铜铬黑陶瓷墨水的耐温性研究
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摘要
陶瓷喷墨打印技术作为现代计算机和陶瓷表面装饰技术的结合,拥有传统装饰技术无法可比的优点。陶瓷墨水的制备是陶瓷喷墨打印技术的核心,本文利用研磨分散法制备出黑色陶瓷墨水,探究了不同的固含量对墨水性能的影响。墨水通过喷码机在堇青石蜂窝陶瓷上打印后进行不同温度区间的耐温性测试,设定的温度区间为600℃-1000℃。测试结果表明:制备的黑色陶瓷墨水能在800℃煅烧30 min后颜色保持不褪色且图案清晰,超过800℃颜色变得暗淡。
As a combination between modern computer technology and ceramic decoration technology, the digital ink-jet printing has many more advantages than traditional ceramic decoration technologies. The preparation of ceramic ink is the key technique for the digital ceramic ink-jet printing. In this paper, a black ceramic ink was successfully prepared by grinding dispersion method. The influence of solid content on the properties of the ceramic ink was investigated. The ink was printed on cordierite honeycomb ceramics by inkjet printer, on which the temperature stability was tested in different temperature ranges from 600 °C to 1000 °C. Results show that the printed picture on the cordierite honeycomb ceramics remains clearly visible without color change after being annealed at 800 °C for 30 minutes. However, with the further increasing of the annealing temperature, the color of the ink becomes gradually lighter.
As a combination between modern computer technology and ceramic decoration technology, the digital ink-jet printing has many more advantages than traditional ceramic decoration technologies. The preparation of ceramic ink is the key technique for the digital ceramic ink-jet printing. In this paper, a black ceramic ink was successfully prepared by grinding dispersion method. The influence of solid content on the properties of the ceramic ink was investigated. The ink was printed on cordierite honeycomb ceramics by inkjet printer, on which the temperature stability was tested in different temperature ranges from 600 °C to 1000 °C. Results show that the printed picture on the cordierite honeycomb ceramics remains clearly visible without color change after being annealed at 800 °C for 30 minutes. However, with the further increasing of the annealing temperature, the color of the ink becomes gradually lighter.
引文
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[2]宋晓岚,祝根,林康,等.喷墨打印用陶瓷墨的研究现状及发展趋势[J].材料导报,2014,28(3):88-92.SONG X T,ZHU G,LIN K,et al.Materials Review,2014,28(3):88-92.
[3]江红涛,王秀峰,牟善勇.陶瓷装饰用彩喷墨水研究进展[J].硅酸盐通报,2004,18(2):57-59.JIANG H T,WANG X F,MOU S Y.Bulletin of the Chinese Ceramic Society,2004,18(2):57-59.
[4]EMRE OZKOL,JORG EBERT,RAINER TELLE.An experimental analysis of the influence of the ink properties on the drop formation for direct thermal inkjet printing of high solid content aqueous 3Y-TZP suspensions[J].Journal of the European Ceramic Society,2010,30:1669-1678.
[5]郭艳杰,周振君,杨正方.Sol-Gel法制备连续式喷墨打印用彩色陶瓷墨水的理化性能[J].中国陶瓷,2002,38(1):17-19.GUO Y J,ZHOU Z J,YANG Z F.China Ceramics,2002,38(1):17-19.
[6]CHOUIKI M,SCHOEFTNER R.Inkjet printing of inorganic solgel ink and control of the geometrical characteristics[J].Journal of Sol-Gel Science and Technology,2011,58(1):91-95.
[7]江红涛,王秀峰.反相微乳液法制备陶瓷彩喷墨水(Ⅰ)[J].中国陶瓷,2006,42(8):24-27.JIANG H T,WANG X F.China Ceramics,2006,42(8):24-27.
[8]江红涛,王秀峰.反相微乳液法制备陶瓷彩喷墨水(Ⅱ)[J].中国陶瓷,2006,42(9):18-21.JIANG H T,WANG X F.China Ceramics,2006,42(9):18-21.
[9]江红涛,王秀峰,牟善勇,等.反相微乳液法制备陶瓷装饰用彩喷墨水[J].陶瓷,2004:15-18.JIANG H T,WANG X F,MOU S Y,et al.Ceramics,2004:15-18.
[10]GUO R S,QI H T,YANG Z F,et al.Preparation and properties of the AEO9/alcohol/alkane/water reverse microemulsion ceramic inks[J].Ceramics International,2004,30:2259-2267.
[11]王利锋,王富民,张旭斌,等.喷墨打印用陶瓷墨水的研究进展[J].硅酸盐通报,2013,32(5):863-867.WANG L F,WANG F M,ZHANG X B,et al.Bulletin of the Chinese Ceramic Society,2013,32(5):863-867.
[12]江红涛,王秀峰,于成龙,等.正交试验研究陶瓷装饰用蓝色喷墨墨水[J].中国陶瓷,2011,47(8):20-24.JIANG H T,WANG X F,YU C L,et al.China Ceramics,2011,47(8):20-24.
[13]PEYMANNIA M,SOLEIMANI-GORGANI A,GHAHARIM,et al.The effect of different dispersants on the physical properties of nano CoAl2O4 ceramic ink-jet ink[J].Ceramics International,2015,41:9115-9121.
[14]TOMOV R I,KRAUZ M,JEWULSKI J,et al.Direct ceramic inkjet printing of yttria-stabilized zirconia electrolyte layers for anode-supported solid oxide fuel cells[J].Journal of Power Sources,2010,195:7160-7167.
[15]GIABLE G.The structural and optical studies of titanium doped rare earth pigments and coloring applications[J].Dyes and Pigments,2015,112(1):81-85.
[16]周春隆,穆振义.有机颜料化学及工艺学[M].北京:中国石化出版社,1997:372.
[17]陈红,刘凌云.颜料分散及超分散剂的应用[J].印染,1998,(8):50-53.CHEN H,LIU L Y.Printing and Dyeing,1998,(8):50-53.
[18]邱再林,骆颂,李家铎,等.颗粒度对陶瓷釉用色料发色的影响研究[J].中国陶瓷工业,2015,1(5):11-16.QIU Z L,LUO S,LI J D,et al.China Ceramic Industry,2015,1(5):11-16.
[19]秦威,鲁欢欢,田洪鑫,等.浅析分散法陶瓷喷墨打印墨水的研制[J].佛山陶瓷,2013,1(4):1-6.QIN W,LU H H,TIAN H X,et al.Foshan Ceramics,2013,1(4):1-6.
[20]EPPLER R A.Cobalt-free black pigments[J].Bulletin of the American Ceramic Society,1981,60(5):562.
[21]DONDI M,ZANELLI C,ARDIT M,et al.Ni-free,black ceramic pigments based on Co-Cr-Fe-Mn spinels:Areappraisal of crystal structure,colour and technological behavior[J].Ceramics International,2013,39(8):9533-9547.