电去离子(EDI)技术处理低浓度重金属废水的研究进展
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摘要
介绍了EDI在处理低浓度重金属废水过程中的去离子原理和几种传质模型;综述了填充材料、膜堆结构、床层结构以及工艺流程的最新进展;分析了EDI技术在处理低浓度重金属废水中存在的问题,提出了今后的发展方向。
The principle of ion removal in low concentration heavy metal wastewater treatment process by EDI and several mass transfer models were introduced in this paper. The research progresses of filling materials, membrane stack structure, bed structure and technological process were summarized. Meanwhile, the existing problems of low concentration heavy metal wastewater treatment by EDI were analyzed and the developing tendency was pointed out.
The principle of ion removal in low concentration heavy metal wastewater treatment process by EDI and several mass transfer models were introduced in this paper. The research progresses of filling materials, membrane stack structure, bed structure and technological process were summarized. Meanwhile, the existing problems of low concentration heavy metal wastewater treatment by EDI were analyzed and the developing tendency was pointed out.
引文
[1]吴彦军,张林楠,李振山.重金属废水无害化处理技术最新进展[J].工业水处理,2009,29(3):1-3.
[2]邹照华,何素芳,韩彩芸,等.重金属废水处理技术研究进展[J].水处理技术,2010,30(6):17-21.
[3]王乾,任秀.重金属废水处理及回收的研究进展[J].中国科技博览,2014(2):209-209.
[4]ARAR,YüKSEL,KABAY N,et al.Removal of Cu2+ions by a micro-flow electrodeionization(EDI)system[J].Desalination,2011,277(1):296-300.
[5]LIN F,WANG J,SU Y.Removal of low concentrations of hardness ions from aqueous solutions using electrodeionization process[J].Separation&Purification Technology,2009,68(3):390-396.
[6]LU H X,WANG J Y,BU S F,et al.Removal of nickel ions from dilute heavy metal solutions by electrodeionization process[J].Advanced Materials Research,2011,183-185:580-584.
[7]TAGHDIRIAN H R,MOHEB A,MEHDIPOURGHAZI M.Selective separation of Ni(II)/Co(II)ions from dilute aqueous solutions using continuous electrodeionization in the presence of EDTA[J].Journal of Membrane Science,2010,362(s1-2):68-75.
[8]WANG L,ZHANG Y,LI J,et al.Removal of Sr2+ions from simulated wastewater by electrodeionization[J].Desalination&Water Treatment,2015,53(8):2125-2133.
[9]MATEJKA Z.Continuous production of high purity water by electrodeionisation[J].Journal of Applied Chemistry&Biotechnology,1971,21:117-120.
[10]SONG J-H,YEON K-H,MOON S-H.Effect of current density on ionic transport and water dissociation phenomena in a continuous electrodeionization(CEDI)[J].Journal of Membrane Science,2007,291(1-2):165-171.
[11]HELFFERICH F.Ion Exchange[M].New York:Mc Graw-Hill,1962.
[12]GLUECKAUF E.Electro-deionisation through a packed[J].Bri,Chem.Eng,1959,4(646).
[13]SAUER M C,SOUTHWICK P F,SPIEGLER K S,et al.Electrical conductance of porous plugs-ion exchange resin-solution systems[J].Ind Eng Chem,1955,47(10):2187-2193.
[14]SONG J H,YEON K H,MOON S H.Transport characteristics of Co2+through an ion exchange textile in a continuous electrodeionization(CEDI)system under electro‐regeneration[J].Separation Science&Technology,2005,39(15):3601-3619.
[15]MAHMOUD A,MUHR L,GREVILLOT G,et al.Experimental tests and modelling of an electrodeionization cell for the treatment of dilute copper solutions[J].Canadian Journal of Chemical Engineering,2007,85(2):171-179.
[16]管山.电去离子(EDI)过程及其用于水中Cu2+离子的脱除与浓缩的研究[D].天津大学,2004.
[17]LU H,WANG J,BU S,et al.Influence of Resin particle size distribution on the performance of electrodeionization process for Ni2+removal from synthetic wastewater[J].Separation Science and Technology,2011,46(3):404-408.
[18]MAHMOUD A,HOADLEY A F A.An evaluation of a hybrid ion exchange electrodialysis process in the recovery of heavy metals from simulated dilute industrial wastewater[J].Water Research,2012,46(10):3364-3376.
[19]XING Y,CHEN X,YAO P,et al.Continuous electrodeionization for removal and recovery of Cr(VI)from wastewater[J].Separation&Purification Technology,2009,67(2):123-126.
[20]DZYAZKO Y S,ROZHDESTVENSKA L M,PALCHIK A V,et al.Ion-exchange properties and mobility of Cu2+ions in zirconium hydrophosphate ion exchangers[J].Separation&Purification Technology,2005,45(2):141-146.
[21]DZYAZ'KO Y S,ROZHDESTVENSKAYA L M,PAL'CHIK A V,et al.Mobility of Ni(II)ions in inorganic ion exchangers based on zirconium hydroxophosphate[J].Theoretical&Experimental Chemistry,2003,39(6):380-384.
[22]ROZHDESTVENSKA L M,DZYAZKO Y S,BELYAKOV V N.Electrodeionization of a Ni2+solution using highly hydrated zirconium hydrophosphate[J].Desalination,2006,198(s1-3):247-255.
[23]DZYAZ'KO Y S,ROZHDESTVENSKAYA L M,PAL'CHIK A V.Recovery of nickel ions from dilute solutions by electrodialysis combined with ion exchange[J].Russian Journal of Applied Chemistry,2005,78(3):414-421.
[24]BINGCAI P,QINGRUI Z,WEI D,et al.Selective heavy metals removal from waters by amorphous zirconium phosphate:behavior and mechanism[J].Water Research,2007,41(14):3103-11.
[25]DZYAZKO Y S,PONOMARYOVA L N,ROZHDESTVENSKAYA L M,et al.Electrodeionization of low-concentrated multicomponent Ni2+-containing solutions using organic-inorganic ion-exchanger[J].Desalination,2014,342(6):43-51.
[26]HO T,KURUP A,DAVIS T,et al.Wafer chemistry and properties for ion removal by wafer enhanced electrodeionization[J].Separation Science&Technology,2010,45(4):433-446.
[27]ARORA M B,HESTEKIN J A,SNYDER S W,et al.The separative bioreactor:a continuous separation process for the simultaneous production and direct capture of organic acids[J].Sep Sci Technol,2007,42(11):2519-2538.
[28]GREBEN'V P,RODZIK I G.Transport selectivity of carbonate and chloride ions througha strongly alkaline anion-exchange membrane before and after its modification with sodium alginate[J].Russian Journal of Electrochemistry,2009,45(45):286-290.
[29]佐田俊胜.离子交换膜:制备,表征,改性和应用[M].北京:化学工业出版社,2015.
[30]董恒,王建友,边艳芳,等.“双极膜-电去离子”耦合过程浓缩低浓度含镍离子溶液[J].高校化学工程学报,2011,25(6):929-933.
[31]董恒,王建友,卢会霞,等.“双极膜-电去离子”耦合过程处理含镍离子溶液[J].中国科技论文,2010(5):341-346.
[32]YEON K-H,SONG J-H,MOON S-H.A study on stack configuration of continuous electrodeionization for removal of heavy metal ions from the primary coolant of a nuclear power plant[J].Water Research,2004,38(7):1911-1921.
[33]DDERMENTZIS K,DAVIDIS A,CHATZICHRISTOU C,et al.Ammonia removal from fertilizer plant effluents by a coupled electrostatic shielding based electrodialysis/electrodeionization process[J].Global Nest Journal,2012,14(4):468-476.
[34]DERMENTZIS K.Continuous electrodeionization through electrostatic shielding[J].Electrochimica Acta,2008,53(6):2953-2962.
[35]DERMENTZIS K,OUZOUNIS K.Continuous capacitive deionization-electrodialysis reversal through electrostatic shielding for desalination and deionization of water[J].Electrochimica Acta,2008,53(24):7123-7130.
[36]DERMENTZIS K.Removal of nickel from electroplating rinse waters using electrostatic shielding electrodialysis/electrodeionization[J].Journal of Hazardous Materials,2010,173(1-3):647-652.
[37]DERMENTZIS K I,DAVIDIS A E,DERMENTZI A S,et al.An electrostatic shielding-based coupled electrodialysis/electrodeionization process for removal of cobalt ions from aqueous solutions[J].Water Science&Technology,2010,62(62):1947-53.
[38]SHEN X,FANG Z,HU J,et al.Membrane-free electrodeionization for purification of wastewater containing low concentration of nickel ions[J].Chemical Engineering Journal,2015,280:711-719.
[39]SPOOR P B,GRABOVSKA L,KOENE L,et al.Pilot scale deionisation of a ga lvanic nickel solution using a hybrid ion-exchange/electrodialysis system[J].Chemical Engineering Journal,2002,89(s1-3):193-202.
[40]BASTA K,ALIANE A,LOUNIS A,et al.Electroextraction of Pb2+ions from diluted solutions by a process combining ion-exchange textiles and membranes[J].Desalination,1998,120(3):175-184.
[41]LU H,WANG Y,WANG J.Recovery of Ni2+and pure water from electroplating rinse wastewater by an integrated two-stage electrodeionization process[J].Journal of Cleaner Production,2015,92:257-266.
[42]ALVARADO L,RAMíREZ A,RODRíGUEZ I.Cr(VI)removal by continuous electrodeionization:Study of its basic technologies[J].Desalination,2009,249(1):423-428.
[43]ALVARADO L,TORRES I R,CHEN A C.Integration of ion exchange and electrodeionization as a new approach for the continuous treatment of hexavalent chromium wastewater[J].Separation and Purification Technology,2013,105:55-62.
[2]邹照华,何素芳,韩彩芸,等.重金属废水处理技术研究进展[J].水处理技术,2010,30(6):17-21.
[3]王乾,任秀.重金属废水处理及回收的研究进展[J].中国科技博览,2014(2):209-209.
[4]ARAR,YüKSEL,KABAY N,et al.Removal of Cu2+ions by a micro-flow electrodeionization(EDI)system[J].Desalination,2011,277(1):296-300.
[5]LIN F,WANG J,SU Y.Removal of low concentrations of hardness ions from aqueous solutions using electrodeionization process[J].Separation&Purification Technology,2009,68(3):390-396.
[6]LU H X,WANG J Y,BU S F,et al.Removal of nickel ions from dilute heavy metal solutions by electrodeionization process[J].Advanced Materials Research,2011,183-185:580-584.
[7]TAGHDIRIAN H R,MOHEB A,MEHDIPOURGHAZI M.Selective separation of Ni(II)/Co(II)ions from dilute aqueous solutions using continuous electrodeionization in the presence of EDTA[J].Journal of Membrane Science,2010,362(s1-2):68-75.
[8]WANG L,ZHANG Y,LI J,et al.Removal of Sr2+ions from simulated wastewater by electrodeionization[J].Desalination&Water Treatment,2015,53(8):2125-2133.
[9]MATEJKA Z.Continuous production of high purity water by electrodeionisation[J].Journal of Applied Chemistry&Biotechnology,1971,21:117-120.
[10]SONG J-H,YEON K-H,MOON S-H.Effect of current density on ionic transport and water dissociation phenomena in a continuous electrodeionization(CEDI)[J].Journal of Membrane Science,2007,291(1-2):165-171.
[11]HELFFERICH F.Ion Exchange[M].New York:Mc Graw-Hill,1962.
[12]GLUECKAUF E.Electro-deionisation through a packed[J].Bri,Chem.Eng,1959,4(646).
[13]SAUER M C,SOUTHWICK P F,SPIEGLER K S,et al.Electrical conductance of porous plugs-ion exchange resin-solution systems[J].Ind Eng Chem,1955,47(10):2187-2193.
[14]SONG J H,YEON K H,MOON S H.Transport characteristics of Co2+through an ion exchange textile in a continuous electrodeionization(CEDI)system under electro‐regeneration[J].Separation Science&Technology,2005,39(15):3601-3619.
[15]MAHMOUD A,MUHR L,GREVILLOT G,et al.Experimental tests and modelling of an electrodeionization cell for the treatment of dilute copper solutions[J].Canadian Journal of Chemical Engineering,2007,85(2):171-179.
[16]管山.电去离子(EDI)过程及其用于水中Cu2+离子的脱除与浓缩的研究[D].天津大学,2004.
[17]LU H,WANG J,BU S,et al.Influence of Resin particle size distribution on the performance of electrodeionization process for Ni2+removal from synthetic wastewater[J].Separation Science and Technology,2011,46(3):404-408.
[18]MAHMOUD A,HOADLEY A F A.An evaluation of a hybrid ion exchange electrodialysis process in the recovery of heavy metals from simulated dilute industrial wastewater[J].Water Research,2012,46(10):3364-3376.
[19]XING Y,CHEN X,YAO P,et al.Continuous electrodeionization for removal and recovery of Cr(VI)from wastewater[J].Separation&Purification Technology,2009,67(2):123-126.
[20]DZYAZKO Y S,ROZHDESTVENSKA L M,PALCHIK A V,et al.Ion-exchange properties and mobility of Cu2+ions in zirconium hydrophosphate ion exchangers[J].Separation&Purification Technology,2005,45(2):141-146.
[21]DZYAZ'KO Y S,ROZHDESTVENSKAYA L M,PAL'CHIK A V,et al.Mobility of Ni(II)ions in inorganic ion exchangers based on zirconium hydroxophosphate[J].Theoretical&Experimental Chemistry,2003,39(6):380-384.
[22]ROZHDESTVENSKA L M,DZYAZKO Y S,BELYAKOV V N.Electrodeionization of a Ni2+solution using highly hydrated zirconium hydrophosphate[J].Desalination,2006,198(s1-3):247-255.
[23]DZYAZ'KO Y S,ROZHDESTVENSKAYA L M,PAL'CHIK A V.Recovery of nickel ions from dilute solutions by electrodialysis combined with ion exchange[J].Russian Journal of Applied Chemistry,2005,78(3):414-421.
[24]BINGCAI P,QINGRUI Z,WEI D,et al.Selective heavy metals removal from waters by amorphous zirconium phosphate:behavior and mechanism[J].Water Research,2007,41(14):3103-11.
[25]DZYAZKO Y S,PONOMARYOVA L N,ROZHDESTVENSKAYA L M,et al.Electrodeionization of low-concentrated multicomponent Ni2+-containing solutions using organic-inorganic ion-exchanger[J].Desalination,2014,342(6):43-51.
[26]HO T,KURUP A,DAVIS T,et al.Wafer chemistry and properties for ion removal by wafer enhanced electrodeionization[J].Separation Science&Technology,2010,45(4):433-446.
[27]ARORA M B,HESTEKIN J A,SNYDER S W,et al.The separative bioreactor:a continuous separation process for the simultaneous production and direct capture of organic acids[J].Sep Sci Technol,2007,42(11):2519-2538.
[28]GREBEN'V P,RODZIK I G.Transport selectivity of carbonate and chloride ions througha strongly alkaline anion-exchange membrane before and after its modification with sodium alginate[J].Russian Journal of Electrochemistry,2009,45(45):286-290.
[29]佐田俊胜.离子交换膜:制备,表征,改性和应用[M].北京:化学工业出版社,2015.
[30]董恒,王建友,边艳芳,等.“双极膜-电去离子”耦合过程浓缩低浓度含镍离子溶液[J].高校化学工程学报,2011,25(6):929-933.
[31]董恒,王建友,卢会霞,等.“双极膜-电去离子”耦合过程处理含镍离子溶液[J].中国科技论文,2010(5):341-346.
[32]YEON K-H,SONG J-H,MOON S-H.A study on stack configuration of continuous electrodeionization for removal of heavy metal ions from the primary coolant of a nuclear power plant[J].Water Research,2004,38(7):1911-1921.
[33]DDERMENTZIS K,DAVIDIS A,CHATZICHRISTOU C,et al.Ammonia removal from fertilizer plant effluents by a coupled electrostatic shielding based electrodialysis/electrodeionization process[J].Global Nest Journal,2012,14(4):468-476.
[34]DERMENTZIS K.Continuous electrodeionization through electrostatic shielding[J].Electrochimica Acta,2008,53(6):2953-2962.
[35]DERMENTZIS K,OUZOUNIS K.Continuous capacitive deionization-electrodialysis reversal through electrostatic shielding for desalination and deionization of water[J].Electrochimica Acta,2008,53(24):7123-7130.
[36]DERMENTZIS K.Removal of nickel from electroplating rinse waters using electrostatic shielding electrodialysis/electrodeionization[J].Journal of Hazardous Materials,2010,173(1-3):647-652.
[37]DERMENTZIS K I,DAVIDIS A E,DERMENTZI A S,et al.An electrostatic shielding-based coupled electrodialysis/electrodeionization process for removal of cobalt ions from aqueous solutions[J].Water Science&Technology,2010,62(62):1947-53.
[38]SHEN X,FANG Z,HU J,et al.Membrane-free electrodeionization for purification of wastewater containing low concentration of nickel ions[J].Chemical Engineering Journal,2015,280:711-719.
[39]SPOOR P B,GRABOVSKA L,KOENE L,et al.Pilot scale deionisation of a ga lvanic nickel solution using a hybrid ion-exchange/electrodialysis system[J].Chemical Engineering Journal,2002,89(s1-3):193-202.
[40]BASTA K,ALIANE A,LOUNIS A,et al.Electroextraction of Pb2+ions from diluted solutions by a process combining ion-exchange textiles and membranes[J].Desalination,1998,120(3):175-184.
[41]LU H,WANG Y,WANG J.Recovery of Ni2+and pure water from electroplating rinse wastewater by an integrated two-stage electrodeionization process[J].Journal of Cleaner Production,2015,92:257-266.
[42]ALVARADO L,RAMíREZ A,RODRíGUEZ I.Cr(VI)removal by continuous electrodeionization:Study of its basic technologies[J].Desalination,2009,249(1):423-428.
[43]ALVARADO L,TORRES I R,CHEN A C.Integration of ion exchange and electrodeionization as a new approach for the continuous treatment of hexavalent chromium wastewater[J].Separation and Purification Technology,2013,105:55-62.