1999,(5):41-44.
[42]HARTMANOVA M,GMUCOVA K,JERGEL M,et al.Structural and electrical properties of double-layer ceria/yttria stabilized zirconia deposited on silicon substrate[J].Solid State Ionics,1999,119(1):85-90.
[43]赵兵,卢立柱.中低温固体氧化物燃料电池(SOFC)电解质材料[J].稀土,1998,(4):55-61.
[44]李京萍,刘世友.燃料电池的开发与展望[J].中国能源,1999,(6):39-41.
[45]ISHIHARA T,MATSUDA H,TAKITA Y.Doped LaGa03 perovskite type oxide as a new oxide ionic conductor[J].Journal of the American chemical society,1994,116(9):3801-3803.
[46]孙杰,吴锋,邱新平,et al.燃料电池的氢源技术——乙醇重整制氢研究进展[J].电源技术,2004,28(7):452-457.
[47]ZHAN Zhongling,BARNETT S A.An octane-fueled solid oxide fuel cell[J].Science,2005,308(5723):844-847.
[2]张中太,黄传勇.固体氧化物燃料电池的研究进展[J].稀有金属材料与工程,2005,34(8):2-9.
[3]BOSSCHE M V D,MCINTOSH S.Direct Hydrocarbon Solid Oxide Fuel Cells[J].Chemical Reviews,2004,35(50):4845-4865.
[4]POMFRET M B.MARDA J,JACKSON G S,et al.Hydrocarbon Fuels in Solid Oxide Fuel Cells:In Situ Raman Studies of Graphite Formation and Oxidation[J].The Journal of Physical Chemistry C,2008,112(13):5232-5240.
[5]SHAO Zongping,CHAN K,HAILE S M.Anode-supported thin-film fuel cells operated in a single chamber configuration 2T-I-12[J].Solid State Ionics,2004,175(1):39-46.
[6]KRONEMAYER H,BARZAN D,Horiuchi M,et al.A direct-flame solid oxide fuel cell(DFFC)operated on methane,propane,and butane[J].Journal of Power Sources,2007,166(1):120-126.
[7]WANG Yuqing,SHI Yixiang,NI Meng,,et al.A micro tri-generation system based on direct flame fuel cells for residential applications[J].International Journal of Hydrogen Energy,2014,39(11):5996-6005.
[8]ZHU Xingbao,WEI Bo,LU Zhe,et al.A direct flame solid oxide fuel cell for potential combined heat and power generation[J].International Journal of Hydrogen Energy,2012,37(10):8621-8629.
[9]WANG Yuguang,SUN Liangliang,LUO Linghong,et al.The study of portable direct-flame solid oxide fuel cell(DF-SOFC)stack with butane fuel[J].Journal of Fuel Chemistry&Technology,2014,42(9):1135-1139.
[10]王雨晴,史翊翔,余先恺,等.直接火焰燃料电池热应力分析及性能研究[J].燃烧科学与技术,2014,20(3):238-244.
[11]ITOH H,MORI M,MORI N,et al.Production cost estimation of solid oxide fuelcells[J].Journal of Power Sources,1994,49(1-3):315-332.
[12]王康.一种高性能火焰燃料电池的研究[D].南京:南京工业大学,2008:10-48.
[13]EYRAUD C,LENOIR J,GERY M.Fuel cells utilizing the electrochemicalproperties ofabsorbates[J].Compt Rend,1961,252(1):599-1.
[14]陈胜洲,董新法,林维明.单室固体氧化物燃料电池的研究进展[J].电源技术,2003,27(2):134-136.
[15]GUO Youmin,BESSAA M,AGUADO S,et al An all porous solid oxide fuel cell(SOFC):a bridging technology between dual and single chamber SOFCs[J].Energy&Environmental Science,2013,6(7):2119-2123.
[16]JACQUES BEDARD X,NAPPORN T W,ROBERGE R,et al.Performance and ageing of an anode-supported SOFC operated in single-chamber conditions[J].Journal of Power Sources,2006,153(1):108-113.
[17]艾刚.单气室固体氧化物燃料电池性能的研究[D].哈尔滨:哈尔滨工业大学,2006:1-65.
[18]吕喆,魏波,田彦婷,等,单气室固体氧化物燃料电池关键材料与微堆系统[J].化学进展,2011,23(z1):449-462.
[19]DYER C K.A novel thin-film electrochemical device for energy conversionCuO[J].Nature,1990,343(6258):547-548.
[20]IWAHARA H.A one-chamber solid electrolyte fuel cell for chemical cogeneration[J].Ionics,1998,4(5):409-414.
[21]JASINSKI P Z,SUZUKI T,BYARS Z,et al.Comparison of anode and electrolyte support configuration of single chamber solid oxide fuel cell[J].2003,(7):1101-1108.
[22]HORIUCHI M,SUGANUMA S,WATANABE M.Electrochemical Power Generation Directly from Combustion Flame of Gases,Liquids,and Solids[J].Journal of the Electrochemical Society,2004,151(9):A1402-A1405.
[23]SUN Liangliang,HAO Yong,ZHANG Chunming,et al.Coking-free direct-methanol-flame fuel cell with traditional nickel cermet anode[J].International Journal ofHydrogen Energy,2010,35(15):7971-7981.
[24]HORICHI M,KATAGIRI F,YOSHIIKE J,et al.Performance of a solid oxide fuelcell couple operated via in situ catalytic partial oxidation of n-butane[J].Joumal of Power Sources,2009,189(2):950-957.
[25]韩敏芳.固体氧化物燃料电池材料及制备[M].北京:中国科学出版社,2004.
[26]黄贤良,赵海雷,吴卫江,等.固体氧化物燃料电池阳极材料的研究进展[J].硅酸盐学报,2005,3(11):1407-1413.
[27]BIEBERLE A,GAUCKLER L J.Reaction mechanism of Ni pattern anodes for solid oxide fuel cells[J].Solid State Ionics,2000,135(1-4):337-345.
[28]王其艮.YSZ粉体的制备与表征及其在燃料电池中的应用[D].合肥:中国科学技术大学,2007:4.
[29]WANG Shizhong,JIANG Yi,ZHANG Yahong,et al.Electrochemical performance of mixed ionic electronic conducting oxides as anodes for solid oxide fuel cell[J].Solid State Ionics,1999,120(1-4):75-84.
[30]CHEN Min,KIM B H,XU Qing,et al.Synthesis and perfor mances of Ni SDC cermets for IT-SOFC anode[J].Journal of the European Ceramic Society,2008,28(15):2947-2953.
[31]MARINA O A,BAGGER C,PRIMDAHL S,et al.A solid oxide fuel cell with a gadolinia-doped ceria anode:preparation and performance[J].Solid State Ionics,1999,123(1-4):199-208.
[32]TAO Shanwen,IRVINE J T.A redox-stable efficient anode for solid-oxide fuelcells[J].Nature Materials,2003,2(5):320-323.
[33]郑尧,周嵬,冉然,等.钙钛矿型固体氧化物燃料电池阳极材料[J].化学进展,2008,20(z1):413-421.
[34]SHAO Zongping,HAILE S M.A high-performance cathode for the next generationof solid-oxide fuel cells[J].Cheminform,2004,35(47):170-173.
[35]张士军,魏亦军.固体氧化物燃料电池的研究进展[J].淮南师范学院学报,2006,8(3):53-56.
[36]孙帆,郑勇,高小龙,等.固体氧化物燃料电池电解质和电极材料的研究进展[J].金属功能材料,2010,17(4):75-80.
[37]JIANG Sanping.Issue on Development of(La,Sr)MnO3 cathode for Solid Oxide Fuel Cell[J].Journal of Power Sources,2003,124(2):390-402.
[38]SHAO Zonping,HAILE S M,AHN J,et al.A thermally self-sustained micro solid-oxide fuel-cell stack with high power density[J].Nature,2005,435(7043):795.
[39]KIM S G,YOON S P,NAM S W,et al.Fabrication and characterization of a YSZ/YDC composite electrolyte by a sol-gel coating method[J].Journal of Power Sources,2002,110(1):222-228.
[40]于兴文,黄学杰,陈立泉.固体氧化物燃料电池研究进展[J].电池,2002,32(2):110-112.
[41]梁广川,刘文西.复合掺杂CeO2基电解质性能与烧结温度关系[J].河北工业大学学报,1999,(5):41-44.
[42]HARTMANOVA M,GMUCOVA K,JERGEL M,et al.Structural and electrical properties of double-layer ceria/yttria stabilized zirconia deposited on silicon substrate[J].Solid State Ionics,1999,119(1):85-90.
[43]赵兵,卢立柱.中低温固体氧化物燃料电池(SOFC)电解质材料[J].稀土,1998,(4):55-61.
[44]李京萍,刘世友.燃料电池的开发与展望[J].中国能源,1999,(6):39-41.
[45]ISHIHARA T,MATSUDA H,TAKITA Y.Doped LaGa03 perovskite type oxide as a new oxide ionic conductor[J].Journal of the American chemical society,1994,116(9):3801-3803.
[46]孙杰,吴锋,邱新平,et al.燃料电池的氢源技术——乙醇重整制氢研究进展[J].电源技术,2004,28(7):452-457.
[47]ZHAN Zhongling,BARNETT S A.An octane-fueled solid oxide fuel cell[J].Science,2005,308(5723):844-847.