含砷废水处理研究进展
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摘要
在环境污染中,砷是最常见、危害最严重的物质之一,其对水资源的污染是一个全球性环境问题,严重威胁着人类健康,含砷废水的处理一直受到人们的广泛关注.文中总结了近年来含砷废水主要处理方法的原理、特点和应用现状,对吸附法和生物法进行了重点阐述,分析了它们的优势与共性,以期在实际处理过程中提供技术支持和帮助.
Arsenic is one of the most common and harmful substances in environmental pollution,Its pollution of water resources is a global environmental problem, a serious threat to human health, so the treatment of arsenic containing wastewater has been widespread concern.The principle, characteristics and application status of the main treatment methods of arsenic containing wastewater in recent years were summarized. The adsorption and biological methods were mainly elaborated, and their advantages and commonalities were analyzed, so as to provide technical support and help in the actual process.
Arsenic is one of the most common and harmful substances in environmental pollution,Its pollution of water resources is a global environmental problem, a serious threat to human health, so the treatment of arsenic containing wastewater has been widespread concern.The principle, characteristics and application status of the main treatment methods of arsenic containing wastewater in recent years were summarized. The adsorption and biological methods were mainly elaborated, and their advantages and commonalities were analyzed, so as to provide technical support and help in the actual process.
引文
[1]FENDORF S,MICHAEL H A,VAN G A.Spatial and temporal variations of groundwater arsenic in South and Southeast Asia[J].Science,2010,328(5982):1123.
[2]肖细元,陈同斌,廖晓勇,等.中国主要含砷矿产资源的区域分布与砷污染问题[J].地理研究,2008,27(1):201-212.
[3]廖国权,李华.土壤砷污染的淋洗修复研究进展[J].图书情报导刊,2011,21(34):172-174.
[4]SONG S,LOPEZ-VALDIVIESO A,HERNANDEZ-CAMPOS D J,et al.Arsenic removal from high-arsenic water by enhanced coagulation with ferric ions and coarse calcite[J].Water Research,2006,40(2):364-372.
[5]刘辉利,朱义年.CO2对砷酸钙稳定性影响的热力学分析[J].环境保护科学,2006,32(3):7-9.
[6]ROBINS R G.The solubility of metal arsenates[J].Metallurgical Transactions B,1981,12(1):103-109.
[7]陈云.硫化法从砷滤饼中分离砷的试验研究[J].湿法冶金,2009,28(4):233-235.
[8]应国民,阴树标,陈雯,等.两段石灰中和—洗涤—絮凝沉淀法脱除污酸中砷的研究[J].矿冶,2017,26(2):71-76.
[9]王德峰,彭先佳,张卫民,等.硫化氢净化强酸性高砷废液[J].环境化学,2015,34(12):2233-2238.
[10]王世阳,徐环昕,宁方红,等.新型载锆树脂除As(V)的研究[J].离子交换与吸附,2015(4):347-358.
[11]OCHROMOWICZ K,CHMIELEWSKI T.Solvent extraction in hydrometallurgical processing of polish copper concentrates[J].Physicochemical Problems of Mineral Processing,2011,46(46):207-218.
[12]IBERHAN L,WI S'NIEWSKI M.Removal of arsenic(III)and arsenic(V)from sulfuric acid solution by liquid-liquid extraction[J].Journal of Chemical Technology&Biotechnology,2010,78(6):659-665.
[13]IBERHAN L,WIS'NIEWSKI M.Extraction of arsenic(III)and arsenic(V)with Cyanex 925,Cyanex 301 and their mixtures[J].Hydrometallurgy,2002,63(1):23-30.
[14]丁爱中,陈海英,程莉蓉,等.地下水除砷技术的研究进展[J].安徽农业科学,2008,36(27):11979-11982.
[15]邹路易,毛小庆,李磊,等.巯基壳聚糖/活性炭复合功能膜的砷吸附性能研究[J].安全与环境学报,2013,13(6):31-33.
[16]席北斗,王晓伟,霍守亮,等.纳滤膜技术在地下水除砷应用中的研究进展[J].环境工程学报,2012,6(2):353-360.
[17]PILLEWAN P,MUKHERJEE S,MEHER A K,et al.Removal of arsenic(III)and arsenic(V)using copper exchange zeolite-a[J].Environmental Progress&Sustainable Energy,2015,33(4):1274-1282.
[18]曹秉帝,徐绪筝,王东升,等.三价铁改性活性炭对水中微量砷的吸附特性[J].环境工程学报,2016,10(5):2321-2328.
[19]HUANG Y B,WANG L L,TU S X,et al.Influence of various factors on arsenic removal using ferruginous manganese ore[J].Applied Mechanics&Materials,2011,71/78:2753-2758.
[20]AHMAD H B,AZHAR M,HUSSAIN M,et al.Synthesis and characterization of kaolin supported metallic nanocomposites for the removal of arsenic[J].Fresenius Environmental Bulletin,2015,24(11):4019-4024.
[21]钟松雄,尹光彩,何宏飞,等.不同铁矿物对水稻土砷的稳定化效果及机制[J].环境科学学报,2017,37(5):1931-1938.
[22]赵雅光,万俊锋,王杰,等.零价铁(ZVI)去除水中的As(Ⅲ)[J].化工学报,2015,66(2):730-737.
[23]卞战强,谢莉,田向红,等.三种晶型纳米二氧化锰对水中As(Ⅲ)和As(Ⅴ)的吸附性能研究[J].环境与健康杂志,2012,29(7):645-648.
[24]王文凯,阎莉,段晋明,等.二氧化钛滤柱对高砷污酸废水的吸附去除[J].环境工程学报,2017,11(3):1322-1328.
[25]姜海钰,荆玉姝,高莹,等.活性氧化铝吸附水中砷的动态试验研究[J].青岛理工大学学报,2014,35(2):53-58.
[26]王琼,胡健,黄亚许,等.粉煤灰及其改性材料对废水中砷离子的吸附研究[J].矿冶,2015,24(1):74-76.
[27]YANG L.Simultaneous removal of fluoride and arsenic from aqueous solution using activated red mud[J].Separation Science&Technology,2014,49(15):2412-2425.
[28]杨长明,陈氏秋张,沈烁.钢渣对水溶液中砷的吸附动力学和热力学特性试验[J].净水技术,2015(2):83-89.
[29]NELSON P O,CHUNG A K,HUDSON M C.Factors affecting the fate of heavy metals in the activated sludge process[J].Journal,1981,53(8):1323-1333.
[30]CHENG M H,PATTERSON J W,MINEAR R A.Heavy metals uptake by activated sludge[J].Journal,1975,47(2):362-376.
[31]NEUFELD R D,HERMANN E R.Heavy metal removal by acclimated activated sludge[J].J Water Pollut Control Fed,1975,47(2):310-329.
[32]王岩,刘奉滨,郎龙麒,等.三价砷对SBRs反应系统中活性污泥的影响研究[J].郑州大学学报(工学版),2013,34(5):109-112.
[33]AGRAFIOTI E,KALDERIS D,DIAMADOPOULOS E.Arsenic and chromium removal from water using biochars derived from rice husk,organic solid wastes and sewage sludge.[J].Journal of Environmental Management,2014,133(133):309.
[34]ANDERSON C R,COOK G M.Isolation and characterization of arsenate-reducing bacteria from arsenic-contaminated sites in New Zealand[J].Current Microbiology,2004,48(5):341-7.
[35]许平平,刘聪,王亚,等.共生细菌对盐生小球藻富集和转化砷酸盐的影响[J].环境科学,2016,37(9):3438-3446.
[36]王亚,张春华,王淑,等.带菌盐藻对不同形态砷的富集和转化研究[J].环境科学,2013,34(11):4257-4265.
[37]朱时佳,花修艺,郭志勇,等.铜、铬、铅和砷对自然水体生物膜吸附五氯酚的影响[J].科学技术与工程,2015,15(18):10-15.
[38]A NDJELKOVIC I,AZARI S,ERKELENS M,et al.Bacterial iron-oxide nanowires from biofilm waste as a new adsorbent for the removal of arsenic from water[J].Rsc Advances,2017,7(7):3941-3948.
[39]潘思宇,夏四清,王晨辉,等.利用氢基质生物膜反应器去除水中砷酸盐[J].环境科学学报,2015,35(12):3781-3788.
[40]POON L,YOUNUS S,WILSON L D.Adsorption study of an organo-arsenical with chitosan-based sorbents[J].Journal of Colloid&Interface Science,2014,420(8):136-144.
[41]李雅轩,陈梅青,王瑜瑜,等.铁锰氧化物/醋酸纤维素复合材料制备及除砷性能研究[C]//中国环境科学学会2013年学术年会.北京:中国环境科学学会,2013.
[42]HAN Y H,FU J W,CHEN Y,et al.Arsenic uptake,arsenite efflux and plant growth in hyperaccumulator Pteris vittata:Role of arsenic-resistant bacteria.[J].Chemosphere,2016,144:1937-1942.
[43]PODDER M S,MAJUMDER C B.Characterization and modelling of biosorptive performance of living cells of Bacillus arsenicus,MTCC 4380 for the removal of As(III)and As(V)[J].Journal of Water Process Engineering,2016(9):135-154.
[2]肖细元,陈同斌,廖晓勇,等.中国主要含砷矿产资源的区域分布与砷污染问题[J].地理研究,2008,27(1):201-212.
[3]廖国权,李华.土壤砷污染的淋洗修复研究进展[J].图书情报导刊,2011,21(34):172-174.
[4]SONG S,LOPEZ-VALDIVIESO A,HERNANDEZ-CAMPOS D J,et al.Arsenic removal from high-arsenic water by enhanced coagulation with ferric ions and coarse calcite[J].Water Research,2006,40(2):364-372.
[5]刘辉利,朱义年.CO2对砷酸钙稳定性影响的热力学分析[J].环境保护科学,2006,32(3):7-9.
[6]ROBINS R G.The solubility of metal arsenates[J].Metallurgical Transactions B,1981,12(1):103-109.
[7]陈云.硫化法从砷滤饼中分离砷的试验研究[J].湿法冶金,2009,28(4):233-235.
[8]应国民,阴树标,陈雯,等.两段石灰中和—洗涤—絮凝沉淀法脱除污酸中砷的研究[J].矿冶,2017,26(2):71-76.
[9]王德峰,彭先佳,张卫民,等.硫化氢净化强酸性高砷废液[J].环境化学,2015,34(12):2233-2238.
[10]王世阳,徐环昕,宁方红,等.新型载锆树脂除As(V)的研究[J].离子交换与吸附,2015(4):347-358.
[11]OCHROMOWICZ K,CHMIELEWSKI T.Solvent extraction in hydrometallurgical processing of polish copper concentrates[J].Physicochemical Problems of Mineral Processing,2011,46(46):207-218.
[12]IBERHAN L,WI S'NIEWSKI M.Removal of arsenic(III)and arsenic(V)from sulfuric acid solution by liquid-liquid extraction[J].Journal of Chemical Technology&Biotechnology,2010,78(6):659-665.
[13]IBERHAN L,WIS'NIEWSKI M.Extraction of arsenic(III)and arsenic(V)with Cyanex 925,Cyanex 301 and their mixtures[J].Hydrometallurgy,2002,63(1):23-30.
[14]丁爱中,陈海英,程莉蓉,等.地下水除砷技术的研究进展[J].安徽农业科学,2008,36(27):11979-11982.
[15]邹路易,毛小庆,李磊,等.巯基壳聚糖/活性炭复合功能膜的砷吸附性能研究[J].安全与环境学报,2013,13(6):31-33.
[16]席北斗,王晓伟,霍守亮,等.纳滤膜技术在地下水除砷应用中的研究进展[J].环境工程学报,2012,6(2):353-360.
[17]PILLEWAN P,MUKHERJEE S,MEHER A K,et al.Removal of arsenic(III)and arsenic(V)using copper exchange zeolite-a[J].Environmental Progress&Sustainable Energy,2015,33(4):1274-1282.
[18]曹秉帝,徐绪筝,王东升,等.三价铁改性活性炭对水中微量砷的吸附特性[J].环境工程学报,2016,10(5):2321-2328.
[19]HUANG Y B,WANG L L,TU S X,et al.Influence of various factors on arsenic removal using ferruginous manganese ore[J].Applied Mechanics&Materials,2011,71/78:2753-2758.
[20]AHMAD H B,AZHAR M,HUSSAIN M,et al.Synthesis and characterization of kaolin supported metallic nanocomposites for the removal of arsenic[J].Fresenius Environmental Bulletin,2015,24(11):4019-4024.
[21]钟松雄,尹光彩,何宏飞,等.不同铁矿物对水稻土砷的稳定化效果及机制[J].环境科学学报,2017,37(5):1931-1938.
[22]赵雅光,万俊锋,王杰,等.零价铁(ZVI)去除水中的As(Ⅲ)[J].化工学报,2015,66(2):730-737.
[23]卞战强,谢莉,田向红,等.三种晶型纳米二氧化锰对水中As(Ⅲ)和As(Ⅴ)的吸附性能研究[J].环境与健康杂志,2012,29(7):645-648.
[24]王文凯,阎莉,段晋明,等.二氧化钛滤柱对高砷污酸废水的吸附去除[J].环境工程学报,2017,11(3):1322-1328.
[25]姜海钰,荆玉姝,高莹,等.活性氧化铝吸附水中砷的动态试验研究[J].青岛理工大学学报,2014,35(2):53-58.
[26]王琼,胡健,黄亚许,等.粉煤灰及其改性材料对废水中砷离子的吸附研究[J].矿冶,2015,24(1):74-76.
[27]YANG L.Simultaneous removal of fluoride and arsenic from aqueous solution using activated red mud[J].Separation Science&Technology,2014,49(15):2412-2425.
[28]杨长明,陈氏秋张,沈烁.钢渣对水溶液中砷的吸附动力学和热力学特性试验[J].净水技术,2015(2):83-89.
[29]NELSON P O,CHUNG A K,HUDSON M C.Factors affecting the fate of heavy metals in the activated sludge process[J].Journal,1981,53(8):1323-1333.
[30]CHENG M H,PATTERSON J W,MINEAR R A.Heavy metals uptake by activated sludge[J].Journal,1975,47(2):362-376.
[31]NEUFELD R D,HERMANN E R.Heavy metal removal by acclimated activated sludge[J].J Water Pollut Control Fed,1975,47(2):310-329.
[32]王岩,刘奉滨,郎龙麒,等.三价砷对SBRs反应系统中活性污泥的影响研究[J].郑州大学学报(工学版),2013,34(5):109-112.
[33]AGRAFIOTI E,KALDERIS D,DIAMADOPOULOS E.Arsenic and chromium removal from water using biochars derived from rice husk,organic solid wastes and sewage sludge.[J].Journal of Environmental Management,2014,133(133):309.
[34]ANDERSON C R,COOK G M.Isolation and characterization of arsenate-reducing bacteria from arsenic-contaminated sites in New Zealand[J].Current Microbiology,2004,48(5):341-7.
[35]许平平,刘聪,王亚,等.共生细菌对盐生小球藻富集和转化砷酸盐的影响[J].环境科学,2016,37(9):3438-3446.
[36]王亚,张春华,王淑,等.带菌盐藻对不同形态砷的富集和转化研究[J].环境科学,2013,34(11):4257-4265.
[37]朱时佳,花修艺,郭志勇,等.铜、铬、铅和砷对自然水体生物膜吸附五氯酚的影响[J].科学技术与工程,2015,15(18):10-15.
[38]A NDJELKOVIC I,AZARI S,ERKELENS M,et al.Bacterial iron-oxide nanowires from biofilm waste as a new adsorbent for the removal of arsenic from water[J].Rsc Advances,2017,7(7):3941-3948.
[39]潘思宇,夏四清,王晨辉,等.利用氢基质生物膜反应器去除水中砷酸盐[J].环境科学学报,2015,35(12):3781-3788.
[40]POON L,YOUNUS S,WILSON L D.Adsorption study of an organo-arsenical with chitosan-based sorbents[J].Journal of Colloid&Interface Science,2014,420(8):136-144.
[41]李雅轩,陈梅青,王瑜瑜,等.铁锰氧化物/醋酸纤维素复合材料制备及除砷性能研究[C]//中国环境科学学会2013年学术年会.北京:中国环境科学学会,2013.
[42]HAN Y H,FU J W,CHEN Y,et al.Arsenic uptake,arsenite efflux and plant growth in hyperaccumulator Pteris vittata:Role of arsenic-resistant bacteria.[J].Chemosphere,2016,144:1937-1942.
[43]PODDER M S,MAJUMDER C B.Characterization and modelling of biosorptive performance of living cells of Bacillus arsenicus,MTCC 4380 for the removal of As(III)and As(V)[J].Journal of Water Process Engineering,2016(9):135-154.