国防专用无机成分量标准物质定值技术
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摘要
综述国防专用无机成分量标准物质应用广泛的3种定值技术:原子吸收光谱法、电感耦合等离子体发射光谱法、电感耦合等离子体质谱法。介绍了每种定值技术的检测原理、优势与不足,并列举了标准物质定值实例。3种定值方法各有特点,实验室应根据标准物质特性量值的范围、不确定度水平等实际情况,选择经济适宜的定值方法,保证定值结果的准确可靠。
The three most widely used characterization technology for defense special inorganic component reference material, including atomic absorption spectrometry(AAS), inductively coupled plasma atomic emission spectrometry(ICP–AES) and inductively coupled plasma mass spectrometry(ICP–MS) was reviewed. The detection principle, advantages and disadvantages, and the application examples were introduced for each characterization technology. Each characterization technology has its own characteristics, the laboratory should choose the economic and suitable characterization technology according to the range of the property value and the level of uncertainty, so as to ensure the accuracy and reliability of the result.
The three most widely used characterization technology for defense special inorganic component reference material, including atomic absorption spectrometry(AAS), inductively coupled plasma atomic emission spectrometry(ICP–AES) and inductively coupled plasma mass spectrometry(ICP–MS) was reviewed. The detection principle, advantages and disadvantages, and the application examples were introduced for each characterization technology. Each characterization technology has its own characteristics, the laboratory should choose the economic and suitable characterization technology according to the range of the property value and the level of uncertainty, so as to ensure the accuracy and reliability of the result.
引文
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[5]靳京民,赵华,张辉,等.标准物质定值方法优选方案[J].化学分析计量,2005,14(6):1-3.
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[7]杨松戈,杨佳.GFAAS测定铂光谱标样中的锰、锌、铬、锡、镁、铋[J].有色矿冶,2009,25(6):51-53.
[8]孙倩芸,隋峰,叶谦辉,等.铜离子溶液标准物质的比较法定值[J].化学分析计量,2016,25(4):15-18.
[9]芦新根,陈永红,洪博,等.金矿石和金精矿国家标准物质的研制[J].黄金2016,37(2):75-79.
[10]侯列奇,王树安,李洁,等.电感耦合等离子体原子发射光谱法测定铀-钼合金中15种微量杂质元素[J].理化检验(化学分册),2007,43(3):179-184.
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[13]陈安明.电感耦合等离子体发射光谱法测定低合金钢中痕量硼[J].理化检验(化学分册),2007,43(8):644-646.
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[22]刘婷,黄永红,白焕焕.ICP-AES法同时测定钛合金中钽、铌、钨元素含量[J].钛工业进展,2013,30(6):38-41.
[23]羊送球,黄永红.ICP-OES法测定钛合金中硼含量[J].钛工业进展,2006,23(2):35-36.
[24]刘虎生.ICP-AES法测定荧光级Y2O3标准物质中硅[J].冶金分析,1993(5):56-57.
[25]王军.ICP-AES法对钢铁冶炼过程生产试样定值分析的探讨与应用[J].中国高新技术企业,2017(4):12-14.
[26]王践,印凤娟,夏旭娟.电感耦合等离子体原子发射光谱(ICP-OES)在发动机油元素分析中的应用[J].润滑油,2015(2):45-49.
[27]刘孟刚,史乃捷,胡晓明,等.氧弹燃烧-ICP-OES用于柴油标准物质中硫含量的定值[J].光谱学与光谱分析,2003,23(5):965-967.
[28]刘英,李宝成,张金娥.高纯金属分析技术[C]//全国有色金属理化检验学术报告会论文集,2012.
[29]田孔泉,郝红梅,张卫杰,等.ICP-MS测定超高纯钽铌及其化合物中痕量杂质元素[J].光谱实验室,2004,3(5):425-426.
[30]王长华,李继东,潘元海,等.电感耦合等离子体质谱法测定高纯钨中15种痕量杂质元素[J].质谱学报,2011,32(4):216一221.
[31]张世涛.ICP-MS法对稀散元素矿石标准物质中多种元素定值的研究[J].农业科技与装备,2015(2):42-44.
[32]吴淑芳,姜玉梅.35CrMoA标准物质中的8种微量元素的ICP-MS定值[J].江西化工,2005(1):109-110.
[33]王婧.原子吸收光谱法测定锌单标准样品与含锌多金属混合标准样品中锌浓度的探讨[J].化学工程与装备,2016(5):247-250.
[34]RITTENBERG D,FOSTER G L.A new procedure for quantitative analysis by isotope dilution,with application to the determination of amino acids and fatty acids[J].J Bio Chem,1940,133(3):737-744.
[35]HINTENBERGER H.Electromagnetically separated as mass spectrometry[M].London:Butterworths,1956,177-178.
[36]孟宪厚,毕松苓.同位素稀释质谱法测定粉煤灰标准参考物质中痕量铅[J].环境污染与防治,1990,12(1):43-44.
[37]黄达峰.同位素稀释质谱(IDMS)法在高纯试剂分析中的应用[J].化学试剂,1987,9(4):217-218.
[38]逯海,马联弟,韦超,等.同位素稀释质谱法在丙烯腈-丁二烯-苯乙烯聚合物标准物质汞定值中的应用[J].原子能科学技术,2008,42(12):1 098-1 102.
[39]IVAN Tre?l,CHRISTOPHE R Quétel.Low uncertainty reverse isotope dilution ICP-MS applied to certifying an isotopically enriched Cd candidate reference material:A case study[J].Journal of the american society for mass spectrometry,2005,16(5):708-716.
[40]CHRISTOPHER S J,LONG S E,REARICK M S and Fassett J D.Development of isotope dilution cold vapor inductively coupled plasma mass spectrometry and its application to the certification of mercury in NIST standard reference materials[J].Anal Chem,2001,73(10):2 190-2 199.
[41]杨朝勇,庄峙厦,谷胜,等.同位素稀释法电感耦合等离子体质谱在痕量元素分析中的应用[J].分析测试学报,2001,20(2):87-92.
[42]JOANNON S,TELOUK P,PIN C.Determination of U and That ultra-trace levels by isotope dilution inductively coupled plasma mass spectrometry using a geyser-type ultrasonic nebulizer:application to geological samples[J].Spectrochim Acta,B,1997,52(12):1 783-1 789.
[43]XIE Q L,KERRICH R.Application of isotope dilution for precise measurement of Zr and Hf in low-abundance samples and international reference materials by inductively coupled plasma mass spectrometry:implications for Zr(Hf)/REE fractionations in komatiites[J].Chem Geol,1995,123(1-4):17-27.
[44]VANHAECKE F,MOENS L,DAMS R.The accurate determination of copper in two groundwater candidate reference materials by means of high resolution inductively coupled plasma mass spectrometry using isotope dilution for calibration[J].JAnal at Spectrom,1998,13(10):1 189-1 192.
[45]PIN C,JOANNON S.Low-level analysis of lanthanides in eleven silicate rock standards by ICP-MS after group separation using cation-exchange chromotography[J].Geostandard Newslett,1997,21(1):43-50.
[46]PAPADAKIS I,TAYLOR P D P,De Bièvre P.SI-traceable values for cadmium and lead concentration in the candidate reference material,MURST-ISS A1 Antarctic sediment,by combination of ICP-MS with isotope dilution[J].Anal Chim Acta 1997,346(1):17-22.
[2]卢晓华,李红梅,郭敬.标准物质领域总体发展趋势[J].中国计量,2010(7):75-76.
[3]韩永志.标准物质的定值[J].化学分析计量,2001,l0(5):38-39.
[4]蒋文钧.锌合金标准物质中铅的测定[J].化学分析计量,1992(1):24-27.
[5]靳京民,赵华,张辉,等.标准物质定值方法优选方案[J].化学分析计量,2005,14(6):1-3.
[6]王少明,赵华,王爱萍,等.高纯硅溶胶成分标准物质的制备[J].化学分析计量,2006,15(5):4-6.
[7]杨松戈,杨佳.GFAAS测定铂光谱标样中的锰、锌、铬、锡、镁、铋[J].有色矿冶,2009,25(6):51-53.
[8]孙倩芸,隋峰,叶谦辉,等.铜离子溶液标准物质的比较法定值[J].化学分析计量,2016,25(4):15-18.
[9]芦新根,陈永红,洪博,等.金矿石和金精矿国家标准物质的研制[J].黄金2016,37(2):75-79.
[10]侯列奇,王树安,李洁,等.电感耦合等离子体原子发射光谱法测定铀-钼合金中15种微量杂质元素[J].理化检验(化学分册),2007,43(3):179-184.
[11]陈炽荣.二氧化钛中微量杂质的光谱分析[J].光谱实验室,1994,11(3):67-69.
[12]邹玲玲,张学俊,郭玉生.电感耦合等离子体原子发射光谱法测定高纯钛中痕量元素[J].理化检验(化学分册),2007,43(3):213-214,220.
[13]陈安明.电感耦合等离子体发射光谱法测定低合金钢中痕量硼[J].理化检验(化学分册),2007,43(8):644-646.
[14]赵玉珍,吕佩德.ICP-AES法测定钕铁硼永磁材料中常量及微量元索[J].分析试验室,1997,16(6):25-28.
[15]叶晓英,李帆.ICP-AES法测定铁钕合金中主量元素钕及7种杂质元素的研究[J].光谱实验室,2001,18(5):697-699.
[16]李帆,叶晓英.ICP-AES测定Nd-Pr合金中的杂质元素[J].光谱实验室,2003,20(1):122-124.
[17]刘永明.ICP-AES法测定钕铁硼永磁材料中常量元素[J].光谱学与光谱分析,2004,24(10):1 257-1 259.
[18]叶晓英,李帆,庞晓辉.ICP-AES测定铁钕合金中Ho,Er,Tb,Tm,Cu,Mo,Nb等7种杂质元素[J].光谱实验室,2003,20(1):113-116.
[19]蒋苏琼,张忠亭,邓飞跃.电感耦合等离子体发射光谱法(ICP-AES)测定铝-钛-硼合金中10种元素[J].中国无机分析化学,2011,1(1):65-68.
[20]裘立奋,王吉申,杜方才.ICP-AES测定高纯钨中杂质元素[J].中南工业大学学报,1999,30(l):71-73.
[21]李帆,叶晓英.ICP-AES法测定镍基高温合金中16个元素的方法研究[J].光谱学与光谱分析,2003,23(6):1 174-1 175.
[22]刘婷,黄永红,白焕焕.ICP-AES法同时测定钛合金中钽、铌、钨元素含量[J].钛工业进展,2013,30(6):38-41.
[23]羊送球,黄永红.ICP-OES法测定钛合金中硼含量[J].钛工业进展,2006,23(2):35-36.
[24]刘虎生.ICP-AES法测定荧光级Y2O3标准物质中硅[J].冶金分析,1993(5):56-57.
[25]王军.ICP-AES法对钢铁冶炼过程生产试样定值分析的探讨与应用[J].中国高新技术企业,2017(4):12-14.
[26]王践,印凤娟,夏旭娟.电感耦合等离子体原子发射光谱(ICP-OES)在发动机油元素分析中的应用[J].润滑油,2015(2):45-49.
[27]刘孟刚,史乃捷,胡晓明,等.氧弹燃烧-ICP-OES用于柴油标准物质中硫含量的定值[J].光谱学与光谱分析,2003,23(5):965-967.
[28]刘英,李宝成,张金娥.高纯金属分析技术[C]//全国有色金属理化检验学术报告会论文集,2012.
[29]田孔泉,郝红梅,张卫杰,等.ICP-MS测定超高纯钽铌及其化合物中痕量杂质元素[J].光谱实验室,2004,3(5):425-426.
[30]王长华,李继东,潘元海,等.电感耦合等离子体质谱法测定高纯钨中15种痕量杂质元素[J].质谱学报,2011,32(4):216一221.
[31]张世涛.ICP-MS法对稀散元素矿石标准物质中多种元素定值的研究[J].农业科技与装备,2015(2):42-44.
[32]吴淑芳,姜玉梅.35CrMoA标准物质中的8种微量元素的ICP-MS定值[J].江西化工,2005(1):109-110.
[33]王婧.原子吸收光谱法测定锌单标准样品与含锌多金属混合标准样品中锌浓度的探讨[J].化学工程与装备,2016(5):247-250.
[34]RITTENBERG D,FOSTER G L.A new procedure for quantitative analysis by isotope dilution,with application to the determination of amino acids and fatty acids[J].J Bio Chem,1940,133(3):737-744.
[35]HINTENBERGER H.Electromagnetically separated as mass spectrometry[M].London:Butterworths,1956,177-178.
[36]孟宪厚,毕松苓.同位素稀释质谱法测定粉煤灰标准参考物质中痕量铅[J].环境污染与防治,1990,12(1):43-44.
[37]黄达峰.同位素稀释质谱(IDMS)法在高纯试剂分析中的应用[J].化学试剂,1987,9(4):217-218.
[38]逯海,马联弟,韦超,等.同位素稀释质谱法在丙烯腈-丁二烯-苯乙烯聚合物标准物质汞定值中的应用[J].原子能科学技术,2008,42(12):1 098-1 102.
[39]IVAN Tre?l,CHRISTOPHE R Quétel.Low uncertainty reverse isotope dilution ICP-MS applied to certifying an isotopically enriched Cd candidate reference material:A case study[J].Journal of the american society for mass spectrometry,2005,16(5):708-716.
[40]CHRISTOPHER S J,LONG S E,REARICK M S and Fassett J D.Development of isotope dilution cold vapor inductively coupled plasma mass spectrometry and its application to the certification of mercury in NIST standard reference materials[J].Anal Chem,2001,73(10):2 190-2 199.
[41]杨朝勇,庄峙厦,谷胜,等.同位素稀释法电感耦合等离子体质谱在痕量元素分析中的应用[J].分析测试学报,2001,20(2):87-92.
[42]JOANNON S,TELOUK P,PIN C.Determination of U and That ultra-trace levels by isotope dilution inductively coupled plasma mass spectrometry using a geyser-type ultrasonic nebulizer:application to geological samples[J].Spectrochim Acta,B,1997,52(12):1 783-1 789.
[43]XIE Q L,KERRICH R.Application of isotope dilution for precise measurement of Zr and Hf in low-abundance samples and international reference materials by inductively coupled plasma mass spectrometry:implications for Zr(Hf)/REE fractionations in komatiites[J].Chem Geol,1995,123(1-4):17-27.
[44]VANHAECKE F,MOENS L,DAMS R.The accurate determination of copper in two groundwater candidate reference materials by means of high resolution inductively coupled plasma mass spectrometry using isotope dilution for calibration[J].JAnal at Spectrom,1998,13(10):1 189-1 192.
[45]PIN C,JOANNON S.Low-level analysis of lanthanides in eleven silicate rock standards by ICP-MS after group separation using cation-exchange chromotography[J].Geostandard Newslett,1997,21(1):43-50.
[46]PAPADAKIS I,TAYLOR P D P,De Bièvre P.SI-traceable values for cadmium and lead concentration in the candidate reference material,MURST-ISS A1 Antarctic sediment,by combination of ICP-MS with isotope dilution[J].Anal Chim Acta 1997,346(1):17-22.