食品中痕量汞的检测方法研究进展
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摘要
近年来,食品安全问题逐渐得到关注,众多食品安全事件也引发了消费者的信任危机。汞作为重金属元素当中的一种,对人类以及植物具有相当大的毒害作用,对给人类的健康带来极大危害。本文对食品样品汞检测前处理方法及汞的检测技术进行了综述,以期为相关人员在汞检测方法的选择方面提供参考。
In recent years, food safety issues have gradually gained attention, and many food safety incidents have also triggered consumer confidence crisis. As one of the heavy metal elements, mercury has a considerable toxic effect on humans and plants, and it is extremely harmful to human health. This paper reviewed the pretreatment methods of food samples and the detection techniques of mercury, in order to provide references for relevant personnel in the selection of mercury detection methods.
In recent years, food safety issues have gradually gained attention, and many food safety incidents have also triggered consumer confidence crisis. As one of the heavy metal elements, mercury has a considerable toxic effect on humans and plants, and it is extremely harmful to human health. This paper reviewed the pretreatment methods of food samples and the detection techniques of mercury, in order to provide references for relevant personnel in the selection of mercury detection methods.
引文
[1]Ullrich SM,Tanton TW,Abdrashitova SA.Mercury in the aquatic environment:A review of factors affecting methylation[J].Crit Rev Environ Sci Technol,2001,(31):241-293.
[2]袁倬斌,朱敏.汞的形态分析研究进展[J].岩矿测试,1999,20(2):150-156.Li BB,Zhu M.Progress in the study of the morphological analysis of mercury[J].Rock Ore Test,1999,20(2):150-156.
[3]王孝文,郭晏强,宋秋坤.蔬菜汞污染检测结果分析[J].微量元素与健康研究,2013,30(1):44-45.Wang XW,Guo YQ,Song QK.Analysis of mercury pollution in vegetables[J].Stud Trac Element Health,2013,30(1):44-45.
[4]彭国俊.采用高效液相色谱-电感耦合等离子体质谱联用技术同时检测超痕量铅和汞形态[D].宁波:宁波大学,2015.Peng GJ.High performance liquid chromatography(HPLC)and inductively coupled plasma mass spectrometry(ICP-MS)were used to simultaneously detect ultratrace lead and mercury speciation[D].Ningbo:University of Ningbo,2015.
[5]王振旭,程海芳,赵芳,等.食品中汞含量测定方法的优化研究[J].食品研究与开发,2018,(6):35-37.Wang ZX,Cheng HF,Zhao F,et al.Study on optimization of method for determination of mercury in food[J].Food Res Dev,2018,(6):35-37.
[6]万双秀,王俊东.汞对人体神经的毒性及其危害[J].微量元素与健康研究,2005,22(2):67-69.Wan SX,Wang JD.Toxicity of mercury to human nerves and its harm[J].Stud Trac Element Health,2005,22(2):67-69.
[7]孙淑兰.汞的来源、特性、用途及对环境的污染和对人类健康的危害[J].上海计量测试,2006,(5):6-9.Sun SL.Sources,characteristics,uses,pollution of the Environment and harm to Human Health of Mercury[J].Shanghai Metrol Test,2006,(5):6-9.
[8]臧琳,姜登东.汞对人体的危害及其预防[J].中国个体防护装备,1999,5(1):36-37.Zang L,Jiang DD.The harm of mercury to human body and its prevention[J].China's Person Protect Equip,1999,5(1):36-37.
[9]Hight SC,Cheng J.Determination of total mercury in seafood by cold vapor-atomic absorption spectroscopy(CVAAS)after microwave decomposition[J].Food Chem,2005,91(3):557-570.
[10]宋跃群.浅析环评中重金属第一类污染物源强计算--以电镀企业为例[J].环境科学与管理,2013,38(2):177-180.Song YQ.A brief Analysis on the calculation of the Source strength of the first kind of heavy metals pollutant in EIA:take the electroplating enterprise as an example[J].Environ Sci Manag,2013,38(2):177-180.
[11]Llop S,Ibarlucea J,Sunyer J,et al.Current dietary exposure to mercury during pregnancy and childhood,and public health recommendations[J].Gaceta Sanitaria,2013,27(3):273-278.
[12]邱会东,赵波,张红,等.食用植物油中重金属分析方法的研究进展[J].中国油脂,2017,42(1):76-79.Qiu HD,Zhao B,Zhang H,et al.Advances in the analysis of heavy metals in edible vegetable oil[J].Chin Oil,2017,42(1):76-79.
[13]Yin Y,Chen M,Peng J,et al.Dithizone-functionalized solid phase extraction-displacement elution-high performance liquid chromatographyinductively coupled plasma mass spectrometry for mercury speciation in water samples[J].Talanta,2010,81(4):1788-1792.
[14]唐晓萍,孙晓光,刘阳,等.汞的检测方法及纺织品中汞含量的测定研究进展[J].纺织导报,2013,(11):80-82.Tang XP,Sun XG,Liu Y,et al.Methods for determination of mercury and determination of mercury in textiles[J].Text Guid,2013,(11):80-82.
[15]Tsoi YK,Tam S,Leung KSY.Rapid speciation of methylated and ethylated mercury in urine using headspace solid phase microextraction coupled to LC-ICP-MS[J].J Anal Atom Spectr,2010,(1):35-46.
[16]高勇,马东升,白月,等.微波消解测定食品中Pb、As等金属元素方法的研究[J].检验检疫学刊,2005,15(5):13-15.Gao Y,Ma DS,Bai Y,et al.Study on microwave digestion method for determination of Pb,As and other metal elements in food[J].J Inspect Quarant,2005,15(5):13-15.
[17]Munoz J,Gallego M,Valcárcel M.Speciation analysis of mercury and tin compounds in water and sediments by gas chromatography-mass spectrometry following pre-concentration on C60 fullerene[J].Anal Chimica Acta,2005,548(1):66-72.
[18]刘丽萍,张妮娜,李筱薇,等.直接测汞仪测定食品中的总汞[J].中国食品卫生杂志,2010,22(1):19-23.Liu LP,Zhang NN,Li XW,et al.Determination of total mercury in food by direct mercury analyzer[J].Chin J Food Hyg,2010,22(1):2319-2323.
[19]Pérez-Sirvent C,Martínez-Sánchez MJ,García-Lorenzo M,et al.Instrumental modification intended to save time,and volumes of sample and reagent solutions,in the atomic fluorescence spectrometric determination of mercury[J].Anal Bioanal Chem,2007,388(2):495-498.
[20]刘志江,金文英,党明岩,等.气相色谱-质谱联用技术在砷、硒、汞和铅形态分析中的应用[J].冶金分析,2011,31(6):34-42.Liu ZJ,Jin WY,Dang MY,et al.Application of gas chromatography-mass spectrometry in speciation analysis of arsenic,selenium,mercury and lead[J].Metallurg Anal,2011,31(6):34-42.
[21]李吉龙,李姗,何霜,等.测汞仪/高效液相色谱-电感耦合等离子体质谱联用法测定鱼松中总汞和甲基汞的含量[J].食品安全质量检测学报,2017,8(1):82-87.Li JL,Li Shan,he H,et al.Determination of total mercury and methylmercury in Pine by HPLC/ICP-MS[J].J Food Safety Qual,2017,8(1):82-87.
[22]Vieira MA,Ribeiro AS,Curtius AJ,et al.Determination of total mercury and methylmercury in biological samples by photochemical vapor generation[J].Anal Bioanal Chem,2007,388(4):837-847.
[23]Vihas P,Pardo-Martínez M,López-García I,et al.Rapid determination of mercury in food colorants using electrother-mal atomic absorption spectrometry with slurry sample introduction[J].J Agric Food Chem,2002,50(5):949-954
[24]覃柳,刘仲明,邹小勇.电化学生物传感器研究进展[J].中国医学物理学杂志,2007,24(1):60-62.Qin L,Liu ZM,Zou XY.Advances in electrochemical biosensors[J].Chin J Med Phys,2007,24(1):60-62.
[25]Jiang H,Hu B,Jiang Z,et al.Microcolumn packed with YPA 4 chelating resin on-line separation/preconcentration combined with graphite furnace atomic absorption spectrometry using Pd as a permanent modifier for the determination of trace mercury in water samples[J].Talanta,2006,70(1):7-13.
[26]Jin HK,Su JL,Su YK,et al.Association of food consumption during pregnancy with mercury and lead levels in cord blood[J].Sci Total Environ,2016,82(4):118-124.
[27]闫珂,刘亚芹,魏福祥.食品中重金属铅、镉电化学检测的前处理技术[J].河北科技大学学报,2015,36(2):170-175.Yan K,Liu YQ,Wei FX.Pretreatment technique for electrochemical determination of heavy metals lead and cadmium in food[J].J Hebei Univ Sci Technol,2015,36(2):170-175.
[28]Coufalík P,Zvě?ina O,Komárek J.Determination of mercury species using thermal desorption analysis in AAS[J].Chem Paper,2014,68(4):427-434.
[29]李萍,吕任一,肖丽恒,等.测汞仪原子吸收光谱法测定野生食用菌中的总汞[J].食品安全质量检测学报,2015,(1):328-333.Li P,Lu Y,Xiao LH,et al.Determination of total mercury in wild edible fungi by atomic absorption spectrometry[J].J Food Saf Qual,2015,(1):328-333.
[30]Zhu X,Alexandratos SD.Determination of trace levels of mercury in aqueous solutions by inductively coupled plasma atomic emission spectrometry:elimination of the‘memory effect[J].Microchem J,2007,86(1):37-41.
[31]卑占宇,黄志勤,丁冶春,等.火焰原子吸收光谱法对伸筋草中金属元素含量的测定分析[J].广东微量元素科学,2007,14(1):37-39.Bei ZY,Huang ZQ,Ding YC,et al.Determination of metal elements in herba sagitta by flame atomic absorption spectrometry[J].Guangdong Microelement Sci,2007,14(1):37-39.
[32]Yang J,Wang ZT,Yang DJ.Advances in the determination of total mercury in food[J].Chin J Food Hyg,2008,20(4):346-351.
[33]Anonymous.Quality Control and data Standardization of isotope ratio mass spectrometry for isotope isotopes of low mass number elements online[J].Rock Miner Test,2014,33(4):453-467.
[34]石元值,马立锋,韩文炎,等.第四讲:茶叶中重金属元素的原子发射光谱测定法[J].中国茶叶,2008,30(3):7-9.Shi YZ,Ma LF,Han WY,et al.Chapter 4:atomic emission spectrometry for the determination of heavy metals in tea[J].Chin Tea,2008,30(3):7-9.
[35]Paul MC,Toia RF,von Nagy-Felsobuki EI.A novel method for the determination of mercury and selenium in shark tissue using high-resolution inductively coupled plasma-mass spectrometry[J].Spectrochim Acta B,2003,58(9):1687-1697.
[36]Zhang J,Lu BK,Ma JY,et al.A new method for orbit determination:Unit vector method[J].Sci Chin Series G,2009,52(7):1115-1119.
[37]王征,游飞明,邱秀玉,等.HPLC-ICP-MS法测定水样中的甲基汞、乙基汞和无机汞[J].福建分析测试,2009,18(1):28-31.Wang Z,You FM,Qiu XY,et al.Determination of methylmercury,ethyl mercury and inorganic mercury in water by HPLC-ICP-MS[J].Fujian Anal Test,2009,18(1):28-31.
[38]Teránbaamonde J,Bouchet S,Tessier E,et al.Development of a large volume injection method using a programmed temperature vaporization injector-gas chromatography hyphenated to ICP-MS for the simultaneous determination of mercury,tin and lead species at ultra-trace levels in natural waters[J].J Chromatogr A,2018,(1547):77-85.
[39]盛健.原子荧光光谱法测定汞的方法探讨[J].化学工程与装备,2011,(3):157-158.Sheng J.Determination of mercury by atomic fluorescence spectrometry[J].Chem Eng Equip,2011,(3):157-158.
[40]Yan H,Feng X,Li Z,et al.A methodological development in measuring total mercury in fish using semi-closed digestion and CVAFS[J].Geol Geochem,2005,33(1):89-92.
[41]Pitt JJ.Principles and applications of liquid chromatography-mass spectrometry in clinical biochemistry[J].Clin Biochem Rev,2009,30(1):19-34.
[42]Marcinkowska M,Baralkiewicz D.Multielemental speciation analysis by advanced hyphenated technique-HPLC/ICP-MS:A review[J].Talanta,2016,(161):177-204.
[43]Jagtap R,Maher W.Measurement of mercury species in sediments and soils by HPLC-ICPMS microchem[J].2015,(121):65-98.
[44]刘丽萍,张妮娜,李筱薇,等.直接测汞仪测定食品中的总汞[J].中国食品卫生杂志,2010,22(1):19-23.Liu LP,Zhang NN,Li XW,et al.Determination of total mercury in food by direct mercury analyzer[J].Chin J Food Hyg,2010,22(1):19-23.
[45]Rodrigues JL,Alvarez CR,Farias NR,et al.Mercury speciation in whole blood by gas chromatography coupled to ICP-MS with a fast microwave-assisted sample preparation procedure[J].J Anal Atomic Spectrom,2011,26(2):436-442.
[46]朱国英.AFS-3100型原子荧光光谱仪测定食品中汞含量[J].现代农业科技,2012,(13):298.Zhu GY.Determination of mercury in food by afs-3100 atomic fluorescence spectrometer[J].Mod Agric Sci Technol,2012,(13):298.
[47]Cloarec S,Deschênes G,Sagnier M,et al.Arterial hypertension due to mercury poisoning:diagnostic value of captopril[J].Arch de Pédiatrie,1995,2(1):72-77
[48]刘垚,赵喜红,谭贵良,等.微波消解-ICP-MS同时检测茶叶中的铅、砷、镉、铬、汞和16种稀土元素[J].安徽农业科学,2014,(20):6793-6795.Liu Y,Zhao XH,Tan GL,et al.Microwave digestion-ICP-MSsimultaneous determination of lead,arsenic,cadmium,chromium,mercury and 16 rare earth elements in tea[J].Anhui Agric Sci,2014,(20):6793-6795.
[49]陈岩,刘永涛,赵晓丽,等.HPLC-ICP-MS联用技术测定水产品中的汞形态[J].食品研究与开发,2016,37(23):129-133.Chen Y,Liu YT,Zhao XL,et al.Determination of Mercury speciation in Aquatic products by HPLC-ICP-MS[J].Food Res Dev,2016,37(23):129-133.
[50]程晓宏,谢超,魏要武,等.胶体金-DNA体系法测定食品中汞离子[J].环境与职业医学,2013,30(10):800-801.Cheng XH,Xie C,Wei YW,et al.Determination of mercury ion in food by colloidal Gold-DNA system[J].Environ Occup Med,2013,30(10):800-801.
[2]袁倬斌,朱敏.汞的形态分析研究进展[J].岩矿测试,1999,20(2):150-156.Li BB,Zhu M.Progress in the study of the morphological analysis of mercury[J].Rock Ore Test,1999,20(2):150-156.
[3]王孝文,郭晏强,宋秋坤.蔬菜汞污染检测结果分析[J].微量元素与健康研究,2013,30(1):44-45.Wang XW,Guo YQ,Song QK.Analysis of mercury pollution in vegetables[J].Stud Trac Element Health,2013,30(1):44-45.
[4]彭国俊.采用高效液相色谱-电感耦合等离子体质谱联用技术同时检测超痕量铅和汞形态[D].宁波:宁波大学,2015.Peng GJ.High performance liquid chromatography(HPLC)and inductively coupled plasma mass spectrometry(ICP-MS)were used to simultaneously detect ultratrace lead and mercury speciation[D].Ningbo:University of Ningbo,2015.
[5]王振旭,程海芳,赵芳,等.食品中汞含量测定方法的优化研究[J].食品研究与开发,2018,(6):35-37.Wang ZX,Cheng HF,Zhao F,et al.Study on optimization of method for determination of mercury in food[J].Food Res Dev,2018,(6):35-37.
[6]万双秀,王俊东.汞对人体神经的毒性及其危害[J].微量元素与健康研究,2005,22(2):67-69.Wan SX,Wang JD.Toxicity of mercury to human nerves and its harm[J].Stud Trac Element Health,2005,22(2):67-69.
[7]孙淑兰.汞的来源、特性、用途及对环境的污染和对人类健康的危害[J].上海计量测试,2006,(5):6-9.Sun SL.Sources,characteristics,uses,pollution of the Environment and harm to Human Health of Mercury[J].Shanghai Metrol Test,2006,(5):6-9.
[8]臧琳,姜登东.汞对人体的危害及其预防[J].中国个体防护装备,1999,5(1):36-37.Zang L,Jiang DD.The harm of mercury to human body and its prevention[J].China's Person Protect Equip,1999,5(1):36-37.
[9]Hight SC,Cheng J.Determination of total mercury in seafood by cold vapor-atomic absorption spectroscopy(CVAAS)after microwave decomposition[J].Food Chem,2005,91(3):557-570.
[10]宋跃群.浅析环评中重金属第一类污染物源强计算--以电镀企业为例[J].环境科学与管理,2013,38(2):177-180.Song YQ.A brief Analysis on the calculation of the Source strength of the first kind of heavy metals pollutant in EIA:take the electroplating enterprise as an example[J].Environ Sci Manag,2013,38(2):177-180.
[11]Llop S,Ibarlucea J,Sunyer J,et al.Current dietary exposure to mercury during pregnancy and childhood,and public health recommendations[J].Gaceta Sanitaria,2013,27(3):273-278.
[12]邱会东,赵波,张红,等.食用植物油中重金属分析方法的研究进展[J].中国油脂,2017,42(1):76-79.Qiu HD,Zhao B,Zhang H,et al.Advances in the analysis of heavy metals in edible vegetable oil[J].Chin Oil,2017,42(1):76-79.
[13]Yin Y,Chen M,Peng J,et al.Dithizone-functionalized solid phase extraction-displacement elution-high performance liquid chromatographyinductively coupled plasma mass spectrometry for mercury speciation in water samples[J].Talanta,2010,81(4):1788-1792.
[14]唐晓萍,孙晓光,刘阳,等.汞的检测方法及纺织品中汞含量的测定研究进展[J].纺织导报,2013,(11):80-82.Tang XP,Sun XG,Liu Y,et al.Methods for determination of mercury and determination of mercury in textiles[J].Text Guid,2013,(11):80-82.
[15]Tsoi YK,Tam S,Leung KSY.Rapid speciation of methylated and ethylated mercury in urine using headspace solid phase microextraction coupled to LC-ICP-MS[J].J Anal Atom Spectr,2010,(1):35-46.
[16]高勇,马东升,白月,等.微波消解测定食品中Pb、As等金属元素方法的研究[J].检验检疫学刊,2005,15(5):13-15.Gao Y,Ma DS,Bai Y,et al.Study on microwave digestion method for determination of Pb,As and other metal elements in food[J].J Inspect Quarant,2005,15(5):13-15.
[17]Munoz J,Gallego M,Valcárcel M.Speciation analysis of mercury and tin compounds in water and sediments by gas chromatography-mass spectrometry following pre-concentration on C60 fullerene[J].Anal Chimica Acta,2005,548(1):66-72.
[18]刘丽萍,张妮娜,李筱薇,等.直接测汞仪测定食品中的总汞[J].中国食品卫生杂志,2010,22(1):19-23.Liu LP,Zhang NN,Li XW,et al.Determination of total mercury in food by direct mercury analyzer[J].Chin J Food Hyg,2010,22(1):2319-2323.
[19]Pérez-Sirvent C,Martínez-Sánchez MJ,García-Lorenzo M,et al.Instrumental modification intended to save time,and volumes of sample and reagent solutions,in the atomic fluorescence spectrometric determination of mercury[J].Anal Bioanal Chem,2007,388(2):495-498.
[20]刘志江,金文英,党明岩,等.气相色谱-质谱联用技术在砷、硒、汞和铅形态分析中的应用[J].冶金分析,2011,31(6):34-42.Liu ZJ,Jin WY,Dang MY,et al.Application of gas chromatography-mass spectrometry in speciation analysis of arsenic,selenium,mercury and lead[J].Metallurg Anal,2011,31(6):34-42.
[21]李吉龙,李姗,何霜,等.测汞仪/高效液相色谱-电感耦合等离子体质谱联用法测定鱼松中总汞和甲基汞的含量[J].食品安全质量检测学报,2017,8(1):82-87.Li JL,Li Shan,he H,et al.Determination of total mercury and methylmercury in Pine by HPLC/ICP-MS[J].J Food Safety Qual,2017,8(1):82-87.
[22]Vieira MA,Ribeiro AS,Curtius AJ,et al.Determination of total mercury and methylmercury in biological samples by photochemical vapor generation[J].Anal Bioanal Chem,2007,388(4):837-847.
[23]Vihas P,Pardo-Martínez M,López-García I,et al.Rapid determination of mercury in food colorants using electrother-mal atomic absorption spectrometry with slurry sample introduction[J].J Agric Food Chem,2002,50(5):949-954
[24]覃柳,刘仲明,邹小勇.电化学生物传感器研究进展[J].中国医学物理学杂志,2007,24(1):60-62.Qin L,Liu ZM,Zou XY.Advances in electrochemical biosensors[J].Chin J Med Phys,2007,24(1):60-62.
[25]Jiang H,Hu B,Jiang Z,et al.Microcolumn packed with YPA 4 chelating resin on-line separation/preconcentration combined with graphite furnace atomic absorption spectrometry using Pd as a permanent modifier for the determination of trace mercury in water samples[J].Talanta,2006,70(1):7-13.
[26]Jin HK,Su JL,Su YK,et al.Association of food consumption during pregnancy with mercury and lead levels in cord blood[J].Sci Total Environ,2016,82(4):118-124.
[27]闫珂,刘亚芹,魏福祥.食品中重金属铅、镉电化学检测的前处理技术[J].河北科技大学学报,2015,36(2):170-175.Yan K,Liu YQ,Wei FX.Pretreatment technique for electrochemical determination of heavy metals lead and cadmium in food[J].J Hebei Univ Sci Technol,2015,36(2):170-175.
[28]Coufalík P,Zvě?ina O,Komárek J.Determination of mercury species using thermal desorption analysis in AAS[J].Chem Paper,2014,68(4):427-434.
[29]李萍,吕任一,肖丽恒,等.测汞仪原子吸收光谱法测定野生食用菌中的总汞[J].食品安全质量检测学报,2015,(1):328-333.Li P,Lu Y,Xiao LH,et al.Determination of total mercury in wild edible fungi by atomic absorption spectrometry[J].J Food Saf Qual,2015,(1):328-333.
[30]Zhu X,Alexandratos SD.Determination of trace levels of mercury in aqueous solutions by inductively coupled plasma atomic emission spectrometry:elimination of the‘memory effect[J].Microchem J,2007,86(1):37-41.
[31]卑占宇,黄志勤,丁冶春,等.火焰原子吸收光谱法对伸筋草中金属元素含量的测定分析[J].广东微量元素科学,2007,14(1):37-39.Bei ZY,Huang ZQ,Ding YC,et al.Determination of metal elements in herba sagitta by flame atomic absorption spectrometry[J].Guangdong Microelement Sci,2007,14(1):37-39.
[32]Yang J,Wang ZT,Yang DJ.Advances in the determination of total mercury in food[J].Chin J Food Hyg,2008,20(4):346-351.
[33]Anonymous.Quality Control and data Standardization of isotope ratio mass spectrometry for isotope isotopes of low mass number elements online[J].Rock Miner Test,2014,33(4):453-467.
[34]石元值,马立锋,韩文炎,等.第四讲:茶叶中重金属元素的原子发射光谱测定法[J].中国茶叶,2008,30(3):7-9.Shi YZ,Ma LF,Han WY,et al.Chapter 4:atomic emission spectrometry for the determination of heavy metals in tea[J].Chin Tea,2008,30(3):7-9.
[35]Paul MC,Toia RF,von Nagy-Felsobuki EI.A novel method for the determination of mercury and selenium in shark tissue using high-resolution inductively coupled plasma-mass spectrometry[J].Spectrochim Acta B,2003,58(9):1687-1697.
[36]Zhang J,Lu BK,Ma JY,et al.A new method for orbit determination:Unit vector method[J].Sci Chin Series G,2009,52(7):1115-1119.
[37]王征,游飞明,邱秀玉,等.HPLC-ICP-MS法测定水样中的甲基汞、乙基汞和无机汞[J].福建分析测试,2009,18(1):28-31.Wang Z,You FM,Qiu XY,et al.Determination of methylmercury,ethyl mercury and inorganic mercury in water by HPLC-ICP-MS[J].Fujian Anal Test,2009,18(1):28-31.
[38]Teránbaamonde J,Bouchet S,Tessier E,et al.Development of a large volume injection method using a programmed temperature vaporization injector-gas chromatography hyphenated to ICP-MS for the simultaneous determination of mercury,tin and lead species at ultra-trace levels in natural waters[J].J Chromatogr A,2018,(1547):77-85.
[39]盛健.原子荧光光谱法测定汞的方法探讨[J].化学工程与装备,2011,(3):157-158.Sheng J.Determination of mercury by atomic fluorescence spectrometry[J].Chem Eng Equip,2011,(3):157-158.
[40]Yan H,Feng X,Li Z,et al.A methodological development in measuring total mercury in fish using semi-closed digestion and CVAFS[J].Geol Geochem,2005,33(1):89-92.
[41]Pitt JJ.Principles and applications of liquid chromatography-mass spectrometry in clinical biochemistry[J].Clin Biochem Rev,2009,30(1):19-34.
[42]Marcinkowska M,Baralkiewicz D.Multielemental speciation analysis by advanced hyphenated technique-HPLC/ICP-MS:A review[J].Talanta,2016,(161):177-204.
[43]Jagtap R,Maher W.Measurement of mercury species in sediments and soils by HPLC-ICPMS microchem[J].2015,(121):65-98.
[44]刘丽萍,张妮娜,李筱薇,等.直接测汞仪测定食品中的总汞[J].中国食品卫生杂志,2010,22(1):19-23.Liu LP,Zhang NN,Li XW,et al.Determination of total mercury in food by direct mercury analyzer[J].Chin J Food Hyg,2010,22(1):19-23.
[45]Rodrigues JL,Alvarez CR,Farias NR,et al.Mercury speciation in whole blood by gas chromatography coupled to ICP-MS with a fast microwave-assisted sample preparation procedure[J].J Anal Atomic Spectrom,2011,26(2):436-442.
[46]朱国英.AFS-3100型原子荧光光谱仪测定食品中汞含量[J].现代农业科技,2012,(13):298.Zhu GY.Determination of mercury in food by afs-3100 atomic fluorescence spectrometer[J].Mod Agric Sci Technol,2012,(13):298.
[47]Cloarec S,Deschênes G,Sagnier M,et al.Arterial hypertension due to mercury poisoning:diagnostic value of captopril[J].Arch de Pédiatrie,1995,2(1):72-77
[48]刘垚,赵喜红,谭贵良,等.微波消解-ICP-MS同时检测茶叶中的铅、砷、镉、铬、汞和16种稀土元素[J].安徽农业科学,2014,(20):6793-6795.Liu Y,Zhao XH,Tan GL,et al.Microwave digestion-ICP-MSsimultaneous determination of lead,arsenic,cadmium,chromium,mercury and 16 rare earth elements in tea[J].Anhui Agric Sci,2014,(20):6793-6795.
[49]陈岩,刘永涛,赵晓丽,等.HPLC-ICP-MS联用技术测定水产品中的汞形态[J].食品研究与开发,2016,37(23):129-133.Chen Y,Liu YT,Zhao XL,et al.Determination of Mercury speciation in Aquatic products by HPLC-ICP-MS[J].Food Res Dev,2016,37(23):129-133.
[50]程晓宏,谢超,魏要武,等.胶体金-DNA体系法测定食品中汞离子[J].环境与职业医学,2013,30(10):800-801.Cheng XH,Xie C,Wei YW,et al.Determination of mercury ion in food by colloidal Gold-DNA system[J].Environ Occup Med,2013,30(10):800-801.