石墨烯及其衍生物/金纳米粒子复合材料的表面增强拉曼散射研究进展
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摘要
由于石墨烯及其衍生物/金纳米粒子复合材料可以产生剧烈的表面增强性拉曼散射(SERS),因而被广泛应用到医学检验、环境监测和生物化学等领域。基于这种新型的复合材料,首先从复合材料SERS的增强机制出发,系统介绍了其电磁场增强机制和化学增强机制。随后,阐述了基于石墨烯及其衍生物/金纳米粒子复合材料的国内外SERS研究现状。最后,展望了石墨烯及其衍生物/金纳米粒子复合材料在各个领域的应用前景。
Due to the graphene and its derivatives/gold nanoparticles hybrid material can produce severe surface enhanced raman scattering(SERS),therefore it is widely applied to medical examination,environment monitoring,biological,chemical and other fields.Based on these new materials,firstly from the angle of SERS enhancement mechanism,systematically introduced the electromagnetic enhancement mechanism and chemical enhancement mechanism.Then SERS study status was elaborated based on graphene and its derivatives/gold nanoparticle hybrid material at home and abroad.Finally,the application prospect for the grapheme and its derivatives/gold nanoparticles composite SERS material in various fields was discussed.
Due to the graphene and its derivatives/gold nanoparticles hybrid material can produce severe surface enhanced raman scattering(SERS),therefore it is widely applied to medical examination,environment monitoring,biological,chemical and other fields.Based on these new materials,firstly from the angle of SERS enhancement mechanism,systematically introduced the electromagnetic enhancement mechanism and chemical enhancement mechanism.Then SERS study status was elaborated based on graphene and its derivatives/gold nanoparticle hybrid material at home and abroad.Finally,the application prospect for the grapheme and its derivatives/gold nanoparticles composite SERS material in various fields was discussed.
引文
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[2]Lin D,Qin T,Wang Y,et al.Graphene oxide wrapped SERStags:multifunctional platforms toward optical labeling,photothermal ablation of bacteria,and the monitoring of killing effect[J].Acs Applied Materials&Interfaces,2013,6(2):1320.
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[4]Zhao Y,Li X,Du Y,et al.Strong light-matter interactions in sub-nanometer gaps defined by monolayer graphene:toward highly sensitive SERS substrates[J].Nanoscale,2014,6(19):11112.
[5]Osvath Z,Deak A,Kertész K,et al.The structure and properties of graphene on gold nanoparticles[J].Nanoscale,2015,7(12):5503.
[6]Du Y,Zhao Y,Qu Y,et al.Enhanced light-matter interaction of graphene-gold nanoparticle hybrid films for high-performance SERS detection[J].Journal of Materials Chemistry C,2014,2(23):4683-4691.
[7]Jeanmaire D L,Duyne R P V.Surface raman spectroelectro chemistry;part 1.heterocyclic,aromatic,and aliphatic amines adsorbed on the anodized silver electrode[J].Electroanal Chem,1977,84(1):1-20.
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[9]Moskovits M J.Surface enhanced raman spectroscopy:a brief retrospective[J].Raman Spectrosc,2005,36(6-7):485-496.
[10]Li J W,Bai Y,Mo Y J,et al.Calculation of the SERS enhancement factors of pyridine molecules adsorbed on the substrates of Fe,Co and Ni using antenna resonace model[J].Spectroscpy and Spetral Analysis,2006,8(3):463-466.
[11]Kong X,Chen Q.A positive influence on the SERS of borondoped graphene with pyridine as a probe molecule:a density functional theory study[J].Journal of Materials Chemistry,2012,22(30):15336-15341.
[12]Xia L,Chen M,Zhao X,et al.Visualized method of chemical enhancement mechanism on SERS and TERS[J].Journal of Raman Spectroscopy,2014,45(7):533-540.
[13]Morton S M,Ewusiannan E,Jensen L.Controlling the nonresonant chemical mechanism of SERS using a molecular photoswitch[J].Physical Chemistry Chemical Physics,2009,11(34):7424-7429.
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[15]Ling X,Xie L,Fang Y,et al.Can graphene be used as a substrate for raman enhancement[J].Nano Letters,2010,10(2):553.
[16]Goncalves G,Marques P A A P,Granadeiro C M,et al.Surface modification of graphene nanosheets with gold nanoparticles:the role of oxygen moieties at graphene surface on gold nucleation and growth[J].Chemistry of Materials,2009,21:4796-4802.
[17]Lu R,Konzelmann A,Xu F,et al.High sensitivity surface enhanced raman spectroscopy of R6Gon in situ fabricated Au nanoparticle/graphene plasmonic substrates[J].Carbon,2015,86:78-85.
[18]Chen H,Shao L,Ming T,et al.Observation of the Fano resonance in gold nanorods supported on high-dielectric-constant substrates[J].Acs Nano,2011,5(8):6754-63.
[19]Kanchanapally R,Sinha S S,Fan Z,et al.Graphene oxide-gold nanocage hybrid platform for trace level identification of nitro explosives using a raman fingerprint[J].Journal of Physical Chemistry C,2014,118(13):7070-7075.
[20]Wang Y,Polavarapu L,Liz-Marzan L M.Reduced graphene oxide-supported gold nanostars for improved SERS sensing and drug delivery[J].Acs Applied Materials&Interfaces,2014,6(24):21798-805.
[21]Wang P,Xia M,Liang O,et al.Label-free SERS selective detection of dopamine and serotonin using graphene-Au nanopyramid heterostructure[J].Analytical Chemistry,2015,87(20):10255.
[22]Lee S,Kumar P,Hu Y,et al.Graphene laminated gold bipyramids as sensitive detection platforms of antibiotic molecules[J].Chemical Communications,2015,51(85):15494-15497.
[23]Cao X,Yan S,Cheng Y,et al.Cysteine-modified graphene/gold nanorod composites toward rhodamine 6Gdetection by surface-enhanced raman scattering[J].Journal of Nanoscience&Nanotechnology,2016,16(7):6697-6704.
[24]El Amri C,Maurel M.Adenine adsorption on and release from meteorite specimens assessed by surface-enhanced raman spectroscopy[J].Journal of Raman Spectroscopy,2004,35(2):170-177.
[25]Luo Y,Ma L,Zhang X,et al.SERS detection of dopamine using label-free acridine red as molecular probe in reduced graphene oxide/silver nanotriangle sol substrate[J].Nanoscale Research Letters,2015,10(1):230.
[26]Chettri P,Vendamani V S,Tripathi A,et al.Green synthesis of silver nanoparticle-reduced graphene oxide using pPsidium guajava,and its application in SERS for the detection of methylene blue[J].Applied Surface Science,2017,406:312-318.
[2]Lin D,Qin T,Wang Y,et al.Graphene oxide wrapped SERStags:multifunctional platforms toward optical labeling,photothermal ablation of bacteria,and the monitoring of killing effect[J].Acs Applied Materials&Interfaces,2013,6(2):1320.
[3]Qin Y,Li J,Kong Y,et al.In situ growth of Au nanocrystals on graphene oxide sheets[J].Nanoscale,2013,6(3):1281-1285.
[4]Zhao Y,Li X,Du Y,et al.Strong light-matter interactions in sub-nanometer gaps defined by monolayer graphene:toward highly sensitive SERS substrates[J].Nanoscale,2014,6(19):11112.
[5]Osvath Z,Deak A,Kertész K,et al.The structure and properties of graphene on gold nanoparticles[J].Nanoscale,2015,7(12):5503.
[6]Du Y,Zhao Y,Qu Y,et al.Enhanced light-matter interaction of graphene-gold nanoparticle hybrid films for high-performance SERS detection[J].Journal of Materials Chemistry C,2014,2(23):4683-4691.
[7]Jeanmaire D L,Duyne R P V.Surface raman spectroelectro chemistry;part 1.heterocyclic,aromatic,and aliphatic amines adsorbed on the anodized silver electrode[J].Electroanal Chem,1977,84(1):1-20.
[8]Boyack R,Le R E.Investigation of particle shape and size effects in SERS using T-matrix calculations[J].Physical Chemistry Chemical Physics,2009,11(34):7398-7405.
[9]Moskovits M J.Surface enhanced raman spectroscopy:a brief retrospective[J].Raman Spectrosc,2005,36(6-7):485-496.
[10]Li J W,Bai Y,Mo Y J,et al.Calculation of the SERS enhancement factors of pyridine molecules adsorbed on the substrates of Fe,Co and Ni using antenna resonace model[J].Spectroscpy and Spetral Analysis,2006,8(3):463-466.
[11]Kong X,Chen Q.A positive influence on the SERS of borondoped graphene with pyridine as a probe molecule:a density functional theory study[J].Journal of Materials Chemistry,2012,22(30):15336-15341.
[12]Xia L,Chen M,Zhao X,et al.Visualized method of chemical enhancement mechanism on SERS and TERS[J].Journal of Raman Spectroscopy,2014,45(7):533-540.
[13]Morton S M,Ewusiannan E,Jensen L.Controlling the nonresonant chemical mechanism of SERS using a molecular photoswitch[J].Physical Chemistry Chemical Physics,2009,11(34):7424-7429.
[14]Arenas J F,Fernandez D J,Soto J,et al.Role of the electrode potential in the charge-transfer mechanism of surface-enhanced Raman scattering[J].Journal of Physical Chemistry B,2008,107(47):13143-13149.
[15]Ling X,Xie L,Fang Y,et al.Can graphene be used as a substrate for raman enhancement[J].Nano Letters,2010,10(2):553.
[16]Goncalves G,Marques P A A P,Granadeiro C M,et al.Surface modification of graphene nanosheets with gold nanoparticles:the role of oxygen moieties at graphene surface on gold nucleation and growth[J].Chemistry of Materials,2009,21:4796-4802.
[17]Lu R,Konzelmann A,Xu F,et al.High sensitivity surface enhanced raman spectroscopy of R6Gon in situ fabricated Au nanoparticle/graphene plasmonic substrates[J].Carbon,2015,86:78-85.
[18]Chen H,Shao L,Ming T,et al.Observation of the Fano resonance in gold nanorods supported on high-dielectric-constant substrates[J].Acs Nano,2011,5(8):6754-63.
[19]Kanchanapally R,Sinha S S,Fan Z,et al.Graphene oxide-gold nanocage hybrid platform for trace level identification of nitro explosives using a raman fingerprint[J].Journal of Physical Chemistry C,2014,118(13):7070-7075.
[20]Wang Y,Polavarapu L,Liz-Marzan L M.Reduced graphene oxide-supported gold nanostars for improved SERS sensing and drug delivery[J].Acs Applied Materials&Interfaces,2014,6(24):21798-805.
[21]Wang P,Xia M,Liang O,et al.Label-free SERS selective detection of dopamine and serotonin using graphene-Au nanopyramid heterostructure[J].Analytical Chemistry,2015,87(20):10255.
[22]Lee S,Kumar P,Hu Y,et al.Graphene laminated gold bipyramids as sensitive detection platforms of antibiotic molecules[J].Chemical Communications,2015,51(85):15494-15497.
[23]Cao X,Yan S,Cheng Y,et al.Cysteine-modified graphene/gold nanorod composites toward rhodamine 6Gdetection by surface-enhanced raman scattering[J].Journal of Nanoscience&Nanotechnology,2016,16(7):6697-6704.
[24]El Amri C,Maurel M.Adenine adsorption on and release from meteorite specimens assessed by surface-enhanced raman spectroscopy[J].Journal of Raman Spectroscopy,2004,35(2):170-177.
[25]Luo Y,Ma L,Zhang X,et al.SERS detection of dopamine using label-free acridine red as molecular probe in reduced graphene oxide/silver nanotriangle sol substrate[J].Nanoscale Research Letters,2015,10(1):230.
[26]Chettri P,Vendamani V S,Tripathi A,et al.Green synthesis of silver nanoparticle-reduced graphene oxide using pPsidium guajava,and its application in SERS for the detection of methylene blue[J].Applied Surface Science,2017,406:312-318.