硬质合金粘结相研究进展
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摘要
综述了近年来国内外关于硬质合金粘结相的研究进展,分析了Ni粘结相、金属间化合物粘结相及高熵合金粘结相替代Co粘结相的可能性,并展望了硬质合金粘结相的发展前景和今后研究开发的重点。
The research progress of binder phase in cemented carbides at home and abroad in recent years was reviewed.The possibility of substituting Ni binder phase,intermetallic compound binder phase and high-entropy alloy binder phase for Co binder phase was analyzed.The development prospect and the key points for future research of binder phase in cemented carbides were prospected.
The research progress of binder phase in cemented carbides at home and abroad in recent years was reviewed.The possibility of substituting Ni binder phase,intermetallic compound binder phase and high-entropy alloy binder phase for Co binder phase was analyzed.The development prospect and the key points for future research of binder phase in cemented carbides were prospected.
引文
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[2] 文彦,张钦英,郭圣达,等.WC-6Co硬质合金SPS烧结工艺[J].有色金属科学与工程,2017,8(3):74-78.
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[4] 张贺佳,陈礼清,王文广,等.超细晶WC-10Co硬质合金制备的主要影响因素[J].有色金属科学与工程,2014(6):47-52.
[5] 羊求民,羊建高,苏伟,等.纳米/超细晶 WC-Co 类硬质合金的研究进展[J].稀有金属与硬质合金,2018,46(1):76-83.
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[7] 高飞.我国电动汽车研发战略联盟模式选择研究[D].石家庄:河北师范大学,2012.
[8] 刘寿荣.WC-Co硬质合金的热处理[J].金属热处理学报,1988,9(2):30-36.
[9] 王忆民,李锐,曹群.淬火回火热处理对WC-25%Co硬质合金组织与性能的影响[J].硬质合金,2014,31(3):149-154.
[10] 吴冲浒,陈杉杉.热处理对超细晶硬质合金性能的影响[J].热处理技术与装备,2014,35(6):7-10.
[11] 郭智兴,熊计.WC-Ni硬质合金的研究与应用[J].工具技术,2005,39(8):15-19.
[12] 龙坚战,陆必志,易茂中,等.新型粘结相硬质合金的研究进展[J].硬质合金,2015,32(3):204-212.
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[15] NORGREN S,GARCíA J,BLOMQVIST A,et al.Trends in the P/M hard metal industry[J].International Journal of Refractory Metals and Hard Materials,2015,48:31-45.
[16] RONG H,PENG Z,REN X,et al.Ultrafine WC-Ni cemented carbides fabricated by spark plasma sintering[J].Materials Science and Engineering:A,2012,532:543-547.
[17] CORREA E O,SANTOS J N,KLEIN A N.Microstructure and mechanical properties of WC Ni-Si based cemented carbides developed by powder metallurgy[J].International Journal of Refractory Metals and Hard Materials,2010,28(5):572-575.
[18] WITTMANN B,SCHUBERT W D,LUX B.WC grain growth and grain growth inhibition in nickel and iron binder hardmetals[J].International Journal of Refractory Metals and Hard Materials,2002,20(1):51-60.
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[20] HIBINO A,MATSUOKA S,KIUCHI M.Synthesis and sintering of Ni3Al intermetallic compound by combustion synthesis process[J].Journal of Materials Processing Technology,2001,112(1):127-135.
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[23] TIEGS T N,ALEXANDER K B,PLUCKNETT K P,et al.Ceramic composites with a ductile Ni3Al binder phase[J].Materials Science & Engineering A,1996,209(1-2):243-247.
[24] AHMADIAN M,WEXLER D,CALKA A,et al.The effect of boron on the hardness and fracture toughness of WC-FeAl-B and WC-Ni3Al-B composites[J].Materials Science Forum,2007,539-543:962-967.
[25] SCHNEIBEL J H,GEORGE E P,MCKAMEY C G,et.al.Fabrication and tensile properties of continuous-fiber reinforced Ni3Al-Al2O3composites[J].Journal of Materials Research,1991,6(8):1 673-1 679.
[26] SKIRL S,KRAUSE R,WIEDERHORN S M,et al.Processing and mechanical properties of Al2O3/Ni3Al composites with interpenetrating network microstructure[J].Journal of the American Ceramic Society,2001,84(9):2 034-2 040.
[27] BRENNAN P C,KAO W H,YANG J M.Mechanical properties of an Al2O3/Ni3Al particulate-reinforced composite[J].Materials Science & Engineering A,1992,153(1-2):635-640.
[28] 陈健.WC-Ni3Al复合材料的力学性能及其抗氧化和耐腐蚀性能的研究[D].广州:华南理工大学,2013.
[29] 肖章怡.含板状WC晶粒的WC-10Ni3Al硬质合金的制备与性能研究[D].广州:华南理工大学,2011.
[30] 龙坚战,张忠健,彭文,等.Ni3Al添加量对WC-Co硬质合金中WC晶粒形状的影响[J].硬质合金,2013,30(6):308-315.
[31] 马春红,马瑞新,肖代红,等.超细晶WC-Ni3Al硬质合金的显微组织与性能研究[J].热加工工艺,2016(16):72-75.
[32] 肖代红,李秀秀,申婷婷,等.添加LaB6对超细晶WC-Ni3Al合金的组织与力学性能影响[J].中南大学学报(自然科学版),2015(1):81-87.
[33] YE Y F,WANG Q,LU J,et al.High-entropy alloy:challenges and prospects[J].Materials Today,2016,19(6):349-362.
[34] LIU W H,LU Z P,HE J Y,et al.Ductile CoCrFeNiMox,high entropy alloys strengthened by hard intermetallic phases[J].Acta Materialia,2016,116:332-342.
[35] MIRACLE D B,SENKOV O N,A critical review of high entropy alloys and related concepts[J].Acta Mater,2017,122:448-511.
[36] PICKERING E J,JONES N G.High-entropy alloys:a critical assessment of their founding principles and future prospects[J].International Materials Reviews,2016,61(3):183-202.
[37] NONG Z S,ZHU J C,ZHAO R D.Prediction of structure and elastic properties of AlCrFeNiTi system high entropy alloys[J].Intermetallics,2017,86:134-146.
[38] LI P,WANG A,LIU C T.Composition dependence of structure,physical and mechanical properties of FeCo-Ni(MnAl)x,high entropy alloys[J].Intermetallics,2017,87:21-26.
[39] ZHU G,LIU Y,YE J.Fabrication and properties of Ti(C,N)-based cermets with multi-component AlCo-CrFeNi high-entropy alloys binder[J].Materials Letters,2013,113(12):80-82.
[40] OBRA A G D L,AVILéS M A,TORRES Y,et al.A new family of cermets:Chemically complex but microstructurally simple[J].International Journal of Refractory Metals & Hard Materials,2016,63:17-25.
[41] JI W,ZHANG J,WANG W,et al.Fabrication and properties of TiB2-based cermets by spark plasma sintering with CoCrFeNiTiAl high-entropy alloy as sintering aid[J].Journal of the European Ceramic Society,2015,35(3):879-886.
[42] ZHAO K,NIU B,ZHANG F,et al.Microstructure and mechanical properties of spark plasma sintered TiB2 ceramics combined with a high-entropy alloy sintering aid[J].British Ceramic Transactions,2016,116(1):19-23.
[43] CHEN C S,YANG C C,CHAI H Y,et al.Novel cermet material of WC/multi-element alloy[J].International Journal of Refractory Metals & Hard Materials,2014,43(12):200-204.
[44] ZHOU P F,XIAO D H,YUAN T C.Comparison between ultrafine-grained WC-Co and WC-HEA-cemented carbides[J].Powder Metallurgy,2016,60(1):1-6.
[2] 文彦,张钦英,郭圣达,等.WC-6Co硬质合金SPS烧结工艺[J].有色金属科学与工程,2017,8(3):74-78.
[3] SONG X Y,GAO Y,LIU X M,et al.Effect of interfacial characteristics on toughness of nanocrystalline cemented carbides[J].Acta Materialia,2013,61(6):2 154-2 162.
[4] 张贺佳,陈礼清,王文广,等.超细晶WC-10Co硬质合金制备的主要影响因素[J].有色金属科学与工程,2014(6):47-52.
[5] 羊求民,羊建高,苏伟,等.纳米/超细晶 WC-Co 类硬质合金的研究进展[J].稀有金属与硬质合金,2018,46(1):76-83.
[6] 孙娟.中国新能源汽车国际竞争力研究[D].北京:对外经济贸易大学,2016.
[7] 高飞.我国电动汽车研发战略联盟模式选择研究[D].石家庄:河北师范大学,2012.
[8] 刘寿荣.WC-Co硬质合金的热处理[J].金属热处理学报,1988,9(2):30-36.
[9] 王忆民,李锐,曹群.淬火回火热处理对WC-25%Co硬质合金组织与性能的影响[J].硬质合金,2014,31(3):149-154.
[10] 吴冲浒,陈杉杉.热处理对超细晶硬质合金性能的影响[J].热处理技术与装备,2014,35(6):7-10.
[11] 郭智兴,熊计.WC-Ni硬质合金的研究与应用[J].工具技术,2005,39(8):15-19.
[12] 龙坚战,陆必志,易茂中,等.新型粘结相硬质合金的研究进展[J].硬质合金,2015,32(3):204-212.
[13] ARRAGó J M,ROA J J,VALLE V,et al.Fracture and fatigue behavior of WC-Co and WC-CoNi cemented carbides[J].International Journal of Refractory Metals and Hard Materials,2015,49:184-191.
[14] FERNANDES C M,SENOS A M R,VIEIRA M T,et al.Mechanical characterization of composites prepared from WC powders coated with Ni rich binders[J].International Journal of Refractory Metals and Hard Materials,2008,26(5):491-498.
[15] NORGREN S,GARCíA J,BLOMQVIST A,et al.Trends in the P/M hard metal industry[J].International Journal of Refractory Metals and Hard Materials,2015,48:31-45.
[16] RONG H,PENG Z,REN X,et al.Ultrafine WC-Ni cemented carbides fabricated by spark plasma sintering[J].Materials Science and Engineering:A,2012,532:543-547.
[17] CORREA E O,SANTOS J N,KLEIN A N.Microstructure and mechanical properties of WC Ni-Si based cemented carbides developed by powder metallurgy[J].International Journal of Refractory Metals and Hard Materials,2010,28(5):572-575.
[18] WITTMANN B,SCHUBERT W D,LUX B.WC grain growth and grain growth inhibition in nickel and iron binder hardmetals[J].International Journal of Refractory Metals and Hard Materials,2002,20(1):51-60.
[19] MINGARD K P,ROEBUCK B,MARSHALL J,et al.Some aspects of the structure of cobalt and nickel binder phases in hardmetals[J].Acta Materialia,2011,59(6):2 277-2 290.
[20] HIBINO A,MATSUOKA S,KIUCHI M.Synthesis and sintering of Ni3Al intermetallic compound by combustion synthesis process[J].Journal of Materials Processing Technology,2001,112(1):127-135.
[21] 黄斌.Ni3Al粘结金属陶瓷制备工艺、组织结构及性能的研究[D].武汉:华中科技大学,2016.
[22] ZHANG L M,LIU J,YUAN R Z,et al.Properties of TiC-Ni3Al composites and structural optimization of TiC-Ni3Al functionally gradient materials[J].Materials Science & Engineering A,1995,203(1-2):272-277.
[23] TIEGS T N,ALEXANDER K B,PLUCKNETT K P,et al.Ceramic composites with a ductile Ni3Al binder phase[J].Materials Science & Engineering A,1996,209(1-2):243-247.
[24] AHMADIAN M,WEXLER D,CALKA A,et al.The effect of boron on the hardness and fracture toughness of WC-FeAl-B and WC-Ni3Al-B composites[J].Materials Science Forum,2007,539-543:962-967.
[25] SCHNEIBEL J H,GEORGE E P,MCKAMEY C G,et.al.Fabrication and tensile properties of continuous-fiber reinforced Ni3Al-Al2O3composites[J].Journal of Materials Research,1991,6(8):1 673-1 679.
[26] SKIRL S,KRAUSE R,WIEDERHORN S M,et al.Processing and mechanical properties of Al2O3/Ni3Al composites with interpenetrating network microstructure[J].Journal of the American Ceramic Society,2001,84(9):2 034-2 040.
[27] BRENNAN P C,KAO W H,YANG J M.Mechanical properties of an Al2O3/Ni3Al particulate-reinforced composite[J].Materials Science & Engineering A,1992,153(1-2):635-640.
[28] 陈健.WC-Ni3Al复合材料的力学性能及其抗氧化和耐腐蚀性能的研究[D].广州:华南理工大学,2013.
[29] 肖章怡.含板状WC晶粒的WC-10Ni3Al硬质合金的制备与性能研究[D].广州:华南理工大学,2011.
[30] 龙坚战,张忠健,彭文,等.Ni3Al添加量对WC-Co硬质合金中WC晶粒形状的影响[J].硬质合金,2013,30(6):308-315.
[31] 马春红,马瑞新,肖代红,等.超细晶WC-Ni3Al硬质合金的显微组织与性能研究[J].热加工工艺,2016(16):72-75.
[32] 肖代红,李秀秀,申婷婷,等.添加LaB6对超细晶WC-Ni3Al合金的组织与力学性能影响[J].中南大学学报(自然科学版),2015(1):81-87.
[33] YE Y F,WANG Q,LU J,et al.High-entropy alloy:challenges and prospects[J].Materials Today,2016,19(6):349-362.
[34] LIU W H,LU Z P,HE J Y,et al.Ductile CoCrFeNiMox,high entropy alloys strengthened by hard intermetallic phases[J].Acta Materialia,2016,116:332-342.
[35] MIRACLE D B,SENKOV O N,A critical review of high entropy alloys and related concepts[J].Acta Mater,2017,122:448-511.
[36] PICKERING E J,JONES N G.High-entropy alloys:a critical assessment of their founding principles and future prospects[J].International Materials Reviews,2016,61(3):183-202.
[37] NONG Z S,ZHU J C,ZHAO R D.Prediction of structure and elastic properties of AlCrFeNiTi system high entropy alloys[J].Intermetallics,2017,86:134-146.
[38] LI P,WANG A,LIU C T.Composition dependence of structure,physical and mechanical properties of FeCo-Ni(MnAl)x,high entropy alloys[J].Intermetallics,2017,87:21-26.
[39] ZHU G,LIU Y,YE J.Fabrication and properties of Ti(C,N)-based cermets with multi-component AlCo-CrFeNi high-entropy alloys binder[J].Materials Letters,2013,113(12):80-82.
[40] OBRA A G D L,AVILéS M A,TORRES Y,et al.A new family of cermets:Chemically complex but microstructurally simple[J].International Journal of Refractory Metals & Hard Materials,2016,63:17-25.
[41] JI W,ZHANG J,WANG W,et al.Fabrication and properties of TiB2-based cermets by spark plasma sintering with CoCrFeNiTiAl high-entropy alloy as sintering aid[J].Journal of the European Ceramic Society,2015,35(3):879-886.
[42] ZHAO K,NIU B,ZHANG F,et al.Microstructure and mechanical properties of spark plasma sintered TiB2 ceramics combined with a high-entropy alloy sintering aid[J].British Ceramic Transactions,2016,116(1):19-23.
[43] CHEN C S,YANG C C,CHAI H Y,et al.Novel cermet material of WC/multi-element alloy[J].International Journal of Refractory Metals & Hard Materials,2014,43(12):200-204.
[44] ZHOU P F,XIAO D H,YUAN T C.Comparison between ultrafine-grained WC-Co and WC-HEA-cemented carbides[J].Powder Metallurgy,2016,60(1):1-6.