Ba-Gd(Y)-O三元体系荧光材料制备研究进展
|
摘要
总结Ba-Gd(Y)-O三元体系荧光材料的组成结构及发光机理,简要概述高温固相法、自蔓延合成法、沉淀法、溶胶-凝胶法、水热法以及气相法等在制备Ba-Gd(Y)-O体系荧光材料中的应用,分析各自在制备基质化合物过程中的优、缺点以及对荧光材料应用性能的影响,为研究更高性能的新型稀土荧光材料提出明确方向。
The structure and luminescence mechanism of fluorescent materials in Ba-Gd(Y)-O system were summarized.The different methods,such as high temperature solid state,self-propagating synthesis,precipitation,sol-gel,hydrothermal method and gas phase method,used in the preparation of fluorescent materials in Ba-Gd(Y)-O system were briefly introduced,and the advantages and disadvantages of each method in preparing process of the basic compound and influences on the application performance of fluorescent materials were discussed,which provided a clear direction for the research of new fluorescent materials with better performance in the future.
The structure and luminescence mechanism of fluorescent materials in Ba-Gd(Y)-O system were summarized.The different methods,such as high temperature solid state,self-propagating synthesis,precipitation,sol-gel,hydrothermal method and gas phase method,used in the preparation of fluorescent materials in Ba-Gd(Y)-O system were briefly introduced,and the advantages and disadvantages of each method in preparing process of the basic compound and influences on the application performance of fluorescent materials were discussed,which provided a clear direction for the research of new fluorescent materials with better performance in the future.
引文
[1]李金凯,滕鑫,段广彬,等.石榴石基荧光材料研究进展[J].济南大学学报(自然科学版),2015,29(1):69-74.
[2] POTDEVIN A,CHADEYRON G,BOYER D,et al. Optical properties upon vacuum ultraviolet excitation of sol-gel based Y3Al5O12:Tb3+,Ce3+powders[J]. J Appl Phys,2007,102(7):073536. 1-073536. 6.
[3] LI J K,LI J G,ZHANG Z,et al. Gadolinium aluminate garnet(Gd3Al5O12):crystal structure stabilization via lutetium doping and properties of the(Gd1-xLux)3Al5O12(x=0~0. 5)solid solutions[J]. J Am Ceram Soc,2012,95(3):931-936.
[4] LI J K,TENG X,WANG W Z,et al. Investigation on the preparation and luminescence property of(Gd1-xDyx)2O3,(x=0. 01~0. 10)spherical phosphors[J]. Ceram Int,2017,43(13):10166-10173.
[5]李金凯.钆铝石榴石(Gd3Al5O12)的晶格稳定化及其新型发光材料[D].沈阳:东北大学,2014.
[6] LI J K,TENG X,CAO B Q,et al. Synthesis and property of spherical Lu3Al5O12:Eu3+phosphor[J]. J Inorg Mater,2016,31(6):634-640.
[7]张培善.中国稀土矿物学[M].北京:科学出版社,1998.
[8]张希艳.稀土发光材料[M].北京:国防工业出版社,2005.
[9]赵瑾.稀土掺杂下转换发光材料的光谱调制和能量传递研究[D].西安:西北大学,2016.
[10]李建宇.稀土发光材料及其应用[M].北京:化学工业出版社,2003.
[11]吴凌远.稀土掺杂红外下转换材料研究[D].合肥:中国科学技术大学,2013.
[12]熊光楠,徐力,刘俊英,等.高能量激发的发光材料[J].中国稀土学报,2001,19(6):494-497.
[13] KARUNADASA H,HUANG Q,UELAND B G,et al. Honeycombs of triangles and magnetic frustration in Sr L2O4(L=Gd,Dy,Ho,Er,Tm,and Yb)[J]. Phys Rev:B,2005,71(71):144414.
[14]宋春艳.核壳结构掺杂Zn S纳米颗粒团簇的制备与光谱学性能研究[D].杭州:浙江大学,2014.
[15] AUZEL F. Multiphonon-assisted anti-Stokes and Stokes fluorescence of triply ionized rare-earth ions[J]. J Lumin,1976,12/13(7):715-722.
[16] MASSAROTTI V,CAPSONI D,BINI M,et al. X-ray diffraction study of poly crystalline Y2BaO4:a test of the new EXPO program[J]. Z Kristallogr,1999,214(4):200-204.
[17] MULLERBUSCHBAUM H,WITZMANN H. The fluorescence of rare earths:I. emission spectra of samarium in phosphors based on borate compounds of group II elements[J]. Opt Spectry,1965,18(9):432-449.
[18] ALLEN I C,LOUIS G. Co-precipitation in some binary sulphate systems[J]. Talanta,1961,2(7):195-211.
[19] SKOLIS Y Y,PASHIN S F. The thermodynamic properties of BaY2O4[J]. Russ J Phys Chem,2001,75(11):1780-1783.
[20] COSTA G A,FERRETTI M,FORNASINI M L,et al. The crystal structure of BaY2O4,isotypic with SrY2O4[J]. Powder Diffraction,1989,4(1):24-25.
[21] ISHIHARA T,GOTO K. Direct decomposition of NO over BaO/Y2O3,catalyst[J]. Catal Today,2011,164(1):484-488.
[22]车广灿,梁敬魁,陈维,等. BaO-Y2O3(La2O3)-CuO三元系相图的研究[J].科学通报,1988(1):57-69.
[23] LIANG S,SEO H J. Site-occupation and crystal-field splitting of Eu3+in BaY2O4with calcium-ferrite structure[J]. J Electro Chem Soc,2011,158(12):399-404.
[24] MAEKAWA T,KUROSAKI K,YAMANAKA S. Thermophysical properties of BaY2O4:a new candidate material for thermal barrier coatings[J]. Mater Lett,2007,61(11):2303-2306.
[25] KALE G M,JACOB K T. Phase relations and thermodynamic properties of compounds in the pseudobinary system BaO-Y2O3[J]. Solid State Ionics,1989,34(4):247-252.
[26] VAHLAS C,BESMANN T M. Thermodynamics of the Y-Ba-Cu-C-O-H System:application to the organometallic chemical vapor deposition of the YBa2Cu3O7-xphase[J]. J Am Ceram Soc,1992,75(10):2679-2686.
[27] WONG-NG W,ROTH R S,SWARTZENDRUBER L J,et al.X-ray powder characterization of Ba2YCu3O7-x[J]. Adv Ceram Mater,1987,38(2):565-576.
[28] SZYMANIK B,BUCKLEY R G,TRODAHL H J,et al. Structure and decomposition of ceramic Ba3Y4O9[J]. Solid State Ionics,1998,109(3/4):223-228.
[29] BOBYLEV I B,ZYUZEVA N A,DEGTYAREV M V,et al.Effect of plastic deformation on the electrophysical properties and structure of YBa2Cu3Oy ceramics subjected to low-temperature treatment[J]. Phys Met Metallogr,2015,116(12):1213-1220.
[30] LI J Y,PANG R,YU Z,et al. Preparation and luminescence properties of orange-red Ba3Y4O9:Sm3+phosphors[J]. J Rare Earth,2018,36(7):680-684.
[31] ABBATTISTA F,VALLINO M,MAZZA D. Comprehensive review of the BaO-Y2O3-CuO-O phase diagram[J]. Mater Chem Phys,1989,21(5):521-528.
[32] ZHANG W,Osamura K. Phase-equilibrium in Y-Ba-O system[J]. Mater Trans,1991,32(11):1048-1052.
[33] LIN C M,HU R M,CHEN G Y,et al. Thermodynamic reassessment of BaO-YO1. 5system[C]//TMS 2015 144th Annual Meeting&Exhibition.[S. l.]:Springer International Publishing,2015:123-130.
[34] WARNER D A,RIMAN R E. Role of intermediate phase formation in the preparation of Ba4Y2O7·CO2[J]. Chem Mater,1992,4(1):197-204.
[35] ZHOU L,SHI J,GONG M. Synthesis and luminescent properties of BaGd2O4:Eu phosphor[J]. J Phys Chem Solids,2007,68(8):1471-1475.
[36] WU L T Y. Synthesis and luminescent properties of red phosphor BaY2O4:Eu3+for white light-emitting diodes[J]. Adv Mater Res,2013,811:181-185.
[37] LI K,LIAN H,SHANG M,et al. A novel greenish yelloworange red Ba3Y4O9:Bi3+,Eu3+phosphor with efficient energy transfer for UV-LEDs.[J]. Dalton T,2015,44(47):20542-20550.
[38] LAWRENCE P C,WINNIE W N,JULIA S. DTA/TGA study of eutectic melting in the system BaF2-BaO-Y2O3-CuOx-H2O[J]. Mater Proc,2000,659:481-486.
[39]王雪俊,夏海平. Bi离子掺杂Ge O2-Al2O3-M(M=Na2O,BaO,Y2O3)玻璃的光学性质[J].物理学报,2006,55(10):5263-5267.
[40]吴玉胜,李明春.功能陶瓷材料及制备工艺[M].北京:化学工业出版社,2013.
[41]闻雷,孙旭东,马伟民.固相反应法制备YAG透明陶瓷[J].硅酸盐学报,2003,31(9):295-301.
[42]姜洪义,徐博.高温固相法制备硅酸盐长余辉发光材料[J].硅酸盐学报,2006,34(9):1154-1157.
[43] XU H W,WANG L L,SHI Y S,et al. Color-tunable emission by cation substitution in Ba3-ySryY4O9:Bi3+and sites occupation preference[J]. Mater Res Bull,2018,102:8-15.
[44]周传仓,卢忠远,王兵,等.高温固相法制备Zn P:Zn荧光粉的研究[J].化工新型材料,2005,33(1):30-32.
[45]张少卿.自蔓延高温合成——无机材料制造新技术[J].材料工程,1993(7):41-44.
[46]宋桂明,周玉,白后善.纳米陶瓷粉体的制备技术及产业化[J].矿冶,2001,10(2):55-60.
[47] LI H Y,ZHANG S Y,ZHOU S H,et al. Chemical bond characteristics, thermal expansion property and compressibility of AR2O4(A=Ca,Sr,Ba; R=rare earths)[J]. Mater Chem Phys,114,2009:451-455.
[48] WU H,HAO Z D,ZHANG L L,et al. Er3+/Yb3+codoped phosphor Ba3Y4O9with intense red upconversion emission and optical temperature sensing behavior[J]. J Mater Chem:C,2018(6):3459-3467.
[49]易回阳.液相法制备纳米微粒的研究进展[J].化学世界,2002,43(7):385-388.
[50]杨咏来,宁桂玲.液相法制备纳米粉体时防团聚方法概述[J].材料导报,1998(2):11-13.
[51]高雪艳.纳米氧化物的制备、分析及应用[D].上海:华东师范大学,2006.
[52]王小兰,李历历,段学臣,等.氧化钇纳米粉末的制备[J].稀有金属与硬质合金,2004,32(1):26-28.
[53]张顺利,黄小卫,崔大立,等.碳酸氢铵沉淀法制备氧化钇粉体时反应条件对产物粒度的影响[J].中国稀土学报,2003,21(6):643-646.
[54]田玉明,黄平.沉淀法的研究及其应用现状[J].材料导报,2000,14(2):47-48.
[55]徐跃萍,郭景坤,黄校先,等.无团聚Zr O2-Y2O3陶瓷超细粉的制备及微观结构表征[J].硅酸盐学报,1991,19(3):269-273.
[56]李继光,孙旭东.湿化学法合成单分散陶瓷超微粉体的基本原理[J].功能材料,1997(4):333-336.
[57]符连社,张洪杰,邵华,等.溶胶-凝胶法稀土光学材料研究进展[J].稀土,1998,19(2):49-53.
[58]郭海,张慰萍,楼立人,等.溶胶-凝胶法制备的Y2O3薄膜的光波导性质研究[J].中国稀土学报,2001,19(6):511-514.
[59]郭鹏,邵光杰,胡婕,等.有机溶剂中溶胶-凝胶法制备纳米钙钛矿型氧化物[J].中国稀土学报,2006,24(增刊2):49-52.
[60]王文经,陈前火,生瑜.溶胶凝胶法制备稀土发光杂化材料的研究[J].厦门大学学报(自然科学版),2011,50(9):131-136.
[61]王洪洪,陈永生,周建朋,等.氧化锌微米棱棒的水热法制备和稀土掺杂[J].人工晶体学报,2012,41(5):1250-1253.
[62]王展,李继文,魏世忠,等. La2O3/Y2O3对水热法制备WCu粉体的影响[J].稀土,2017(2):31-37.
[63]袁春华.二氧化铈纳米粒子的制备方法评述[J].无机盐工业,2007,39(5):10-11.
[64]马琰华,李继文,魏世忠,等.水热合成法制备稀土掺杂Mo粉的工艺研究[J].稀有金属与硬质合金,2013(5):15-18.
[65] TAN N H,WANG Y Y,LIAO P K,et al. Nanocrystals Y2O2S:Eu3+prepared by thermolysis[J]. Chinese J Inorg Chem,2010,26(8):1421-1425.
[66]王海增,庞文琴.水热晶化法在材料制备中的应用[J].功能材料,1993(4):289-296.
[67]李霞,刘宏,王继扬,等.醇-水热法制备钇铝石榴石(YAG)纳米粉体[C]//中国硅酸盐学会2003年学术年会论文摘要集,北京:中国硅酸盐学会,2003:1168-1172.
[68]裴晓将,侯延冰,徐征,等.水热法合成稀土氟化物材料YLi F4:Er,Tm,Yb的上转换发光特性[J].光谱学与光谱分析,2005,25(6):819-823.
[69] BAU M. Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium[J]. Chem Geol,1991,93(3/4):219-230.
[70] QI F X,WANG H B,ZHU X Z. Spherical YAG:Ce3+phosphor particles prepared by spray pyrolysis[J]. J Rare Earth,2005,23(4):397-400.
[71] SKOMSKI R,COEY J M D. Gas-phase modification of rare-earth intermetallic compounds[J]. J Mater Eng Perform,1993,2(2):241-247.
[72] LI X,LIU B,XIE C. Preparation and conductivity of rare earth tungsten bronze KxLnyWO3by rare earth gas phase permeation[J]. Rare Metal Mat Eng,2008,37(5):900-904.
[73] PANDA A B,GARRY GLASPELL A,ELSHALL M S. Microwave synthesis and optical properties of uniform nanorods and nanoplates of rare earth oxides[J]. J Phys Chem:C,2007,111(5):1861-1864.
[74] HAO J,COCIVERA M. Optical and luminescent properties of undoped and rare-earth-doped Ga2O3thin films deposited by spray pyrolysis[J]. J Phys:D,2002,35(5):433-438.
[75] COEY J M D,SKOMSKI R,WIRTH S. Gas phase interstitial modification of rare-earth intermetallics[J]. IEEE Transactions on Magnetics,1992,28(5):2332-2337.
[2] POTDEVIN A,CHADEYRON G,BOYER D,et al. Optical properties upon vacuum ultraviolet excitation of sol-gel based Y3Al5O12:Tb3+,Ce3+powders[J]. J Appl Phys,2007,102(7):073536. 1-073536. 6.
[3] LI J K,LI J G,ZHANG Z,et al. Gadolinium aluminate garnet(Gd3Al5O12):crystal structure stabilization via lutetium doping and properties of the(Gd1-xLux)3Al5O12(x=0~0. 5)solid solutions[J]. J Am Ceram Soc,2012,95(3):931-936.
[4] LI J K,TENG X,WANG W Z,et al. Investigation on the preparation and luminescence property of(Gd1-xDyx)2O3,(x=0. 01~0. 10)spherical phosphors[J]. Ceram Int,2017,43(13):10166-10173.
[5]李金凯.钆铝石榴石(Gd3Al5O12)的晶格稳定化及其新型发光材料[D].沈阳:东北大学,2014.
[6] LI J K,TENG X,CAO B Q,et al. Synthesis and property of spherical Lu3Al5O12:Eu3+phosphor[J]. J Inorg Mater,2016,31(6):634-640.
[7]张培善.中国稀土矿物学[M].北京:科学出版社,1998.
[8]张希艳.稀土发光材料[M].北京:国防工业出版社,2005.
[9]赵瑾.稀土掺杂下转换发光材料的光谱调制和能量传递研究[D].西安:西北大学,2016.
[10]李建宇.稀土发光材料及其应用[M].北京:化学工业出版社,2003.
[11]吴凌远.稀土掺杂红外下转换材料研究[D].合肥:中国科学技术大学,2013.
[12]熊光楠,徐力,刘俊英,等.高能量激发的发光材料[J].中国稀土学报,2001,19(6):494-497.
[13] KARUNADASA H,HUANG Q,UELAND B G,et al. Honeycombs of triangles and magnetic frustration in Sr L2O4(L=Gd,Dy,Ho,Er,Tm,and Yb)[J]. Phys Rev:B,2005,71(71):144414.
[14]宋春艳.核壳结构掺杂Zn S纳米颗粒团簇的制备与光谱学性能研究[D].杭州:浙江大学,2014.
[15] AUZEL F. Multiphonon-assisted anti-Stokes and Stokes fluorescence of triply ionized rare-earth ions[J]. J Lumin,1976,12/13(7):715-722.
[16] MASSAROTTI V,CAPSONI D,BINI M,et al. X-ray diffraction study of poly crystalline Y2BaO4:a test of the new EXPO program[J]. Z Kristallogr,1999,214(4):200-204.
[17] MULLERBUSCHBAUM H,WITZMANN H. The fluorescence of rare earths:I. emission spectra of samarium in phosphors based on borate compounds of group II elements[J]. Opt Spectry,1965,18(9):432-449.
[18] ALLEN I C,LOUIS G. Co-precipitation in some binary sulphate systems[J]. Talanta,1961,2(7):195-211.
[19] SKOLIS Y Y,PASHIN S F. The thermodynamic properties of BaY2O4[J]. Russ J Phys Chem,2001,75(11):1780-1783.
[20] COSTA G A,FERRETTI M,FORNASINI M L,et al. The crystal structure of BaY2O4,isotypic with SrY2O4[J]. Powder Diffraction,1989,4(1):24-25.
[21] ISHIHARA T,GOTO K. Direct decomposition of NO over BaO/Y2O3,catalyst[J]. Catal Today,2011,164(1):484-488.
[22]车广灿,梁敬魁,陈维,等. BaO-Y2O3(La2O3)-CuO三元系相图的研究[J].科学通报,1988(1):57-69.
[23] LIANG S,SEO H J. Site-occupation and crystal-field splitting of Eu3+in BaY2O4with calcium-ferrite structure[J]. J Electro Chem Soc,2011,158(12):399-404.
[24] MAEKAWA T,KUROSAKI K,YAMANAKA S. Thermophysical properties of BaY2O4:a new candidate material for thermal barrier coatings[J]. Mater Lett,2007,61(11):2303-2306.
[25] KALE G M,JACOB K T. Phase relations and thermodynamic properties of compounds in the pseudobinary system BaO-Y2O3[J]. Solid State Ionics,1989,34(4):247-252.
[26] VAHLAS C,BESMANN T M. Thermodynamics of the Y-Ba-Cu-C-O-H System:application to the organometallic chemical vapor deposition of the YBa2Cu3O7-xphase[J]. J Am Ceram Soc,1992,75(10):2679-2686.
[27] WONG-NG W,ROTH R S,SWARTZENDRUBER L J,et al.X-ray powder characterization of Ba2YCu3O7-x[J]. Adv Ceram Mater,1987,38(2):565-576.
[28] SZYMANIK B,BUCKLEY R G,TRODAHL H J,et al. Structure and decomposition of ceramic Ba3Y4O9[J]. Solid State Ionics,1998,109(3/4):223-228.
[29] BOBYLEV I B,ZYUZEVA N A,DEGTYAREV M V,et al.Effect of plastic deformation on the electrophysical properties and structure of YBa2Cu3Oy ceramics subjected to low-temperature treatment[J]. Phys Met Metallogr,2015,116(12):1213-1220.
[30] LI J Y,PANG R,YU Z,et al. Preparation and luminescence properties of orange-red Ba3Y4O9:Sm3+phosphors[J]. J Rare Earth,2018,36(7):680-684.
[31] ABBATTISTA F,VALLINO M,MAZZA D. Comprehensive review of the BaO-Y2O3-CuO-O phase diagram[J]. Mater Chem Phys,1989,21(5):521-528.
[32] ZHANG W,Osamura K. Phase-equilibrium in Y-Ba-O system[J]. Mater Trans,1991,32(11):1048-1052.
[33] LIN C M,HU R M,CHEN G Y,et al. Thermodynamic reassessment of BaO-YO1. 5system[C]//TMS 2015 144th Annual Meeting&Exhibition.[S. l.]:Springer International Publishing,2015:123-130.
[34] WARNER D A,RIMAN R E. Role of intermediate phase formation in the preparation of Ba4Y2O7·CO2[J]. Chem Mater,1992,4(1):197-204.
[35] ZHOU L,SHI J,GONG M. Synthesis and luminescent properties of BaGd2O4:Eu phosphor[J]. J Phys Chem Solids,2007,68(8):1471-1475.
[36] WU L T Y. Synthesis and luminescent properties of red phosphor BaY2O4:Eu3+for white light-emitting diodes[J]. Adv Mater Res,2013,811:181-185.
[37] LI K,LIAN H,SHANG M,et al. A novel greenish yelloworange red Ba3Y4O9:Bi3+,Eu3+phosphor with efficient energy transfer for UV-LEDs.[J]. Dalton T,2015,44(47):20542-20550.
[38] LAWRENCE P C,WINNIE W N,JULIA S. DTA/TGA study of eutectic melting in the system BaF2-BaO-Y2O3-CuOx-H2O[J]. Mater Proc,2000,659:481-486.
[39]王雪俊,夏海平. Bi离子掺杂Ge O2-Al2O3-M(M=Na2O,BaO,Y2O3)玻璃的光学性质[J].物理学报,2006,55(10):5263-5267.
[40]吴玉胜,李明春.功能陶瓷材料及制备工艺[M].北京:化学工业出版社,2013.
[41]闻雷,孙旭东,马伟民.固相反应法制备YAG透明陶瓷[J].硅酸盐学报,2003,31(9):295-301.
[42]姜洪义,徐博.高温固相法制备硅酸盐长余辉发光材料[J].硅酸盐学报,2006,34(9):1154-1157.
[43] XU H W,WANG L L,SHI Y S,et al. Color-tunable emission by cation substitution in Ba3-ySryY4O9:Bi3+and sites occupation preference[J]. Mater Res Bull,2018,102:8-15.
[44]周传仓,卢忠远,王兵,等.高温固相法制备Zn P:Zn荧光粉的研究[J].化工新型材料,2005,33(1):30-32.
[45]张少卿.自蔓延高温合成——无机材料制造新技术[J].材料工程,1993(7):41-44.
[46]宋桂明,周玉,白后善.纳米陶瓷粉体的制备技术及产业化[J].矿冶,2001,10(2):55-60.
[47] LI H Y,ZHANG S Y,ZHOU S H,et al. Chemical bond characteristics, thermal expansion property and compressibility of AR2O4(A=Ca,Sr,Ba; R=rare earths)[J]. Mater Chem Phys,114,2009:451-455.
[48] WU H,HAO Z D,ZHANG L L,et al. Er3+/Yb3+codoped phosphor Ba3Y4O9with intense red upconversion emission and optical temperature sensing behavior[J]. J Mater Chem:C,2018(6):3459-3467.
[49]易回阳.液相法制备纳米微粒的研究进展[J].化学世界,2002,43(7):385-388.
[50]杨咏来,宁桂玲.液相法制备纳米粉体时防团聚方法概述[J].材料导报,1998(2):11-13.
[51]高雪艳.纳米氧化物的制备、分析及应用[D].上海:华东师范大学,2006.
[52]王小兰,李历历,段学臣,等.氧化钇纳米粉末的制备[J].稀有金属与硬质合金,2004,32(1):26-28.
[53]张顺利,黄小卫,崔大立,等.碳酸氢铵沉淀法制备氧化钇粉体时反应条件对产物粒度的影响[J].中国稀土学报,2003,21(6):643-646.
[54]田玉明,黄平.沉淀法的研究及其应用现状[J].材料导报,2000,14(2):47-48.
[55]徐跃萍,郭景坤,黄校先,等.无团聚Zr O2-Y2O3陶瓷超细粉的制备及微观结构表征[J].硅酸盐学报,1991,19(3):269-273.
[56]李继光,孙旭东.湿化学法合成单分散陶瓷超微粉体的基本原理[J].功能材料,1997(4):333-336.
[57]符连社,张洪杰,邵华,等.溶胶-凝胶法稀土光学材料研究进展[J].稀土,1998,19(2):49-53.
[58]郭海,张慰萍,楼立人,等.溶胶-凝胶法制备的Y2O3薄膜的光波导性质研究[J].中国稀土学报,2001,19(6):511-514.
[59]郭鹏,邵光杰,胡婕,等.有机溶剂中溶胶-凝胶法制备纳米钙钛矿型氧化物[J].中国稀土学报,2006,24(增刊2):49-52.
[60]王文经,陈前火,生瑜.溶胶凝胶法制备稀土发光杂化材料的研究[J].厦门大学学报(自然科学版),2011,50(9):131-136.
[61]王洪洪,陈永生,周建朋,等.氧化锌微米棱棒的水热法制备和稀土掺杂[J].人工晶体学报,2012,41(5):1250-1253.
[62]王展,李继文,魏世忠,等. La2O3/Y2O3对水热法制备WCu粉体的影响[J].稀土,2017(2):31-37.
[63]袁春华.二氧化铈纳米粒子的制备方法评述[J].无机盐工业,2007,39(5):10-11.
[64]马琰华,李继文,魏世忠,等.水热合成法制备稀土掺杂Mo粉的工艺研究[J].稀有金属与硬质合金,2013(5):15-18.
[65] TAN N H,WANG Y Y,LIAO P K,et al. Nanocrystals Y2O2S:Eu3+prepared by thermolysis[J]. Chinese J Inorg Chem,2010,26(8):1421-1425.
[66]王海增,庞文琴.水热晶化法在材料制备中的应用[J].功能材料,1993(4):289-296.
[67]李霞,刘宏,王继扬,等.醇-水热法制备钇铝石榴石(YAG)纳米粉体[C]//中国硅酸盐学会2003年学术年会论文摘要集,北京:中国硅酸盐学会,2003:1168-1172.
[68]裴晓将,侯延冰,徐征,等.水热法合成稀土氟化物材料YLi F4:Er,Tm,Yb的上转换发光特性[J].光谱学与光谱分析,2005,25(6):819-823.
[69] BAU M. Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium[J]. Chem Geol,1991,93(3/4):219-230.
[70] QI F X,WANG H B,ZHU X Z. Spherical YAG:Ce3+phosphor particles prepared by spray pyrolysis[J]. J Rare Earth,2005,23(4):397-400.
[71] SKOMSKI R,COEY J M D. Gas-phase modification of rare-earth intermetallic compounds[J]. J Mater Eng Perform,1993,2(2):241-247.
[72] LI X,LIU B,XIE C. Preparation and conductivity of rare earth tungsten bronze KxLnyWO3by rare earth gas phase permeation[J]. Rare Metal Mat Eng,2008,37(5):900-904.
[73] PANDA A B,GARRY GLASPELL A,ELSHALL M S. Microwave synthesis and optical properties of uniform nanorods and nanoplates of rare earth oxides[J]. J Phys Chem:C,2007,111(5):1861-1864.
[74] HAO J,COCIVERA M. Optical and luminescent properties of undoped and rare-earth-doped Ga2O3thin films deposited by spray pyrolysis[J]. J Phys:D,2002,35(5):433-438.
[75] COEY J M D,SKOMSKI R,WIRTH S. Gas phase interstitial modification of rare-earth intermetallics[J]. IEEE Transactions on Magnetics,1992,28(5):2332-2337.