微电池薄膜电极的制备及发展趋势
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摘要
基于微型化设备在传感器、自主微电子机械、医疗等领域需求的日益增加,微电池作为能源装置也必将替代传统电池。重点阐述了微电池薄膜电极的制备方法以及喷墨式和挤压式3D打印技术在薄膜电极制备方面的应用。最后对3D打印薄膜电极所用墨水进行了介绍,并对3D打印薄膜电极的优势及发展趋势进行了分析。
Based on the increasing demand for micro devices in the fields of sensors,autonomous microelectronics and medical treatment,the micro battery as an energy device will replace the traditional battery.The preparation methods of thin film electrode and the application of 3 Dprinting technology including ink-jet and extrusion type in the preparation of thin film electrode were discussed.At last,the ink used in 3 Dprinting film electrode was introduced,the advantages and development trend were analyzed.
Based on the increasing demand for micro devices in the fields of sensors,autonomous microelectronics and medical treatment,the micro battery as an energy device will replace the traditional battery.The preparation methods of thin film electrode and the application of 3 Dprinting technology including ink-jet and extrusion type in the preparation of thin film electrode were discussed.At last,the ink used in 3 Dprinting film electrode was introduced,the advantages and development trend were analyzed.
引文
[1]Chavoshi S Z,Luo X C.Hybrid micro-machining processes:a review[J].Precision Engineering,2015,41:1-23.
[2]Terada F.Solar cell array for MES power supply[DB/OL].(2000).http://www.I ijnet.or.jp/MMC/no.15/act/actvi.htm.
[3]Humble P H,Harb J N,Lafollett R M.Microscopic nickel-zinc batteries for use in autonomous microsystems[J].Journal of the Electrochemical Society,2001,148(12):A1357-A1361.
[4]Lamberti A,Garino N,Sacco A,et al.As-grown vertically aligned amorphous TiO2 nanotube arrays as high-rate Libased micro-battery anodes with improved long-term performance[J].Electrochimica Acta,2015,151:222-229.
[5]Leijonmarck S,Carlson T,Lindbergh L.Solid polymer electrolyte-coated carbon fibres for structural and novel micro batteries[J].Composites Science and Technology,2013,89:149-157.
[6]Lee J,Kim S H,Jee S H,et al.Characteristics of Sn/Li2O multi-layer composite anode for thin film microbattery[J].Power Sources,2008,178:434-438.
[7]Wen Z S,Cheng M K,Sun J C,et al.Composite silicon film with connected silicon nanowires for lithium ion batteries[J].Electrochim Acta,2010,56(1):372.
[8]Zeng Z Y,Tu J P,Huan X H,et al.Electrochemical investigation on silicon/titanium carbide nano composite film anode for Li ion batteries[J].Thin Solid Films,2009,517(17):4767.
[9]张凯,白红美,程方益,等.真空蒸镀法制备锡薄膜及其嵌锂电化学性能[J].应用化学,2011,28(8):918-923.
[10]Yu Y,Gu L,Dhanabalan A,et al.Three-dimensional porous amorphous SnO2thin films as anodes for Li-ion batteries[J].Electrochimica Acta,2009,54(28):7227-7230.
[11]Oltean G,Valvo M.On the electrophoretic and sol-gel deposition of active materials on aluminium rod current collectors for three-dimensional Li-ion micro-batteries[J].Thin Solid Films,2014,562:63-69.
[12]Lamberti A,Sacco A,Bianco S,et al.Charge transport improvement employing TiO2nanotube arrays as front-side illuminated dye-sensitized solar cell photoanodes[J].Physical Chemistry and Chemical Physics,2013,15,2596-2602.
[13]Kyeremateng N A,Vacandio F,Sougrati M T,et al.Effect of Sn-doping on the electrochemical behaviour of TiO2 nanotubes as potential negative electrode materials for 3D Li-ion micro batteries[J].Journal of Power Source,2013,224:269-277.
[14]Liang H X,Zhao X,Yu Z Y,et al.Effect of ultrasonic irradiation on structure and electrochemical properties of LiMn2O4thin films cathode material for Li-ion micro-batteries[J].Solid State Ionics,2011,192:339-342.
[15]Xia H,Xiong W,Lim C K,et al.Hierarchical TiO2-B nanowire@α-Fe2O3nanothorn core-branch arrays as superior electrodes for lithium-ion microbatteries[J].Nano Research,2014,7(12):1797-1808.
[16]Rolison R D,Long W J.Multifunctional 3Dnano architectures for energy storage and conversion[J].Chemical Society Reviews,2009,38:226.
[17]Valvo M,Roberts M,Oltean G,et al.Electroc hemical elaboration of electrodes and electrolytes for 3Dstructured batteries[J].Mater Chem,2013,(1),9281.
[18]Roberts M,Jhons P.3DLi-thiumion batteries-from fundamentals to fabrication[J].Chemistry of Materials,2011,21:9876.
[19]Sun K,Wei T S,Ahn B Y,et al.3DPrinting of interdigitated Li-ion microbattery architectures[J].Advanced Materials,2013,25:4539-4543.
[20]Yin Z,Huang Y,Bu N,et al.Inkjet printing for flexible electronics:materials,processes and equipments[J].Chinese Science Bulletin,2010,55:3383-3407.
[21]Kim D,Jeong S,Lee S,et al.Organic thin film transistor using silver electrodes technology by the ink-jet prining[J].Thin Solid Films,2007,515(19):7692-7696.
[22]Delannoy P E,Riou V B,Brousse T,et al.Ink-jet printed porous composite LiFePO4 electrode from aqueous suspension for microbatteries[J].Journal of Power Sources,2015,287:261-268.
[23]Ricardo E S,Carlos M C,Senentxu L M.Advances and future challenges in printed batteries[J].Chemsuschem Reviews,2015(8),3539-3555.
[24]黄俊杰,江志裕.喷墨打印制备LiMn2O4薄膜电极及其电化学性能[J].物理化学学报,2008,24(9):1563-1567.
[25]王永庆,郭玉国,万立骏.锂离子电池纳米电极薄膜的喷墨打印研究[J].科学通报,2013,58(31):3227-3232.
[26]Fu K,Wang Y B,Yan C Y,et al.Graphene oxide-based electrode inks for 3D-printed Lithium-ion batteries[J].Advanced Materials,2016,28,2587-2594.
[27]Delannoy P E,Riou B,Brousse T,et al.Ink-jet printed porous composite LiFePO4 electrode from aqueous suspension for microbatteries[J].Journal of Power Sources,2015,287:261-268.
[2]Terada F.Solar cell array for MES power supply[DB/OL].(2000).http://www.I ijnet.or.jp/MMC/no.15/act/actvi.htm.
[3]Humble P H,Harb J N,Lafollett R M.Microscopic nickel-zinc batteries for use in autonomous microsystems[J].Journal of the Electrochemical Society,2001,148(12):A1357-A1361.
[4]Lamberti A,Garino N,Sacco A,et al.As-grown vertically aligned amorphous TiO2 nanotube arrays as high-rate Libased micro-battery anodes with improved long-term performance[J].Electrochimica Acta,2015,151:222-229.
[5]Leijonmarck S,Carlson T,Lindbergh L.Solid polymer electrolyte-coated carbon fibres for structural and novel micro batteries[J].Composites Science and Technology,2013,89:149-157.
[6]Lee J,Kim S H,Jee S H,et al.Characteristics of Sn/Li2O multi-layer composite anode for thin film microbattery[J].Power Sources,2008,178:434-438.
[7]Wen Z S,Cheng M K,Sun J C,et al.Composite silicon film with connected silicon nanowires for lithium ion batteries[J].Electrochim Acta,2010,56(1):372.
[8]Zeng Z Y,Tu J P,Huan X H,et al.Electrochemical investigation on silicon/titanium carbide nano composite film anode for Li ion batteries[J].Thin Solid Films,2009,517(17):4767.
[9]张凯,白红美,程方益,等.真空蒸镀法制备锡薄膜及其嵌锂电化学性能[J].应用化学,2011,28(8):918-923.
[10]Yu Y,Gu L,Dhanabalan A,et al.Three-dimensional porous amorphous SnO2thin films as anodes for Li-ion batteries[J].Electrochimica Acta,2009,54(28):7227-7230.
[11]Oltean G,Valvo M.On the electrophoretic and sol-gel deposition of active materials on aluminium rod current collectors for three-dimensional Li-ion micro-batteries[J].Thin Solid Films,2014,562:63-69.
[12]Lamberti A,Sacco A,Bianco S,et al.Charge transport improvement employing TiO2nanotube arrays as front-side illuminated dye-sensitized solar cell photoanodes[J].Physical Chemistry and Chemical Physics,2013,15,2596-2602.
[13]Kyeremateng N A,Vacandio F,Sougrati M T,et al.Effect of Sn-doping on the electrochemical behaviour of TiO2 nanotubes as potential negative electrode materials for 3D Li-ion micro batteries[J].Journal of Power Source,2013,224:269-277.
[14]Liang H X,Zhao X,Yu Z Y,et al.Effect of ultrasonic irradiation on structure and electrochemical properties of LiMn2O4thin films cathode material for Li-ion micro-batteries[J].Solid State Ionics,2011,192:339-342.
[15]Xia H,Xiong W,Lim C K,et al.Hierarchical TiO2-B nanowire@α-Fe2O3nanothorn core-branch arrays as superior electrodes for lithium-ion microbatteries[J].Nano Research,2014,7(12):1797-1808.
[16]Rolison R D,Long W J.Multifunctional 3Dnano architectures for energy storage and conversion[J].Chemical Society Reviews,2009,38:226.
[17]Valvo M,Roberts M,Oltean G,et al.Electroc hemical elaboration of electrodes and electrolytes for 3Dstructured batteries[J].Mater Chem,2013,(1),9281.
[18]Roberts M,Jhons P.3DLi-thiumion batteries-from fundamentals to fabrication[J].Chemistry of Materials,2011,21:9876.
[19]Sun K,Wei T S,Ahn B Y,et al.3DPrinting of interdigitated Li-ion microbattery architectures[J].Advanced Materials,2013,25:4539-4543.
[20]Yin Z,Huang Y,Bu N,et al.Inkjet printing for flexible electronics:materials,processes and equipments[J].Chinese Science Bulletin,2010,55:3383-3407.
[21]Kim D,Jeong S,Lee S,et al.Organic thin film transistor using silver electrodes technology by the ink-jet prining[J].Thin Solid Films,2007,515(19):7692-7696.
[22]Delannoy P E,Riou V B,Brousse T,et al.Ink-jet printed porous composite LiFePO4 electrode from aqueous suspension for microbatteries[J].Journal of Power Sources,2015,287:261-268.
[23]Ricardo E S,Carlos M C,Senentxu L M.Advances and future challenges in printed batteries[J].Chemsuschem Reviews,2015(8),3539-3555.
[24]黄俊杰,江志裕.喷墨打印制备LiMn2O4薄膜电极及其电化学性能[J].物理化学学报,2008,24(9):1563-1567.
[25]王永庆,郭玉国,万立骏.锂离子电池纳米电极薄膜的喷墨打印研究[J].科学通报,2013,58(31):3227-3232.
[26]Fu K,Wang Y B,Yan C Y,et al.Graphene oxide-based electrode inks for 3D-printed Lithium-ion batteries[J].Advanced Materials,2016,28,2587-2594.
[27]Delannoy P E,Riou B,Brousse T,et al.Ink-jet printed porous composite LiFePO4 electrode from aqueous suspension for microbatteries[J].Journal of Power Sources,2015,287:261-268.