紫外上转换发光材料在光催化中的应用研究进展
|
摘要
介绍了紫外上转换发光材料复合光催剂的实验研究现状,阐述了上转换发光材料的发光机理,讨论了制备工艺、基质、激活离子及其掺杂浓度、添加剂等对上转换材料发光性能的影响,并对该技术的研究方向、在光催化领域的应用前景做了展望。
The ultraviolet up-conversion luminous composited photocatalysis technology is introduced and the research progress is reviewed.The luminous mechanism of the up-conversion luminous is expounded.Those factors impact the properties of up-conversion such as preparation technology,base compounds,activating ions and its doping concentration,and the additive is discussed.The research direction of the technique and its application prospect are discussed.
The ultraviolet up-conversion luminous composited photocatalysis technology is introduced and the research progress is reviewed.The luminous mechanism of the up-conversion luminous is expounded.Those factors impact the properties of up-conversion such as preparation technology,base compounds,activating ions and its doping concentration,and the additive is discussed.The research direction of the technique and its application prospect are discussed.
引文
[1]Meng N,Michael K H L,Dennis Y C L,et al.A review and recent developments in photocatalytic water-splitting using TiO2for hydrogen production[J].Renewable and Sustainable Energy Reviews,2007,11(3):401-425.
[2]叶岩溪,刘恩周,胡晓云,等.高比表面积Y2O3:Er3++TiO2的制备及上转换发光特性研究[J].科学通报,2011,56(22):1797-1803.
[3]郑红艾,潘理黎.高级氧化技术在水处理中的研究进展[J].上海电力学院学报,2006,22(2):158-162.
[4]Mwabora J M,Lindgren T,Avendano E,et al.Structure,composition and morphology of photoelectronChemicallyactiveTiO2-xNx thin films deposited by reactive DC magnetron sputtering[J].Journal of Physical Chemistry B,2004,108(52):1797-1803.
[5]冯光建,刘素文,修志亮,等.可见光响应型TiO2光催化剂的机理研究进展[J].稀有金属材料与工程,2009,38(1):185-187.
[6]Lin Zhe-shuai,Orlov A,Lambert R M,et al.New insights into the origin of visible light photocatalytic activity of nitrogen-doped and oxygen-deficient anatase TiO2[J].Journal of Physical Chemistry B,2005,109(44):20948-20952.
[7]Subramanian V,Wolf E E,Kamat P V.Catalysis with TiO2/gold nanocomposites,effect of metal particle size on the Fermi level equilibration[J].Journal of American Chemical Society,2004.126(15):4943-4950.
[8]张强,田雨.TiO2光催化性能影响因素的研究进展[J].应用化工,2011,40(11):2022-2055.
[9]Corstjens Plam,Zuiderwijk M,Nilsson M,et al.Lateral-flow and up-converting to Phosphor reporters detect single-stranded nucleic acid s in a sandwich hybridization assay[J].Analytical Biochemistry,2003,312(2):191-200.
[10]Sandrock T,Scheife H,Heumann E.et al.High power continuous wave up-conversion fiber laser at room temperature[J].Optics Letters,1997,22:808.
[11]Zhao Y X,Simon F,Simon P.22mW blue output power from a Pr3+fluoride fibre up-conversion laser[J].Optics Communications,1995,114:285.
[12]Auzel F.Up conversion and Anti-Stokes Processes with f and d Ions in Solids[J].Chemical Reviews,2004,104(1):139-173.
[13]何捍卫,周科朝,熊翔,等.红外-可见光的上转换研究进展[J].中国稀土学报,2003,2(2):123-128.
[14]杨建虎,戴世勋,姜中宏.稀土离子的上转换发光及研究进展[J].物理学进展,2003,23(3):284-298.
[15]王君,温福宇,张朝红,等.上转换发光剂掺杂纳米TiO2的制备及可见光降解乙基紫的研究[J].环境科学,2006,27(6):1133-1139.
[16]何奇,樊君,胡晓云.NaYF4∶Er3+的水热合成及其紫外上转换发光性能[J].发光学报,2012,33(2):122-127.
[17]Chivian J S,Case W E,Eden D D.The photon avalanche:A new phenomenon in Pr-based infrared quatum counters[J].Appl Phys Lett,1979,35(2):124-126.
[18]Wan Wei,Huan Wenjuan,Ni Yaru,et al.Graphene supported NaYF4:Yb3+,Tm3+and N doped P25nanocomposite as an advanced NIR and sunlight driven up-conversion photocatalyst[J].Applied Surface Science,2013,282:832-837.
[19]王君,赵刚,张朝红,等.稀土上转光剂掺杂纳米TiO2催化可见光降解甲基紫[J].染料与染色,2006,43(6),40-44.
[20]Wang Jun,Weng Fuyu,Zhang Chaohong.et al.Efficient photocatalytic degradation of organic dyes over titanium dioxide coating up-conversion luminescence agent under visible and sunlight irradiation[J].Applied Catalysis A:General,2008,334:227-233.
[21]Wang Jun,Weng Fuyu,Zhang Chaohong.et al.Investigation on degradation of dyestuff wastewater using visible light in the presence of a novel nano TiO2catalyst doped with up-conversion luminescence agent.Journal of Photochemistry and Photobiology A:Chemistry,2006,180(1/2):189-195.
[22]许凤秀,冯光建,刘素文,等.可见光下上转换发光材料掺杂纳米TiO2光催化活性研究[J].硅酸盐通报,2008,27(6):1140-1145.
[23]臧竞存,李晓,谢丽艳.Er3+:Yb3+:Y3Al5O12单晶中Er3+离子光谱参数的计算[J].硅酸盐学报,2006,34(9):1037-1040.
[24]翟宇.Er3+:Y3Al5O12/TiO2复合膜的制备及可见光光催化活性的研究[D].沈阳:辽宁大学,2013:19-34.
[25]王健.Yb,N,F,B和Ga掺杂Er3+:Y3Al5O12对TiO2声催化活性影响的研究[D].沈阳:辽宁大学,2013:22-33.
[26]谢英鹏.Er3+:Y3Al5O12和Er3+:YAlO3对二氧化钛和氧化锌光催化活性影响的研究[D].沈阳:辽宁大学,2009:21-25.
[27]栾晓宇.Er3+:Y3Al5O12对半导体及复合物光催化活性影响的研究[D].沈阳:辽宁大学,2011:21-25.
[28]李堂刚,刘素文,王恩华,等.Y2O3:Yb3+,Tm3+纳米材料的可见及紫外上转换发光[J].物理学报,2011,60(7):073201-1-073206.
[29]高鹏,黄浪欢.TiO2包覆上转化发光材料Pr3+:Y2SiO5的制备及其可见光催化性能的研究[J].功能材料,2013,8(44):1-5.
[30]梁利芳,庄健乐,吴昊,等.水热合成六方相NaYbF4:Er3+/Tm3+的上转换白光性质[J].发光学报,2008,29(6):996-1002.
[31]李岳,翟海青,杨魁胜,等.水热法合成纳米晶NaYF4:Er3+,Tm3+,Yb3+的上转换发光特性[J].发光学报,2009,30(2):239-242.
[32]林君,苏锵.溶胶-凝胶法及其在稀土发光材料合成中的应用[J].1994,15(1):42-46.
[33]Vetrone F,Boyer J C,Capobianco J A,et al.Concentration-dependent near-infrared to visible up-conversion in nanocrystalline and bulk Y2O3:Er3+[J].Chemistry of Materials,2003,15(14):2737-2743.
[34]李玮楠,邹快盛,陆敏,等.掺Er3+硅酸盐玻璃上转换发光特性研究[J].无机材料学报,2007,22(1):30-34.
[35]Aleksandrovsky A S,Gudim L A,Krylov A S,et al.Upconversion luminescence of YA13(BO3)4:(Yb3+,Tm3+)crystals[J].Journal of Alloys and Compounds,2010,496:18-21.
[36]罗军明,李永绣,邓莉萍,等.共沉淀法制备Er3+:Y2O3上转换发光纳米粉[J].稀有金属材料与工程,2007,36(8):1436-1439.
[37]孙家跃,杨志萍,杜海燕.共沉淀法制备NaYF4:Tm3+,Yb3+的上转换发光[J].发光学报,2009,30(2):195-200.
[38]Suyver J F,Grimm J,Kramer K W,et al.Highly efficient near-infrared to visible up-conversion process in NaYF4:Er3+,Yb3+[J].Journal of Luminescence,2005,114(1):53-59.
[39]Liu M,Wang S W,Zhang J,et al.Upconversion luminescence of Y3Al5O12:Yb3+,Tm3+nano-crystals[J].Opt Lett,2007,30(7):370-374.
[40]Liu M,Wang S W,Zhang J,et al.Dominant red emission(4F9/2-4I15/2)via upconversion in YAG(Y3Al5O12):Yb3+,Er3+nanopowders[J].Opt Lett,2007,29(3):1352-1357.
[41]Sun Hongtao,Wen Lei,Duan Zhongchao.Intense frequency upconversion fluorescence emission of Er3+/Yb3+codoped oxychloride gemanate glass[J].Journal of Alloys and Compounds,2006,414(1):142-145.
[42]冯丽,吴银素.Ho3+/Yb3+和Er3+/Yb3+共掺氟氧化物玻璃的上转换发光[J].河北师范大学学报:自然科学版,2011,35(5):483-487.
[43]邓圣伟,徐铁峰,戴世勋,等.Er3+掺杂新型GeS2-In2S3-CsI玻璃上转换光谱性质研究[J].光子学报,2010,39(7):1163-1168.
[44]Shi Dongmei,Yang Gangfeng,Yang Zhongmin,et al.Spectral properties and energy transfer of Tm3+/Ho3+-codoped Ga2O3-Bi2O3-GeO2-PbO glasses[J].Journal of rare earths,2008,26(6):912-914.
[45]Kumar K,Rai S B,Rai D K.Up-conversion and concentration quenching in Er3+-doped TeO2-Na2 O binary glasses[J].NonCryst Solids,2007,353(13/14/15):1383-1387.
[46]郭海.稀土离子掺杂的纳米氧化物上转换发光与稀土氧化物功能薄膜研究[D].合肥:中国科学技术大学,2005.
[2]叶岩溪,刘恩周,胡晓云,等.高比表面积Y2O3:Er3++TiO2的制备及上转换发光特性研究[J].科学通报,2011,56(22):1797-1803.
[3]郑红艾,潘理黎.高级氧化技术在水处理中的研究进展[J].上海电力学院学报,2006,22(2):158-162.
[4]Mwabora J M,Lindgren T,Avendano E,et al.Structure,composition and morphology of photoelectronChemicallyactiveTiO2-xNx thin films deposited by reactive DC magnetron sputtering[J].Journal of Physical Chemistry B,2004,108(52):1797-1803.
[5]冯光建,刘素文,修志亮,等.可见光响应型TiO2光催化剂的机理研究进展[J].稀有金属材料与工程,2009,38(1):185-187.
[6]Lin Zhe-shuai,Orlov A,Lambert R M,et al.New insights into the origin of visible light photocatalytic activity of nitrogen-doped and oxygen-deficient anatase TiO2[J].Journal of Physical Chemistry B,2005,109(44):20948-20952.
[7]Subramanian V,Wolf E E,Kamat P V.Catalysis with TiO2/gold nanocomposites,effect of metal particle size on the Fermi level equilibration[J].Journal of American Chemical Society,2004.126(15):4943-4950.
[8]张强,田雨.TiO2光催化性能影响因素的研究进展[J].应用化工,2011,40(11):2022-2055.
[9]Corstjens Plam,Zuiderwijk M,Nilsson M,et al.Lateral-flow and up-converting to Phosphor reporters detect single-stranded nucleic acid s in a sandwich hybridization assay[J].Analytical Biochemistry,2003,312(2):191-200.
[10]Sandrock T,Scheife H,Heumann E.et al.High power continuous wave up-conversion fiber laser at room temperature[J].Optics Letters,1997,22:808.
[11]Zhao Y X,Simon F,Simon P.22mW blue output power from a Pr3+fluoride fibre up-conversion laser[J].Optics Communications,1995,114:285.
[12]Auzel F.Up conversion and Anti-Stokes Processes with f and d Ions in Solids[J].Chemical Reviews,2004,104(1):139-173.
[13]何捍卫,周科朝,熊翔,等.红外-可见光的上转换研究进展[J].中国稀土学报,2003,2(2):123-128.
[14]杨建虎,戴世勋,姜中宏.稀土离子的上转换发光及研究进展[J].物理学进展,2003,23(3):284-298.
[15]王君,温福宇,张朝红,等.上转换发光剂掺杂纳米TiO2的制备及可见光降解乙基紫的研究[J].环境科学,2006,27(6):1133-1139.
[16]何奇,樊君,胡晓云.NaYF4∶Er3+的水热合成及其紫外上转换发光性能[J].发光学报,2012,33(2):122-127.
[17]Chivian J S,Case W E,Eden D D.The photon avalanche:A new phenomenon in Pr-based infrared quatum counters[J].Appl Phys Lett,1979,35(2):124-126.
[18]Wan Wei,Huan Wenjuan,Ni Yaru,et al.Graphene supported NaYF4:Yb3+,Tm3+and N doped P25nanocomposite as an advanced NIR and sunlight driven up-conversion photocatalyst[J].Applied Surface Science,2013,282:832-837.
[19]王君,赵刚,张朝红,等.稀土上转光剂掺杂纳米TiO2催化可见光降解甲基紫[J].染料与染色,2006,43(6),40-44.
[20]Wang Jun,Weng Fuyu,Zhang Chaohong.et al.Efficient photocatalytic degradation of organic dyes over titanium dioxide coating up-conversion luminescence agent under visible and sunlight irradiation[J].Applied Catalysis A:General,2008,334:227-233.
[21]Wang Jun,Weng Fuyu,Zhang Chaohong.et al.Investigation on degradation of dyestuff wastewater using visible light in the presence of a novel nano TiO2catalyst doped with up-conversion luminescence agent.Journal of Photochemistry and Photobiology A:Chemistry,2006,180(1/2):189-195.
[22]许凤秀,冯光建,刘素文,等.可见光下上转换发光材料掺杂纳米TiO2光催化活性研究[J].硅酸盐通报,2008,27(6):1140-1145.
[23]臧竞存,李晓,谢丽艳.Er3+:Yb3+:Y3Al5O12单晶中Er3+离子光谱参数的计算[J].硅酸盐学报,2006,34(9):1037-1040.
[24]翟宇.Er3+:Y3Al5O12/TiO2复合膜的制备及可见光光催化活性的研究[D].沈阳:辽宁大学,2013:19-34.
[25]王健.Yb,N,F,B和Ga掺杂Er3+:Y3Al5O12对TiO2声催化活性影响的研究[D].沈阳:辽宁大学,2013:22-33.
[26]谢英鹏.Er3+:Y3Al5O12和Er3+:YAlO3对二氧化钛和氧化锌光催化活性影响的研究[D].沈阳:辽宁大学,2009:21-25.
[27]栾晓宇.Er3+:Y3Al5O12对半导体及复合物光催化活性影响的研究[D].沈阳:辽宁大学,2011:21-25.
[28]李堂刚,刘素文,王恩华,等.Y2O3:Yb3+,Tm3+纳米材料的可见及紫外上转换发光[J].物理学报,2011,60(7):073201-1-073206.
[29]高鹏,黄浪欢.TiO2包覆上转化发光材料Pr3+:Y2SiO5的制备及其可见光催化性能的研究[J].功能材料,2013,8(44):1-5.
[30]梁利芳,庄健乐,吴昊,等.水热合成六方相NaYbF4:Er3+/Tm3+的上转换白光性质[J].发光学报,2008,29(6):996-1002.
[31]李岳,翟海青,杨魁胜,等.水热法合成纳米晶NaYF4:Er3+,Tm3+,Yb3+的上转换发光特性[J].发光学报,2009,30(2):239-242.
[32]林君,苏锵.溶胶-凝胶法及其在稀土发光材料合成中的应用[J].1994,15(1):42-46.
[33]Vetrone F,Boyer J C,Capobianco J A,et al.Concentration-dependent near-infrared to visible up-conversion in nanocrystalline and bulk Y2O3:Er3+[J].Chemistry of Materials,2003,15(14):2737-2743.
[34]李玮楠,邹快盛,陆敏,等.掺Er3+硅酸盐玻璃上转换发光特性研究[J].无机材料学报,2007,22(1):30-34.
[35]Aleksandrovsky A S,Gudim L A,Krylov A S,et al.Upconversion luminescence of YA13(BO3)4:(Yb3+,Tm3+)crystals[J].Journal of Alloys and Compounds,2010,496:18-21.
[36]罗军明,李永绣,邓莉萍,等.共沉淀法制备Er3+:Y2O3上转换发光纳米粉[J].稀有金属材料与工程,2007,36(8):1436-1439.
[37]孙家跃,杨志萍,杜海燕.共沉淀法制备NaYF4:Tm3+,Yb3+的上转换发光[J].发光学报,2009,30(2):195-200.
[38]Suyver J F,Grimm J,Kramer K W,et al.Highly efficient near-infrared to visible up-conversion process in NaYF4:Er3+,Yb3+[J].Journal of Luminescence,2005,114(1):53-59.
[39]Liu M,Wang S W,Zhang J,et al.Upconversion luminescence of Y3Al5O12:Yb3+,Tm3+nano-crystals[J].Opt Lett,2007,30(7):370-374.
[40]Liu M,Wang S W,Zhang J,et al.Dominant red emission(4F9/2-4I15/2)via upconversion in YAG(Y3Al5O12):Yb3+,Er3+nanopowders[J].Opt Lett,2007,29(3):1352-1357.
[41]Sun Hongtao,Wen Lei,Duan Zhongchao.Intense frequency upconversion fluorescence emission of Er3+/Yb3+codoped oxychloride gemanate glass[J].Journal of Alloys and Compounds,2006,414(1):142-145.
[42]冯丽,吴银素.Ho3+/Yb3+和Er3+/Yb3+共掺氟氧化物玻璃的上转换发光[J].河北师范大学学报:自然科学版,2011,35(5):483-487.
[43]邓圣伟,徐铁峰,戴世勋,等.Er3+掺杂新型GeS2-In2S3-CsI玻璃上转换光谱性质研究[J].光子学报,2010,39(7):1163-1168.
[44]Shi Dongmei,Yang Gangfeng,Yang Zhongmin,et al.Spectral properties and energy transfer of Tm3+/Ho3+-codoped Ga2O3-Bi2O3-GeO2-PbO glasses[J].Journal of rare earths,2008,26(6):912-914.
[45]Kumar K,Rai S B,Rai D K.Up-conversion and concentration quenching in Er3+-doped TeO2-Na2 O binary glasses[J].NonCryst Solids,2007,353(13/14/15):1383-1387.
[46]郭海.稀土离子掺杂的纳米氧化物上转换发光与稀土氧化物功能薄膜研究[D].合肥:中国科学技术大学,2005.