海泡石吸附剂的应用研究进展
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摘要
海泡石是一种纤维状的硅酸盐粘土矿物,具有良好的吸附性能。本文介绍了海泡石的结构特征及其改性方法,并综述海泡石作为吸附剂在吸附处理重金属离子、有机废水、有色废水、无机非金属方面的应用研究现状。
Sepiolite is a natural clay mineral including micro-fibrous structure with strong absorption capacity. This paper introduces the structural features and the modification methods of sepiolite, and reviews the research progress of sepiolite miners as the absorbent in the field of the absorption treatment of heavy metal ion, organic wastewater, pigmented wastewater and inorganic non-mental materials with sepiolite.
Sepiolite is a natural clay mineral including micro-fibrous structure with strong absorption capacity. This paper introduces the structural features and the modification methods of sepiolite, and reviews the research progress of sepiolite miners as the absorbent in the field of the absorption treatment of heavy metal ion, organic wastewater, pigmented wastewater and inorganic non-mental materials with sepiolite.
引文
[1]高程,黄涛,彭道平,等.吸附法处理印染废水的研究进展[J].能源环境保护,2014,28(1):30-34.
[2]Armagan B,Turan M,elik M S,et al.Equilibrium studies on the adsorption of reactive azo dyes into zeolite[J].Desalination,2004,170(1):33-39.
[3]oruh S,Geyiki F,Elevli S.Adsorption of neutral red dye from an aqueous solution onto natural sepiolite using full factorial design[J].Clays and Clay Minerals,2011,59(6):617-625.
[4]oruh S,Geyiki F,oruh U.Removal of Cu2+from copper flotation waste leachant using sepiolite:full factorial design approach[J].Acta Geodynamica et Geomaterialia,2013,10(4):453-458.
[5]Arma gan B,Turan M,elik M S.Equilibrium studies on the adsorption of reactive azo dyes into zeolite[J].Desalination,2004,170(1):33-39.
[6]zcan A S,zcan A.Adsorption of acid dyes from aqueous solutions onto acid-activated bentonite[J].Journal of Colloid and Interface Science,2004,276(1):39-46.
[7]Peng G,Wan L J,Wang L X.Removal of Pb(II)from aqueous solution using tremolite amianthus[J].Asian Journal of Chemistry,2012,24(8):3457-3460.
[8]Dogan M,zdemir Y and Alkan M.Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite[J].Dyes and Pigments,2007,75(3):701-713.
[9]zdemir O,nar M,Sabah E,et al.Adsorption of anionic surfactants onto sepiolite[J].Journal of Hazardous Mater,2007,147(1-2):625-632.
[10]zcan A,ncüE M,zcan A S.Adsorption of acid blue 193 from aqueous solutions onto DEDMA-sepiolite[J].Journal of Hazardous Materials,2006,129(1):244-252.
[11]Rytwo G,Tropp D,Serban C.Adsorption of diquat,paraquat and methyl green on sepiolite:experimental results and model calculations[J].Applied Clay Science,2002,20(6):273-282.
[12]zcan A,zcan A S.Adsorption of acid Red 57 from aqueous solutions onto surfactant-modified sepiolite[J].Journal of Hazardous Materials,2005,125(1-3):252-259.
[13]梁凯.海泡石的矿物学研究与其在环境治理中的应用[D].湖南:中南大学,2008:13.
[14]Shimizu K,Maruyama R,Komai S,et al.Pd-sepiolite catalyst for suzuki coupling reaction in water:structural and catalytic investigations[J].Journal of Catalysis,2004,227(1):202-209.
[15]Lazarevic'S,Jankovi c'-C姚astvan I,Jovanovic'D,et al.Removal of Co2+ions from aqueous solutions using ironfunctionalized sepiolite[J].Chemical Engineering and Processing:Process Intensification,2012,55:40-47.
[16]Lemic'J,Tomasevic'C M,Djuricic'M,et al.Surface modification of sepiolite with quaternary amines[J].Journal of Colloid and Interface Science,2005,292(1):11-19.
[17]李松军,罗来涛.海泡石的改性研究[J].江西科学,2001,19(1):62-66.
[18]Campelo J M,Garcia A,Luna D,et al.Textural properties surface chemistry and catalytic activity in cyclohexene skeletal isomenizaton of acid treated natural sepiolite[J].Materials Chemistry Physics,1984,24:51-70.
[19]González-Pradas E,Socías-Viciana M,Uren軌a-Amate M D,et al.Adsorption of chloridazon from aqueous solution on heat and acid treated sepiolites[J].Water Research,2005,39:1849-1857.
[20]高银萍,瞿学良,申玉双.海泡石对金属离子的吸附作用及再生性研究[J].无机盐工业,1995(2):17-19.
[21]瞿学良,刘辉,周相廷.海泡石的组成对离子交换作用的影响[J].矿产综合利用,1998(3):15-18.
[22]梁凯,唐丽永,王大伟.海泡石活化改性的研究现状及应用前景[J].化工矿物与加工,2006(4):5-9.
[23]瞿学良,李纪标,周相廷.海泡石的水热法超细化处理后结构、形态与活性研究[J].化学世界1998(3):126-129.
[24]林春.海泡石作为吸附剂在废水处理中的应用研究[D].江苏:南京理工大学,2004:20.
[25]王吉中,陈安国.热处理海泡石石棉研究[J].河北地质学院学报,1996,19(3):12-16.
[26]张丽蓉.有机改性海泡石对染料孔雀石绿的吸附试验研究[D].湖南:湖南大学,2013:25.
[27]Kanedak K,Kiriyamat T,Hiraokat T,et al.Preparation of divalent Pd(Ⅱ)species on sepiolite and its catalysis of olefin dimerizations[J].J Mol Catal,1988,48:343-347.
[28]张建梅,韩志萍,王亚军.重金属废水的生物处理技术[J].环境污染治理技术与设备,2003,4(4):75-78.
[29]Brigattietal M F,et al.Sepiolite and industrial waste water purification:removal of Zn2+and Pb2+from aqueous solutions[J].Applied Clay Science,1996,11(1):43-54.
[30]Lazarevic'S,Jankovi c'-Castvan I,Jovanovic'D,et al.Adsorption of Pb2+,Cd2+and Sr2+ions onto natural and acid-activated sepiolites[J].Applied Clay Science,2007,37(1-2):47-57.
[31]王宁,侯艳伟,彭静静,等.生物炭吸附有机污染物的研究进展[J].环境科学,2012,31(3):47-57.
[32]González-Pradas E,Villafranca-Sánchez M,Socías-Viciana M,et al.Preliminary studies in removing atrazine,isoproturon and imidacloprid from water by natural sepiolite[J].Journal of Chemical Technology and Biotechnology,1999,74:417-422.
[33]Yildiz A,Gür A.Adsorption of phenol and chlorophenols on pure and modified sepiolite[J].Journal of the Serbian Chemical Society,2007,72(5):467-474.
[34]Duan E,Han J,Song Y,et al.Adsorption of styrene on the hydrothermal-modified sepiolite[J].Maters Letters,2013,111:150-153.
[35]郑冀鲁,范娟.印染废水脱色技术与理论述评[J].环境污染治理技术与设备,2000,1(5):29-35.
[36]颜靖.有机改性海泡石吸附水中酸性品红的试验研究[D].湖南:湖南大学,2013:21.
[37]Ugurlu M.Adsorption of a textile dye onto activated sepiolite[J].Microporous and Mesoporous Materials,2009,119(1-3):276-283.
[38]oruh S,Elevli S.Optimization of malachite green dye removal by sepiolite clay using a central composite design[J].Global Nest Journal,2014,16(2):339-347.
[39]Murathan A,Ahmet B,Ahmet A,et al.Effects of various parameters on removal of NO2 gases in fixed beds by adsorption on sepiolite[J].Water,Air,and Soil Pollution,2001,132(3):365-372.
[40]Delgado J A,Uguina M A,Sotelo J.Carbon dioxide/methane separation by adsorption on sepiolite[J].Journal of Natural Gas Chemistry,2007,16(3):235-243.
[2]Armagan B,Turan M,elik M S,et al.Equilibrium studies on the adsorption of reactive azo dyes into zeolite[J].Desalination,2004,170(1):33-39.
[3]oruh S,Geyiki F,Elevli S.Adsorption of neutral red dye from an aqueous solution onto natural sepiolite using full factorial design[J].Clays and Clay Minerals,2011,59(6):617-625.
[4]oruh S,Geyiki F,oruh U.Removal of Cu2+from copper flotation waste leachant using sepiolite:full factorial design approach[J].Acta Geodynamica et Geomaterialia,2013,10(4):453-458.
[5]Arma gan B,Turan M,elik M S.Equilibrium studies on the adsorption of reactive azo dyes into zeolite[J].Desalination,2004,170(1):33-39.
[6]zcan A S,zcan A.Adsorption of acid dyes from aqueous solutions onto acid-activated bentonite[J].Journal of Colloid and Interface Science,2004,276(1):39-46.
[7]Peng G,Wan L J,Wang L X.Removal of Pb(II)from aqueous solution using tremolite amianthus[J].Asian Journal of Chemistry,2012,24(8):3457-3460.
[8]Dogan M,zdemir Y and Alkan M.Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite[J].Dyes and Pigments,2007,75(3):701-713.
[9]zdemir O,nar M,Sabah E,et al.Adsorption of anionic surfactants onto sepiolite[J].Journal of Hazardous Mater,2007,147(1-2):625-632.
[10]zcan A,ncüE M,zcan A S.Adsorption of acid blue 193 from aqueous solutions onto DEDMA-sepiolite[J].Journal of Hazardous Materials,2006,129(1):244-252.
[11]Rytwo G,Tropp D,Serban C.Adsorption of diquat,paraquat and methyl green on sepiolite:experimental results and model calculations[J].Applied Clay Science,2002,20(6):273-282.
[12]zcan A,zcan A S.Adsorption of acid Red 57 from aqueous solutions onto surfactant-modified sepiolite[J].Journal of Hazardous Materials,2005,125(1-3):252-259.
[13]梁凯.海泡石的矿物学研究与其在环境治理中的应用[D].湖南:中南大学,2008:13.
[14]Shimizu K,Maruyama R,Komai S,et al.Pd-sepiolite catalyst for suzuki coupling reaction in water:structural and catalytic investigations[J].Journal of Catalysis,2004,227(1):202-209.
[15]Lazarevic'S,Jankovi c'-C姚astvan I,Jovanovic'D,et al.Removal of Co2+ions from aqueous solutions using ironfunctionalized sepiolite[J].Chemical Engineering and Processing:Process Intensification,2012,55:40-47.
[16]Lemic'J,Tomasevic'C M,Djuricic'M,et al.Surface modification of sepiolite with quaternary amines[J].Journal of Colloid and Interface Science,2005,292(1):11-19.
[17]李松军,罗来涛.海泡石的改性研究[J].江西科学,2001,19(1):62-66.
[18]Campelo J M,Garcia A,Luna D,et al.Textural properties surface chemistry and catalytic activity in cyclohexene skeletal isomenizaton of acid treated natural sepiolite[J].Materials Chemistry Physics,1984,24:51-70.
[19]González-Pradas E,Socías-Viciana M,Uren軌a-Amate M D,et al.Adsorption of chloridazon from aqueous solution on heat and acid treated sepiolites[J].Water Research,2005,39:1849-1857.
[20]高银萍,瞿学良,申玉双.海泡石对金属离子的吸附作用及再生性研究[J].无机盐工业,1995(2):17-19.
[21]瞿学良,刘辉,周相廷.海泡石的组成对离子交换作用的影响[J].矿产综合利用,1998(3):15-18.
[22]梁凯,唐丽永,王大伟.海泡石活化改性的研究现状及应用前景[J].化工矿物与加工,2006(4):5-9.
[23]瞿学良,李纪标,周相廷.海泡石的水热法超细化处理后结构、形态与活性研究[J].化学世界1998(3):126-129.
[24]林春.海泡石作为吸附剂在废水处理中的应用研究[D].江苏:南京理工大学,2004:20.
[25]王吉中,陈安国.热处理海泡石石棉研究[J].河北地质学院学报,1996,19(3):12-16.
[26]张丽蓉.有机改性海泡石对染料孔雀石绿的吸附试验研究[D].湖南:湖南大学,2013:25.
[27]Kanedak K,Kiriyamat T,Hiraokat T,et al.Preparation of divalent Pd(Ⅱ)species on sepiolite and its catalysis of olefin dimerizations[J].J Mol Catal,1988,48:343-347.
[28]张建梅,韩志萍,王亚军.重金属废水的生物处理技术[J].环境污染治理技术与设备,2003,4(4):75-78.
[29]Brigattietal M F,et al.Sepiolite and industrial waste water purification:removal of Zn2+and Pb2+from aqueous solutions[J].Applied Clay Science,1996,11(1):43-54.
[30]Lazarevic'S,Jankovi c'-Castvan I,Jovanovic'D,et al.Adsorption of Pb2+,Cd2+and Sr2+ions onto natural and acid-activated sepiolites[J].Applied Clay Science,2007,37(1-2):47-57.
[31]王宁,侯艳伟,彭静静,等.生物炭吸附有机污染物的研究进展[J].环境科学,2012,31(3):47-57.
[32]González-Pradas E,Villafranca-Sánchez M,Socías-Viciana M,et al.Preliminary studies in removing atrazine,isoproturon and imidacloprid from water by natural sepiolite[J].Journal of Chemical Technology and Biotechnology,1999,74:417-422.
[33]Yildiz A,Gür A.Adsorption of phenol and chlorophenols on pure and modified sepiolite[J].Journal of the Serbian Chemical Society,2007,72(5):467-474.
[34]Duan E,Han J,Song Y,et al.Adsorption of styrene on the hydrothermal-modified sepiolite[J].Maters Letters,2013,111:150-153.
[35]郑冀鲁,范娟.印染废水脱色技术与理论述评[J].环境污染治理技术与设备,2000,1(5):29-35.
[36]颜靖.有机改性海泡石吸附水中酸性品红的试验研究[D].湖南:湖南大学,2013:21.
[37]Ugurlu M.Adsorption of a textile dye onto activated sepiolite[J].Microporous and Mesoporous Materials,2009,119(1-3):276-283.
[38]oruh S,Elevli S.Optimization of malachite green dye removal by sepiolite clay using a central composite design[J].Global Nest Journal,2014,16(2):339-347.
[39]Murathan A,Ahmet B,Ahmet A,et al.Effects of various parameters on removal of NO2 gases in fixed beds by adsorption on sepiolite[J].Water,Air,and Soil Pollution,2001,132(3):365-372.
[40]Delgado J A,Uguina M A,Sotelo J.Carbon dioxide/methane separation by adsorption on sepiolite[J].Journal of Natural Gas Chemistry,2007,16(3):235-243.