油田注水结垢及阻垢剂研究进展
|
摘要
油气生产系统中油田注水结垢问题日益严重,如不进行适当处理,可能造成了巨大的经济损失。本文首先从垢的生成及危害进行分析,详细介绍了油气生产中垢形成的影响因素。结合现有比较常用的防垢处理方法,并对三种方法进行了分析,给出了油田注水结垢的控制措施。单一的控制措施存在着一定的弊端,采用复合绿色环保型阻垢剂技术,不但能够很好的处理油田注水结垢的问题,也能最大限度地控制油田注水结垢的问题。
The oilfield water injection scaling problem in oil and gas production systems has become increasingly serious. If the problem is not properly handled, it may cause huge economic losses. In this paper, the formation and hazards of scale were analyzed, and the factors affecting the formation of scale in oil and gas production were described in detail. Combined with the existing commonly used anti-scaling treatment methods, the three anti-scaling treatment methods were analyzed, the control measures for oil field water injection scaling were given. It's pointed out that the single control measure has some drawbacks; the compound green environmental protection scale inhibitor technology can well solve the problem of water injection scaling in oil fields.
The oilfield water injection scaling problem in oil and gas production systems has become increasingly serious. If the problem is not properly handled, it may cause huge economic losses. In this paper, the formation and hazards of scale were analyzed, and the factors affecting the formation of scale in oil and gas production were described in detail. Combined with the existing commonly used anti-scaling treatment methods, the three anti-scaling treatment methods were analyzed, the control measures for oil field water injection scaling were given. It's pointed out that the single control measure has some drawbacks; the compound green environmental protection scale inhibitor technology can well solve the problem of water injection scaling in oil fields.
引文
[1]王忠辉.油田污水回注阻垢剂的研制[D].大庆石油学院东北石油大学,2005.
[2]韩嘉平.聚驱管道腐蚀结垢机理及防护技术研究[D].东北石油大学,2014.
[3]徐素鹏,邢晓轲.油田注水结垢综述及阻垢剂研究进展[J].许昌学院学报,2013,32(2):93-98.
[4]刘志超,刘云铎,刘博文,等.油田结垢及阻垢剂研究进展[J].广州化工,2016,44(8):33-34.
[5]邹玮.阻钙垢聚合物的合成与性能研究[D].长江大学,2013.
[6]左景栾,任韶然,于洪敏.油田防垢技术研究与应用进展[J].石油工程建设,2008,34(2):7-14.
[7]李兴华,张挺,夏红宇,等.油田注水系统结垢及治理措施[J].化工管理,2017(29).
[8]Shu F.Study on scaling cause and antiscaling measure in wuqi oilfield[J].Petroleum Geology&Engineering,2007.
[9]杜媛斐.生活污水深度处理用于油田采油水配聚的应用研究[D].哈尔滨工业大学,2014.
[10]Stumm W,Morgan J J.Aquatic chemistry:chemical equilibria and rates in natural waters[J].Cram101 Textbook Outlines to Accompany,1996,179(11):A277.
[11]左景栾,任韶然,于洪敏.油田防垢技术研究与应用进展[J].石油工程建设,2008,34(2):7-14.
[12]陈龙驹.碳酸钙垢生长规律及阻垢剂对其影响的EQCM研究[D].西南石油大学,2015.
[13]陈明明.油田水处理中的变频电磁防垢技术研究[D].东北石油大学,2013.
[14]初杰.声波防垢机理及实验研究[D].中国石油大学(华东),2006.
[15]杨建华,钱伟平,陈传东.化学法防垢除垢工艺技术[J].清洗世界,1999(6):21-24.
[16]M.H.V.Quiroga,秦薇.机械法清除硬水垢:巴西海上油田采用的除垢方法[J].海洋石油,2005,25(2):80-85.
[17]王闰.胡尖山油田A8区结垢影响因素及阻垢效果实验研究[D].西南石油大学,2014.
[18]夏明珠,王风云,雷武.羧酸聚合物对油田回注水中硫酸盐垢的抑制作用和机理[J].水处理信息报导,2009(1):18-20.
[19]Zhou S.Exploration and practice of offshore oilfield effective development technology[J].Engineering Sciences,2009.
[20]Wanlun Y,Xinmin Z,Laxun Y,et al.Spectroscopic properties of Cr3+ions at the defect sites in cubic fluoroperovskite crystals[J].Phys.rev.b,1994,50(10):6756-6764.
[21]Sorbie K S,Laing N.How Scale Inhibitors Work:Mechanisms of Selected Barium Sulphate Scale inhibitors Across a Wide Temperature Range[J].2004.
[22]李荫刚.油田用高效阻垢剂的合成及性能评价[D].中国海洋大学,2011.
[23]何焕杰,王永红,詹适新,等.膦基丙烯酸-马来酸酐共聚物阻垢剂ZP S-01的合成及阻垢性能[J].油田化学,1999,16(2):143-145.
[24]陈燕敏,孙彩霞,徐会武.环境友好型缓蚀阻垢剂生物降解性能研究[J].河南科学,2014(9):1842-1844.
[25]徐僖,郑邦乾,朱清泉.油田用阻垢剂及其筛选[J].大庆石油地质与开发,1984(3):19-32.
[26]王丽荣,付朝阳.丙烯酸均聚物及共聚物缓蚀阻垢剂[C].全国缓蚀剂学术讨论会,2006.
[27]胡晓静,刘振法,武秀丽,等.环境友好型缓蚀阻垢剂的研制及性能研究[J].水处理技术,2010,36(3):38-41.
[28]Zhang B R,Zhang L,Li F T,et al.Testing the formation of Ca-phosphonate precipitates and evaluating the anionic polymers as Ca-phosphonate precipitates and CaCO scale inhibitor in simulated cooling water[J].Corrosion Science,2010,52(12):3883-3890.
[29]侯振宇,张秋禹,李丹,等.聚环氧琥珀酸的合成及其阻垢性能研究[J].工业用水与废水,2006,37(2):73-76.
[2]韩嘉平.聚驱管道腐蚀结垢机理及防护技术研究[D].东北石油大学,2014.
[3]徐素鹏,邢晓轲.油田注水结垢综述及阻垢剂研究进展[J].许昌学院学报,2013,32(2):93-98.
[4]刘志超,刘云铎,刘博文,等.油田结垢及阻垢剂研究进展[J].广州化工,2016,44(8):33-34.
[5]邹玮.阻钙垢聚合物的合成与性能研究[D].长江大学,2013.
[6]左景栾,任韶然,于洪敏.油田防垢技术研究与应用进展[J].石油工程建设,2008,34(2):7-14.
[7]李兴华,张挺,夏红宇,等.油田注水系统结垢及治理措施[J].化工管理,2017(29).
[8]Shu F.Study on scaling cause and antiscaling measure in wuqi oilfield[J].Petroleum Geology&Engineering,2007.
[9]杜媛斐.生活污水深度处理用于油田采油水配聚的应用研究[D].哈尔滨工业大学,2014.
[10]Stumm W,Morgan J J.Aquatic chemistry:chemical equilibria and rates in natural waters[J].Cram101 Textbook Outlines to Accompany,1996,179(11):A277.
[11]左景栾,任韶然,于洪敏.油田防垢技术研究与应用进展[J].石油工程建设,2008,34(2):7-14.
[12]陈龙驹.碳酸钙垢生长规律及阻垢剂对其影响的EQCM研究[D].西南石油大学,2015.
[13]陈明明.油田水处理中的变频电磁防垢技术研究[D].东北石油大学,2013.
[14]初杰.声波防垢机理及实验研究[D].中国石油大学(华东),2006.
[15]杨建华,钱伟平,陈传东.化学法防垢除垢工艺技术[J].清洗世界,1999(6):21-24.
[16]M.H.V.Quiroga,秦薇.机械法清除硬水垢:巴西海上油田采用的除垢方法[J].海洋石油,2005,25(2):80-85.
[17]王闰.胡尖山油田A8区结垢影响因素及阻垢效果实验研究[D].西南石油大学,2014.
[18]夏明珠,王风云,雷武.羧酸聚合物对油田回注水中硫酸盐垢的抑制作用和机理[J].水处理信息报导,2009(1):18-20.
[19]Zhou S.Exploration and practice of offshore oilfield effective development technology[J].Engineering Sciences,2009.
[20]Wanlun Y,Xinmin Z,Laxun Y,et al.Spectroscopic properties of Cr3+ions at the defect sites in cubic fluoroperovskite crystals[J].Phys.rev.b,1994,50(10):6756-6764.
[21]Sorbie K S,Laing N.How Scale Inhibitors Work:Mechanisms of Selected Barium Sulphate Scale inhibitors Across a Wide Temperature Range[J].2004.
[22]李荫刚.油田用高效阻垢剂的合成及性能评价[D].中国海洋大学,2011.
[23]何焕杰,王永红,詹适新,等.膦基丙烯酸-马来酸酐共聚物阻垢剂ZP S-01的合成及阻垢性能[J].油田化学,1999,16(2):143-145.
[24]陈燕敏,孙彩霞,徐会武.环境友好型缓蚀阻垢剂生物降解性能研究[J].河南科学,2014(9):1842-1844.
[25]徐僖,郑邦乾,朱清泉.油田用阻垢剂及其筛选[J].大庆石油地质与开发,1984(3):19-32.
[26]王丽荣,付朝阳.丙烯酸均聚物及共聚物缓蚀阻垢剂[C].全国缓蚀剂学术讨论会,2006.
[27]胡晓静,刘振法,武秀丽,等.环境友好型缓蚀阻垢剂的研制及性能研究[J].水处理技术,2010,36(3):38-41.
[28]Zhang B R,Zhang L,Li F T,et al.Testing the formation of Ca-phosphonate precipitates and evaluating the anionic polymers as Ca-phosphonate precipitates and CaCO scale inhibitor in simulated cooling water[J].Corrosion Science,2010,52(12):3883-3890.
[29]侯振宇,张秋禹,李丹,等.聚环氧琥珀酸的合成及其阻垢性能研究[J].工业用水与废水,2006,37(2):73-76.