添加型阻燃聚氨酯泡沫的研究进展
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摘要
综述了近年来国内外对添加型阻燃聚氨酯泡沫的研究进展;介绍了添加型阻燃剂的分类、特点和阻燃剂阻燃作用的机理,并对聚氨酯泡沫用阻燃剂的发展方向进行了展望。
The recent development trend of additive flame retardant polyurethane foam was reviewed. The classification and characteristics of the additive type flame retardant were introduced. The mechanism of the flame retardant was discussed. The development trend of halogen-free and additive flame retardents in polyurethane was pointed out.
The recent development trend of additive flame retardant polyurethane foam was reviewed. The classification and characteristics of the additive type flame retardant were introduced. The mechanism of the flame retardant was discussed. The development trend of halogen-free and additive flame retardents in polyurethane was pointed out.
引文
[1]李兆星,段燕芳,刘小会.阻燃聚合物聚醚多元醇的合成及其阻燃性能的研究[J].聚氨酯工业,2011,26(4):21-24.
[2]王建琪.无卤阻燃聚合物基础与应用[M].北京:科学出版社,2005:1-3.
[3]王紫潇,文庆珍,朱金华.用于聚氨酯材料的无卤添加型阻燃剂研究进展[J].聚氨酯工业,2015,30(3):31-34.
[4]陈佳蕾,陈华,应雷,等.聚氨酯泡沫用反应型阻燃剂的发展现状[J].聚氨酯工业,2014,29(6):1-4.
[5]李博.添加型阻燃剂对聚氨酯泡沫燃烧性能的影响[J].消防科学与技术,2014,33(9):1055-1058.
[6]KABISCH B,FEHRENBACHER U,KROKE E.Hexa methoxy cyclo triphosphazene as a flame retardant for polyurethane foams[J].Fire and Material,2014,308(4):462-473.
[7]KNIG A,KROKE E.Methyl-DOPO—a new flame retardant for flexible polyurethane foam[J].Adv Technol,2010,22(1):5-13.
[8]WU Denghui,ZHAO Peihua,LIU Yaqing,et al.Halogen free flame retardant rigid polyurethane foam with a novel phosphorus nitrogen intumescent flame retardant[J].J Appl Polym Sci,2014,131(11):1-7.
[9]张立强,张猛,周永红,等.阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究[J].中国塑料,2014,27(11):84-88.
[10]马蕊英,赵亮,王海洋,等.微胶囊红磷的制备及其在聚氨酯硬泡中的阻燃应用[J].石油化工,2013,42(9):1014-1018.
[11]杨旭峰,曹阳,张伟伟,等.次磷酸铝阻燃剂的合成及应用[J].精细化工,2014,51(1):99-102.
[12]CUI Yao,LIU Xiaoli,TIAN Yumei.Controllable synthesis of three kinds of zinc borates and flame retardant properties in polyurethane foam[J].Physicochemical and Engineering Aspects,2012,414:274-280.
[13]周云,祝社民,陶亚秋.NH4H2PO4/三聚氰胺阻燃硬质聚氨酯泡沫的性能研究[J].聚氨酯工业,2012,27(4):20-22.
[14]许东梅.可膨胀石墨填充硬质聚氨酯泡沫塑料的阻燃抑烟研究[D].北京:北京理工大学,2014.
[15]陶亚秋,周云,祝社民.无卤添加型阻燃剂对硬质聚氨酯泡沫阻燃性能研究[J].化工新型材料,2012,40(8):123-125.
[16]梁克瑞.铝/磷/氮三元体系阻燃PU硬泡的制备与性能研究[J].聚氨酯工业,2013,28(4),41-43.
[17]THIRUMAL M,KHASTGIR D,SINGHA N K,et al.Effect of expandable graphite on the properties of intumescent flame-retardant polyurethane foam[J].Journal of Applied Polymer Science,2008,110(5):2586-2594.
[18]陈涛,胡爽,林倬仕,等.纳米金属氧化物对聚氨酯硬泡阻燃性能的影响[J].聚氨酯工业,2015,30(1):18-21.
[19]李毅,王道亮,邹华维,等.可膨胀石墨阻燃半硬质聚氨酯缓冲泡沫研究[J].载人航天,2015,21(4):351-354.
[20]梁克瑞.铝/磷/氮三元体系阻燃PU硬泡的制备与性能研究[J].聚氨酯工业,2013,28(4):41-43.
[21]徐平选,杨建军,张建安,等.无卤阻燃聚氨酯泡沫技术的研究进展[J].聚氨酯工业,2014,29(4):1-5.
[22]XU Wenzong,LIU Liang,WANG Shaoqing,et al.Synergistic effect of expandable graphite and aluminum hypophosphite on flame-retardant properties of rigid polyurethane foam[J].J Appl Polym Sci,2015,132(47),DOI:10.1002/app.42842.
[23]张腊,米金英.EG/MRP/DMMP协同阻燃硬质聚氨酯泡沫塑料的性能研究[J].山西煤炭管理干部学院学报,2015,28(2):177-179.
[24]XU Wei,WANG Guojian,ZHENG Xiaorui.Research on highly flame-retardant rigid PU foams by combination of nanostructured additives and phosphorus flame retardants[J].Polymer Degradation and Stability,2015,111:142-150.
[25]张志毅,孙付宇,刘亚青.新型磷-氮膨胀阻燃剂的合成及其在硬质聚氨酯泡沫中的应用[J].合成化学,2014,22(1):20-23.
[26]董信,王彦林,李果.阻燃剂乙二氧撑双硅酸二氯异丙酯的合成及应用研究[J].工程塑料应用,2014,42(7):104-108.
[2]王建琪.无卤阻燃聚合物基础与应用[M].北京:科学出版社,2005:1-3.
[3]王紫潇,文庆珍,朱金华.用于聚氨酯材料的无卤添加型阻燃剂研究进展[J].聚氨酯工业,2015,30(3):31-34.
[4]陈佳蕾,陈华,应雷,等.聚氨酯泡沫用反应型阻燃剂的发展现状[J].聚氨酯工业,2014,29(6):1-4.
[5]李博.添加型阻燃剂对聚氨酯泡沫燃烧性能的影响[J].消防科学与技术,2014,33(9):1055-1058.
[6]KABISCH B,FEHRENBACHER U,KROKE E.Hexa methoxy cyclo triphosphazene as a flame retardant for polyurethane foams[J].Fire and Material,2014,308(4):462-473.
[7]KNIG A,KROKE E.Methyl-DOPO—a new flame retardant for flexible polyurethane foam[J].Adv Technol,2010,22(1):5-13.
[8]WU Denghui,ZHAO Peihua,LIU Yaqing,et al.Halogen free flame retardant rigid polyurethane foam with a novel phosphorus nitrogen intumescent flame retardant[J].J Appl Polym Sci,2014,131(11):1-7.
[9]张立强,张猛,周永红,等.阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究[J].中国塑料,2014,27(11):84-88.
[10]马蕊英,赵亮,王海洋,等.微胶囊红磷的制备及其在聚氨酯硬泡中的阻燃应用[J].石油化工,2013,42(9):1014-1018.
[11]杨旭峰,曹阳,张伟伟,等.次磷酸铝阻燃剂的合成及应用[J].精细化工,2014,51(1):99-102.
[12]CUI Yao,LIU Xiaoli,TIAN Yumei.Controllable synthesis of three kinds of zinc borates and flame retardant properties in polyurethane foam[J].Physicochemical and Engineering Aspects,2012,414:274-280.
[13]周云,祝社民,陶亚秋.NH4H2PO4/三聚氰胺阻燃硬质聚氨酯泡沫的性能研究[J].聚氨酯工业,2012,27(4):20-22.
[14]许东梅.可膨胀石墨填充硬质聚氨酯泡沫塑料的阻燃抑烟研究[D].北京:北京理工大学,2014.
[15]陶亚秋,周云,祝社民.无卤添加型阻燃剂对硬质聚氨酯泡沫阻燃性能研究[J].化工新型材料,2012,40(8):123-125.
[16]梁克瑞.铝/磷/氮三元体系阻燃PU硬泡的制备与性能研究[J].聚氨酯工业,2013,28(4),41-43.
[17]THIRUMAL M,KHASTGIR D,SINGHA N K,et al.Effect of expandable graphite on the properties of intumescent flame-retardant polyurethane foam[J].Journal of Applied Polymer Science,2008,110(5):2586-2594.
[18]陈涛,胡爽,林倬仕,等.纳米金属氧化物对聚氨酯硬泡阻燃性能的影响[J].聚氨酯工业,2015,30(1):18-21.
[19]李毅,王道亮,邹华维,等.可膨胀石墨阻燃半硬质聚氨酯缓冲泡沫研究[J].载人航天,2015,21(4):351-354.
[20]梁克瑞.铝/磷/氮三元体系阻燃PU硬泡的制备与性能研究[J].聚氨酯工业,2013,28(4):41-43.
[21]徐平选,杨建军,张建安,等.无卤阻燃聚氨酯泡沫技术的研究进展[J].聚氨酯工业,2014,29(4):1-5.
[22]XU Wenzong,LIU Liang,WANG Shaoqing,et al.Synergistic effect of expandable graphite and aluminum hypophosphite on flame-retardant properties of rigid polyurethane foam[J].J Appl Polym Sci,2015,132(47),DOI:10.1002/app.42842.
[23]张腊,米金英.EG/MRP/DMMP协同阻燃硬质聚氨酯泡沫塑料的性能研究[J].山西煤炭管理干部学院学报,2015,28(2):177-179.
[24]XU Wei,WANG Guojian,ZHENG Xiaorui.Research on highly flame-retardant rigid PU foams by combination of nanostructured additives and phosphorus flame retardants[J].Polymer Degradation and Stability,2015,111:142-150.
[25]张志毅,孙付宇,刘亚青.新型磷-氮膨胀阻燃剂的合成及其在硬质聚氨酯泡沫中的应用[J].合成化学,2014,22(1):20-23.
[26]董信,王彦林,李果.阻燃剂乙二氧撑双硅酸二氯异丙酯的合成及应用研究[J].工程塑料应用,2014,42(7):104-108.