四川省制鞋行业挥发性有机物成分谱研究
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摘要
为探究四川省制鞋行业挥发性有机物(VOCs)的主要组分,通过现场采样的方法,对四川省整鞋制造、中大底制造、改性橡胶鞋底制造、橡胶鞋底制造、鞋跟制造以及鞋模制造6种制鞋类型企业排放的VOCs进行了采样分析。结果表明:四川省制鞋行业的VOCs成分谱中,含氧化合物和烷烃含量最高。有组织VOCs排名前三的组分为丙酮、二氯甲烷、甲苯,质量分数分别为30.82%、16.04%、11.06%;无组织VOCs排名前三的组分为正戊烷、丙酮、2-甲基戊烷,质量分数分别为20.26%、17.10%、10.31%。
In order to explore the main components of volatile organic compounds(VOCs)in the shoe industry of Sichuan,six types of shoe-making enterprises including shoe,middle and large shoe sole,modified rubber sole,rubber sole,heel and shoe mold manufacturing were investigated in this paper.The results showed that oxygenated compounds and alkanes were the most abundant in the source profile of VOCs in the shoe industry of Sichuan.Among the organized emissions,the top three species of VOCs were acetone,dichloromethane and toluene,with the mass percentages of 30.82%,16.04% and 11.06%,respectively.Among the unorganized emissions,the top three species of VOCs were n-pentane,acetone and 2-methylpentane,with the mass percentages of 20.26%,17.10% and 10.31%,respectively.
In order to explore the main components of volatile organic compounds(VOCs)in the shoe industry of Sichuan,six types of shoe-making enterprises including shoe,middle and large shoe sole,modified rubber sole,rubber sole,heel and shoe mold manufacturing were investigated in this paper.The results showed that oxygenated compounds and alkanes were the most abundant in the source profile of VOCs in the shoe industry of Sichuan.Among the organized emissions,the top three species of VOCs were acetone,dichloromethane and toluene,with the mass percentages of 30.82%,16.04% and 11.06%,respectively.Among the unorganized emissions,the top three species of VOCs were n-pentane,acetone and 2-methylpentane,with the mass percentages of 20.26%,17.10% and 10.31%,respectively.
引文
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[22]韩丽,王幸锐,何敏,等.四川省典型人为污染源VOCs排放清单及其对大气环境的影响[J].环境科学,2013,34(12):4535-4542.
[23]CHANG C T,LIN K L.Assessment of the strategies for reducing VOCs emission from polyurea-formaldehyde resin synthetic fiber leather industry in Taiwan[J].Resources Conservation and Recycling,2006,46(4):321-334.
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[26]HJ 759-2015,环境空气挥发性有机物的测定罐采样/气相色谱-质谱法[S].
[27]许伟,刘军利,孙康.活性炭吸附法在挥发性有机物治理中的应用研究进展[J].化工进展,2016,35(4):1223-1229.
[28]YUAN B,SHAO M,LU S H,et al.Source profiles of volatile organic compounds associated with solvent use in Beijing,China[J].Atmospheric Environment,2010,44(15):1919-1926.
[29]乔月珍.上海市机动车和涂料VOCs源成分谱特征及其大气反应活性研究[D].上海:华东理工大学,2011.
[30]ZHENG J Y,YU Y F,MO Z W,et al.Industrial sector-based volatile organic compound source profiles measured in manufacturing facilities in the Pearl River Delta,China[J].Science of the Total Environment,2013,456:127-136.
[31]赵锐,黄络萍,张建强,等.成都市典型溶剂源使用行业VOCs排放成分特征[J].环境科学学报,2018,38(3):1-5.
[32]莫梓伟,邵敏,陆思华.中国挥发性有机物(VOCs)排放源成分谱研究进展[J].环境科学学报,2014,34(9):2179-2189.
[2]田锋,施文静,何欢,等.某化学工业园区重点行业企业VOCs污染问题初探[J].环境监测管理与技术,2015,27(5):59-62.
[3]冯小琼,彭康,凌镇浩,等.香港地区2005-2010年VOCs污染来源解析及特征研究[J].环境科学学报,2013,33(1):173-180.
[4]邓雪娇,王新明,赵春生,等.珠江三角洲典型过程VOCs的平均浓度与化学反应活性[J].中国环境科学,2010,30(9):1153-1161.
[5]ZHENG C H,SHEN J L,ZHANG Y X,et al.Quantitative assessment of industrial VOC emissions in China:historical trend,spatial distribution,uncertainties,and projection[J].Atmospheric Environment,2017,150:116-125.
[6]SEINFELD J H,PANDIS S N.Atmospheric chemistry and physics[M].New York:Wiley,1998.
[7]陈多宏,张涛,蒋斌,等.典型二次有机气溶胶危害性及环境监测技术研究进展[J].环境科学与技术,2014,37(增刊2):305-309.
[8]WANG H L,NIE L,LI J,et al.Characterization and assessment of volatile organic compounds(VOCs)emissions from typical industries[J].Chinese Science Bulletin,2013,58(7):724-730.
[9]李明哲,黄正宏,康飞宇.挥发性有机物的控制技术进展[J].化学工业与工程,2015,32(3):2-9.
[10]CARMEN E,FRANCISCA F,MIGUEL A S,et al.Characterization and evolution of exposure to volatile organic compounds in the Spanish shoemaking industry over a 5-year period[J].Journal of Occupational and Environmental Hygiene,2012,9(11):653-622.
[11]周郁潮,郑海英,冯简青,等.珠三角某市制鞋行业有机溶剂成分检测分析[J].职业卫生与应急救援,2015,33(3):176-177.
[12]刘玲英,蔡慧华,罗超.制鞋行业挥发性有机化合物(VOCs)排放特征研究[J].广东化工,2012,39(6).
[13]龚芳.我国人为源VOCs排放清单及行业排放特征分析[D].西安:西安建筑科技大学,2013.
[14]王红丽,杨肇勋,景盛翱.工艺过程源和溶剂使用源挥发性有机物排放成分谱研究进展[J].环境科学,2017,38(6).
[15]ZHONG Z M,SHA Q E,ZHENG J Y,et al.Sector-based VOCs emission factors and source profiles for the surface coating industry in the Pearl River Delta region of China[J].Science of the Total Environment,2017,583:19-28.
[16]徐志荣,姚轶,蔡卫丹,等.浙江省制鞋行业挥发性有机物污染特征及其排放系数[J].环境科学,2016,37(10):3702-3707.
[17]余宇帆,卢清,郑君瑜,等.珠江三角洲地区重点VOC排放行业的排放清单[J].中国环境科学,2011,31(2):195-201.
[18]吴洪杰,刘玲英,蔡慧华,等.珠江三角洲制鞋行业挥发性有机化合物排放系数研究[J].中国环境监测,2013,29(4):74-78.
[19]余宇帆.珠江三角洲地区典型工业VOCs源排放成分谱研究[D].广州:华南理工大学,2012.
[20]黄络萍.基于GIS平台的成都市工业源VOCs空间分布特征[D].成都:西南交通大学,2017.
[21]何敏,王幸锐,韩丽.四川省大气固定污染源排放清单及特征[J].环境科学学报,2013,33(11):3127-3137.
[22]韩丽,王幸锐,何敏,等.四川省典型人为污染源VOCs排放清单及其对大气环境的影响[J].环境科学,2013,34(12):4535-4542.
[23]CHANG C T,LIN K L.Assessment of the strategies for reducing VOCs emission from polyurea-formaldehyde resin synthetic fiber leather industry in Taiwan[J].Resources Conservation and Recycling,2006,46(4):321-334.
[24]NIU H,MO Z W,SHAO M,et al.Screening the emission sources of volatile organic compounds in China by multieffects evaluation[J].Frontiers of Environmental Science&Engineering,2016,10(5):1-10.
[25]HJ 732-2014,固定污染源废气挥发性有机物的采样气袋法[S].
[26]HJ 759-2015,环境空气挥发性有机物的测定罐采样/气相色谱-质谱法[S].
[27]许伟,刘军利,孙康.活性炭吸附法在挥发性有机物治理中的应用研究进展[J].化工进展,2016,35(4):1223-1229.
[28]YUAN B,SHAO M,LU S H,et al.Source profiles of volatile organic compounds associated with solvent use in Beijing,China[J].Atmospheric Environment,2010,44(15):1919-1926.
[29]乔月珍.上海市机动车和涂料VOCs源成分谱特征及其大气反应活性研究[D].上海:华东理工大学,2011.
[30]ZHENG J Y,YU Y F,MO Z W,et al.Industrial sector-based volatile organic compound source profiles measured in manufacturing facilities in the Pearl River Delta,China[J].Science of the Total Environment,2013,456:127-136.
[31]赵锐,黄络萍,张建强,等.成都市典型溶剂源使用行业VOCs排放成分特征[J].环境科学学报,2018,38(3):1-5.
[32]莫梓伟,邵敏,陆思华.中国挥发性有机物(VOCs)排放源成分谱研究进展[J].环境科学学报,2014,34(9):2179-2189.