锡石浮选工艺和药剂研究现状
|
摘要
随着锡矿资源的不断开采利用,矿石中"贫、细、杂"问题愈加突出,微细粒级锡矿和锡尾矿的回收利用成为研究重点。概述了锡石浮选技术的研究现状及进展,主要介绍了浮选工艺和药剂研究现状。在此基础上,展望了今后锡矿浮选的研究方向,内容可为锡矿浮选的新工艺和新药剂研发提供参考。
The problem of"poor,fine,and complicated"in ore has become more and more prominent,and the recycling of fine-grained tin ore and tin tailings has become the focus of research,due to the continuous exploitation and utilization of tin resources.The research status and progress of cassiterite flotation technology are summarized,and the research status of flotation process and agentia research is introduced.On this basis,the future research direction of tin ore flotation is prospected,and the content can provide reference for the new process and reagent of tin ore flotation.
The problem of"poor,fine,and complicated"in ore has become more and more prominent,and the recycling of fine-grained tin ore and tin tailings has become the focus of research,due to the continuous exploitation and utilization of tin resources.The research status and progress of cassiterite flotation technology are summarized,and the research status of flotation process and agentia research is introduced.On this basis,the future research direction of tin ore flotation is prospected,and the content can provide reference for the new process and reagent of tin ore flotation.
引文
[1]ANGADI S I,SREENIVAS T,JEON H S,et al.Areview of cassiterite beneficiation fundamentals and plant practices[J].Minerals Engineering,2015,70:178-200.
[2]LEISTNER T,EMBRECHTS M,LEIβNER T,et al.A study of the reprocessing of fine and ultrafine cassiterite from gravity tailing residues by using various flotation techniques[J].Minerals Engineering,2016,96-97:94-98.
[3]梁增永,邓海波.“磁-浮-重”联合流程分选某锡石多金属硫化矿的研究[J].有色金属(选矿部分),2012(1):29-32.
[4]兰希雄,何东,何庆浪.细粒锡石浮选工艺研究实践与展望[J].矿物学报,2016,36(4):544-548.
[5]汪泰.“重-浮-重”联合流程回收低品位细粒锡石[J].矿冶工程,2015,35(6):68-71.
[6]许大洪,郑文军,黄闰芝.某选矿厂尾矿微细粒级锡石回收利用试验研究[J].大众科技,2012(1):121-123.
[7]蒋素芳.国外某高硫锡矿石选矿工艺研究[J].矿冶工程,2015,35(3):66-69.
[8]刘厚明,戴新宇,王昌良,等.一种铜锡矿石的综合回收试验研究[J].金属矿山,2009(5):75-79.
[9]GOCHIN R J,SOLARI J A,杨敖.溶气浮选法回收细粒锡石[J].国外金属矿选矿,1985(3):10-18.
[10]QIN W Q,REN L Y,WANG P P,et al.Electroflotation and collision-attachment mechanism of fine cassiterite[J].Transactions of Nonferrous Metals Society of China,2012,22(4):917-924.
[11]REN L Y,ZHANG Y M,QIN W Q,et al.Collision and attachment behavior between fine cassiterite particles and H2,bubbles[J].Transactions of Nonferrous Metals Society of China,2014,24(2):520-527.
[12]周德炎,韦丽广,黄闰芝.某低品位微细泥锡石浮选新工艺研究[J].大众科技,2015(11):46-49.
[13]严伟平.微细粒锡石的载体浮选工艺研究[D].江西赣州:江西理工大学,2012.
[14]高跃升,高志勇,孙伟.金属离子对矿物浮选行为的影响及机理研究进展[J].中国有色金属学报,2017,27(4):859-868.
[15]张周位.锡石浮选体系中金属离子作用机理及其应用[D].长沙:中南大学,2013.
[16]普拉蒂普,汪镜亮,李长根.浮选药剂的分子模拟及合理设计[J].国外金属矿选矿,2004,41(10):28-34.
[17]朱建光,朱一民.用浮选药剂的同分异构原理寻找浮选锡石和黑钨矿捕收剂[J].矿产综合利用,2012(2):10-13.
[18]丁可鉴,田忠诚.水杨氧肟酸对锡石的捕收性能及其作用机理[J].矿冶工程,1991,11(3):20-22.
[19]WU X Q,ZHU J G.Selective flotation of cassiterite with benzohydroxamic acid[J].Minerals Engineering,2006,19(14):1410-1417.
[20]漆燕,尤翔宇,向仁军,等.尾砂中锡石的综合回收及浮选机理[J].湖南科技大学学报(自然科学版),2015,30(3):119-124.
[21]孙伟,柯丽芳,孙磊.苯甲羟肟酸在锡石浮选中的应用及作用机理研究[J].中国矿业大学学报,2013,42(1):62-68.
[22]TIAN M J,GAO Z Y,HAN H S,et al.Improved flotation separation of cassiterite from calcite using a mixture of lead(II)ion/benzohydroxamic acid as collector and carboxymethyl cellulose as depressant[J].Minerals Engineering,2017,113:68-70.
[23]WANG P P,QIN W Q,REN L Y,et al.Solution chemistry and utilization of alkyl hydroxamic acid in flotation of fine cassiterite[J].Transactions of Nonferrous Metals Society of China,2013,23(6):1789-1796.
[24]TAN X,HE F Y,SHANG Y B,et al.Flotation behavior and adsorption mechanism of(1-hydroxy-2-methyl-2-octenyl)phosphonic acid to cassiterite[J].Transactions of Nonferrous Metals Society of China,2016,26(9):2469-2478.
[25]钟宏,张鹏飞.膦酸类捕收剂对细粒锡石和赤铁矿捕收性能的研究[J].有色金属(选矿部分),1988(3):52-56.
[26]覃文庆,王佩佩,任浏祎,等.颗粒气泡的匹配关系对细粒锡石浮选的影响[J].中国矿业大学学报,2012,41(3):420-424.
[27]曾清华,张秀华.烷基磺化琥珀酰胺酸盐类锡石捕收剂的研究及应用[J].国外金属矿选矿,1995(2):27-29.
[28]曾清华,张秀华.Aerosol-22与锡石浮选作用机理[J].有色金属,1996(4):29-34.
[29]姚建伟,袁经中,汪泰.云锡卡房铜硫浮选尾矿中细粒锡石的回收[J].金属矿山,2015,44(7):159-163.
[30]黄顶.铁铬盐木质素在锡石浮选中的应用[J].有色金属(选矿部分),1985(3):64-65.
[31]钟宏,张鹏飞.膦酸类捕收剂对细粒锡石和赤铁矿捕收性能的研究[J].有色金属(选矿部分),1988(3):52-56.
[32]张泾生.腐殖酸用于玻利维亚锡石浮选的研究[J].有色金属(选矿部分),1988(5):23-25.
[33]徐龙华,田佳,巫侯琴,等.组合捕收剂在矿物表面的协同效应及其浮选应用综述[J].矿产保护与利用,2017(2):107-112.
[34]刘德全,朱建光.水杨羟肟酸与铜铁灵浮选锡石的协同作用及其机理研究[J].矿冶工程,1994,14(2):27-31.
[35]刘德全,周春山.铜铁灵与苯异羟肟酸浮选锡石的交互作用及其机理[J].中国有色金属学报,1994(4):46-49.
[36]朱建光,周春山.混合捕收剂的协同效应在黑钨、锡石细泥浮选中的应用[J].中南大学学报(自然科学版),1995(4):465-469.
[37]刘祁,王三海,胡瑞彪.某高硫细泥锡矿浮选试验研究[J].矿产保护与利用,2016(3):35-39.
[38]SUN L,HU Y H,SUN W.Effect and mechanism of octanol in cassiterite flotation using benzohydroxamic acid as collector[J].Transactions of Nonferrous Metals Society of China,2016,26(12):3253-3257.
[39]宫贵臣,刘杰,韩跃新.金属离子对微细粒锡石浮选行为的影响[J].矿产综合利用,2016(4):43-47.
[40]FENG Q C,WEN S M,ZHAO W J,et al.Effect of calcium ions on adsorption of sodium oleate onto cassiterite and quartz surfaces and implications for their flotation separation[J]Separation and Purification Technology,2018,200:300-306.
[41]TIAN M J,HU Y H,SUN W,et al.Study on the mechanism and application of a novel collectorcomplexes in cassiterite flotation[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2017,522:635-641.
[42]FENG Q C,ZHAO W J,WEN S M,et al.Activation mechanism of lead ions in cassiterite flotation with salicylhydroxamic acid as collector[J].Separation&Purification Technology,2017,178:193-199.
[43]石道民.锡石浮选与表面电性[J].昆明理工大学学报(自然科学版),1987(3):42-49.
[44]曾清华,赵宏,王淀佐.锡石浮选中捕收剂和金属离子的作用[J].有色金属,1998(4):21-25.
[45]张亚辉.浮选药剂与矿物界面作用的镜像对称规则[J].有色金属(选矿部分),2016(4):87-93.
[2]LEISTNER T,EMBRECHTS M,LEIβNER T,et al.A study of the reprocessing of fine and ultrafine cassiterite from gravity tailing residues by using various flotation techniques[J].Minerals Engineering,2016,96-97:94-98.
[3]梁增永,邓海波.“磁-浮-重”联合流程分选某锡石多金属硫化矿的研究[J].有色金属(选矿部分),2012(1):29-32.
[4]兰希雄,何东,何庆浪.细粒锡石浮选工艺研究实践与展望[J].矿物学报,2016,36(4):544-548.
[5]汪泰.“重-浮-重”联合流程回收低品位细粒锡石[J].矿冶工程,2015,35(6):68-71.
[6]许大洪,郑文军,黄闰芝.某选矿厂尾矿微细粒级锡石回收利用试验研究[J].大众科技,2012(1):121-123.
[7]蒋素芳.国外某高硫锡矿石选矿工艺研究[J].矿冶工程,2015,35(3):66-69.
[8]刘厚明,戴新宇,王昌良,等.一种铜锡矿石的综合回收试验研究[J].金属矿山,2009(5):75-79.
[9]GOCHIN R J,SOLARI J A,杨敖.溶气浮选法回收细粒锡石[J].国外金属矿选矿,1985(3):10-18.
[10]QIN W Q,REN L Y,WANG P P,et al.Electroflotation and collision-attachment mechanism of fine cassiterite[J].Transactions of Nonferrous Metals Society of China,2012,22(4):917-924.
[11]REN L Y,ZHANG Y M,QIN W Q,et al.Collision and attachment behavior between fine cassiterite particles and H2,bubbles[J].Transactions of Nonferrous Metals Society of China,2014,24(2):520-527.
[12]周德炎,韦丽广,黄闰芝.某低品位微细泥锡石浮选新工艺研究[J].大众科技,2015(11):46-49.
[13]严伟平.微细粒锡石的载体浮选工艺研究[D].江西赣州:江西理工大学,2012.
[14]高跃升,高志勇,孙伟.金属离子对矿物浮选行为的影响及机理研究进展[J].中国有色金属学报,2017,27(4):859-868.
[15]张周位.锡石浮选体系中金属离子作用机理及其应用[D].长沙:中南大学,2013.
[16]普拉蒂普,汪镜亮,李长根.浮选药剂的分子模拟及合理设计[J].国外金属矿选矿,2004,41(10):28-34.
[17]朱建光,朱一民.用浮选药剂的同分异构原理寻找浮选锡石和黑钨矿捕收剂[J].矿产综合利用,2012(2):10-13.
[18]丁可鉴,田忠诚.水杨氧肟酸对锡石的捕收性能及其作用机理[J].矿冶工程,1991,11(3):20-22.
[19]WU X Q,ZHU J G.Selective flotation of cassiterite with benzohydroxamic acid[J].Minerals Engineering,2006,19(14):1410-1417.
[20]漆燕,尤翔宇,向仁军,等.尾砂中锡石的综合回收及浮选机理[J].湖南科技大学学报(自然科学版),2015,30(3):119-124.
[21]孙伟,柯丽芳,孙磊.苯甲羟肟酸在锡石浮选中的应用及作用机理研究[J].中国矿业大学学报,2013,42(1):62-68.
[22]TIAN M J,GAO Z Y,HAN H S,et al.Improved flotation separation of cassiterite from calcite using a mixture of lead(II)ion/benzohydroxamic acid as collector and carboxymethyl cellulose as depressant[J].Minerals Engineering,2017,113:68-70.
[23]WANG P P,QIN W Q,REN L Y,et al.Solution chemistry and utilization of alkyl hydroxamic acid in flotation of fine cassiterite[J].Transactions of Nonferrous Metals Society of China,2013,23(6):1789-1796.
[24]TAN X,HE F Y,SHANG Y B,et al.Flotation behavior and adsorption mechanism of(1-hydroxy-2-methyl-2-octenyl)phosphonic acid to cassiterite[J].Transactions of Nonferrous Metals Society of China,2016,26(9):2469-2478.
[25]钟宏,张鹏飞.膦酸类捕收剂对细粒锡石和赤铁矿捕收性能的研究[J].有色金属(选矿部分),1988(3):52-56.
[26]覃文庆,王佩佩,任浏祎,等.颗粒气泡的匹配关系对细粒锡石浮选的影响[J].中国矿业大学学报,2012,41(3):420-424.
[27]曾清华,张秀华.烷基磺化琥珀酰胺酸盐类锡石捕收剂的研究及应用[J].国外金属矿选矿,1995(2):27-29.
[28]曾清华,张秀华.Aerosol-22与锡石浮选作用机理[J].有色金属,1996(4):29-34.
[29]姚建伟,袁经中,汪泰.云锡卡房铜硫浮选尾矿中细粒锡石的回收[J].金属矿山,2015,44(7):159-163.
[30]黄顶.铁铬盐木质素在锡石浮选中的应用[J].有色金属(选矿部分),1985(3):64-65.
[31]钟宏,张鹏飞.膦酸类捕收剂对细粒锡石和赤铁矿捕收性能的研究[J].有色金属(选矿部分),1988(3):52-56.
[32]张泾生.腐殖酸用于玻利维亚锡石浮选的研究[J].有色金属(选矿部分),1988(5):23-25.
[33]徐龙华,田佳,巫侯琴,等.组合捕收剂在矿物表面的协同效应及其浮选应用综述[J].矿产保护与利用,2017(2):107-112.
[34]刘德全,朱建光.水杨羟肟酸与铜铁灵浮选锡石的协同作用及其机理研究[J].矿冶工程,1994,14(2):27-31.
[35]刘德全,周春山.铜铁灵与苯异羟肟酸浮选锡石的交互作用及其机理[J].中国有色金属学报,1994(4):46-49.
[36]朱建光,周春山.混合捕收剂的协同效应在黑钨、锡石细泥浮选中的应用[J].中南大学学报(自然科学版),1995(4):465-469.
[37]刘祁,王三海,胡瑞彪.某高硫细泥锡矿浮选试验研究[J].矿产保护与利用,2016(3):35-39.
[38]SUN L,HU Y H,SUN W.Effect and mechanism of octanol in cassiterite flotation using benzohydroxamic acid as collector[J].Transactions of Nonferrous Metals Society of China,2016,26(12):3253-3257.
[39]宫贵臣,刘杰,韩跃新.金属离子对微细粒锡石浮选行为的影响[J].矿产综合利用,2016(4):43-47.
[40]FENG Q C,WEN S M,ZHAO W J,et al.Effect of calcium ions on adsorption of sodium oleate onto cassiterite and quartz surfaces and implications for their flotation separation[J]Separation and Purification Technology,2018,200:300-306.
[41]TIAN M J,HU Y H,SUN W,et al.Study on the mechanism and application of a novel collectorcomplexes in cassiterite flotation[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2017,522:635-641.
[42]FENG Q C,ZHAO W J,WEN S M,et al.Activation mechanism of lead ions in cassiterite flotation with salicylhydroxamic acid as collector[J].Separation&Purification Technology,2017,178:193-199.
[43]石道民.锡石浮选与表面电性[J].昆明理工大学学报(自然科学版),1987(3):42-49.
[44]曾清华,赵宏,王淀佐.锡石浮选中捕收剂和金属离子的作用[J].有色金属,1998(4):21-25.
[45]张亚辉.浮选药剂与矿物界面作用的镜像对称规则[J].有色金属(选矿部分),2016(4):87-93.