摘要
综述了近年来国内外关于硬质合金粘结相的研究进展,分析了Ni粘结相、金属间化合物粘结相及高熵合金粘结相替代Co粘结相的可能性,并展望了硬质合金粘结相的发展前景和今后研究开发的重点。
The research progress of binder phase in cemented carbides at home and abroad in recent years was reviewed.The possibility of substituting Ni binder phase,intermetallic compound binder phase and high-entropy alloy binder phase for Co binder phase was analyzed.The development prospect and the key points for future research of binder phase in cemented carbides were prospected.
引文
[1] FANG Z Z,WANG H,KUMAR V.Coarsening,densification,and grain growth during sintering of nano-sized powders—A perspective[J].International Journal of Refractory Metals and Hard Materials,2017,62:110-117.
[2] 文彦,张钦英,郭圣达,等.WC-6Co硬质合金SPS烧结工艺[J].有色金属科学与工程,2017,8(3):74-78.
[3] SONG X Y,GAO Y,LIU X M,et al.Effect of interfacial characteristics on toughness of nanocrystalline cemented carbides[J].Acta Materialia,2013,61(6):2 154-2 162.
[4] 张贺佳,陈礼清,王文广,等.超细晶WC-10Co硬质合金制备的主要影响因素[J].有色金属科学与工程,2014(6):47-52.
[5] 羊求民,羊建高,苏伟,等.纳米/超细晶 WC-Co 类硬质合金的研究进展[J].稀有金属与硬质合金,2018,46(1):76-83.
[6] 孙娟.中国新能源汽车国际竞争力研究[D].北京:对外经济贸易大学,2016.
[7] 高飞.我国电动汽车研发战略联盟模式选择研究[D].石家庄:河北师范大学,2012.
[8] 刘寿荣.WC-Co硬质合金的热处理[J].金属热处理学报,1988,9(2):30-36.
[9] 王忆民,李锐,曹群.淬火回火热处理对WC-25%Co硬质合金组织与性能的影响[J].硬质合金,2014,31(3):149-154.
[10] 吴冲浒,陈杉杉.热处理对超细晶硬质合金性能的影响[J].热处理技术与装备,2014,35(6):7-10.
[11] 郭智兴,熊计.WC-Ni硬质合金的研究与应用[J].工具技术,2005,39(8):15-19.
[12] 龙坚战,陆必志,易茂中,等.新型粘结相硬质合金的研究进展[J].硬质合金,2015,32(3):204-212.
[13] ARRAGó J M,ROA J J,VALLE V,et al.Fracture and fatigue behavior of WC-Co and WC-CoNi cemented carbides[J].International Journal of Refractory Metals and Hard Materials,2015,49:184-191.
[14] FERNANDES C M,SENOS A M R,VIEIRA M T,et al.Mechanical characterization of composites prepared from WC powders coated with Ni rich binders[J].International Journal of Refractory Metals and Hard Materials,2008,26(5):491-498.
[15] NORGREN S,GARCíA J,BLOMQVIST A,et al.Trends in the P/M hard metal industry[J].International Journal of Refractory Metals and Hard Materials,2015,48:31-45.
[16] RONG H,PENG Z,REN X,et al.Ultrafine WC-Ni cemented carbides fabricated by spark plasma sintering[J].Materials Science and Engineering:A,2012,532:543-547.
[17] CORREA E O,SANTOS J N,KLEIN A N.Microstructure and mechanical properties of WC Ni-Si based cemented carbides developed by powder metallurgy[J].International Journal of Refractory Metals and Hard Materials,2010,28(5):572-575.
[18] WITTMANN B,SCHUBERT W D,LUX B.WC grain growth and grain growth inhibition in nickel and iron binder hardmetals[J].International Journal of Refractory Metals and Hard Materials,2002,20(1):51-60.
[19] MINGARD K P,ROEBUCK B,MARSHALL J,et al.Some aspects of the structure of cobalt and nickel binder phases in hardmetals[J].Acta Materialia,2011,59(6):2 277-2 290.
[20] HIBINO A,MATSUOKA S,KIUCHI M.Synthesis and sintering of Ni3Al intermetallic compound by combustion synthesis process[J].Journal of Materials Processing Technology,2001,112(1):127-135.
[21] 黄斌.Ni3Al粘结金属陶瓷制备工艺、组织结构及性能的研究[D].武汉:华中科技大学,2016.
[22] ZHANG L M,LIU J,YUAN R Z,et al.Properties of TiC-Ni3Al composites and structural optimization of TiC-Ni3Al functionally gradient materials[J].Materials Science & Engineering A,1995,203(1-2):272-277.
[23] TIEGS T N,ALEXANDER K B,PLUCKNETT K P,et al.Ceramic composites with a ductile Ni3Al binder phase[J].Materials Science & Engineering A,1996,209(1-2):243-247.
[24] AHMADIAN M,WEXLER D,CALKA A,et al.The effect of boron on the hardness and fracture toughness of WC-FeAl-B and WC-Ni3Al-B composites[J].Materials Science Forum,2007,539-543:962-967.
[25] SCHNEIBEL J H,GEORGE E P,MCKAMEY C G,et.al.Fabrication and tensile properties of continuous-fiber reinforced Ni3Al-Al2O3composites[J].Journal of Materials Research,1991,6(8):1 673-1 679.
[26] SKIRL S,KRAUSE R,WIEDERHORN S M,et al.Processing and mechanical properties of Al2O3/Ni3Al composites with interpenetrating network microstructure[J].Journal of the American Ceramic Society,2001,84(9):2 034-2 040.
[27] BRENNAN P C,KAO W H,YANG J M.Mechanical properties of an Al2O3/Ni3Al particulate-reinforced composite[J].Materials Science & Engineering A,1992,153(1-2):635-640.
[28] 陈健.WC-Ni3Al复合材料的力学性能及其抗氧化和耐腐蚀性能的研究[D].广州:华南理工大学,2013.
[29] 肖章怡.含板状WC晶粒的WC-10Ni3Al硬质合金的制备与性能研究[D].广州:华南理工大学,2011.
[30] 龙坚战,张忠健,彭文,等.Ni3Al添加量对WC-Co硬质合金中WC晶粒形状的影响[J].硬质合金,2013,30(6):308-315.
[31] 马春红,马瑞新,肖代红,等.超细晶WC-Ni3Al硬质合金的显微组织与性能研究[J].热加工工艺,2016(16):72-75.
[32] 肖代红,李秀秀,申婷婷,等.添加LaB6对超细晶WC-Ni3Al合金的组织与力学性能影响[J].中南大学学报(自然科学版),2015(1):81-87.
[33] YE Y F,WANG Q,LU J,et al.High-entropy alloy:challenges and prospects[J].Materials Today,2016,19(6):349-362.
[34] LIU W H,LU Z P,HE J Y,et al.Ductile CoCrFeNiMox,high entropy alloys strengthened by hard intermetallic phases[J].Acta Materialia,2016,116:332-342.
[35] MIRACLE D B,SENKOV O N,A critical review of high entropy alloys and related concepts[J].Acta Mater,2017,122:448-511.
[36] PICKERING E J,JONES N G.High-entropy alloys:a critical assessment of their founding principles and future prospects[J].International Materials Reviews,2016,61(3):183-202.
[37] NONG Z S,ZHU J C,ZHAO R D.Prediction of structure and elastic properties of AlCrFeNiTi system high entropy alloys[J].Intermetallics,2017,86:134-146.
[38] LI P,WANG A,LIU C T.Composition dependence of structure,physical and mechanical properties of FeCo-Ni(MnAl)x,high entropy alloys[J].Intermetallics,2017,87:21-26.
[39] ZHU G,LIU Y,YE J.Fabrication and properties of Ti(C,N)-based cermets with multi-component AlCo-CrFeNi high-entropy alloys binder[J].Materials Letters,2013,113(12):80-82.
[40] OBRA A G D L,AVILéS M A,TORRES Y,et al.A new family of cermets:Chemically complex but microstructurally simple[J].International Journal of Refractory Metals & Hard Materials,2016,63:17-25.
[41] JI W,ZHANG J,WANG W,et al.Fabrication and properties of TiB2-based cermets by spark plasma sintering with CoCrFeNiTiAl high-entropy alloy as sintering aid[J].Journal of the European Ceramic Society,2015,35(3):879-886.
[42] ZHAO K,NIU B,ZHANG F,et al.Microstructure and mechanical properties of spark plasma sintered TiB2 ceramics combined with a high-entropy alloy sintering aid[J].British Ceramic Transactions,2016,116(1):19-23.
[43] CHEN C S,YANG C C,CHAI H Y,et al.Novel cermet material of WC/multi-element alloy[J].International Journal of Refractory Metals & Hard Materials,2014,43(12):200-204.
[44] ZHOU P F,XIAO D H,YUAN T C.Comparison between ultrafine-grained WC-Co and WC-HEA-cemented carbides[J].Powder Metallurgy,2016,60(1):1-6.