新型纳米碳/碳化钼的制备及应用研究
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摘要
碳化钼具有类铂的催化性能,因而纳米碳/碳化钼作为催化剂在许多催化反应、能源和环境领域具有潜在的应用价值。对近年来制备新型纳米碳与碳化钼的方法、在催化等领域的应用研究进行了综述和总结,并展望了在传感领域的应用前景。
Nanocarbon-molybdenum carbide has potential application in the fields of catalysis,energy and environments due to its platinum-like properties.The preparation methods reported recently and application in catalysis were reviewed and summarized,and the sensing applications were forecasted.
Nanocarbon-molybdenum carbide has potential application in the fields of catalysis,energy and environments due to its platinum-like properties.The preparation methods reported recently and application in catalysis were reviewed and summarized,and the sensing applications were forecasted.
引文
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[12]Ma Y F,Guan G Q,Phanthong P,et al.Steam reforming of methanol for hydrogen production over nanostructured wiredlike molybdenum carbide catalyst[J].International Journal of Hydrogen Energy,2014,33(39):18803-18811.
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[22]Huang Y,Gong Q F,Song X N,et al.Mo2C nanoparticles dispersed on hierarchical carbon microflowers for efficient electrocatalytic hydrogen evolution[J].ACS Nano,2016,10(12):11337-11343.
[23]Ren H,Yu W T,Salciccioli M,et al.Selective hydrodeoxygenation of biomass-derived oxygenate to unsaturated hydrocarbons using molybdenum carbide catalysts[J].Chemistry and Sustainable Chemistry,2013,6(5):798-801.
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[25]Liu C C,Lin M G,Fang K G,et al.Preparation of nanostructured molybdenum carbides for CO hydrogenation[J].RSC Advances,2014(40):20948-20954.
[26]Qi K Z,Wang G C,Zheng W J.A first-principles study of CO hydrogenation into methane on molybdenum carbides catalyst[J].Surface Science,2013,614:53-63.
[27]Posada-Perez S,Vines F,Ramirez P J,et al.The bending machine:CO2activation and hydrogenation onδ-Mo2C(001)surfaces[J].Physical Chemistry Chemical Physics,2014(28):14912-14921.
[28]曹丹艳,陈平,楼辉,等.多壁碳纳米管负载的碳化钼催化剂在玉米油加氢脱氧反应中的应用[J].浙江大学学报,2015,42(6):637-643.
[29]Choi J S,Zacher A H,Wang H M,et al.Molybdenum carbides,active and in situ regenerable catalysts in hydroprocessing of fast pyrolysis bio-oil[J].Energy&Fuels,2016,30(6):5016-5026.
[30]Liu Y T,Ding J,Sun J Q,et al.Molybdenum carbide as an efficient catalyst for low-temperature hydrogenation of dimethyl oxalate[J].Chemical Communications,2016,52(28):5030-5032.
[31]Quiroz J,Mai E F,da Silva V T.Synthesis of nanostructured molybdenum carbide as catalyst for the hydrogenation of levulinic acid toγ-valerolactone[J].Topics in Catalysis,2016,59(2/4):148-158.
[32]Wang T,Dong Z,Cai W M,et al.An efficient hydrogenation catalyst in sulfuric acid for the conversion of nitrobenzene to p-aminophenol:N-doped carbon with encapsulated molybdenum carbide[J].Chemical Communications,2016,52(70):10672-10675.
[33]Frank B,Cotter T P,Schuster M E,et al.Carbon dynamics on the molybdenum carbide surface during catalytic propane dehydrogenation[J].Chemistry European Journal,2013,50(19):16938-16945.
[34]Li Z C,Chen C H,Zhan E S,et al.Crystal-phase control of molybdenum carbide nanobelts for dehydrogenation of benzyl alcohol[J].Chemical Communications,2014,50(34):4469-4471.
[35]申文杰,李忠成,陈春晖,等.碳化钼纳米带在苯甲醇脱氢制苯甲醛反应中的应用:中国,10060109.4[P].2015-08-26.
[36]Liao L,Wang S N,Xiao J J,et al.A nanoporous molybdenum carbide nanowires as an electrocatalyst for hydrogen evolution reaction[J].Energy Environmental Science,2014(1):387-392.
[37]Chen W F,Muckerman J T,Fujita E.Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts[J].Chemical Communications,2013(79):8896-8909.
[38]Gyula H,Tamas B,Erika V,et al.Photocatalytic decomposition of formic acid on the Mo2C-contianing catalyst[J].Catalysis Letters,2015,145:875-880.
[39]Sljukic B,Santors D M F,Vujkovic M,et al.Molybdenum carbide nanoparticles on carbon nanotubes and carbon xerogel:low-cost cathodes for hydrogen production by alkaline water electrolysis[J].Chemistry and Sustainable Chemistry,2016,10(9):1200-1208.
[40]Lin L L,Zhou W,Gao R,et al.Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts[J].Nature,2017,544:80-83.
[41]Yao S Y,Zhang X,Zhou W,et al.Atomic-layered Au clusters onα-MoC as catalysts for the low-temperature water-gas[J].Science,2017,357:389-393.
[42]Zhai Q F,Zhang X W,Li J,et al.Molybdenum carbide nanotubes:a novel multifunctional material for label-free electrochemical immunosensing[J].Nanoscale,2016(33):15303-15308.
[43]Xing Z C,Wang L,Sun X P,et al.Nanoporous molybdenum carbide nanowires:a novel sensing platform for DNA detection[J].Journal of Materials Chemistry B,2015(36):7173-7176.
[2]Matsumoto T,Nagashima Y,Yamazaki T,et al.Fuel cell anode composed of Mo2C catalyst and carbon nanotube electrodes[J].Electrochemical and Solid State Letters,2006,9(3):A160-A162.
[3]李晓芸,马丁,包信和.不同炭载体上碳化钼催化剂的合成[J].催化学报,2008,29(9):884-888.
[4]Hyeon T,Fang M M,Suslick K S.Nanostructured molybdenum carbide:sonochemical synthesis and catalytic properties[J].Journal of The American Chemical Society,1996,118(23):5492-5493.
[5]Hassan A,Paganin V A,Carreras A,et al.Molybdenum carbide-based electrocatalysts for CO tolerance inproton exchange membrane fuel cell anodes[J].Electrochimica Acta,2014,142:307-316.
[6]Mnatsakanyan R,Zhurnachyan A R,Matyshak V A,et al.Microwave-asisted synthesis of carbon-supported carbides catalysts for hydrous hydrazine decomposition[J].Journal of Physics and Chemistry of Solids,2016,96:115-120.
[7]Biedunkiewicz A,Figiel P,Krawczyk M,et al.Simultaneous synthesis of molybdenum carbides and titaniumcarbides by sol-gel method[J].Journal Thermal Analysis and Calorimetry,2013,113:253-258.
[8]赵立红,闫捷,魏灵朝,等.纳米碳化钼复合物的制备及其CO加氢反应性能[J].化工新型材料,2015,43(4):194-199.
[9]Wan C,Knight N A,Leonard B M.Crystal structure and morphology control of molybdenum carbide nanomaterials synthesized from an amine-metal oxide composite[J].Chem Commun,2013,49(88):10409-10411.
[10]Wu H B,Xiao B Y,Yu L,et al.Porous molybdenum carbide nano-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production[J].Nature Communications,2014,6:1-8.
[11]Liu C C,Lin M G,Jiang D,et al.Preparation of promoted molybdenum carbides nanowirefor CO hydrogenation[J].Catal Lett,2014,144:567-573.
[12]Ma Y F,Guan G Q,Phanthong P,et al.Steam reforming of methanol for hydrogen production over nanostructured wiredlike molybdenum carbide catalyst[J].International Journal of Hydrogen Energy,2014,33(39):18803-18811.
[13]Li J S,Yu W,Liu C H,et al.Coupled molybdenum carbide and reduced graphene oxide electrocatalysts for efficient hydrogen evolution[J].Nature Communications,2016,7:11204-11212.
[14]Gao W,Shi Y Q,Zhang Y F,et al.Molybdenum carbide anchored on graphene nanoribbons as highly efficient all-pH hydrogen evolution reaction electrocatalyst[J].ACS Sustainable Chemistry&Engineering,2016,4(12):6313-6321.
[15]Li X X,Ci S Q,Jia J C,et al.Graphene loading molybdenum carbide/oxide hybrids as advanced electrocatalysts for hydrogen evolution reaction[J].International Journal of Hydrogen Energy,2016,41(46):21246-21250.
[16]Du J P,Wu J T,Guo T Y,et al.Catalytic performance of Mo2C supported on onion-like carbon for dehydrogenation of cyclohexane[J].RSC Advances,2014,4:53950-53953.
[17]Liu Y P,Yu G T,Li G D,et al.Coupling Mo2C with nitrogenrich nanocarbon leads to efficient hydrogen evolution electrocatalytic sites[J].Angewandte Chemie International Edition,2015,54(37):10752-10757.
[18]Wu Z Y,Hu B C,Wu P,et al.Mo2C nanoparticles embedded within bacterial cellulose-derived 3D N-doped carbon nanofiber networks for efficient hydrogen evolution[J].NPG Asia Materials,2016,8:1-8.
[19]Li R,Shahbazi A,Wang L J,et al.Graphite encapsulated molybdenum carbide core/shell nanocomposite for highly selective conversion of guaiacol to phenolic compounds in methanol[J].Applied Catalysis A General,2016,528:123-130.
[20]Lv C C,Wang J,Huang Q L,et al.Facile synthesis of hollow carbon microspheres embedded with molybdenum carbide nanoparticles as an efficient electrocatalyst for hydrogen generation[J].RSC Advances,2016,79:75870-75874.
[21]Chen Y Y,Zhang Y,Jiang W J,et al.Pomegranate-like N,Pdoped Mo2C@C nanosheres as highly active electrocatalysts for alkaline hydrogen evolution[J].ACS Nano,2016,10(9):8851-8860.
[22]Huang Y,Gong Q F,Song X N,et al.Mo2C nanoparticles dispersed on hierarchical carbon microflowers for efficient electrocatalytic hydrogen evolution[J].ACS Nano,2016,10(12):11337-11343.
[23]Ren H,Yu W T,Salciccioli M,et al.Selective hydrodeoxygenation of biomass-derived oxygenate to unsaturated hydrocarbons using molybdenum carbide catalysts[J].Chemistry and Sustainable Chemistry,2013,6(5):798-801.
[24]Chai S H,Schwartz V,Howe J Y,et al.Graphitic mesoporous carbon-supported molybdenum carbides for catalytic hydrogenation of carbon monoxide to mixed alcohols[J].Microporous and Mesoporous Materials,2013,170:141-149.
[25]Liu C C,Lin M G,Fang K G,et al.Preparation of nanostructured molybdenum carbides for CO hydrogenation[J].RSC Advances,2014(40):20948-20954.
[26]Qi K Z,Wang G C,Zheng W J.A first-principles study of CO hydrogenation into methane on molybdenum carbides catalyst[J].Surface Science,2013,614:53-63.
[27]Posada-Perez S,Vines F,Ramirez P J,et al.The bending machine:CO2activation and hydrogenation onδ-Mo2C(001)surfaces[J].Physical Chemistry Chemical Physics,2014(28):14912-14921.
[28]曹丹艳,陈平,楼辉,等.多壁碳纳米管负载的碳化钼催化剂在玉米油加氢脱氧反应中的应用[J].浙江大学学报,2015,42(6):637-643.
[29]Choi J S,Zacher A H,Wang H M,et al.Molybdenum carbides,active and in situ regenerable catalysts in hydroprocessing of fast pyrolysis bio-oil[J].Energy&Fuels,2016,30(6):5016-5026.
[30]Liu Y T,Ding J,Sun J Q,et al.Molybdenum carbide as an efficient catalyst for low-temperature hydrogenation of dimethyl oxalate[J].Chemical Communications,2016,52(28):5030-5032.
[31]Quiroz J,Mai E F,da Silva V T.Synthesis of nanostructured molybdenum carbide as catalyst for the hydrogenation of levulinic acid toγ-valerolactone[J].Topics in Catalysis,2016,59(2/4):148-158.
[32]Wang T,Dong Z,Cai W M,et al.An efficient hydrogenation catalyst in sulfuric acid for the conversion of nitrobenzene to p-aminophenol:N-doped carbon with encapsulated molybdenum carbide[J].Chemical Communications,2016,52(70):10672-10675.
[33]Frank B,Cotter T P,Schuster M E,et al.Carbon dynamics on the molybdenum carbide surface during catalytic propane dehydrogenation[J].Chemistry European Journal,2013,50(19):16938-16945.
[34]Li Z C,Chen C H,Zhan E S,et al.Crystal-phase control of molybdenum carbide nanobelts for dehydrogenation of benzyl alcohol[J].Chemical Communications,2014,50(34):4469-4471.
[35]申文杰,李忠成,陈春晖,等.碳化钼纳米带在苯甲醇脱氢制苯甲醛反应中的应用:中国,10060109.4[P].2015-08-26.
[36]Liao L,Wang S N,Xiao J J,et al.A nanoporous molybdenum carbide nanowires as an electrocatalyst for hydrogen evolution reaction[J].Energy Environmental Science,2014(1):387-392.
[37]Chen W F,Muckerman J T,Fujita E.Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts[J].Chemical Communications,2013(79):8896-8909.
[38]Gyula H,Tamas B,Erika V,et al.Photocatalytic decomposition of formic acid on the Mo2C-contianing catalyst[J].Catalysis Letters,2015,145:875-880.
[39]Sljukic B,Santors D M F,Vujkovic M,et al.Molybdenum carbide nanoparticles on carbon nanotubes and carbon xerogel:low-cost cathodes for hydrogen production by alkaline water electrolysis[J].Chemistry and Sustainable Chemistry,2016,10(9):1200-1208.
[40]Lin L L,Zhou W,Gao R,et al.Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts[J].Nature,2017,544:80-83.
[41]Yao S Y,Zhang X,Zhou W,et al.Atomic-layered Au clusters onα-MoC as catalysts for the low-temperature water-gas[J].Science,2017,357:389-393.
[42]Zhai Q F,Zhang X W,Li J,et al.Molybdenum carbide nanotubes:a novel multifunctional material for label-free electrochemical immunosensing[J].Nanoscale,2016(33):15303-15308.
[43]Xing Z C,Wang L,Sun X P,et al.Nanoporous molybdenum carbide nanowires:a novel sensing platform for DNA detection[J].Journal of Materials Chemistry B,2015(36):7173-7176.