微山湖流域高氟地下水的成因分析
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摘要
依据2006—2016年间采集的区内475件地下水无机分析数据以及钻探岩心易溶盐测试数据,详细研究了微山湖流域高氟地下水的分布特征和富集机制。结果表明:微山湖流域高氟地下水的分布有明显的东西分区特征,湖西冲积、湖积平原区有大范围的高氟地下水,在深度0—40 m的浅层孔隙地下水中,氟含量以1~2 mg/L为主,仅现代黄河影响带地下水氟含量小于1 mg/L,金乡、单县、嘉祥局部超过3 mg/L,最大值9.5 mg/L;在深度150—400 m的深层孔隙地下水中,氟含量以1~1.5 mg/L为主,菏泽—单县条带氟含量超过2 mg/L,最大值3.5 mg/L。微山湖东冲积、洪积平原浅层孔隙地下水、深层岩溶地下水氟含量均小于1 mg/L。湖西冲积、湖积平原沉积物中可溶性氟含量随深度增加而降低。微山湖流域湖西高氟地下水形成受物质来源、淋滤和蒸发浓缩等三方面因素共同控制,CaF_2的溶解平衡是控制地下水F–含量的重要因素。
Based on the analysis of 475 groundwater inorganic data collected from 2006 to 2016 and the data of soluble salts in sediments, the authors studied in detail the distribution characteristics and enrichment mechanism of high fluoride groundwater in Weishan Lake watershed. The results show that the distribution of high fluoride groundwater in Weishan Lake watershed is obviously characterized by east and west partitioning, and there is a wide range of high fluoride groundwater in the west alluvial and lacustrine plain. In the west alluvial and lacustrine plain, the fluoride concentration in shallow groundwater at the depth of 0–40 m is mainly 1~2 mg/L, only under the impact of the modern Yellow River the fluoride concentration is lower than 1 mg/L, and in the areas of Jinxiang, Shanxian, Jiaxiang, the fluoride concentration is higher than 3 mg/L, with the maximum being 9.5 mg/L; in deep confined groundwater at the depth of 150–400 m, the fluoride concentration is mainly 1~1.5 mg/L, the fluoride whose concentration is higher than 2 mg/L is distributed in the area of Heze–Shanxian stripe, with the maximum concentration being 3.5 mg/L. In the east alluvial and flood plain, the fluoride concentration is lower than 1 mg/L both in the shallow groundwater and deep confined groundwater. The concentration of soluble fluorine in the sediments of the west alluvial and lacustrine plain decreases with the increasing depth. The formation of high fluoride groundwater in the west Weishan Lake watershed is controlled by three factors, i.e., material source, leaching and evaporation concentration. The dissolution equilibrium of calcium fluoride is an important controlling factor responsible for the fluoride content in groundwater.
Based on the analysis of 475 groundwater inorganic data collected from 2006 to 2016 and the data of soluble salts in sediments, the authors studied in detail the distribution characteristics and enrichment mechanism of high fluoride groundwater in Weishan Lake watershed. The results show that the distribution of high fluoride groundwater in Weishan Lake watershed is obviously characterized by east and west partitioning, and there is a wide range of high fluoride groundwater in the west alluvial and lacustrine plain. In the west alluvial and lacustrine plain, the fluoride concentration in shallow groundwater at the depth of 0–40 m is mainly 1~2 mg/L, only under the impact of the modern Yellow River the fluoride concentration is lower than 1 mg/L, and in the areas of Jinxiang, Shanxian, Jiaxiang, the fluoride concentration is higher than 3 mg/L, with the maximum being 9.5 mg/L; in deep confined groundwater at the depth of 150–400 m, the fluoride concentration is mainly 1~1.5 mg/L, the fluoride whose concentration is higher than 2 mg/L is distributed in the area of Heze–Shanxian stripe, with the maximum concentration being 3.5 mg/L. In the east alluvial and flood plain, the fluoride concentration is lower than 1 mg/L both in the shallow groundwater and deep confined groundwater. The concentration of soluble fluorine in the sediments of the west alluvial and lacustrine plain decreases with the increasing depth. The formation of high fluoride groundwater in the west Weishan Lake watershed is controlled by three factors, i.e., material source, leaching and evaporation concentration. The dissolution equilibrium of calcium fluoride is an important controlling factor responsible for the fluoride content in groundwater.
引文
曹志洋,冯启言,吴晴晴,孟磊.2010.江苏丰沛地区浅层地下水氟含量的空间变异与分布特征[J].水文地质工程地质,37(3):127-132.
中华人民共和国卫生部.2006.生活饮用水卫生标准GB5749-2006[J].北京:标准出版社.
冯翠娥,高存荣,王俊涛,刘文波,宋建新,康伟.2015.内蒙古河套平原浅层高铁高氟地下水分布与成因[J].地球学报,36(1):67-75.
李向全,祝立人,侯新伟,张莉.2007.太原盆地浅层高氟水分布特征及形成机制研究[J].地球学报,28(1):55-61.
梁秀娟.2008.吉林西部洋沙泡水库水土环境中氟的迁移转化机理研究[D].长春:吉林大学:5-12.
刘征原,郝瑞彬.2007.氟的环境地球化学特征及生物效应[J].唐山师范学院学报,29(2):34-35.
毛若愚,郭华明,贾永峰,姜玉肖,曹永生,赵威光,王振.2016.内蒙古河套盆地含氟地下水分布特点及成因[J].地学前缘,23(2):260-268.
戎秋涛,翁焕新.1990.环境地球化学[M].北京:地质出版社:228-229.
石维栋,郭建强,张森琦,叶成明,李健,马新华.2010.贵德盆地高氟、高砷地下热水分布及水化学特征[J].水文地质工程地质,37(2):36-40.
孙一博,王文科,张春潮,段磊,王宇航,李慧.2013.关中盆地浅层高氟水形成演化机制[J].水文地质工程地质,40(6):117-122.
吴旸,郭华明,韩双宝,张福存.2013.宁南西吉含水层沉积物的氟释放特征[J].水文地质工程地质,40(5):117-123.
邢怀学,李亮,葛伟亚,叶念军,龚建师,周锴锷,朱春芳.2014.安徽省淮北市地下水中氟的空间分布特征及成因[J].地球学报,35(2):163-168.
云中杰,陈培忠,边建朝,郝继涛,秦玉平,高红旭,王玉涛,马爱华.2003.山东省地方性氟中毒防治工作现状分析[J].中国地方病学杂志,22(7):384-386.
曾溅辉,张宗祜,任福弘.1997.非饱和带土体-浅层地下水系统氟的地球化学--以河北邢台山前平原为例[J].地球学报,18(4):389-396.
赵伦山,武胜,周继华,王敬华,王建武.2007.大同盆地砷、氟中毒地方病生态地球化学研究[J].地学前缘,14(2):225-235.
左锐,谷鹏,滕彦国,王强,王金生,王膑.2015.下辽河平原高氟地下水空间分布及成因分析[J].水文地质工程地质,42(3):135-140.
CAO Zhi-yang,FENG Qi-yang,WU Qing-qing,MENG Lei.2010.Spatial variability and distribution of fluorine contents in shallow groundwater in the Fengpei area,Jiangsu[J].Hydrogeology&Engineering Geology,37(3):127-132(in Chinese with English abstract).
CHAE G T,YUN S T,MAYER B,KIM K H,KIM S Y,KWON JS,KIM K,KOH Y K.2007.Fluorine geochemistry in bedrock groundwater of South Korea[J].Science of the Total Environment,385(1):272-283.
FENG Cui-e,GAO Cun-rong,WANG Jun-tao,LIU Wen-bo,SONGJian-xin,KANG Wei.2015.Distribution and Causes of High-iron and High-fluoride Shallow Groundwater in the Hetao Plain of Inner Mongolia[J].Acta Geoscientia Sinica,36(1):67-75(in Chinese with English abstract).
LI Xiang-quan,ZHU Li-ren,HOU Xin-wei,ZHANG Li.2007.Distribution and Evolutional Mechanism of Shallow High_Fluoride Groundwater in Taiyuan Basin[J].Acta Geoscientia Sinica,28(1):55-61(in Chinese with English abstract).
LIANG Xiu-juan.2008.Research on the transportation and change mechanism of fluorine in water and soils in Yangshapao reservoir,western Jilin province[D].Changchun:Jilin University:5-12(in Chinese with English abstract).
LIU Zheng-yuan,HAO Rui-bin.2007.Environmental Geochemistry Characteristics of Fluorine and Its Biological Effects[J].Journal of Tangshan Teachers College,29(2):34-35(in Chinese with English abstract).
MAO Ruo-yu,GUO Hua-ming,JIA Yong-feng,JIANG Yu-xiao,CAO Yong-sheng,ZHAO Wei-guang,WANG Zhen.2016.Distribution characteristics and genesis of fluoride groundwater in the Hetao basin,Inner Mongolia[J].Earth Science Frontiers,23(2):260-268(in Chinese with English abstract).
Ministry of Health P.R.China.2006.Standards for Drinking Water Quality GB5749-2006[J].Beijing:Standard Press(in Chinese).
RONG Qiu-tao,WENG Huan-xin.1998.Environmental Geo-chemistry[M].Beijing:Geological Publishing House:217-230(in Chinese).
RUKAH Y A,ALSOKHNY K.2004.Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration,North Jordan[J].Chemie der Erde,64:171-181.
SHI Wei-dong,GUO Jian-qiang,ZHANG Sen-qi,YE Cheng-ming,LI Jian,MA Xin-hua.2010.The distribution and geochemistry of geothermal groundwater bearing F and as in the guide basin[J].Hydrogeology&Engineering Geology,37(2):36-40(in Chinese with English abstract).
SUN Yi-bo,WANG Wen-ke,ZHANG Chun-chao,DUAN Lei,WANG Yu-hang,LI Hui.2013.Evolution mechanism of shallow high fluoride groundwater in the Guanzhong basin[J].Hydrogeology&Engineering Geology,40(6):117-122(in Chinese with English abstract).
WU Yang,GUO Hua-ming,HAN Shuang-bao,ZHANG Fu-cun.2013.Characteristics of fluoride release from aquifer sediments in Xiji of southern Ningxia[J].Hydrogeology&Engineering Geology,40(5):117-123(in Chinese with English abstract).
XING Huai-xue,LI Liang,GE Wei-ya,YE Nian-jun,GONGJian-shi,ZHOU Kai-e,ZHU Chun-fang.2014.Spatial Distribution Characteristics and Origin of Fluorine in Groundwater of Huaibei City,Anhui Province[J].Acta Geoscientia Sinica,35(2):163-168(in Chinese with English abstract).
YUN Zhong-jie,CHEN Pei-zhong,BIAN Jian-chao,HAO Ji-tao,QIN Yu-ping,GAO Hong-xu,WANG Yu-tao,MA Ai-hua.2003.Analysis of endemic fluorosis prevention and control in Shandong[J].Chinese Journal of Endemiology,22(7):384-386(in Chinese).
ZENG Jian-hui,ZHANG Zong-hu,REN Fu-hong.1997.Fluorine Geochemistry in the Unsaturated Soils-Shallow Groundwater Systems-A Case Study on the Xingtai Piedmont Plain,Hebei[J].Acta Geoscientia Sinica,18(4):389-396(in Chinese with English abstract).
ZHAO Lun-shan,WU Sheng,ZHOU Ji-hua,WANG Jin-hua,WANGJian-wu.2007.Eco-geochemical investigation on the endemic As and F poisoning in Datong Basin[J].Earth Science Frontiers,14(2):225-235(in Chinese with English abstract).
ZUO Rui,GU-Peng,TEN Yan-guo,WANG Qiang,WANG Jin-sheng,WANG Bin.2015.Spatial distribution and Genesis of the hig-fluorine groundwater[J].Hydrogeology&Engineering Geology,42(3):135-140(in Chinese with English abstract).
中华人民共和国卫生部.2006.生活饮用水卫生标准GB5749-2006[J].北京:标准出版社.
冯翠娥,高存荣,王俊涛,刘文波,宋建新,康伟.2015.内蒙古河套平原浅层高铁高氟地下水分布与成因[J].地球学报,36(1):67-75.
李向全,祝立人,侯新伟,张莉.2007.太原盆地浅层高氟水分布特征及形成机制研究[J].地球学报,28(1):55-61.
梁秀娟.2008.吉林西部洋沙泡水库水土环境中氟的迁移转化机理研究[D].长春:吉林大学:5-12.
刘征原,郝瑞彬.2007.氟的环境地球化学特征及生物效应[J].唐山师范学院学报,29(2):34-35.
毛若愚,郭华明,贾永峰,姜玉肖,曹永生,赵威光,王振.2016.内蒙古河套盆地含氟地下水分布特点及成因[J].地学前缘,23(2):260-268.
戎秋涛,翁焕新.1990.环境地球化学[M].北京:地质出版社:228-229.
石维栋,郭建强,张森琦,叶成明,李健,马新华.2010.贵德盆地高氟、高砷地下热水分布及水化学特征[J].水文地质工程地质,37(2):36-40.
孙一博,王文科,张春潮,段磊,王宇航,李慧.2013.关中盆地浅层高氟水形成演化机制[J].水文地质工程地质,40(6):117-122.
吴旸,郭华明,韩双宝,张福存.2013.宁南西吉含水层沉积物的氟释放特征[J].水文地质工程地质,40(5):117-123.
邢怀学,李亮,葛伟亚,叶念军,龚建师,周锴锷,朱春芳.2014.安徽省淮北市地下水中氟的空间分布特征及成因[J].地球学报,35(2):163-168.
云中杰,陈培忠,边建朝,郝继涛,秦玉平,高红旭,王玉涛,马爱华.2003.山东省地方性氟中毒防治工作现状分析[J].中国地方病学杂志,22(7):384-386.
曾溅辉,张宗祜,任福弘.1997.非饱和带土体-浅层地下水系统氟的地球化学--以河北邢台山前平原为例[J].地球学报,18(4):389-396.
赵伦山,武胜,周继华,王敬华,王建武.2007.大同盆地砷、氟中毒地方病生态地球化学研究[J].地学前缘,14(2):225-235.
左锐,谷鹏,滕彦国,王强,王金生,王膑.2015.下辽河平原高氟地下水空间分布及成因分析[J].水文地质工程地质,42(3):135-140.
CAO Zhi-yang,FENG Qi-yang,WU Qing-qing,MENG Lei.2010.Spatial variability and distribution of fluorine contents in shallow groundwater in the Fengpei area,Jiangsu[J].Hydrogeology&Engineering Geology,37(3):127-132(in Chinese with English abstract).
CHAE G T,YUN S T,MAYER B,KIM K H,KIM S Y,KWON JS,KIM K,KOH Y K.2007.Fluorine geochemistry in bedrock groundwater of South Korea[J].Science of the Total Environment,385(1):272-283.
FENG Cui-e,GAO Cun-rong,WANG Jun-tao,LIU Wen-bo,SONGJian-xin,KANG Wei.2015.Distribution and Causes of High-iron and High-fluoride Shallow Groundwater in the Hetao Plain of Inner Mongolia[J].Acta Geoscientia Sinica,36(1):67-75(in Chinese with English abstract).
LI Xiang-quan,ZHU Li-ren,HOU Xin-wei,ZHANG Li.2007.Distribution and Evolutional Mechanism of Shallow High_Fluoride Groundwater in Taiyuan Basin[J].Acta Geoscientia Sinica,28(1):55-61(in Chinese with English abstract).
LIANG Xiu-juan.2008.Research on the transportation and change mechanism of fluorine in water and soils in Yangshapao reservoir,western Jilin province[D].Changchun:Jilin University:5-12(in Chinese with English abstract).
LIU Zheng-yuan,HAO Rui-bin.2007.Environmental Geochemistry Characteristics of Fluorine and Its Biological Effects[J].Journal of Tangshan Teachers College,29(2):34-35(in Chinese with English abstract).
MAO Ruo-yu,GUO Hua-ming,JIA Yong-feng,JIANG Yu-xiao,CAO Yong-sheng,ZHAO Wei-guang,WANG Zhen.2016.Distribution characteristics and genesis of fluoride groundwater in the Hetao basin,Inner Mongolia[J].Earth Science Frontiers,23(2):260-268(in Chinese with English abstract).
Ministry of Health P.R.China.2006.Standards for Drinking Water Quality GB5749-2006[J].Beijing:Standard Press(in Chinese).
RONG Qiu-tao,WENG Huan-xin.1998.Environmental Geo-chemistry[M].Beijing:Geological Publishing House:217-230(in Chinese).
RUKAH Y A,ALSOKHNY K.2004.Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration,North Jordan[J].Chemie der Erde,64:171-181.
SHI Wei-dong,GUO Jian-qiang,ZHANG Sen-qi,YE Cheng-ming,LI Jian,MA Xin-hua.2010.The distribution and geochemistry of geothermal groundwater bearing F and as in the guide basin[J].Hydrogeology&Engineering Geology,37(2):36-40(in Chinese with English abstract).
SUN Yi-bo,WANG Wen-ke,ZHANG Chun-chao,DUAN Lei,WANG Yu-hang,LI Hui.2013.Evolution mechanism of shallow high fluoride groundwater in the Guanzhong basin[J].Hydrogeology&Engineering Geology,40(6):117-122(in Chinese with English abstract).
WU Yang,GUO Hua-ming,HAN Shuang-bao,ZHANG Fu-cun.2013.Characteristics of fluoride release from aquifer sediments in Xiji of southern Ningxia[J].Hydrogeology&Engineering Geology,40(5):117-123(in Chinese with English abstract).
XING Huai-xue,LI Liang,GE Wei-ya,YE Nian-jun,GONGJian-shi,ZHOU Kai-e,ZHU Chun-fang.2014.Spatial Distribution Characteristics and Origin of Fluorine in Groundwater of Huaibei City,Anhui Province[J].Acta Geoscientia Sinica,35(2):163-168(in Chinese with English abstract).
YUN Zhong-jie,CHEN Pei-zhong,BIAN Jian-chao,HAO Ji-tao,QIN Yu-ping,GAO Hong-xu,WANG Yu-tao,MA Ai-hua.2003.Analysis of endemic fluorosis prevention and control in Shandong[J].Chinese Journal of Endemiology,22(7):384-386(in Chinese).
ZENG Jian-hui,ZHANG Zong-hu,REN Fu-hong.1997.Fluorine Geochemistry in the Unsaturated Soils-Shallow Groundwater Systems-A Case Study on the Xingtai Piedmont Plain,Hebei[J].Acta Geoscientia Sinica,18(4):389-396(in Chinese with English abstract).
ZHAO Lun-shan,WU Sheng,ZHOU Ji-hua,WANG Jin-hua,WANGJian-wu.2007.Eco-geochemical investigation on the endemic As and F poisoning in Datong Basin[J].Earth Science Frontiers,14(2):225-235(in Chinese with English abstract).
ZUO Rui,GU-Peng,TEN Yan-guo,WANG Qiang,WANG Jin-sheng,WANG Bin.2015.Spatial distribution and Genesis of the hig-fluorine groundwater[J].Hydrogeology&Engineering Geology,42(3):135-140(in Chinese with English abstract).